CN110193454A - A kind of preparation method of enhanced wax-based ribbon - Google Patents
A kind of preparation method of enhanced wax-based ribbon Download PDFInfo
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- CN110193454A CN110193454A CN201910341447.8A CN201910341447A CN110193454A CN 110193454 A CN110193454 A CN 110193454A CN 201910341447 A CN201910341447 A CN 201910341447A CN 110193454 A CN110193454 A CN 110193454A
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- weight percent
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- substrate
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/58—No clear coat specified
- B05D7/584—No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
- B41J31/02—Ink ribbons characterised by the material from which they are woven
- B41J31/04—Ink ribbons characterised by the material from which they are woven woven from synthetic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2507/00—Polyolefins
- B05D2507/02—Polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2508/00—Polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2518/00—Other type of polymers
- B05D2518/10—Silicon-containing polymers
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention discloses a kind of preparation methods of enhanced wax-based ribbon, include the following steps, 3-3.5% components by weight percent organic siliconresin is added into the solvent of 96.5-97% components by weight percent, heating stirring dissolution；Substrate is immersed in solution and is disseminated；Substrate is taken out into solidification drying, forms substrate back coating；The polyester resin of 2-3% components by weight percent is added into the solvent of 97-98% components by weight percent, heating stirring dissolution；Resulting solution is smeared into substrate surface, and heating, drying, forms release coating；The resin of 6% components by weight percent, the pigment of the wax class of 27% components by weight percent and 9-10% components by weight percent are added into the solvent of 50-65% components by weight percent, heating stirring dissolution；It is applied to acquired solution on the release coating of substrate, and heating, drying, forms ink coating, completes preparation.The present invention is matched by the reasonable component to resin and wax class, eliminates the use of dispersing agent, wax-based ribbon using when also reached identical technical effect, saved ink coating preparation when manufacturing cost.
Description
Technical field
The present invention relates to printed material technical field, in particular to a kind of preparation method of enhanced wax-based ribbon.
Background technique
Open CN201210085688.9 discloses a kind of thermal transfer wax-based ribbon, above back coating, substrate and substrate
Release coating, the ink coating above release coating constitute, the ink coating is grouped by following groups by weight percentage
At: resin 1-10.3%, wax class 29-34%, pigment 9-10%, dispersing agent 0.7-0.8% and solvent 51-55%；Publication number
CN201310490780.8 discloses a kind of thermal transfer wax-based ribbon, including the heat resistant oils layer of ink being coated in base band and thermal transfer
Ink layer, the transferred ink layer are made of the raw material components of following parts by weight: 3-5 parts of epoxy resin, 2-8 parts of polyvinyl chloride,
1-3 parts of Petropols, 5-10 parts of polystyrene, 10-20 parts of pigment, 40-50 parts of synthetic wax, 1-2 parts of Dispersant MF, carbon black 20-
30 parts；As can be seen that the ink coating of wax-based ribbon is when preparation from two files, require that dispersing agent is added, point
Powder is the indispensable material composi of ink coating.Preparation test is being carried out to patent No. CN201210085688.9
When, it chances on, is adjusting to resin and wax class special component percentage, and use special preparation method, it can be with
The identical technical effect of ink coating can be also obtained without using dispersing agent.
Summary of the invention
The technical problem to be solved by the present invention is provide a kind of preparation method of enhanced wax-based ribbon, do not using point
In the case where powder, the ink coating of wax-based ribbon can also obtain identical technical effect, save the preparation cost.
To achieve the above object, The technical solution adopted by the invention is as follows:
A kind of preparation method of enhanced wax-based ribbon, comprising the following steps:
S1: the organic siliconresin of 3-3.5% components by weight percent is added into the solvent of 96.5-97% components by weight percent, heating
Stirring and dissolving；
S2: substrate is immersed in solution obtained by step S1；
S3: substrate is taken out from solution, and is toasted at a high temperature of 200~250 DEG C, and the organosilicon on substrate is made
Solidification drying, forms substrate back coating；
S4: the polyester resin of 2-3% components by weight percent is added into the solvent of 97-98% components by weight percent, heating stirring is molten
Solution；
S5: by solution obtained in step S4, substrate surface obtained in step S3, and heating, drying, shape are applied to
At release coating, 0.05-0.06 μm of release coating layer thickness；
S6: by the resin of 5-7% components by weight percent, the pigment of the wax class of 26-30% components by weight percent and 9-10% components by weight percent,
It is added into the solvent of 56-60% components by weight percent, heating stirring dissolution；
S7: solution obtained by step S6 is smeared on the release coating of substrate in step s 5, and heating, drying, shape
At ink coating, preparation is completed.
Preferably, the substrate is polyester material, with a thickness of 4.2-4.5 μm.
Preferably, the organic siliconresin in the step S1 is methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorine
Silane, diphenyl dichlorosilane or dichloromethyl phenylsilane two of them or two or more composed mixtures.
Preferably, the weight resin percentage composition in the step S6 is respectively as follows: vinylite 0-5%, Petropols
1-4%, acrylic resin or polyester resin 0-1.3%.
Preferably, the wax class weight percent composition in the step S6 is as follows: palm wax 13-19%, full refining wax 11-
15%.
Preferably, the ink coating is with a thickness of 2.2-2.8 μm, if coating layer thickness is unsatisfactory for requiring, repeatedly step S7
Until meeting ink coating thickness requirement.
It is further preferred that the ink coating weight percent composition is as follows: vinylite 3%, Petropols
2%, acrylic resin 1%, palm wax 16%, full refining wax 11%, pigment 9.4%, solvent 57.6%.
Compared with prior art, the invention has the following advantages:
The present invention is combined by the reasonable component to resin and wax class, is eliminated in preparation wax-based ribbon ink coating
When dispersing agent use, wax-based ribbon using when also reached identical technical effect, saved ink coating preparation
When manufacturing cost, reduce coating preparation material component, have very strong creation novelty.
Specific embodiment
Below with reference to embodiment, the invention will be further described, and mode of the invention includes but are not limited to following implementation
Example.
A kind of preparation method of enhanced wax-based ribbon, comprising the following steps:
S1: the organic siliconresin of 3-3.5% components by weight percent is added into the solvent of 96.5-97% components by weight percent, heating
Stirring and dissolving；Organic siliconresin is methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane
Dichloromethyl phenylsilane two of them or it is two or more composed by mixture.
S2: substrate is immersed in solution obtained by step S1；The substrate is polyester material, with a thickness of 4.2-4.5 μm.
S3: substrate is taken out from solution, and is toasted at a high temperature of 200~250 DEG C, and the organosilicon on substrate is made
Solidification drying, forms substrate back coating；
S4: the polyester resin of 2-3% components by weight percent is added into the solvent of 97-98% components by weight percent, heating stirring is molten
Solution；
S5: by solution obtained in step S4, substrate surface obtained in step S3, and heating, drying, shape are applied to
At release coating, 0.05-0.06 μm of release coating layer thickness；
S6: by the resin of 5-7% components by weight percent, the pigment of the wax class of 26-30% components by weight percent and 9-10% components by weight percent,
It is added into the solvent of 56-60% components by weight percent, heating stirring dissolution；Weight resin percentage composition is respectively as follows: vinylite
0-5%, Petropols 1-4%, acrylic resin or polyester resin 0-1.3%；Wax class weight percent composition is as follows: palm wax
13-19%, full refining wax 11-15%；Preferably, ink coating weight percent composition is as follows: vinylite 3%, petroleum
Resin 2%, acrylic resin 1%, palm wax 16%, full refining wax 11%, pigment 9.4%, solvent 57.6%.
S7: solution obtained by step S6 is smeared on the release coating of substrate in step s 5, and heating, drying, shape
At ink coating, preparation is completed；Ink coating is with a thickness of 2.2-2.8 μm, if coating layer thickness is unsatisfactory for requiring, repetitive operation is straight
To meeting ink coating thickness requirement.
Embodiment 1
Substrate selects 4.5 μm of polyester material；
The weight percent composition of release coating are as follows: polyester resin 2%, toluene solvant 98%；
The weight percent composition of ink coating are as follows: vinylite 3%, Petropols 2%, acrylic resin 1%, palm fibre
Palmitic acid wax 16%, full refining wax 11%, pigment 9.4%, toluene solvant 57.6%.
Embodiment 2
Substrate selects 4.5 μm of polyester material；
The weight percent composition of release coating are as follows: 2% polyester resin, 98% toluene solvant；
The weight percent composition of ink coating are as follows: vinylite 3%, Petropols 2%, acrylic resin 1%, palm fibre
Palmitic acid wax 16%, full refining wax 11%, pigment 9.5%, toluene solvant 57.5%.
Embodiment 3
Substrate selects 4.5 μm of polyester material；
The weight percent composition of release coating are as follows: 2% polyester resin, 98% toluene solvant；
The weight percent composition of ink coating are as follows: vinylite 3%, Petropols 2%, acrylic resin 1%, palm fibre
Palmitic acid wax 16%, full refining wax 11%, pigment 9.6%, toluene solvant 57.4%.
Embodiment 4
Substrate selects 4.5 μm of polyester material；
The weight percent composition of release coating are as follows: 2% polyester resin, 98% toluene solvant；
The weight percent composition of ink coating are as follows: vinylite 2.5%, Petropols 2.5%, acrylic resin
1%, palm wax 16%, full refining wax 11%, pigment 9.4%, toluene solvant 57.6%.
Embodiment 5
Substrate selects 4.5 μm of polyester material；
The weight percent composition of release coating are as follows: 2% polyester resin, 98% toluene solvant；
The weight percent composition of ink coating are as follows: vinylite 3%, Petropols 2.5%, acrylic resin
0.5%, palm wax 16%, full refining wax 11%, pigment 9.4%, toluene solvant 57.6%.
Embodiment 6
Substrate selects 4.5 μm of polyester material；
The weight percent composition of release coating are as follows: 2% polyester resin, 98% toluene solvant；
The weight percent composition of ink coating are as follows: vinylite 2.5%, Petropols 3%, acrylic resin
0.5%, palm wax 16%, full refining wax 11%, pigment 9.4%, toluene solvant 57.6%.
Embodiment 7
Substrate selects 4.5 μm of polyester material；
The weight percent composition of release coating are as follows: 2% polyester resin, 98% toluene solvant；
The weight percent composition of ink coating are as follows: vinylite 2%, Petropols 1%, acrylic resin 3%, palm fibre
Palmitic acid wax 16%, full refining wax 11%, pigment 9.4%, toluene solvant 57.6%.
The compatibility test of adhesive force and printing carrier, attachment are carried out to the resulting wax-based ribbon of above-described embodiment 1~7
Power uses the bistrique of loading 800g, rubs 50 times to printing paper, and observation has transferred the damaged area of ink layer.
The adaptability of printing carrier does printing test with different type printing paper, observes the ratio of the clear writing on printing paper
Example.
Obtain following data:
By data as can be seen that using enhanced wax-based ribbon obtained by the method, when carrying out printing
The percent articulation of the adhesive force and ink printing that have been able to maintain, the applicable effect by the resulting enhanced wax-based ribbon of this method are non-
Coated paper > heat-transferring printing paper > coated paper.
Above-described embodiment is only one of the preferred embodiment of the present invention, should not be taken to limit protection model of the invention
It encloses, as long as that in body design thought of the invention and mentally makes has no the change of essential meaning or polishing, is solved
The technical issues of it is still consistent with the present invention, should all be included within protection scope of the present invention.
Claims (7)
1. a kind of preparation method of enhanced wax-based ribbon, which comprises the following steps:
S1: by the organic siliconresin of 3-3.5% components by weight percent, the heating stirring into the solvent of 96.5-97% components by weight percent is added
Dissolution；
S2: substrate is immersed in solution obtained by step S1；
S3: substrate is taken out from solution, and is toasted at a high temperature of 200~250 DEG C, and the organosilicon on substrate is solidified
Drying forms the substrate for having back coating；
S4: the polyester resin of 2-3% components by weight percent is added into the solvent of 97-98% components by weight percent, heating stirring dissolution；
S5: by solution obtained in step S4, being applied to substrate surface obtained in step S3, and heating, drying, formed from
Type coating, 0.05-0.06 μm of release coating layer thickness；
S6: the resin of 5~7% components by weight percent, the pigment of the wax class of 26~30% components by weight percent and 9-10% components by weight percent add
Enter into the solvent of 56-60% components by weight percent, heating stirring dissolution；
S7: solution obtained by step S6 is smeared on the release coating of substrate in step s 5, and heating, drying, forms oil
Black coating completes preparation.
2. a kind of preparation method of enhanced wax-based ribbon according to claim 1, which is characterized in that the substrate is poly-
Ester material, with a thickness of 4.2-4.5 μm.
3. a kind of preparation method of enhanced wax-based ribbon according to claim 2, which is characterized in that in the step S1
Organic siliconresin are as follows: methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane or methyl
Diphenyl dichlorosilane two of them or two or more composed mixtures.
4. a kind of preparation method of enhanced wax-based ribbon according to claim 3, which is characterized in that in the step S6
Weight resin percentage composition be respectively as follows: vinylite 0-5%, Petropols 1-4%, acrylic resin or polyester resin 0-
1.3%.
5. a kind of preparation method of enhanced wax-based ribbon according to claim 4, which is characterized in that in the step S6
Wax class weight percent composition are as follows: palm wax 13-19%, full refining wax 11-15%.
6. a kind of preparation method of enhanced wax-based ribbon according to claim 5, which is characterized in that the ink coating
With a thickness of 2.2-2.8 μm, if coating layer thickness is unsatisfactory for requiring, repeatedly step S7 is until meet ink coating thickness requirement.
7. the preparation method of described in any item a kind of enhanced wax-based ribbons according to claim 1~6, which is characterized in that institute
State ink coating weight percent composition are as follows: vinylite 3%, Petropols 2%, acrylic resin 1%, palm wax
16%, full refining wax 11%, pigment 9.4%, solvent 57.6%.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910341447.8A CN110193454A (en) | 2019-04-26 | 2019-04-26 | A kind of preparation method of enhanced wax-based ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201910341447.8A CN110193454A (en) | 2019-04-26 | 2019-04-26 | A kind of preparation method of enhanced wax-based ribbon |
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| CN110193454A true CN110193454A (en) | 2019-09-03 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1471785A (en) * | 1974-04-25 | 1977-04-27 | Expanded Metal | Coated metal mesh lath |
| CN101033351A (en) * | 2007-04-06 | 2007-09-12 | 北京太禾尚鑫科技发展有限公司 | High speed coating carbon belt printing ink material and producing method thereof |
| CN102616024A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Heat-transfer wax-based carbon ribbon |
| CN102653189A (en) * | 2012-04-16 | 2012-09-05 | 焦作市卓立烫印材料有限公司 | Thermal transfer ribbon for edge-pressing printer and preparation method thereof |
| CN105058999A (en) * | 2015-08-12 | 2015-11-18 | 河南卓立膜材料股份有限公司 | Thermal transfer ribbon with night luminous function and preparation method thereof |
| CN106515235A (en) * | 2016-11-11 | 2017-03-22 | 冯晋 | Thermal sublimation transfer printing ink ribbon |
-
2019
- 2019-04-26 CN CN201910341447.8A patent/CN110193454A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1471785A (en) * | 1974-04-25 | 1977-04-27 | Expanded Metal | Coated metal mesh lath |
| CN101033351A (en) * | 2007-04-06 | 2007-09-12 | 北京太禾尚鑫科技发展有限公司 | High speed coating carbon belt printing ink material and producing method thereof |
| CN102616024A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Heat-transfer wax-based carbon ribbon |
| CN102653189A (en) * | 2012-04-16 | 2012-09-05 | 焦作市卓立烫印材料有限公司 | Thermal transfer ribbon for edge-pressing printer and preparation method thereof |
| CN105058999A (en) * | 2015-08-12 | 2015-11-18 | 河南卓立膜材料股份有限公司 | Thermal transfer ribbon with night luminous function and preparation method thereof |
| CN106515235A (en) * | 2016-11-11 | 2017-03-22 | 冯晋 | Thermal sublimation transfer printing ink ribbon |
Non-Patent Citations (1)
| Title |
|---|
| 刘尊忠: "《防伪印刷与应用》", 31 January 2008, 印刷工业出版社 * |
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Application publication date: 20190903 |