CN107345125A - Dual-purpose transfer film - Google Patents
Dual-purpose transfer film Download PDFInfo
- Publication number
- CN107345125A CN107345125A CN201610292373.XA CN201610292373A CN107345125A CN 107345125 A CN107345125 A CN 107345125A CN 201610292373 A CN201610292373 A CN 201610292373A CN 107345125 A CN107345125 A CN 107345125A
- Authority
- CN
- China
- Prior art keywords
- dual
- transfer film
- transfer
- line
- glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
Present invention is disclosed a kind of dual-purpose transfer film, is formed by paper substrate and coated in the transfer glue-line on paper substrate, and paper substrate is release liners, and transfer glue-line includes（A）In thermoplastic polyurethane, esters of acrylic acid, polystyrene resin and polyethylene vinylacetate copolymers one or more and（B）One or more in ultra-fine polyethylene terephthalate, copolyester and polyamide powder with inner pore, wherein,（B）The weight/mass percentage composition of component is 0 20%.
Description
Technical field
The invention belongs to printing technology field, and in particular to a kind of dual-purpose transfer film of ink-jet or heat sublimation.
Background technology
Thermal dye sublimation transfer printing can realize the colored anhydrous printing of high-quality, but can only preferably apply on the fabric based on polyester fiber at present.Though there is document report, cotton originally has characteristic that its graft copolymerization can be made to complete thermal dye sublimation transfer printing by being impregnated with high polymer material change cotton, but need to moisten fabric and drying in process of production, not only need special equipment, complex process power consumption is big, and the finished product color of transfer is not beautiful enough, the intrinsic gas permeability of cotton and feel are also changed, and the dizzy phenomenon held of color boundaries can more be produced by being long placed in.
The content of the invention
It is an object of the invention to solve limitation of the dyeing and printing process to fabric, there is provided a kind of transfer film that unlike material can be printed and dyed, and make printing and dyeing finished product that there is higher color fastness.
For achieving the above object, the present invention provides a kind of dual-purpose transfer film, is formed by paper substrate and coated in the transfer glue-line on paper substrate, and paper substrate is release liners, and transfer glue-line includes（A）In thermoplastic polyurethane, esters of acrylic acid, polystyrene resin and polyethylene vinyl acetate copolymer one or more and（B）One or more in ultra-fine polyethylene terephthalate, copolyester and polyamide powder with inner pore, wherein,（B）The weight/mass percentage composition of component is 0-20%.
As the further improvement of an embodiment of the present invention, release liners are the Ge Laxin paper containing organic silicon coating, PEK paper or CCK paper.
As the further improvement of an embodiment of the present invention, polyamide powder is porous nylon powder.
As the further improvement of an embodiment of the present invention, after transferring glue-line described in Weak solvent ink or UV ink printeds, pigment can be bonded to the dual-purpose transfer film surface.
As the further improvement of an embodiment of the present invention, transfer glue-line can be as the carrier of heat sublimation dyestuff.
As the further improvement of an embodiment of the present invention, it is 70% that transfer glue-line, which includes mass percent,：20%：10% thermoplastic polyurethane, polystyrene resin and polyethylene vinyl acetate copolymer.
As the further improvement of an embodiment of the present invention, it is 10% that transfer glue-line, which includes mass percent,：72%：18% porous nylon powder, thermoplastic polyurethane and acrylate.
As the further improvement of an embodiment of the present invention, it is 80% that transfer glue-line, which includes mass percent,：8%:12% polyethylene vinyl acetate, ultra-fine polyethylene terephthalate and porous copolyester.
Another aspect of the present invention provides a kind of method of inkjet transfer, comprises the following steps：Transfer film surface inkjet printing pattern to any of the above-described described dual-purpose transfer film；The transfer film surface of dual-purpose transfer film is bonded with fabric；Dual-purpose transfer film is transferred to by fabric with hot-pressing tool.
Another aspect of the present invention provides a kind of method of thermal dye sublimation transfer printing, comprises the following steps：Any of the above-described described dual-purpose transfer film is combined to web surface；The thermal dye sublimation transfer printing paper printed is overlying on dual-purpose transfer film surface；Thermal transfer.
Compared with prior art, dual-purpose transfer film provided by the invention, can be not only used for thermal dye sublimation transfer printing, can be used for inkjet transfer again, and suitable for a variety of different materials, and color fastness is high.
Brief description of the drawings
Fig. 1 is dual-purpose transfer film inkjet transfer flow chart in an embodiment of the present invention；
Fig. 2 is dual-purpose transfer film thermal dye sublimation transfer printing flow chart in an embodiment of the present invention.
Embodiment
Below with reference to embodiment shown in the drawings, the present invention will be described in detail.But these embodiments are not intended to limit the present invention, structure that one of ordinary skill in the art is made according to these embodiments, method or conversion functionally are all contained in protection scope of the present invention.
The dual-purpose transfer film of ink-jet or heat sublimation of the present invention, formed by paper substrate and coated in the transfer glue-line on paper substrate.
Wherein, paper substrate is release liners, such as the Ge Laxin paper with organic silicon coating, PEK paper（Polyether-ketone release liners）Or CCK paper（Clay coated release liners）, peel strength 20-150g/inch.
Release liners are to transfer the carrier of glue-line, have the characteristic for being easy to separate with transfer glue-line, for transfer glue-line to be transferred into fabric top layer.
Transfer glue-line includes（A）One or more in thermoplastic polyurethane, esters of acrylic acid, polystyrene resin and polyethylene vinyl acetate copolymer, and（B）Ultra-fine polyethylene terephthalate（PET）, there are one or more in the copolyester of inner pore, polyamide powder.Wherein,（B）The weight/mass percentage composition of component is 0-20%.
（B）Component plays a part of absorbing ink, improves rate of drying, its particle diameter D<50 microns.
Further, the thickness for transferring glue-line is 10-100 microns.
Transferring can be Nian Jie with fabric after glue-line heats, while has the function of transfer again.Use Weak solvent ink or UV inks（Ultraviolet light solidified ink）After direct-injection printed transfer glue-line, ink can dissolve on film surface slightly, so that pigment anchors at film surface, web surface is then transferred to after transfer.Therefore, after the transfer film surface print pattern to the transfer film, can using hot-pressing tool, the transfer film is transferred to web surface by 10-50s condition with 90-200 DEG C, is realized and is carried out inkjet transfer to the textile of any material.
On the other hand, glue-line is transferred but also as thermal dye sublimation transfer printing intermediate.In thermal dye sublimation transfer printing technique, utilize the adhesive property for transferring glue-line, with 90-200 DEG C, the dual-purpose transfer film can be combined to web surface by 10-50s condition, to be used as the carrier for receiving heat sublimation dyestuff, the dyestuff of thermal dye sublimation transfer printing paper is transferred to transfer glue-line, and takes thermal dye sublimation transfer printing paper off rapidly while hot, so as to complete the transfer of various material.Glue-line is attached to material surface after transfer, neither the significantly additional feel of increase, the beautiful effect for thermal transfer of having got back.
Exemplary embodiment given below：
Embodiment one
Using the Ge Laxin paper containing silicone coating as paper substrate, coated on paper substrate and contain porous nylon powder（Polyamide powder）, thermoplastic polyurethane and acrylate coatings, wherein, three's mass percent is 10%：72%：18%, thickness is 50 microns, forms transfer film.The dual-purpose transfer film is thrown off into paper substrate with 150 DEG C, 20s condition composite to cotton surface.Then the thermal dye sublimation transfer printing paper crossed with heat sublimation ink mirror printed is overlying on the dual-purpose transfer film surface, 180 DEG C, 40s transfers, takes thermal dye sublimation transfer printing paper off rapidly while hot.Heat, which is torn, to keep its gas permeability by the film local failure for overlaying on cotton surface.
After the above method transfers, coating and fabric bonding force are strong, color fastness up to level Four more than, washing is not faded, and maintains the gas permeability of fabric.
Embodiment two
CCK paper to contain silicone coating coats thermoplastic polyurethane and polystyrene resin, the mixed coating of polyethylene vinyl acetate copolymer, the mass percent of three is 70% as paper substrate on paper substrate：20%：10%, thickness is 20 microns, forms transfer film.With Weak solvent ink the transfer film transfer film surface mirror printed pattern, after it is parched completely, will transfer film surface placement is bonded with leather, the transfer film is transferred to by leather surface with 100 DEG C, 40s, throws off paper substrate.Leather can still keep comfortable flexibility after transfer, smaller on feel influence, and transfer glue-line and be firmly combined with not fading with leather.
Embodiment three
To contain the PEK paper of silicone coating as paper substrate, the mixed coating of coating polyethylene-vinyl acetate, ultra-fine PET and porous copolyester on paper substrate, the mass percent of three is 80%：8%:12%, thickness is 100 microns, forms transfer film.Non- mirror image pattern is printed with transfer film surface of the UV inks in the transfer film, after it is parched completely, one layer of PET film is covered in transfer film surface, and bottom PEK paper substrates are thrown off, transparent or light acrylic board surface is transferred to 90 DEG C, 50s afterwards, throws off PET film.Pattern color is vivid after transfer does not fade, and preferable with the firmness of plate face.
It should be understood that, although the present specification is described in terms of embodiments, but not each embodiment only includes an independent technical scheme, this narrating mode of specification is only for clarity, the skilled in the art should refer to the specification as a whole, technical scheme in each embodiment may also be suitably combined to form that other embodiments which can be understood by those skilled in the art.
Those listed above is a series of to describe illustrating only for feasibility embodiment of the invention in detail; they simultaneously are not used to limit the scope of the invention, and all equivalent implementations made without departing from skill spirit of the present invention or change should be included in the scope of the protection.
Claims (10)
- A kind of 1. dual-purpose transfer film, it is characterised in that formed by paper substrate and coated in the transfer glue-line on paper substrate,The paper substrate is release liners,The transfer glue-line includes（A）In thermoplastic polyurethane, esters of acrylic acid, polystyrene resin and polyethylene vinyl acetate copolymer one or more and（B）One or more in ultra-fine polyethylene terephthalate, copolyester and polyamide powder with inner pore, wherein,（B）The weight/mass percentage composition of component is 0-20%.
- 2. dual-purpose transfer film according to claim 1, it is characterised in that the release liners are the Ge Laxin paper containing organic silicon coating, PEK paper or CCK paper.
- 3. dual-purpose transfer film according to claim 1, it is characterised in that the polyamide powder is porous nylon powder.
- 4. dual-purpose transfer film according to claim 1, it is characterised in that after transferring glue-line described in Weak solvent ink or UV ink printeds, pigment can be bonded to the dual-purpose transfer film surface.
- 5. dual-purpose transfer film according to claim 1, it is characterised in that the transfer glue-line can be as the carrier of heat sublimation dyestuff.
- 6. dual-purpose transfer film according to claim 1, it is characterised in that it is 70% that the transfer glue-line, which includes mass percent,：20%：10% thermoplastic polyurethane, polystyrene resin and polyethylene vinyl acetate copolymer.
- 7. dual-purpose transfer film according to claim 3, it is characterised in that it is 10% that the transfer glue-line, which includes mass percent,：72%：18% porous nylon powder, thermoplastic polyurethane and acrylate.
- 8. dual-purpose transfer film according to claim 1, it is characterised in that it is 80% that the transfer glue-line, which includes mass percent,：8%:12% polyethylene vinyl acetate, ultra-fine polyethylene terephthalate and porous copolyester.
- A kind of 9. method of inkjet transfer, it is characterised in that comprise the following steps：The transfer film surface inkjet printing pattern of described dual-purpose transfer film any to claim 1-5；The transfer film surface of the dual-purpose transfer film is bonded with fabric；The dual-purpose transfer film is transferred to by fabric with hot-pressing tool.
- A kind of 10. method of thermal dye sublimation transfer printing, it is characterised in that comprise the following steps：Any described dual-purpose transfer films of claim 1-5 are combined to web surface；The thermal dye sublimation transfer printing paper printed is overlying on the dual-purpose transfer film surface；Thermal transfer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610292373.XA CN107345125A (en) | 2016-05-05 | 2016-05-05 | Dual-purpose transfer film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610292373.XA CN107345125A (en) | 2016-05-05 | 2016-05-05 | Dual-purpose transfer film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107345125A true CN107345125A (en) | 2017-11-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610292373.XA Pending CN107345125A (en) | 2016-05-05 | 2016-05-05 | Dual-purpose transfer film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107345125A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108909224A (en) * | 2018-06-01 | 2018-11-30 | 上海泰画服饰铺料有限公司 | A kind of boiling hot target manufacture craft of digital ink-jet |
| CN109749560A (en) * | 2019-01-25 | 2019-05-14 | 西安天亿胶粘材料有限公司 | A kind of thermal transfer coating high heat resistance resin and preparation method thereof |
| WO2021208506A1 (en) * | 2020-04-16 | 2021-10-21 | 何建雄 | Temperature-resistant lettering film and preparation method therefor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101612843A (en) * | 2009-07-23 | 2009-12-30 | 焦作市卓立烫印材料有限公司 | A kind of sublimation banner thermal transfer ribbons (TTR) and preparation method thereof |
| CN102381069A (en) * | 2011-08-10 | 2012-03-21 | 福州艾瑞数码影像有限公司 | Dual-use heat-transfer paper for ink-jet or laser printing |
| CN204780414U (en) * | 2015-05-27 | 2015-11-18 | 全斯福新材料（苏州）有限公司 | Cold and hot dual -purpose rendition membrane of bafta |
-
2016
- 2016-05-05 CN CN201610292373.XA patent/CN107345125A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101612843A (en) * | 2009-07-23 | 2009-12-30 | 焦作市卓立烫印材料有限公司 | A kind of sublimation banner thermal transfer ribbons (TTR) and preparation method thereof |
| CN102381069A (en) * | 2011-08-10 | 2012-03-21 | 福州艾瑞数码影像有限公司 | Dual-use heat-transfer paper for ink-jet or laser printing |
| CN204780414U (en) * | 2015-05-27 | 2015-11-18 | 全斯福新材料（苏州）有限公司 | Cold and hot dual -purpose rendition membrane of bafta |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108909224A (en) * | 2018-06-01 | 2018-11-30 | 上海泰画服饰铺料有限公司 | A kind of boiling hot target manufacture craft of digital ink-jet |
| CN109749560A (en) * | 2019-01-25 | 2019-05-14 | 西安天亿胶粘材料有限公司 | A kind of thermal transfer coating high heat resistance resin and preparation method thereof |
| CN109749560B (en) * | 2019-01-25 | 2021-06-18 | 西安天亿胶粘材料有限公司 | High-heat-resistant resin for thermal transfer coating and preparation method thereof |
| WO2021208506A1 (en) * | 2020-04-16 | 2021-10-21 | 何建雄 | Temperature-resistant lettering film and preparation method therefor |
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| PB01 | Publication | ||
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| CB02 | Change of applicant information |
Address after: 215143 No. 83-3 Changping Road, Dongqiao, Huangdao Town, Xiangcheng District, Suzhou City, Jiangsu Province Applicant after: Quansifu new materials (Suzhou) Co.,Ltd. Address before: 215137 Anle Village, Taiping Street, Xiangcheng District, Suzhou City, Jiangsu Province Applicant before: Quansifu new materials (Suzhou) Co.,Ltd. |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171114 |
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| RJ01 | Rejection of invention patent application after publication |