CN100389967C - Transfer film for fine transfer pattern using partial evaporation plating - Google Patents
Transfer film for fine transfer pattern using partial evaporation plating Download PDFInfo
- Publication number
- CN100389967C CN100389967C CNB2005100084243A CN200510008424A CN100389967C CN 100389967 C CN100389967 C CN 100389967C CN B2005100084243 A CNB2005100084243 A CN B2005100084243A CN 200510008424 A CN200510008424 A CN 200510008424A CN 100389967 C CN100389967 C CN 100389967C
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- China
- Prior art keywords
- evaporation
- weight portions
- layer
- transfer film
- transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
Abstract
The invention relates to transfer film for fine transfer pattern using partial evaporation plating, comprising priming composition of methyl methacrylate, polyether modified dimethyl polysiloxane copolymer, toluene, methyl ethyl ketone, used for partial evaporation plating; priming composition of vinylchloride vinylacetate copolymer, methyl methacrylate, toluene, methyl ethyl ketone and so on; adhesive composition of vinylchloride vinylacetate copolymer, methyl methacrylate, silica powder, toluene, methyl ethyl ketone, ethyl acetate and so on; pattern can be finely transferred by partial evaporation plating. The aforementioned composition provided by the invention can be used on the transfer film having metal evaporation plating layer and can easily transfer characteristic pattern.
Description
Technical field
The present invention relates to utilize the part evaporation to come the transfer film of transfer pattern subtly, relate to part evaporation paint base composition A, the paint base composition B and the adhesive composition C that utilize transfer film to realize part evaporation effect particularly with metal evaporation layer.
Background technology
In general; transfer film be by with special-shaped agent layer, prime coat, printed layers, adhesive layer etc. optionally the method for lamination on substrate sheet make, wherein priming paint (primer) is used for suitably regulating the bonding between each layer or be used to protect certain characteristic layer etc. when making transfer film.
Metal evaporation layer in transfer film generally is used to give transfer printing object gold or silver color.Can be as an example with reference to disclosed day disclosure special permission communique in 1992 flat 04-163198 number, wherein put down in writing have two metal evaporation layers, transfer film flower-pattern layer and tack coat etc., that metallic luster is arranged.
Though have similarly structure in addition in addition, come the intermittently transfer film of transfer printing metal pattern by part transfer printing metal level.Disclosure special permission communique had been put down in writing " part evaporation transfer film " for flat 08-090999 number in 1996 disclosed day.So-called part evaporation transfer film is meant the transfer film that does not form the metal evaporation layer on the collective transfer film and on partial sheet.Above-mentioned Japan special permission communique put down in writing for 08-090999 number the part that does not need the metal evaporation floor form washing with prime coat after, the method for carrying out metal evaporation successively and described part washing being eliminated etc.
The method that washing is eliminated the part metals layer and formed decorative pattern is a method very commonly used in most part evaporation transfer film, but also disclosed without washing process also can display part evaporation effect method.Described method is not to form part evaporation layer by the part metals evaporation layer of eliminating evaporation on the transfer film, but after utilizing binding agent or priming paint to form given pattern, the image that will be identical with described pattern or the image of transfer printing are stayed on the transfer printing object.Therefore, described adhesive layer or prime coat determine the metal level decorative pattern of transfer printing thereafter.
As an example, after day disclosure special permission communique clear 56-000188 number, clear 63-045081 number have been put down in writing and to have been utilized binding agent to form pattern on the metal evaporation floor, the method for formation and the part metals evaporation layer of the identical decorative pattern of described pattern on the transfer printing object.
But, above-mentioned technology is not owing to be a kind of forming metal level or only need the method for removing a part on only to the part area on the transfer film, so the term of " part evaporation " may be inappropriate, but has similar effect with real part evaporation transfer film, so generally use identical term.
Except above-mentioned day disclosure special permission communique, also having number also to have put down in writing in Korea S's openly specially permit communique special 2002-0080690 number, special 2003-0000241 does not need the part evaporation of washing process heat transfer film.Though openly specially permit the transfer film described in the communique and have for above-mentioned two than above-mentioned day disclosure special permission communique clear 56-000188 number, clear 63-045081 number more complicated structure, but utilize adhesive layer with the method for metal evaporation layer segment ground transfer printing on the transfer printing object owing to use, so think identical method in this.
About the conventional art of the adhesive layer that is used for part transfer printing metal level, number simply introduced in openly specially permit communique special 2002-0080690 number, special 2003-0000241 of above-mentioned Korea S.Openly specially permit communique special 2002-0080690 number with reference to Korea S, produce the binding agent of part evaporation effect as coating back on the aluminium-vapour deposition layer, used the binding agent that on acrylic resin, vinyl resins or polyester resin, adds ketones solvent, acetate esters solvent, aromatic solvent, and in Korea S openly speciallys permit special 2003-0000241 number of communique, also put down in writing part evaporation binding agent with above-mentioned composition.
If utilize the composition of common bond in the past as above, even without washing process, but also can obtain the transfer film of part transfer printing, but also have shortcoming.Described part evaporation with the shortcoming of adhesive composition is: the first since with the cohesive force deficiency of metal evaporation layer, so part evaporation layer can not evaporation and to stay the possibility of substrate sheet one side big; The second, utilize the part evaporation to form required pattern with binding agent after, thereon during the different ink layer of lamination, with the imperfect bonding of ink layer, so the decorative pattern of institute's transfer printing is eliminated etc. easily again.
The objective of the invention is to utilize the part evaporation to solve the shortcoming of the above-mentioned part evaporation that these used in the past with adhesive composition with paint base composition A.Therefore, the technical field of the invention is about being used for the part evaporation paint base composition of part transfer printing metal evaporation layer.
In addition, because the closely related use of paint base composition of paint base composition B of the present invention and adhesive composition C and part evaporation, the present invention also provides these compositions.
Summary of the invention
For solving the problem of above-mentioned conventional art, the present invention seeks to utilize the part evaporation to come with paint base composition A, paint base composition B and adhesive composition C can attractive in appearance ground evaporation metal evaporation layer, but the transfer printing transfer film of distinctness and meticulous decorative pattern more is provided.
Description of drawings
Fig. 1 utilizes part evaporation of the present invention to use paint base composition A after metal evaporation layer printshop needs pattern, the process schematic diagram of metal evaporation layer segment transfer printing on the transfer printing object of pattern transferring.
Fig. 2 be in the transfer film of Fig. 1, omit prime coat 6 and the 2nd printed layers 7 state transfer film and utilize described transfer film to come the transfer printing process schematic diagram of the metal evaporation layer of pattern transferring.
Fig. 3 be in the transfer film of Fig. 1 the clipped evaporation with prime coat 9, prime coat 6 and the 2nd printed layers 7, utilize adhesive composition C of the present invention to come the printshop to need pattern after, will have the process schematic diagram of the metal evaporation layer transfer printing of described pattern.
Fig. 4 utilizes the present composition to come a routine metal evaporation layer schematic diagram of transfer printing.
Description of reference numerals
1: substrate sheet, 2: special-shaped agent layer, 3: the 1 printed layers, 4: evaporation protection and dyed layer, 5: metal evaporation layer, 6: priming paint (primer) layer, 7: the 2 printed layers, 8: adhesive layer, 9: part evaporation prime coat, 10: the transfer printing object
The specific embodiment
But Fig. 1 utilizes part evaporation of the present invention to come the illustration intention of the transfer film of any decorative pattern of transfer printing with paint base composition.With reference to Fig. 1, transfer film of the present invention has: substrate sheet 1, special-shaped agent layer the 2, the 1st printed layers 3, evaporation protection and dyed layer 4, metal evaporation layer 5, prime coat the 6, the 2nd printed layers 7, adhesive layer 8, part evaporation prime coat 9 etc.
In described Fig. 1, substrate sheet 1 is the good glossy or lacklustre polyesters thin slice of hear resistance, is generally PET (PETG) thin slice, in order to regulate the light reflectance of thin slice, can implement matt coating.
The 1st printed layers 3 is provided with in order to embody multiple decorative pattern and color, can use multiple materials such as dyestuff, pigment or metallic powdery pigment.
Evaporation protection and dyed layer 4 are used to protect metal evaporation layer 5, can use the coloring effect that obtains adding with the material of multicolour.
Part evaporation prime coat 9 is set between metal evaporation layer 5 and prime coat 6.As shown in Figure 1, described part evaporation utilizes method such as intaglio printing that the feature decorative pattern is coated on the transfer film with prime coat, after transfer printing process finishes the metal evaporation layer of transfer pattern stay on the transfer printing object 10.
Prime coat 6 is used for complete binding metal evaporation layer the 5, the 2nd printed layers 7 and adhesive layer 8.
The 2nd printed layers 7 and the 1st printed layers 3 are similar, utilize methods such as intaglio printing to embody multiple decorative pattern and color.
All layers that adhesive layer 8 is used for being provided with in the above bond fully.
Describe the manufacture method of the part evaporation of use in the above-mentioned transfer film manufacturing below in detail with paint base composition, adhesive composition, paint base composition.
Part evaporation of the present invention is to utilize the homogenizer dispersion after 15～20 minutes the methyl methacrylate (methyl methacrylate) of 20～30 weight portions, the polyether-modified dimethyl polysiloxane copolymer of 1～5 weight portion (polyether modified dimethylpolysiloane copolymer), the toluene of 30～40 weight portions, the methyl ethyl ketone of 30～40 weight portions etc. with paint base composition A, carry out polymerisation in solution under 100～110 ℃ after 9～10 hours, be cooled to 30～35 ℃ and make.
In described compound, polyether-modified dimethyl polysiloxane copolymer be applicable to the coating object, can reduce capillary additive, the commodity that the commodity BYK-333 by name that the BYK-chemie company of the U.S. sells is typically arranged, when using 1～5 weight portion, can obtain most preferred part evaporation effect.
Methyl methacrylate is used to give the part evaporation and specifies cohesive force with paint base composition A, preferably uses 20～30 weight portions.Its reason is, when less than 20 weight portions, viscosity is too little, and when greater than 30 weight portions, viscosity is too big.
Toluene and methyl ethyl ketone have the effect of solvent, when integral body is used 60～80 weight portions, can obtain most preferred rate of drying, and two kinds of solvents when using same ratio and the intermiscibility of other materials best.
With reference to Fig. 1, described part evaporation prints given pattern with paint base composition A on metal evaporation layer 5, forms the part evaporation prime coat 9 of Fig. 1.When being used in the transfer film of such printed patterns on the transfer printing object, being printed with the part evaporation and eliminating with transfer film, so consequently have only the metal level of transferred image to stay on the transfer printing object with the metal level in the zone of priming paint.
Paint base composition B of the present invention is after utilizing homogenizer to disperse 15～20 minutes the methyl ethyl ketone of the toluene of the methyl methacrylate of the vinyl chloride vinyl acetate copolymer of 10～20 weight portions, 5～15 weight portions, 35～45 weight portions, 30～40 weight portions etc., carry out polymerisation in solution under 90～100 ℃ after 10～11 hours, be cooled to 35～40 ℃ and make.
In the vinyl chloride vinyl acetate copolymer of described paint base composition B, most typical is the commodity of the commodity OXY6338 by name of U.S. OXYDANTAL CHEMICAL company.When described vinyl chloride vinyl acetate copolymer uses 10～20 weight portions, show most preferred coating characteristic.
Compare when making with paint base composition A with the part evaporation, methyl methacrylate uses 5～15 weight portions of paint base composition less amount, this is owing to having used vinyl chloride vinyl acetate copolymer fully in a large number, so use this tittle also can guarantee sufficient cohesive force.
Paint base composition B of the present invention on metal evaporation layer 5 evenly coating prime coat 6 make metal evaporation layer 5 tight bond and using more, and use for the oxidation that prevents the metal evaporation layer.
After the prime coat 6 the 2nd printed layers 7 is set, adhesive layer 8 then is set.The adhesive composition C that uses on described adhesive layer 8 has strong cohesive force to transfer printing objects such as ABS (acrylonitrile-butadiene-styrene (ABS)), PVC (polyvinyl chloride), expanded polystyrene (EPS)s.
Adhesive composition C of the present invention mixes dispersion backs such as the ethyl acetate of the methyl ethyl ketone of the toluene of the silica powder of the Corvic of the methyl methacrylate of the vinyl chloride vinyl acetate copolymer of 4～10 weight portions, 10～20 weight portions, 1～7 weight portion, 1 weight portion, 30～40 weight portions, 30～50 weight portions, 2～8 weight portions 25～30 minutes, then described mixture was carried out polymerisation after 7～8 hours under 75～80 ℃, cooling and make.
Among the adhesive composition C of the present invention, toluene, methyl ethyl ketone, ethyl acetate are solvents, and its weight portion is to consider the solubility of the viscosity of final binding agent and polyvinyl chloride and definite.
The evaporation of part described in the present invention uses modification form as shown in Figures 2 and 3 with paint base composition A, paint base composition B, adhesive composition C.
Transfer film shown in Figure 2 is to omit the state that directly forms tack coat 8 after prime coat 6 and the 2nd printed layers 7 in the transfer film of Fig. 1, has transfer film to be simplified the structure and the advantage of the transfer film same effect of performance and Fig. 1.
Transfer film shown in Figure 3 is to utilize adhesive composition C of the present invention directly to form pattern on metal evaporation layer 5.If when using the method for Fig. 3, the pattern that utilizes binding agent to form will be stayed above the transfer printing object, this with the method that leaves Fig. 1 of pattern transferring antithesis.In addition, Fig. 3 omits the state of the part evaporation of Fig. 1 with prime coat 9, prime coat 6 and the 2nd printed layers 7.
Fig. 4 is that expression utilizes part evaporation of the present invention to come the photo of an example of transfer printing metal evaporation layer with paint base composition A.In the photo of Fig. 4, black place is the part of transfer printing aluminium, and white place is empty space.At this moment, the real area of the photo that Fig. 4 represents is the very little zone of 0.5 centimetre of 0.5 cm x, this shows, utilizes part evaporation paint base composition A of the present invention, can obtain the distinct transfer printing of high image resolution.
Describe composition of the present invention in detail below by embodiment.
1, the part evaporation manufacturing of paint base composition
Utilize the homogenizer dispersion after 20 minutes the methyl methacrylate of 20 weight portions, the polyether-modified dimethyl polysiloxane copolymer of 1 weight portion, the toluene of 30 weight portions, the methyl ethyl ketone of 30 weight portions etc., carrying out polymerisation in solution under 110 ℃ after 10 hours, be cooled to 35 ℃ and come fabrication portion evaporation paint base composition.
2, the manufacturing of paint base composition
Utilize the homogenizer dispersion after 15 minutes the vinyl chloride vinyl acetate copolymer of 10 weight portions, the methyl methacrylate of 5 weight portions, the toluene of 35 weight portions, the methyl ethyl ketone of 30 weight portions etc., carrying out polymerisation in solution under 100 ℃ after 10 hours, be cooled to 40 ℃ and make paint base composition.
Embodiment 3
3, the manufacturing of adhesive composition
Disperse the back to mix 30 minutes in the vinyl chloride vinyl acetate copolymer of 4 weight portions, the methyl methacrylate of 10 weight portions, the Corvic of 1 weight portion, the silica powder of 1 weight portion, the toluene of 40 weight portions, the methyl ethyl ketone of 30 weight portions, the ethyl acetate of 2 weight portions etc., then described mixture was carried out polymerisation after 8 hours under 80 ℃, adhesive composition is made in cooling.
4, the manufacturing of transfer film
After being coated in special-shaped agent layer on the PET thin slice; the part evaporation that be coated with the 1st printed layers, evaporation protection and the dyed layer that are applied to printing decorative pattern and color, metal evaporation layer successively, in embodiment 1, makes with prime coat, the prime coat that in embodiment 2, makes, be used for printing the 2nd printed layers of decorative pattern and color, at the adhesive layer that embodiment 3 makes, make transfer film thus.
The effect of invention
Part evaporation of the present invention is to utilize the methods such as intaglio printing to be printed on metal with paint base composition A Above the evaporation layer, thus can be meticulous and any metal pattern of transfer printing brightly.
Claims (4)
1. one kind is utilized the part evaporation transfer film of transfer pattern subtly, at the transfer film that is used for transfer printing metal evaporation layer and the priming paint and the adhesive composition that are used for described transfer film, it is characterized in that described transfer film has: substrate sheet (1), special-shaped agent layer (2), the 1st printed layers (3), evaporation protection and dyed layer (4), metal evaporation layer (5), part evaporation prime coat (9), prime coat (6), the 2nd printed layers (7), adhesive layer (8); Described transfer film is that described part evaporation is printed on the metal evaporation layer (5) with given pattern with prime coat (9), will be after the transfer printing metal evaporation layer of pattern transferring stay on the transfer printing object; Described part evaporation utilizes the part evaporation to obtain with paint base composition A printing with prime coat (9), and wherein said part evaporation comprises the methyl methacrylate of 20～30 weight portions, the polyether-modified dimethyl polysiloxane copolymer of 1～5 weight portion, the toluene of 30～40 weight portions, the methyl ethyl ketone of 30～40 weight portions with paint base composition A.
2. one kind is utilized the part evaporation transfer film of transfer pattern subtly, in transfer film with metal evaporation layer, it is characterized in that described transfer film has: substrate sheet (1), special-shaped agent layer (2), the 1st printed layers (3), evaporation protection and dyed layer (4), metal evaporation layer (5), part evaporation prime coat (9), adhesive layer (8); Described transfer film is that described part evaporation is printed on the metal evaporation layer (5) with given pattern with prime coat (9), will be after the transfer printing metal evaporation layer of pattern transferring stay on the transfer printing object; Described part evaporation utilizes the part evaporation to obtain with paint base composition A printing with prime coat (9), and wherein said part evaporation comprises the methyl methacrylate of 20～30 weight portions, the polyether-modified dimethyl polysiloxane copolymer of 1～5 weight portion, the toluene of 30～40 weight portions, the methyl ethyl ketone of 30～40 weight portions with paint base composition A.
3. the part evaporation transfer film of transfer pattern subtly that utilizes as claimed in claim 1, it is characterized in that, described prime coat (6) utilizes paint base composition B coating to obtain, and wherein said paint base composition B comprises the vinyl chloride vinyl acetate copolymer of 10～20 weight portions, the methyl methacrylate of 5～15 weight portions, the toluene of 35～45 weight portions, the methyl ethyl ketone of 30～40 weight portions.
4. the part evaporation transfer film of transfer pattern subtly that utilizes as claimed in claim 1 or 2, it is characterized in that, described adhesive layer (8) utilizes adhesive composition C coating to obtain, and wherein said adhesive composition C comprises the vinyl chloride vinyl acetate copolymer of 4～10 weight portions, the methyl methacrylate of 10～20 weight portions, the Corvic of 1～7 weight portion, the silica powder of 1 weight portion, the toluene of 30～40 weight portions, the methyl ethyl ketone of 30～35 weight portions, the ethyl acetate of 2～8 weight portions.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020040110476 | 2004-12-22 | ||
| KR1020040110476A KR100658790B1 (en) | 2004-12-22 | 2004-12-22 | Transfer sheet film using highlight vapeur deposition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1792638A CN1792638A (en) | 2006-06-28 |
| CN100389967C true CN100389967C (en) | 2008-05-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100084243A Expired - Fee Related CN100389967C (en) | 2004-12-22 | 2005-02-18 | Transfer film for fine transfer pattern using partial evaporation plating |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR100658790B1 (en) |
| CN (1) | CN100389967C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101133696B1 (en) | 2009-01-23 | 2012-04-06 | 코리아케미칼 주식회사 | Heat transcription four films and the manufacture method to have negative angle and engraving in relief piece pattern effect |
| CN101746203B (en) * | 2009-11-25 | 2013-07-03 | 保定乐凯新材料股份有限公司 | Preparation method of wire drawing decorative film |
| KR101377393B1 (en) * | 2011-01-13 | 2014-03-25 | (주)엘지하우시스 | Metal-colored and non-conductive transfer film |
| KR20140147925A (en) * | 2013-06-19 | 2014-12-31 | 삼성전자주식회사 | Transfer film, transcripting method and electronic device |
| CN105172453B (en) * | 2015-08-13 | 2017-12-08 | 宁波雅歌新材料科技有限公司 | A kind of preparation method of drawing film |
| CN105504821A (en) * | 2016-01-13 | 2016-04-20 | 宁波创源文化发展股份有限公司 | Base glue for glitter powder pad printing film processing |
| KR101968441B1 (en) * | 2018-05-30 | 2019-04-11 | 용강호 | Transfer film for Melamine board |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5610484A (en) * | 1979-07-05 | 1981-02-02 | Toppan Printing Co Ltd | Manufacture of partially evaporated transfer printing sheet |
| JPS61158493A (en) * | 1984-12-28 | 1986-07-18 | Dainippon Printing Co Ltd | Transfer sheet with partial vapor-deposited layer and production of the same |
| JPH0679997A (en) * | 1991-02-20 | 1994-03-22 | Reiko Co Ltd | Partial evaporation transfer foil |
| US5795527A (en) * | 1994-04-29 | 1998-08-18 | Nissha Printing Co., Ltd. | Method of manufacturing decorated article using a transfer material |
| KR20030000241A (en) * | 2001-06-22 | 2003-01-06 | 코리아케미칼 주식회사 | Heat transcription film transcribing gold or silver foil by partial adhesion having a transparent effect and the method of making it |
| JP2003335099A (en) * | 2002-05-23 | 2003-11-25 | Kyowa Lamicoat:Kk | Manufacturing method for partial transfer metal vapor- deposited sheet material |
-
2004
- 2004-12-22 KR KR1020040110476A patent/KR100658790B1/en active IP Right Grant
-
2005
- 2005-02-18 CN CNB2005100084243A patent/CN100389967C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5610484A (en) * | 1979-07-05 | 1981-02-02 | Toppan Printing Co Ltd | Manufacture of partially evaporated transfer printing sheet |
| JPS61158493A (en) * | 1984-12-28 | 1986-07-18 | Dainippon Printing Co Ltd | Transfer sheet with partial vapor-deposited layer and production of the same |
| JPH0679997A (en) * | 1991-02-20 | 1994-03-22 | Reiko Co Ltd | Partial evaporation transfer foil |
| US5795527A (en) * | 1994-04-29 | 1998-08-18 | Nissha Printing Co., Ltd. | Method of manufacturing decorated article using a transfer material |
| KR20030000241A (en) * | 2001-06-22 | 2003-01-06 | 코리아케미칼 주식회사 | Heat transcription film transcribing gold or silver foil by partial adhesion having a transparent effect and the method of making it |
| JP2003335099A (en) * | 2002-05-23 | 2003-11-25 | Kyowa Lamicoat:Kk | Manufacturing method for partial transfer metal vapor- deposited sheet material |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100658790B1 (en) | 2006-12-15 |
| KR20060071968A (en) | 2006-06-27 |
| CN1792638A (en) | 2006-06-28 |
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Granted publication date: 20080528 Termination date: 20110218 |