CN110205827A - A kind of anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial - Google Patents
A kind of anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial Download PDFInfo
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- CN110205827A CN110205827A CN201910519945.7A CN201910519945A CN110205827A CN 110205827 A CN110205827 A CN 110205827A CN 201910519945 A CN201910519945 A CN 201910519945A CN 110205827 A CN110205827 A CN 110205827A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/10—Complex coacervation, i.e. interaction of oppositely charged particles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
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Abstract
The invention discloses the anti-mite taste Korean pine microcapsules mattress production methods that disappears of natural antibacterial, Korean pine microcapsules are prepared using Korean pine essential oil, then Korean pine microcapsule dressing agent is made after being mixed using the microcapsule emulsion prepared with mite-proof agent, low-temperature adhesive and mildewproof additive, and carries out the arrangement of mattress using the Korean pine microcapsule dressing agent.The anti-mite taste Korean pine microcapsules mattress that disappears of natural antibacterial of the present invention is strong with excellent antibacterial and anti-mite effect, good elimination peculiar smell effect, persistence.
Description
Technical field
The present invention relates to a kind of ecological functions textile development, the anti-mite taste Korean pine microcapsules that disappear of specifically a kind of natural antibacterial
Mattress manufacture method.
Background technique
With enriching for people's material life, indoor living environment is had changed a lot, and house airtight performance changes
It is kind, assemble indoor pollution, while improper ventilation increases the growth that indoor humidity is also beneficial to mould and house dust mite, thus
Make dust mite become living environment in most common allergic effect source, and the change of life style and working method then make people 80% when
Between spend indoors.The change of environment promotes dust mite growth, and the extension of people's residence time indoors also increases and dust mite
The disease incidence of the contact of anaphylactogen, the diseases such as dust mite allergy asthma increases therewith, therefore to receive the world each for the prevention and treatment of dust mite
The extensive concern of state researcher.In society now, the long-term of people relies the textile in life in room, including on bed
Articles, home wear, easy dress, underwear series, various clothes are all the raw breeding grounds of dust mite evil.Korean pine is the evergreen of Pinaceae Pinus
Arbor, containing ingredients such as volatile oil, flavonoids, resins in Korean Needle, have the effects that antibacterial, it is antiviral, ease pain.It is existing
Antibiosis anti-acarien involved in technology often by manufacture these products antibiosis anti-acarien face weave during, with addition
Plant chemical agent and anti-microbial type plant auxiliary agent with mite killing or drive mite effect, it is real during using textile
The effect of existing acarid prevention and driving antibacterial.
Chinese patent application (201510680930.0) discloses a kind of preparation of novel tea tree essential oil microcapsules finishing agent
Method and its application, preparation method include preparing tea tree ethereal oil microcapsules, preparing tea tree ethereal oil microcapsule dressing agent, are disclosed
Application of the tea tree ethereal oil microcapsules finishing fluid in the postfinishing process of textile, the invention surface of microcapsule is continuous, cyst wall tool
There is semi permeability, tea tree ethereal oil there can be very strong affinity by cyst wall slow release, and to textile fabric, can firmly adhere to
On textile fabric, thus the effect for making textile fabric have antibacterial lasting.
Chinese patent application (201710663699.3) disclose a kind of Korean pine phytocide finishing agent preparation and its
The fabric and method for sorting of arrangement are prepared micro- wherein preparing microcapsules using Korean pine bacteriocidin and then arranging to cotton fabric
The process selection of capsule is Lauxite route, this process route has a problem that meeting in the product exactly generated
Containing a certain amount of formaldehyde, if after arranging for wearing next to the skin or using inevitably having injury.
Although by above-mentioned background technique it is found that there is the technology that Korean pine antibiotic is used for textile finishing in the prior art,
But the microcapsule dressing agent of program preparation has not environmentally even there is injury, it is therefore desirable to develop another kind more
Add the Korean pine antibacterial finishing agent of Health security system.
Summary of the invention
The purpose of the present invention is to provide a kind of anti-mite taste Korean pine microcapsules mattress manufacture methods that disappears of natural antibacterial, to solve
The problems mentioned above in the background art.
To achieve the above object, the invention provides the following technical scheme: a kind of anti-mite taste Korean pine microcapsules that disappear of natural antibacterial
Mattress manufacture method, includes the following steps,
S1: the preparation of Korean pine microcapsules；
S2: the preparation of Korean pine microcapsule dressing agent；
S3: the arrangement of mattress is carried out using the Korean pine microcapsule dressing agent of S2 preparation.
As a further solution of the present invention: the S1 prepares gelatin-Arabic gum microcapsules using complex coacervation,
Method particularly includes:
S1.1 weighs core material and wall material raw material:
The core material is Korean pine essential oil, and the wall material raw material is gelatin and Arabic gum, gelatin and Arabic gum
Mass ratio is 1:1, and the mass ratio of core material and wall material is 1:0.5~1:2,
The concentration of the Korean pine essential oil is 70%, medicinal extract yield 30%, and extraction time 24 hours, extraction was three times.
S1.2 prepares the wall material of microcapsules,
After wall material raw material weighed in S1.1 and distilled water are mixed, stirring to dissolution, the wall material raw material and distillation
The mass ratio of water is 1:7~1:10；
The wall material and compound emulsifying agent that prepare in the weighed core material of S1.1, S1.2 are mixed S1.3, stirring speed
Degree is 300~800 turns/min, mixing time is 20~50min, and pre-emulsification is carried out under conditions of 30-50 DEG C.
Product after S1.3 pre-emulsification is acidified and is coagulated again by S1.4,
The product of S1.4 is carried out low temperature basification and curing process, obtains microcapsule emulsion by S1.5.
As the present invention further scheme: compound emulsifying agent in the S1.3 by polysorbas20 and Span-80 this
Two kinds of material compositions, the wherein mass ratio of polysorbas20 and Span-80 are as follows: 1:1~1:2.
As further scheme of the invention: in the low temperature basification in the S1.5, treatment temperature is 0~10
DEG C, the processing time is 30~45min.
As further scheme of the invention: in the curing process in the S1.5, using tannic acid solidification or penta
Dialdehyde solidification, specific curing process time are 30~90min.
As the present invention further scheme: the S2 specifically,
Prepare Korean pine microcapsule dressing agent using the microcapsule emulsion that is prepared in S1, the finishing agent at subpackage
It includes: microcapsule emulsion, mite-proof agent, low-temperature adhesive, mildewproof additive,
Microcapsule emulsion, mite-proof agent, low-temperature adhesive and mildewproof additive are mixed, wherein microcapsule emulsion plus
Entering amount is 10~80g/L, and the additional amount of mite-proof agent is 20~40g/L, and the additional amount of low-temperature adhesive is 20~60g/L, mould proof
The additional amount of additive is 10~40g/L.
As further scheme of the invention: the mildewproof additive is Kathon CG.
As further scheme of the invention: S3 is specifically, carry out PE mattress using the finishing agent prepared in S2 whole
Reason, specific steps include:
S3.1 sprays finishing agent on the surface of mattress,
S3.2 dries the mattress after spraying, drying temperature 60~90, and drying time is 15~25min
S3.3 is washed, and is dried under room temperature after washing.
As further scheme of the invention: in the S3.1, it is no less than 3 times in mattress surface spraying finishing agent,
And the whole surface of entire mattress is covered when spraying.
As further scheme of the invention: temperature is room temperature when the S3.3 is washed.
Compared with prior art, the beneficial effects of the present invention are the anti-mite taste Korean pine microcapsules mattress tools that disappears of: natural antibacterial
There are excellent antibiosis anti-acarien effect, good elimination peculiar smell effect, persistence is strong, and raw material is naturally to extract, in microcapsules preparation
The harmful substances such as formaldehyde will not be generated, so completely harmless to people and animals in use.
Detailed description of the invention
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is the application
Some embodiments for those of ordinary skill in the art without creative efforts, can also basis
These attached drawings obtain other attached drawings.
Fig. 1 is microcapsules preparation route schematic diagram；
Fig. 2 is microcapsules microscope photo figure；
Fig. 3 is core wall ratio and embedding rate relation schematic diagram.
Specific embodiment
To keep the purposes, technical schemes and advantages of the embodiment of the present application clearer, below in conjunction with the embodiment of the present application
In attached drawing, the technical scheme in the embodiment of the application is clearly and completely described, it is clear that described embodiment is
Some embodiments of the present application, instead of all the embodiments, the specific feature of these in embodiment, structure or characteristic can appoint
The suitable mode of meaning combines in one or more embodiments.In the following description, such as specific configuration and component are provided
Specific detail just for the sake of help comprehensive understanding embodiments herein.It therefore, it will be apparent to those skilled in the art that can
To make various changes and modifications the embodiments described herein without departing from the scope and spirit of the present application.In addition, in order to clear
Except with it is succinct, the description to known function and construction is omitted in embodiment.
Embodiment 1
The anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial, includes the following steps:
S1: the preparation of Korean pine microcapsules；Gelatin-Arabic gum microcapsules are prepared using complex coacervation, method particularly includes:
S1.1 weighs core material and wall material raw material:
The core material is Korean pine essential oil, and the wall material raw material is gelatin and Arabic gum, gelatin and Arabic gum
Mass ratio is 1:1, and the mass ratio of core material and wall material is 1:0.67,
The concentration of the Korean pine essential oil is 70%, medicinal extract yield 30%, and extraction time 24 hours, extraction was three times.
S1.2 prepares the wall material of microcapsules,
After wall material raw material weighed in S1.1 and distilled water are mixed, stirring to dissolution, the wall material raw material and distillation
The mass ratio of water is 1:9；
The wall material and compound emulsifying agent that prepare in the weighed core material of S1.1, S1.2 are mixed S1.3, stirring speed
Degree is 650 turns/min, mixing time 38min carries out pre-emulsification under conditions of 42 DEG C.The compound emulsifying agent is by spitting
Both material compositions of 20 and Span-80 of temperature, the wherein mass ratio of polysorbas20 and Span-80 are as follows: 1:1.8.
Product after S1.3 pre-emulsification is acidified and is coagulated again by S1.4,
The product of S1.4 is carried out low temperature basification and curing process by S1.5, and temperature is 7 DEG C when low temperature basification,
The processing time is 41min.In curing process, it is using tannic acid solidification or glutaraldehyde solidification, specific curing process time
35min obtains microcapsule emulsion.
S2: the preparation of Korean pine microcapsule dressing agent；The S2 is specifically, utilize the microcapsule emulsion system being prepared in S1
Standby Korean pine microcapsule dressing agent, the ingredient of the finishing agent includes: microcapsule emulsion, mite-proof agent, low-temperature adhesive, mould proof addition
Agent.
Microcapsule emulsion, mite-proof agent, low-temperature adhesive and mildewproof additive are mixed, wherein microcapsule emulsion plus
Entering amount is 40g/L, and the additional amount of mite-proof agent is 30g/L, and the additional amount of low-temperature adhesive is 25g/L, the addition of mildewproof additive
Amount is 15g/L, and the mildewproof additive is Kathon CG.
S3: using S2 preparation Korean pine microcapsule dressing agent carry out mattress arrangement, S3 specifically,
PE mattress is arranged using the finishing agent prepared in S2, specific steps include:
S3.1 sprays finishing agent on the surface of mattress, covers when being no less than 3 times, and spraying in mattress surface spraying finishing agent
Cover the whole surface of entire mattress.
S3.2 dries the mattress after spraying, and 80 DEG C of drying temperature, drying time 20min
S3.3 is washed, and temperature is room temperature when washing, is dried under room temperature after washing.
Embodiment 2
The anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial, includes the following steps:
S1: the preparation of Korean pine microcapsules；Gelatin-Arabic gum microcapsules are prepared using complex coacervation, method particularly includes:
S1.1 weighs core material and wall material raw material:
The core material is Korean pine essential oil, and the wall material raw material is gelatin and Arabic gum, gelatin and Arabic gum
Mass ratio is 1:1, and the mass ratio of core material and wall material is 1:1,
The concentration of the Korean pine essential oil is 70%, medicinal extract yield 30%, and extraction time 24 hours, extraction was three times.
S1.2 prepares the wall material of microcapsules,
After wall material raw material weighed in S1.1 and distilled water are mixed, stirring to dissolution, the wall material raw material and distillation
The mass ratio of water is 1:8.5；
The wall material and compound emulsifying agent that prepare in the weighed core material of S1.1, S1.2 are mixed S1.3, stirring speed
Degree is 750 turns/min, mixing time is 20~50min, and pre-emulsification is carried out under conditions of 30-50 DEG C.The composite emulsifying
Agent is by polysorbas20 and Span-80 both material compositions, the wherein mass ratio of polysorbas20 and Span-80 are as follows: 1:1.2.
Product after S1.3 pre-emulsification is acidified and is coagulated again by S1.4,
The product of S1.4 is carried out low temperature basification and curing process by S1.5, and temperature is 7 DEG C when low temperature basification,
The processing time is 38min.In curing process, it is using tannic acid solidification or glutaraldehyde solidification, specific curing process time
70min obtains microcapsule emulsion.
S2: the preparation of Korean pine microcapsule dressing agent；The S2 is specifically, utilize the microcapsule emulsion system being prepared in S1
Standby Korean pine microcapsule dressing agent, the ingredient of the finishing agent includes: microcapsule emulsion, mite-proof agent, low-temperature adhesive, mould proof addition
Agent.
Microcapsule emulsion, mite-proof agent, low-temperature adhesive and mildewproof additive are mixed, wherein microcapsule emulsion plus
Entering amount is 20g/L, and the additional amount of mite-proof agent is 32g/L, and the additional amount of low-temperature adhesive is 48g/L, the addition of mildewproof additive
Amount is 33g/L, and the mildewproof additive is Kathon CG.
S3: using S2 preparation Korean pine microcapsule dressing agent carry out mattress arrangement, S3 specifically,
PE mattress is arranged using the finishing agent prepared in S2, specific steps include:
S3.1 sprays finishing agent on the surface of mattress, covers when being no less than 3 times, and spraying in mattress surface spraying finishing agent
Cover the whole surface of entire mattress.
S3.2 dries the mattress after spraying, and 75 DEG C of drying temperature, drying time 23min
S3.3 is washed, and temperature is room temperature when washing, is dried under room temperature after washing.
Embodiment 3
The anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial, includes the following steps:
S1: the preparation of Korean pine microcapsules；Gelatin-Arabic gum microcapsules are prepared using complex coacervation, method particularly includes:
S1.1 weighs core material and wall material raw material:
The core material is Korean pine essential oil, and the wall material raw material is gelatin and Arabic gum, gelatin and Arabic gum
Mass ratio is 1:1, and the mass ratio of core material and wall material is 1:1.5,
The concentration of the Korean pine essential oil is 70%, medicinal extract yield 30%, and extraction time 24 hours, extraction was three times.
S1.2 prepares the wall material of microcapsules,
After wall material raw material weighed in S1.1 and distilled water are mixed, stirring to dissolution, the wall material raw material and distillation
The mass ratio of water is 1:8；
The wall material and compound emulsifying agent that prepare in the weighed core material of S1.1, S1.2 are mixed S1.3, stirring speed
Degree is 600 turns/min, mixing time 40min carries out pre-emulsification under conditions of 40 DEG C.The compound emulsifying agent is by spitting
Both material compositions of 20 and Span-80 of temperature, the wherein mass ratio of polysorbas20 and Span-80 are as follows: 1:1.5.
Product after S1.3 pre-emulsification is acidified and is coagulated again by S1.4,
The product of S1.4 is carried out low temperature basification and curing process by S1.5, and temperature is 5 DEG C when low temperature basification,
The processing time is 35min.In curing process, it is using tannic acid solidification or glutaraldehyde solidification, specific curing process time
80min obtains microcapsule emulsion.
S2: the preparation of Korean pine microcapsule dressing agent；The S2 is specifically, utilize the microcapsule emulsion system being prepared in S1
Standby Korean pine microcapsule dressing agent, the ingredient of the finishing agent includes: microcapsule emulsion, mite-proof agent, low-temperature adhesive, mould proof addition
Agent.
Microcapsule emulsion, mite-proof agent, low-temperature adhesive and mildewproof additive are mixed, wherein microcapsule emulsion plus
Entering amount is 30g/L, and the additional amount of mite-proof agent is 25g/L, and the additional amount of low-temperature adhesive is 40g/L, the addition of mildewproof additive
Amount is 30g/L, and the mildewproof additive is Kathon CG.
S3: using S2 preparation Korean pine microcapsule dressing agent carry out mattress arrangement, S3 specifically,
PE mattress is arranged using the finishing agent prepared in S2, specific steps include:
S3.1 sprays finishing agent on the surface of mattress, covers when being no less than 3 times, and spraying in mattress surface spraying finishing agent
Cover the whole surface of entire mattress.
S3.2 dries the mattress after spraying, drying temperature 75, drying time 22min
S3.3 is washed, and temperature is room temperature when washing, is dried under room temperature after washing.
Embodiment 4
The anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial, includes the following steps:
S1: the preparation of Korean pine microcapsules；Gelatin-Arabic gum microcapsules are prepared using complex coacervation, method particularly includes:
S1.1 weighs core material and wall material raw material:
The core material is Korean pine essential oil, and the wall material raw material is gelatin and Arabic gum, gelatin and Arabic gum
Mass ratio is 1:1, and the mass ratio of core material and wall material is 1:2,
The concentration of the Korean pine essential oil is 70%, medicinal extract yield 30%, and extraction time 24 hours, extraction was three times.
S1.2 prepares the wall material of microcapsules,
After wall material raw material weighed in S1.1 and distilled water are mixed, stirring to dissolution, the wall material raw material and distillation
The mass ratio of water is 1:10；
The wall material and compound emulsifying agent that prepare in the weighed core material of S1.1, S1.2 are mixed S1.3, stirring speed
Degree is 800 turns/min, mixing time 50min carries out pre-emulsification under conditions of 50 DEG C.The compound emulsifying agent is by spitting
Both material compositions of 20 and Span-80 of temperature, the wherein mass ratio of polysorbas20 and Span-80 are as follows: 1:2.
Product after S1.3 pre-emulsification is acidified and is coagulated again by S1.4,
The product of S1.4 is carried out low temperature basification and curing process by S1.5, and temperature is 10 DEG C when low temperature basification,
The processing time is 45min.In curing process, it is using tannic acid solidification or glutaraldehyde solidification, specific curing process time
90min obtains microcapsule emulsion.
S2: the preparation of Korean pine microcapsule dressing agent；The S2 is specifically, utilize the microcapsule emulsion system being prepared in S1
Standby Korean pine microcapsule dressing agent, the ingredient of the finishing agent includes: microcapsule emulsion, mite-proof agent, low-temperature adhesive, mould proof addition
Agent.
Microcapsule emulsion, mite-proof agent, low-temperature adhesive and mildewproof additive are mixed, wherein microcapsule emulsion plus
Entering amount is 80g/L, and the additional amount of mite-proof agent is 40g/L, and the additional amount of low-temperature adhesive is 60g/L, the addition of mildewproof additive
Amount is 40g/L, and the mildewproof additive is Kathon CG.
S3: using S2 preparation Korean pine microcapsule dressing agent carry out mattress arrangement, S3 specifically,
PE mattress is arranged using the finishing agent prepared in S2, specific steps include:
S3.1 sprays finishing agent on the surface of mattress, covers when being no less than 3 times, and spraying in mattress surface spraying finishing agent
Cover the whole surface of entire mattress.
S3.2 dries the mattress after spraying, drying temperature 90, drying time 25min
S3.3 is washed, and temperature is room temperature when washing, is dried under room temperature after washing.
Embodiment 5
The anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial, includes the following steps:
S1: the preparation of Korean pine microcapsules；Gelatin-Arabic gum microcapsules are prepared using complex coacervation, method particularly includes:
S1.1 weighs core material and wall material raw material:
The core material is Korean pine essential oil, and the wall material raw material is gelatin and Arabic gum, gelatin and Arabic gum
Mass ratio is 1:1, and the mass ratio of core material and wall material is 1:0.5,
The concentration of the Korean pine essential oil is 70%, medicinal extract yield 30%, and extraction time 24 hours, extraction was three times.
S1.2 prepares the wall material of microcapsules,
After wall material raw material weighed in S1.1 and distilled water are mixed, stirring to dissolution, the wall material raw material and distillation
The mass ratio of water is 1:7；
The wall material and compound emulsifying agent that prepare in the weighed core material of S1.1, S1.2 are mixed S1.3, stirring speed
Degree is 300 turns/min, mixing time 20min carries out pre-emulsification under conditions of 30 DEG C.The compound emulsifying agent is by spitting
Both material compositions of 20 and Span-80 of temperature, the wherein mass ratio of polysorbas20 and Span-80 are as follows: 1:1.
Product after S1.3 pre-emulsification is acidified and is coagulated again by S1.4,
The product of S1.4 is carried out low temperature basification and curing process by S1.5, and temperature is 0 DEG C when low temperature basification,
The processing time is 30min.In curing process, it is using tannic acid solidification or glutaraldehyde solidification, specific curing process time
30min obtains microcapsule emulsion.
S2: the preparation of Korean pine microcapsule dressing agent；The S2 is specifically, utilize the microcapsule emulsion system being prepared in S1
Standby Korean pine microcapsule dressing agent, the ingredient of the finishing agent includes: microcapsule emulsion, mite-proof agent, low-temperature adhesive, mould proof addition
Agent.
Microcapsule emulsion, mite-proof agent, low-temperature adhesive and mildewproof additive are mixed, wherein microcapsule emulsion plus
Entering amount is 10g/L, and the additional amount of mite-proof agent is 20g/L, and the additional amount of low-temperature adhesive is 20g/L, the addition of mildewproof additive
Amount is 10g/L, and the mildewproof additive is Kathon CG.
S3: using S2 preparation Korean pine microcapsule dressing agent carry out mattress arrangement, S3 specifically,
PE mattress is arranged using the finishing agent prepared in S2, specific steps include:
S3.1 sprays finishing agent on the surface of mattress, covers when being no less than 3 times, and spraying in mattress surface spraying finishing agent
Cover the whole surface of entire mattress.
S3.2 dries the mattress after spraying, drying temperature 60, drying time 15min
S3.3 is washed, and temperature is room temperature when washing, is dried under room temperature after washing.
In method of the invention, Korean pine microcapsules are prepared using complex coacervation and prepare the micro- glue of gelatin-Arabic gum
Capsule, because this method prepares microcapsules, its Durability of antimicrobial effect is longer, and washing fastness is good, and compared to the micro- glue of Lauxite
Capsule is free of any formaldehyde, more environmentally-friendly, to human body without any murder by poisoning.
The specific method for preparing gelatin-Arabic gum microcapsules using complex coacervation is as shown in Figure 1.
Wherein, the core wall ratio used in the method for the present invention is 1:0.5~1:2, in such core wall than in range, such as Fig. 2
Shown in 3, the embedding rate of microcapsules has all reached very high level, wherein when core wall ratio is 1:1, embedding rate highest.
To the anti-mite taste Korean pine microcapsules mattress that disappears of natural antibacterial being obtained by the present invention is adopted, following several surveys are carried out
Examination, to confirm its effect,
1. the test of antibacterial effect: antibiotic property experimental evidence textile industry standard FZ/T01021-92 " antibacterial fabric performance
Test method " it is tested；Its purpose is that the anti-microbial property of verifying mattress.
Antibacterial is prepared according to optimal finishing process to disappear taste PE bedding product, carries out mattress anti-microbial property test.Antibiotic property
Experimental evidence textile industry standard FZ/T01021-92 " antibacterial fabric method for testing performance " is tested, the experiment of mattress antibiotic property
It the results are shown in Table 2.
Influence of the 1 Korean pine antibacterial microcapsule dosage of table to Korean pine microcapsules mattress anti-microbial property
As it can be seen from table 1 even if the dosage of Korean pine microcapsules only has 10g/L, bacteriostasis rate be also be more than 60%, thus
Illustrate, what the fungistatic effect that Korean pine microcapsules arrange was clearly present.Moreover, with the increase of Korean pine essential oil microcapsules dosage,
The bacteriostasis rate of mattress is also gradually increasing after arrangement, when microcapsules dosage is 30g/L, just to the bacteriostasis rates of Escherichia coli
Reached 93.25%, and from the data in table, it can be seen that and dosage compares when being 10g/L, although only mentioning
The high dosage of 20g, but its bacteriostasis rate but increases 30%, from this it can be concluded that being 30g/L's in microcapsules dosage
When, fungistatic effect is obviously improved；With being further added by for microcapsules dosage, the promotion of fungistatic effect is more slowly constant.
94.37% is reached when microcapsules dosage is 30g/L to the bacteriostasis rate of staphylococcus aureus, the case where this dosage
Under, the promotion of fungistatic effect is fairly obvious, and, it is antibacterial with the increase of dosage when microcapsules dosage is greater than 30g/L
Rate increase is slower.Mattress can be made to reach good antibacterial effect in 30g/L from above description microcapsules dosage, when micro- glue
Capsule dosage continues growing,
2. eliminating the test of peculiar smell: eliminating the peculiar smell experimental evidence GB T 33610.2-2017 " survey of textile deodorization
Determine part 2 detection tube method " it is tested；Its purpose is to verify the taste effect that disappears of mattress.
By sample (specification 100cm2) be put into sampler bag, it is then injected into the 3L of gas containing smell component, reaches regulation
Initial concentration, measure constituent concentration using detection pipe after 2h.Fabric eliminates peculiar smell experimental result and is shown in Table 3.
Eliminate the influence of peculiar smell performance after 2 Korean pine antibacterial microcapsule of table after mattress washing to mattress
Korean pine microcapsules mattress prepared by the present invention, eliminate peculiar smell performance it is sufficiently stable, can't because of washing and
Loss, from Table 2, it can be seen that before washing and after washing 10 times, it can be seen that not bright for the elimination factor of gas with foreign flavor
Aobvious reduction illustrates after arranging using microcapsules to mattress in the present invention that, even across certain washing, microcapsules are to different
The absorption of taste is eliminated ability and is not also lost significantly, illustrates that its washing fastness is fine.
3. anti-mite performance test: anti-mite performance test according to GB/T24253-2009 " evaluation of the anti-mite performance of textile " into
Row test, its purpose is to verify the anti-mite effect of mattress.
Sample and control sample are individually placed in culture dish, contacted simultaneously with acarid under the defined conditions.By certain
The mite population survived in sample culture dish and in control sample culture dish is counted after time culture, according to used examination
Quadrat method calculates acarid and walks quickly and keeps away rate.Through test it is found that the acarid of Korean pine microcapsules mattress of the invention walks quickly and keeps away rate greater than 80%, have
There is stronger anti-mite effect.
It is above-described, it is merely preferred embodiments of the present invention, but protection scope of the present invention is not limited to
This, anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention
And its inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial, which is characterized in that include the following steps,
S1: the preparation of Korean pine microcapsules；
S2: the preparation of Korean pine microcapsule dressing agent；
S3: the arrangement of mattress is carried out using the Korean pine microcapsule dressing agent of S2 preparation.
2. a kind of anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 1, feature exist
In, the S1 prepares gelatin-Arabic gum microcapsules using complex coacervation, method particularly includes:
S1.1 weighs core material and wall material raw material:
The core material is Korean pine essential oil, and the wall material raw material is gelatin and Arabic gum, the quality of gelatin and Arabic gum
Than for 1:1, the mass ratio of core material and wall material is 1:0.5~1:2,
The concentration of the Korean pine essential oil is 70%, medicinal extract yield 30%, and extraction time 24 hours, extraction was three times.
S1.2 prepares the wall material of microcapsules,
After wall material raw material weighed in S1.1 and distilled water are mixed, stirring to dissolving, the wall material raw material and distilled water
Mass ratio is 1:7~1:10；
The wall material and compound emulsifying agent that prepare in the weighed core material of S1.1, S1.2 are mixed S1.3, and mixing speed is
300~800 turns/min, mixing time is 20~50min, pre-emulsification is carried out under conditions of 30-50 DEG C,
Product after S1.3 pre-emulsification is acidified and is coagulated again by S1.4,
The product of S1.4 is carried out low temperature basification and curing process, obtains microcapsule emulsion by S1.5.
3. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 2, which is characterized in that
Compound emulsifying agent in the S1.3 is by polysorbas20 and Span-80 both material compositions, wherein polysorbas20 and Span-
80 mass ratio are as follows: 1:1~1:2.
4. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 2, which is characterized in that
In low temperature basification in the S1.5, treatment temperature is 0~10 DEG C, and the processing time is 30~45min.
5. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 2, which is characterized in that institute
In the curing process in S1.5 stated, using tannic acid solidification or glutaraldehyde solidify, the specific curing process time be 30~
90min。
6. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 1, which is characterized in that institute
State S2 specifically,
Korean pine microcapsule dressing agent is prepared using the microcapsule emulsion being prepared in S1, the ingredient of the finishing agent includes: micro-
Capsule lotion, mite-proof agent, low-temperature adhesive, mildewproof additive,
Microcapsule emulsion, mite-proof agent, low-temperature adhesive and mildewproof additive are mixed, wherein the additional amount of microcapsule emulsion
For 10~80g/L, the additional amount of mite-proof agent is 20~40g/L, and the additional amount of low-temperature adhesive is 20~60g/L, mould proof addition
The additional amount of agent is 10~40g/L.
7. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 6, which is characterized in that institute
The mildewproof additive stated is Kathon CG.
8. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 1, which is characterized in that S3
Specifically, being arranged using the finishing agent prepared in S2 to PE mattress, specific steps include:
S3.1 sprays finishing agent on the surface of mattress,
S3.2 dries the mattress after spraying, drying temperature 60~90, and drying time is 15~25min
S3.3 is washed, and is dried under room temperature after washing.
9. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 7, which is characterized in that institute
In the S3.1 stated, the whole surface of entire mattress is covered when being no less than 3 times, and spraying in mattress surface spraying finishing agent.
10. the anti-mite taste Korean pine microcapsules mattress manufacture method that disappears of natural antibacterial according to claim 6, which is characterized in that
Temperature is room temperature when the S3.3 is washed.
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