CN102616024A - Heat-transfer wax-based carbon ribbon - Google Patents
Heat-transfer wax-based carbon ribbon Download PDFInfo
- Publication number
- CN102616024A CN102616024A CN2012100856889A CN201210085688A CN102616024A CN 102616024 A CN102616024 A CN 102616024A CN 2012100856889 A CN2012100856889 A CN 2012100856889A CN 201210085688 A CN201210085688 A CN 201210085688A CN 102616024 A CN102616024 A CN 102616024A
- Authority
- CN
- China
- Prior art keywords
- wax
- coating
- carbon ribbon
- transfer printing
- cerul
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 61
- 238000000576 coating method Methods 0.000 claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 29
- 239000002904 solvent Substances 0.000 claims abstract description 28
- 238000010023 transfer printing Methods 0.000 claims abstract description 27
- 239000002270 dispersing agent Substances 0.000 claims abstract description 22
- 239000000049 pigment Substances 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000001993 wax Substances 0.000 claims description 22
- 229920006387 Vinylite Polymers 0.000 claims description 18
- 239000004203 carnauba wax Substances 0.000 claims description 18
- 238000007670 refining Methods 0.000 claims description 18
- 229920000728 polyester Polymers 0.000 claims description 15
- 229920002799 BoPET Polymers 0.000 claims description 14
- 239000005041 Mylar™ Substances 0.000 claims description 14
- 239000004925 Acrylic resin Substances 0.000 claims description 12
- 229920000178 Acrylic resin Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 3
- 239000011247 coating layer Substances 0.000 claims description 2
- 238000007639 printing Methods 0.000 abstract description 19
- 239000000853 adhesive Substances 0.000 abstract description 9
- 230000001070 adhesive effect Effects 0.000 abstract description 9
- 239000000969 carrier Substances 0.000 abstract description 3
- 239000000976 ink Substances 0.000 description 29
- 239000004575 stone Substances 0.000 description 6
- 239000012467 final product Substances 0.000 description 4
- 230000003678 scratch resistant effect Effects 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000002469 basement membrane Anatomy 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention belongs to the technical field of thermal transfer printing materials, and particularly relates to a thermal transfer wax-based carbon ribbon. The transfer printing wax-based carbon belt comprises a back coating, a base material, a release coating on the base material and an ink coating on the release coating, wherein the ink coating comprises the following components in percentage by weight: 1 to 10.3 percent of resin, 29 to 34 percent of wax, 9 to 10 percent of pigment, 0.7 to 0.8 percent of dispersant and 51 to 55 percent of solvent. The thermal transfer wax-based carbon ribbon provided by the invention has the advantages of high transfer rate, good adhesive force, scratch resistance and no adhesion, and can be suitable for thermal transfer bar code printers with various speeds, wider printing temperature and different printing carriers.
Description
Technical field
The invention belongs to hot transfer printing printed material technical field, particularly a kind of hot transfer printing cerul carbon ribbon.
Background technology
The supporting use of heat transfer printing carbon tape and bar code printer is widely used in the sign and the explanatory note of lot number in logistics, electronics, food and the commodity industry.Its structure mainly is made up of four parts, back coating, base material, release layer, ink coating.Require its ink coating after being heated under the suitable temperature, to be transferred to fully on the carrier of undertaking the printing of during use, ink coating has adaptability widely to the carrier of undertaking the printing of, and requires that adhesive force is good, scratch-resistant, adhesion.On the domestic market to being in great demand of cerul carbon ribbon, but present cerul product all can not well satisfy above-mentioned requirement.
Summary of the invention
The object of the present invention is to provide a kind of hot transfer printing cerul carbon ribbon, can well satisfy the requirement of market to hot transfer printing cerul carbon ribbon, after being heated, can be transferred to fully on the carrier of undertaking the printing of, the China ink layer has adaptability widely to the carrier of undertaking the printing of, and adhesive force is good, scratch-resistant.
The technical scheme that the present invention adopts is following:
A kind of hot transfer printing cerul carbon ribbon; Constitute by back coating, base material and the release coating above the base material, ink coating above the release coating; Described ink coating is made up of following component by weight percentage: resin 1-10.3%; Wax class 29-34%, pigment 9-10%, dispersant 0.7-0.8% and solvent 51-55%.
Described weight resin percentage composition is: vinylite 0-3%, Petropols 1-6%, acrylic resin or mylar 0-1.3%.
Described wax class weight percent is formed as follows: palm wax 16-17%, full refining wax 13-17%.
Preferably; Described ink coating is formed as follows: vinylite 2.5%, Petropols 3.9%, acrylic resin 1%, palm wax 16.5%, full refining wax 13.2%, pigment 9.6%, dispersant 0.7%, solvent 52.6%, described ink coating thickness are the preferred 2.5 μ m of 2.2-2.8 μ m.
The weight percent of described release coating consists of: mylar 2-3%, solvent 97-98%, release coating layer thickness are 0.05-0.06 μ m.
Described back coating and release coating lay respectively at the two sides of base material, and the weight percent of said back coating consists of: organosilicon 3-3.5%, solvent 96.5-97%.The thickness of said back coating can be ignored.
Said base material is a polyester material, and thickness is 4.2-4.5 μ m.
Dispersant major function in the ink lay component is to solve the dispersing of pigments problem, granules of pigments can be scattered in the system equably get final product.
Described hot transfer printing cerul carbon ribbon gets final product according to the conventional method preparation, has no special requirements.
Hot transfer printing cerul carbon ribbon provided by the invention; Ink coating can be transferred on the carrier of undertaking the printing of (transferring rate>95%) after suitable energy level is heated; Ink coating has adaptability widely to the carrier of undertaking the printing of, and can on the carriers of undertaking the printing of such as non-coated paper, coated paper, heat-transferring printing paper, realize the high-quality transfer printing; Adhesive force is good, scratch-resistant, adhesion, can be fit to various speed (2ips, 4ips, 6ips), more extensively print the heat transfer type bar code printer of energy level (the printing gear of bar code printer, generally from 0 to 30, energy level scope of the present invention can be 14-28).Ink coating and release coating have good adhesion simultaneously; Its release coating has good intermediary performance, with the adhesive force of base material less than with the adhesive force of ink coating, transfer printing property is fine, the transfer printing character edge is neat, has good flexibility.
The present invention has following advantage with respect to prior art:
Hot transfer printing cerul carbon ribbon provided by the invention, transferring rate is high, and adhesive force is good, scratch-resistant, adhesion, can be fit to various speed, more extensively print the heat transfer type bar code printer of energy level and the different carriers of undertaking the printing of.
The specific embodiment
Below with specific embodiment technical scheme of the present invention is described, but protection scope of the present invention is not limited thereto:
Embodiment 1
Base material is polyester (a PET basement membrane), and thickness is 4.5 μ m;
The every 100g of ink coating forms as follows:
| Dispersant | 0.8 |
| Palm wax | 16.5 |
| Vinylite | 2.5 |
| Pigment | 9.6 |
| Full refining wax | 16.8 |
| Petropols | 1.2 |
| Solvent | 52.6 |
The every 100g of release coating forms as follows:
| Mylar | 2g |
| Solvent | 98g |
The every 100g of back coating forms as follows:
| Organosilicon | 3g |
| Solvent | 97g |
Vinylite is selected the VA-600 of Hunan petrochemistry company for use; Petropols are selected the A-1100 of permanent stone company for use; Palm wax is selected the Carnauba-3 of Foncepi company for use, and full refining wax is selected the AP-1000 of permanent stone company for use, and pigment is selected the BeBlack6316F1 of brave cutting edge of a knife or a sword company for use; Dispersant is selected the scientific and technological A4300 and 1005 of refined rich color for use, and (the A4300:1005 mass ratio=5:2), solvent uses toluene.Mylar is selected the ES-110 of SK chemical industry for use.Organosilicon is selected the KR-605 of Ke Lin company for use.
Press the back coating compositing formula, process mixed solution, at the substrate backside coating film forming, under 105 ℃ of conditions, dry and get final product through coating apparatus.Process the hybrid resin solvent by release coating formula again, be coated with into the film that thickness is 0.05-0.06 μ m, under 105 ℃ of conditions, dry and get final product through coating apparatus.According to the ink lay prescription; In solvent, the order by above-mentioned prescription adds other components again, through grinder system is uniformly dispersed the dispersant heating for dissolving in elder generation; Be coated on the release coating through coating machine; Under 105 ℃ temperature, dry, its thickness is 2.5 μ m, forms hot transfer printing cerul carbon ribbon.
Embodiment 2
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.8 |
| Palm wax | 16.5 |
| Vinylite | 2.5 |
| Pigment | 9.6 |
| Full refining wax | 14.4 |
| Petropols | 2.9 |
| Mylar | 0.7 |
| Solvent | 52.6 |
Wherein mylar is selected the ES-812 of SK chemical industry for use; All the other material therefors are identical with embodiment 1.By as above filling a prescription, elder generation in solvent, adds other components to the dispersant heating for dissolving in the order by above-mentioned prescription; Through grinder system is uniformly dispersed, is coated on the release coating, under 105 ℃ temperature, dry through coating machine; Its thickness is 2.5 μ m, forms hot transfer printing cerul carbon ribbon.
The composition of release coating, back coating and preparation method are with embodiment 1.
Embodiment 3
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 2.5g |
| Petropols | 3.9g |
| Mylar | 1.0g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 4
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.8g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 14.4g |
| Vinylite | 0g |
| Petropols | 4.9g |
| Mylar | 1.2g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 5
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 1.3g |
| Petropols | 4.9g |
| Mylar | 1.2g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 6
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.8g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 1.3g |
| Petropols | 6.0g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 7
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 14.4g |
| Vinylite | 1.3g |
| Petropols | 3.9g |
| Mylar | 1.0g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 8
Base material is a polyester, and thickness is 4.5 μ m
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 1.3g |
| Petropols | 5.5g |
| Mylar | 0.6g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 9
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.8g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 2.5g |
| Petropols | 4.3g |
| Mylar | 0.5g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 10
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 1.3g |
| Pigment | 9.6g |
| Full refining wax | 13.2g |
| Petropols | 4.9g |
| Acrylic resin | 1.2g |
| Solvent | 52.6g |
Wherein acrylic resin is selected the 13LP of permanent stone for use; Other are with embodiment 1.
Embodiment 11
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 1.3g |
| Pigment | 9.6g |
| Full refining wax | 13.2g |
| Petropols | 5.5g |
| Acrylic resin | 0.6g |
| Solvent | 52.6g |
Wherein acrylic resin is selected the 13LP of permanent stone for use, and other are with embodiment 1.
Embodiment 12
Base material is a polyester, and thickness is 4.5 μ m
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 1.3g |
| Pigment | 9.6g |
| Full refining wax | 14.4g |
| Petropols | 3.9g |
| Acrylic resin | 1.0g |
| Solvent | 52.6g |
Wherein acrylic resin is selected the CPP of permanent stone for use, and other are with embodiment 1.
Embodiment 13
Base material is a polyester, and thickness is 4.5 μ m;
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 2.5g |
| Pigment | 9.6g |
| Full refining wax | 13.2g |
| Petropols | 3.9g |
| Acrylic resin | 1.0g |
| Solvent | 52.6g |
Wherein acrylic resin is selected the CPP of permanent stone for use, and other are with embodiment 1.
Effect
The hot transfer printing cerul carbon ribbon that the foregoing description 1-13 is made observes its transfer printing effect, with the adhesive force of the paper of undertaking the printing of and to the adaptability of the carrier of undertaking the printing of.
The transfer printing effect is that the transferring rate of ink lay is realized, is divided into three phases by following benchmark through after printing,>95% → A, 95-90% → B, < 90% → C.
Adhesive force is the bistrique with loading 800 gram, to the paper friction 50 times of undertaking the printing of, observes the damaged area of transfer ink layer, with no breakage → A, breakage fewer than half → B, complete breakage → C estimate damaged area.
The adaptability of carrier of undertaking the printing of is done printing test with the dissimilar paper of undertaking the printing of, and its applicability is estimated with the rank of transferring rate,>95% → A, 95-90% → B, < 90% → C.
The foregoing description is the preferred embodiment of the present invention, but embodiment of the present invention is not restricted to the described embodiments, and other the change that any the present invention of not deviating from did all should be the substitute mode of equivalence, is included within protection scope of the present invention.
Claims (7)
1. hot transfer printing cerul carbon ribbon; Constitute by back coating, base material and the release coating above the base material, ink coating above the release coating; It is characterized in that described ink coating is made up of following component by weight percentage: resin 1-10.3%, wax class 29-34%; Pigment 9-10%, dispersant 0.7-0.8% and solvent 51-55%.
2. hot transfer printing cerul carbon ribbon as claimed in claim 1 is characterized in that described weight resin percentage composition is: vinylite 0-3%, Petropols 1-6%, acrylic resin or mylar 0-1.3%.
3. hot transfer printing cerul carbon ribbon as claimed in claim 1 is characterized in that, described wax class weight percent is formed as follows: palm wax 16-17%, full refining wax 13-17%.
4. like the described hot transfer printing cerul carbon ribbon of one of claim 1-3; It is characterized in that; Described ink coating is formed as follows: vinylite 2.5%, Petropols 3.9%, acrylic resin 1%, palm wax 16.5%, full refining wax 13.2%, pigment 9.6%, dispersant 0.7%, solvent 52.6%, described ink coating thickness are 2.2-2.8 μ m.
5. like the described hot transfer printing cerul carbon ribbon of one of claim 1-3, it is characterized in that the weight percent of described release coating consists of: mylar 2-3%, solvent 97-98%, release coating layer thickness are 0.05-0.06 μ m.
6. hot transfer printing cerul carbon ribbon as claimed in claim 5 is characterized in that the weight percent of described back coating consists of: organosilicon 3-3.5%, solvent 96.5-97%.
7. hot transfer printing cerul carbon ribbon as claimed in claim 6 is characterized in that said base material is a polyester material, and thickness is 4.2-4.5 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210085688.9A CN102616024B (en) | 2012-03-28 | 2012-03-28 | Heat-transfer wax-based carbon ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210085688.9A CN102616024B (en) | 2012-03-28 | 2012-03-28 | Heat-transfer wax-based carbon ribbon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102616024A true CN102616024A (en) | 2012-08-01 |
| CN102616024B CN102616024B (en) | 2015-06-24 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210085688.9A Active CN102616024B (en) | 2012-03-28 | 2012-03-28 | Heat-transfer wax-based carbon ribbon |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105034621A (en) * | 2015-09-15 | 2015-11-11 | 河南卓立膜材料股份有限公司 | Magnetic anti-counterfeiting thermal transfer ribbon |
| CN110193454A (en) * | 2019-04-26 | 2019-09-03 | 深圳市新伟林科技有限公司 | A kind of preparation method of enhanced wax-based ribbon |
| CN111907235A (en) * | 2020-08-07 | 2020-11-10 | 广州中码科技股份有限公司 | Special bar code printing thermal transfer ribbon and preparation method thereof |
| CN113263850A (en) * | 2021-05-13 | 2021-08-17 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
| CN113442609A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer printing resin-based carbon ribbon and preparation method thereof |
| CN114312063A (en) * | 2021-12-23 | 2022-04-12 | 湖南鼎一致远科技发展有限公司 | Thermal transfer resin ribbon suitable for traffic signboard, preparation method thereof and traffic signboard |
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| CN1052450A (en) * | 1990-11-29 | 1991-06-26 | 天津光电通信公司 | At thermosensitive ribbon for transfer print surface of non-absorbent matter |
| CN1351933A (en) * | 2000-11-07 | 2002-06-05 | 潘浦敦 | Heat transfer colour ribbon |
| CN1485217A (en) * | 2002-09-29 | 2004-03-31 | 张振宇 | Blanching pattern mark carbon band |
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2012
- 2012-03-28 CN CN201210085688.9A patent/CN102616024B/en active Active
Patent Citations (3)
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|---|---|---|---|---|
| CN1052450A (en) * | 1990-11-29 | 1991-06-26 | 天津光电通信公司 | At thermosensitive ribbon for transfer print surface of non-absorbent matter |
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| CN1485217A (en) * | 2002-09-29 | 2004-03-31 | 张振宇 | Blanching pattern mark carbon band |
Non-Patent Citations (1)
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| 王永明: "热转印色带的研制", 《电子计算机与外部设备》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105034621A (en) * | 2015-09-15 | 2015-11-11 | 河南卓立膜材料股份有限公司 | Magnetic anti-counterfeiting thermal transfer ribbon |
| CN110193454A (en) * | 2019-04-26 | 2019-09-03 | 深圳市新伟林科技有限公司 | A kind of preparation method of enhanced wax-based ribbon |
| CN113442609A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer printing resin-based carbon ribbon and preparation method thereof |
| CN111907235A (en) * | 2020-08-07 | 2020-11-10 | 广州中码科技股份有限公司 | Special bar code printing thermal transfer ribbon and preparation method thereof |
| CN113263850A (en) * | 2021-05-13 | 2021-08-17 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
| CN113263850B (en) * | 2021-05-13 | 2022-11-01 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
| CN114312063A (en) * | 2021-12-23 | 2022-04-12 | 湖南鼎一致远科技发展有限公司 | Thermal transfer resin ribbon suitable for traffic signboard, preparation method thereof and traffic signboard |
| CN114312063B (en) * | 2021-12-23 | 2023-12-19 | 湖南鼎一致远科技发展有限公司 | Thermal transfer resin ribbon suitable for traffic sign board, preparation method thereof and traffic sign board |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102616024B (en) | 2015-06-24 |
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Address after: 454000 Shenzhou Road, Jiaozuo high tech Zone, Henan, No. 2758 Applicant after: Henan Zhuoli Imaging Technology Co., Ltd. Address before: 454000 Shenzhou Road, Jiaozuo high tech Zone, Henan, No. 2758 Applicant before: Zhuoli Thermoprinting Material Co., Ltd., Jianzuo City |
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Free format text: CORRECT: APPLICANT; FROM: ZHUOLI THERMOPRINTING MATERIAL CO., LTD., JIANZUO CITY TO: HENAN ZHUOLI IMAGING TECHNOLOGY CO., LTD. |
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Effective date of registration: 20191206 Address after: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province (in the hospital of Henan Zhuoli membrane materials Co., Ltd.) Patentee after: Jiaozuo Zhuoli membrane materials Co., Ltd Address before: 454000 No. 2758 Shenzhou Road, hi tech Zone, Henan, Jiaozuo Patentee before: Henan Zhuoli Imaging Technology Co., Ltd. |
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| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee after: Jiaozuo Zhuoli film material Co.,Ltd. Address before: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province, 454000 Patentee before: Jiaozuo Zhuoli membrane materials Co.,Ltd. |