CN1351933A - Heat transfer colour ribbon - Google Patents
Heat transfer colour ribbon Download PDFInfo
- Publication number
- CN1351933A CN1351933A CN 00127292 CN00127292A CN1351933A CN 1351933 A CN1351933 A CN 1351933A CN 00127292 CN00127292 CN 00127292 CN 00127292 A CN00127292 A CN 00127292A CN 1351933 A CN1351933 A CN 1351933A
- Authority
- CN
- China
- Prior art keywords
- parts
- heat transfer
- colour ribbon
- wax
- thermal transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920006267 polyester film Polymers 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims description 36
- 238000000576 coating method Methods 0.000 claims description 36
- 239000006185 dispersion Substances 0.000 claims description 20
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000004040 coloring Methods 0.000 claims description 10
- 239000004150 EU approved colour Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 4
- 239000003086 colorant Substances 0.000 abstract 2
- 239000003973 paint Substances 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 38
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
- 239000001993 wax Substances 0.000 description 21
- 238000010023 transfer printing Methods 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000010410 layer Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000002346 layers by function Substances 0.000 description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 9
- 239000004952 Polyamide Substances 0.000 description 8
- 229920002647 polyamide Polymers 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 7
- 235000019241 carbon black Nutrition 0.000 description 7
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 6
- 239000004203 carnauba wax Substances 0.000 description 6
- 239000012188 paraffin wax Substances 0.000 description 6
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 6
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 description 5
- 239000010408 film Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- -1 Merlon Polymers 0.000 description 3
- 239000004234 Yellow 2G Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000007984 tetrahydrofuranes Chemical class 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- 235000019235 yellow 2G Nutrition 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000012164 animal wax Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000012184 mineral wax Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000012178 vegetable wax Substances 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical class CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- MKYLOMHWHWEFCT-UHFFFAOYSA-N Manthidine Natural products C1C2=CC=3OCOC=3C=C2C2C3=CC(OC)C(O)CC3N1C2 MKYLOMHWHWEFCT-UHFFFAOYSA-N 0.000 description 1
- SNFRINMTRPQQLE-JQWAAABSSA-N Montanin Chemical compound O[C@H]([C@@]1(CO)O[C@H]1[C@H]1[C@H]2O3)[C@]4(O)C(=O)C(C)=C[C@H]4[C@]11OC3(CCCCCCCCCCC)O[C@@]2(C(C)=C)C[C@H]1C SNFRINMTRPQQLE-JQWAAABSSA-N 0.000 description 1
- SNFRINMTRPQQLE-OFGNMXNXSA-N Montanin Natural products O=C1[C@@]2(O)[C@@H](O)[C@@]3(CO)O[C@H]3[C@@H]3[C@H]4[C@@]5(C(=C)C)O[C@](CCCCCCCCCCC)(O4)O[C@@]3([C@H](C)C5)[C@@H]2C=C1C SNFRINMTRPQQLE-OFGNMXNXSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- QTZPBQMTXNEKRX-UHFFFAOYSA-N Voacristine pseudoindoxyl Natural products N1C2=CC=C(OC)C=C2C(=O)C21CCN(C1)C3C(C(C)O)CC1CC32C(=O)OC QTZPBQMTXNEKRX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical group 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- TVZIWRMELPWPPR-UHFFFAOYSA-N n-(2-methylphenyl)-3-oxobutanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C TVZIWRMELPWPPR-UHFFFAOYSA-N 0.000 description 1
- WNWZKKBGFYKSGA-UHFFFAOYSA-N n-(4-chloro-2,5-dimethoxyphenyl)-2-[[2,5-dimethoxy-4-(phenylsulfamoyl)phenyl]diazenyl]-3-oxobutanamide Chemical compound C1=C(Cl)C(OC)=CC(NC(=O)C(N=NC=2C(=CC(=C(OC)C=2)S(=O)(=O)NC=2C=CC=CC=2)OC)C(C)=O)=C1OC WNWZKKBGFYKSGA-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000004170 rice bran wax Substances 0.000 description 1
- 235000019384 rice bran wax Nutrition 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 238000007651 thermal printing Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The present invention relates to a kind of heat-transfer color ribbon and its making process. The color ribbon includes one heat-transfer layer coated to the base belt comprising waxy material in 10-85 portions, resin 20-40 portions, assistant 0.5-15 portions and coloring agent 10-40 portions. During its preparation, the coloring agent and assistant are compounded and mixed in a three-roller mixer; the waxy material, resin and solvent are mixed; all the above-said material are mixed in the three-roller mixer and dispersed in a dispersing machine while adding solvent; and the mixture as heat-transfer paint is finally painted to a polyester film. The heat-transfer color ribbon of the present invention has excellent transfer performance.
Description
The present invention relates to a kind of colour band that is used for contactless thermal transfer printer, particularly a kind of heat transfer colour ribbon and preparation method thereof.
Along with developing rapidly of computer technology and application thereof, the feature of multiple class, high-performance and professional purpose has also appearred as the printer of computer peripheral equipment output equipment.Thermal transfer printer is the very high special printer of occupation rate of market, and its principle is that nineteen fifty-three Miller proposes, and along with the development of microelectric technique, photoetching technique, electrothermal semiconductor Element Technology, appears on the market to the existing ripe product of the nineties.Its operation principle is that signal drives the heating dot matrix on the heat-transferring head, and heat reaches hot transfer printing functional layer by base material and its fusion transferred to be subjected on the picture medium.Colour band is a black, can export the image or the literal of black and white.Hot transfer printing printing type has moderate cost, and print quality is good, and speed is fast, to the paper no requirement (NR), and non-fading advantage is widely used in fields such as certificate printing, ticket, IC-card, bar code and facsimile machine.High-quality thermal transfer ribbon heated portion after transfer printing does not have heat and shifts black residue, and mostly is disposable use greatly, thereby the thermal transfer ribbon after using is then for future reference as counterfoil in railway ticket department.
Heat transfer colour ribbon is the core devices of thermal transfer imaging, also is consumable material.
United States Patent (USP) 4,273,602 disclose a kind of colour band that is made of matrix and heat-sensitive substance, but the contrast of its image is not enough.
Chinese patent CN1052450a discloses a kind of thermal-printing thin film that hot transfer printing is used on the nonabsorbable object plane, but it does not solve the adhesive force problem of ink lay and base band, and ink lay can fall down en bloc.
The objective of the invention is provides a kind of ink lay and matrix adhesive force strong for the deficiency that solves above-mentioned technical existence, and transfer printing is highly sensitive, picture contrast height, clear-cut heat transfer colour ribbon and preparation method thereof.
In order to achieve the above object, the heat transfer colour ribbon of the present invention's design, it comprises the thermal transfer layer that applies on the base band, thermal transfer layer mainly is made up of 10 to 85 parts of waxs, 20 to 40 parts of resins, 0.5 to 15 part of auxiliary agent and 10 to 40 parts of colouring agents.
Described 10 to 40 parts of colouring agents can be dyestuffs, also can be pigment.When making colouring agent with pigment, this colouring agent can be a kind of microencapsulation colouring agent that is coated with the one layer of polymeric film.Used pigment has:
Black: carbon black, nigrosine,
Cyan: phthalocyanine blue, phthalocyanine green,
Pinkish red: permanent bordeaux 2B, permanent bordeaux 7B, Lithol Red, fuchsin 6B,
Yellow: benzidine yellow 2G, benzidine yellow 10G, permanent yellow GT, permanent yellow FGL, permanent yellow 2GS, benzidine yellow AAOT.
The Microencapsulation Method of microencapsulation colouring agent adopts flocculence, that is, with high-speed mixer pigment is uniformly dispersed in polymer solution at normal temperatures, progressively drips the flocculant of polymer subsequently, filters, drying, pigment that must microencapsulation.Used polymer is: polystyrene, ethene-vinyl acetate (EVA) copolymer, Merlon, polyamide, polyvinyl alcohol, PVP etc.
Described 10 to 85 parts wax can be a kind of wax, and this wax comprises animal wax, vegetable wax, mineral wax or synthetic wax; This wax comprises higher aliphatic, higher fatty acids, and particularly: said wax or wax are animal wax such as beeswax, river wax, insect wax, spermaceti; Vegetable wax such as brazil wax, candelila wax, rice bran wax, sugarcane wax; Mineral wax if you would dawn wax, paraffin, ceresine: synthetic wax such as Tissuemat E, OPE, F-T wax, S wax, OP wax, O wax; Higher fatty acids such as laurate, myristic acid, palmitic acid, stearic acid, mountain Yu's acid; Higher aliphatic is as 18 alcohol, docosanol etc.The fusing point of employed wax or wax should be lower than 200 ℃, preferably 40-130 ℃.Shared ratio is 10-85%;
Described 20 to 40 parts of resins can be a kind of thermoplastic resins, this thermoplastic resin can strengthen the adhesive strength of hot transfer printing functional layer and tape base, prevent that it from coming off, one or more form used thermoplastic resin by polyamide, ethene-vinyl acetate (EVA) resin, AS resin, modified poly ester (SYPD2000 resin), polystyrene resin, SB, polyvinyl acetate resins etc.
Said 0.5 to 15 part of auxiliary agent comprises dispersant, glazing agent, plasticizer, said dispersant is rosin, surfactant such as positive surfactant, cloudy surfactant and non-surface-active agent, said glazing agent is for transferring essential oil, atoleine, vegetable oil, silicone oil, glycerine, and said plasticizer is compositions such as DOP.
Described base band is 3 to 6 microns a polyester film of biaxial tension.The base material of the thermal transfer ribbon that the present invention uses is the polyester film of 3-50 micron, more preferably 3 to 6 microns polyester film preferably.
The thickness of described thermal transfer layer is 2 to 5 microns.
The production method of the heat transfer colour ribbon of the present invention's design, be earlier colouring agent to be mixed on three-roller in the ratio preparation back of determining with auxiliary agent, again wax and resin are prepared solvent back and definite ratio in proportion, fully mix on three-roller with colouring agent, auxiliary agent again, transfer on the dispersion machine, add the solvent of determining ratio and carry out high speed dispersion, become the required definite viscosity of coating machine coating, will determine that by coating machine the thermal transfer layer coating of viscosity coats on definite polyester film then.
Heat transfer colour ribbon of the present invention is when making, earlier thermal transfer layer material and solvent are made into thermal transfer layer coating, coat again on definite polyester film, used solvent is aromatic compound such as toluene, dimethylbenzene, ketone such as acetone, butanone, cyclohexanone, chlorohydrocarbon such as carrene, dichloroethanes, trichloroethanes, isopropyl alcohol, oxolane, used amount is 0.5 to 4 times of thermal transfer layer quantity of material.
Heat transfer colour ribbon is the most common form of heat transfer media.The most heat transfer colour ribbon of determining is to adopt polyester (PET) film as its base material, and the thermal transfer layer coated generally scribbles the back coating of protection in the one side of polyester (PET) film substrate at the another side of polyester (PET) film substrate.Back coating will directly contact with hot transfer head.The advantage of not using back coating is to make manufacturing process simple, and the reduction expense can make to penetrate the only thermal capacity increase of thermal transfer layer simultaneously.Thermal transfer layer is the core of heat transfer colour ribbon, and its performance directly influences the fast light erasibility that shines property, trace of the color of transfer printing temperature, lettering quality, colour band, cold-resistant hot property, trace definition, trace, and the serviceability temperature of colour band is determined by it.Clear, the fast light photograph of heat transfer colour ribbon trace, wear-resisting wiping, cold-resistant good in thermal property, the look that the present invention obtains bright-coloured, and it has very active operation significance to the development of hot transfer printing.
Fig. 1 is the sectional view of heat transfer colour ribbon.
The present invention is further described by the following embodiment, and wherein " part " is parts by weight.
Embodiment 1
Normal temperature is uniformly dispersed carbon black in the toluene solution of polystyrene with high-speed mixer down, progressively drips methyl alcohol subsequently, filters, drying, carbon black that must microencapsulation.
10 parts of encapsulated carbon blacks, 2 parts glycerine were mixed on three-roller 0.5 hour with 10 parts dimethylbenzene, again with 10 parts brazil wax, 10 parts 58 degree paraffin, 10 parts rosin, 5 parts ethene-vinyl acetate (EVA) copolymer, 5 parts polyamide (PA) with after 10 parts dimethylbenzene mixes, after last three-roller and carbon black, auxiliary agent are mixed together 1-12 hour, be transferred to dispersion machine, add part 10 toluene and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.
Embodiment 2
10 parts carbon blacks, 5 parts glycerine were mixed on three-roller 0.5 hour with 10 parts dimethylbenzene, again with 5 parts brazil wax, 10 parts the rosin, 10 parts EVA, 5 parts PA of 10 parts of 58 degree paraffin resins with after 10 parts dimethylbenzene mixes, after last three-roller and carbon black, auxiliary agent are mixed together 1-12 hour, be transferred to dispersion machine, add part 10 toluene and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.
Embodiment 3
10 parts phthalocyanine blues, 2 parts dioctyl phthalate (DOP) were mixed on three-roller 0.5 hour with 10 parts dimethylbenzene, again with 5 parts brazil wax, 10 parts 58 degree paraffin, 10 parts rosin, 10 parts EVA, 5 parts PA with after 10 parts dimethylbenzene mixes, after last three-roller and phthalocyanine blue, auxiliary agent are mixed together 1-12 hour, be transferred to dispersion machine, add part 10 toluene and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.
Embodiment 4
12 parts permanent bordeaux 2B, 5 parts glycerine were mixed on three-roller 0.5 hour with 15 parts dimethylbenzene, again with 15 parts brazil wax, 10 parts rosin, 10 parts EVA, 5 parts PA with after 10 parts dimethylbenzene mixes, after last three-roller and permanent bordeaux 2B, auxiliary agent are mixed together 1-12 hour, be transferred to dispersion machine, add part 10 oxolanes and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.Embodiment 5
12 parts benzidine yellow 2G, 5 parts glycerine were mixed on three-roller 0.5 hour with 15 parts dimethylbenzene, again with 15 parts brazil wax, 10 parts rosin, 10 parts EVA, 5 parts PA with after 10 parts dimethylbenzene mixes, after last three-roller and benzidine yellow 2G, auxiliary agent are mixed together 1-12 hour, be transferred to dispersion machine, add part 10 oxolanes and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.
Embodiment 6
Normal temperature is uniformly dispersed phthalocyanine green in the toluene solution of Merlon with high-speed mixer down, progressively drips methyl alcohol subsequently, filters, drying, phthalocyanine green that must microencapsulation.
The phthalocyanine green of 40 parts microencapsulations, 0.5 part accent essential oil were mixed on three-roller 0.5 hour with 15 parts dimethylbenzene, again with 60 parts 50 degree paraffin, 10 parts rosin, 10 parts EVA resin, 5 parts modified poly ester (SYPD2000 resin) with after 10 parts dimethylbenzene mixes, after the phthalocyanine green of last three-roller and microencapsulation, auxiliary agent are mixed together 1-12 hour, be transferred to dispersion machine, add part 10 oxolanes and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.
Embodiment 7
Normal temperature is uniformly dispersed Lithol Red in the toluene solution of Merlon with high-speed mixer down, progressively drips methyl alcohol subsequently, filters, drying, Lithol Red that must microencapsulation.The Lithol Red of 8 parts of microencapsulations, 5 parts accent essential oil were mixed on three-roller 0.5 hour with 15 parts dimethylbenzene, again with 60 parts 50 degree paraffin, 10 parts rosin, 10 parts EVA resin, 5 parts SYPD2000 resin with after 10 parts dimethylbenzene mixes, after the Lithol Red of last three-roller and microencapsulation, auxiliary agent are mixed together 1-12 hour, be transferred to dispersion machine, add 10 parts of dimethylbenzene and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.
Embodiment 8
Normal temperature is dispersed in permanent yellow FG in the toluene solution of Merlon with high-speed mixer down, progressively drips methyl alcohol subsequently, filters, drying, permanent yellow FG that must microencapsulation.The permanent yellow FG of 8 parts of microencapsulations, 2 parts silicone oil were mixed on three-roller 0.5 hour with 15 parts dimethylbenzene, again with 10 parts Tissuemat E, 10 parts montanin wax, 15 parts stearic acid, 10 parts rosin, 10 parts EVA resin, 5 parts SYPD2000 resin with after 10 parts dimethylbenzene mixes, after the permanent yellow FG of last three-roller and microencapsulation, auxiliary agent are mixed together 8 hours, be transferred to dispersion machine, add 10 parts of dimethylbenzene and carry out high speed dispersion, hot transfer printing functional layer coating accent is rare, last coating machine coating.
Claims (10)
1, a kind of heat transfer colour ribbon, it comprises the thermal transfer layer (2) that base band (1) go up to apply, and it is characterized in that described thermal transfer layer (2) mainly is made up of 10 to 85 parts of waxs, 20 to 40 parts of resins, 0.5 to 15 part of auxiliary agent and 10 to 40 parts of colouring agents.
2, heat transfer colour ribbon according to claim 1 is characterized in that described colouring agent is a kind of microencapsulation colouring agent that is coated with the one layer of polymeric film.
3, heat transfer colour ribbon according to claim 1 and 2 is characterized in that described 10 to 60 parts wax can be a kind of wax
4, heat transfer colour ribbon according to claim 1 and 2 is characterized in that described base band (1) is 3 to 6 microns a polyester film of biaxial tension.
5, heat transfer colour ribbon according to claim 3 is characterized in that described base band (1) is 3 to 6 microns a polyester film of biaxial tension.
6, heat transfer colour ribbon according to claim 1 and 2, the thickness that it is characterized in that described thermal transfer layer (2) are 2 to 5 microns.
7, heat transfer colour ribbon according to claim 3, the thickness that it is characterized in that described thermal transfer layer (2) are 2 to 5 microns.
8, heat transfer colour ribbon according to claim 4, the thickness that it is characterized in that described thermal transfer layer (2) are 2 to 5 microns.
9, heat transfer colour ribbon according to claim 5, the thickness that it is characterized in that described thermal transfer layer (2) are 2 to 5 microns.
10, a kind of production method of heat transfer colour ribbon, it is characterized in that earlier colouring agent being mixed on three-roller in the ratio preparation back of determining with auxiliary agent, again wax and resin are prepared solvent back and definite ratio in proportion, fully mix on three-roller with colouring agent, auxiliary agent again, transfer on the dispersion machine, add the solvent of determining ratio and carry out high speed dispersion, become the required definite viscosity of coating machine coating, will determine that by coating machine the thermal transfer layer coating of viscosity coats on definite polyester film then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00127292 CN1128064C (en) | 2000-11-07 | 2000-11-07 | Heat transfer colour ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00127292 CN1128064C (en) | 2000-11-07 | 2000-11-07 | Heat transfer colour ribbon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1351933A true CN1351933A (en) | 2002-06-05 |
| CN1128064C CN1128064C (en) | 2003-11-19 |
Family
ID=4592308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00127292 Expired - Lifetime CN1128064C (en) | 2000-11-07 | 2000-11-07 | Heat transfer colour ribbon |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1128064C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101837690A (en) * | 2010-05-31 | 2010-09-22 | 焦作市卓立烫印材料有限公司 | Mixed base bar code printing thermal transfer ribbon and preparation method thereof |
| CN101049773B (en) * | 2006-08-17 | 2011-01-05 | 杭州兴甬复合材料有限公司 | Heat blocking film |
| CN102211478A (en) * | 2011-04-02 | 2011-10-12 | 泉州市山水电脑耗材有限公司 | Thermal transfer wax ribbon |
| CN102616024A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Heat-transfer wax-based carbon ribbon |
| CN109808395A (en) * | 2019-01-10 | 2019-05-28 | 浙江晶通塑胶有限公司 | A kind of coloring process of plastic floor groove |
-
2000
- 2000-11-07 CN CN 00127292 patent/CN1128064C/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101049773B (en) * | 2006-08-17 | 2011-01-05 | 杭州兴甬复合材料有限公司 | Heat blocking film |
| CN101837690A (en) * | 2010-05-31 | 2010-09-22 | 焦作市卓立烫印材料有限公司 | Mixed base bar code printing thermal transfer ribbon and preparation method thereof |
| CN101837690B (en) * | 2010-05-31 | 2012-08-29 | 焦作市卓立烫印材料有限公司 | Mixed base bar code printing thermal transfer ribbon and preparation method thereof |
| CN102211478A (en) * | 2011-04-02 | 2011-10-12 | 泉州市山水电脑耗材有限公司 | Thermal transfer wax ribbon |
| CN102616024A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Heat-transfer wax-based carbon ribbon |
| CN102616024B (en) * | 2012-03-28 | 2015-06-24 | 河南卓立膜材料股份有限公司 | Heat-transfer wax-based carbon ribbon |
| CN109808395A (en) * | 2019-01-10 | 2019-05-28 | 浙江晶通塑胶有限公司 | A kind of coloring process of plastic floor groove |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1128064C (en) | 2003-11-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1206112C (en) | Thermal transfer printing ribbon, and its prodn, art | |
| EP0205567A1 (en) | Thermal transfer ink formulation and medium. | |
| JPH0694232B2 (en) | Method for manufacturing heat transfer sheet for sublimation transfer recording | |
| CN113771520B (en) | Structural color thermal sensitive paper based on thermochromic photonic crystals and preparation and application thereof | |
| CN1128064C (en) | Heat transfer colour ribbon | |
| CN111845134A (en) | Water-based color-changeable thermal transfer ribbon and manufacturing method thereof | |
| US5546114A (en) | Systems and methods for making printed products | |
| US4960632A (en) | Thermal transfer material | |
| CN1280920A (en) | Reversible thermosensitive display material and its preparing process | |
| JPS63222892A (en) | Thermal transfer material | |
| CN115447304A (en) | Resin thermal transfer ribbon for thermal transfer printing and preparation method thereof | |
| JPS62122790A (en) | Color ink sheet for thermal transfer | |
| JP2722466B2 (en) | Thermal transfer recording material | |
| JPS6061290A (en) | Thermal transfer recording medium | |
| CA2193023A1 (en) | Thermo-transfer ribbon | |
| KR200417096Y1 (en) | transfer paper | |
| JP2726928B2 (en) | Resin-type thermal transfer recording material | |
| JP2001322360A (en) | Melt type thermal transfer ink ribbon, printed product and printer | |
| JPH06312567A (en) | Thermal transfer recording medium | |
| JP3623280B2 (en) | Binder for thermal transfer layer, thermal transfer ink ribbon, and thermal transfer method | |
| KR100590358B1 (en) | Thermal recording material | |
| JPS6270088A (en) | Thermal transfer ink | |
| JPS6094386A (en) | Thermal transfer recording medium | |
| JPH02155692A (en) | Thermal transfer recording medium | |
| JPS63319189A (en) | Thermal transfer recording sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: HANGZHOU TIANDI DIGITAL SCIENCE CO., LTD. Free format text: FORMER OWNER: PAN PUDUN; CHEN BOCHUAN Effective date: 20080509 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20080509 Address after: Building five, hi tech software park, Zhijiang hi tech Industrial Park, Zhejiang, Hangzhou: 310053 Patentee after: Hangzhou Todaytec Digital Co., Ltd. Address before: Zhejiang Province, Hangzhou City, Zhejiang Province, swing dormitory 4-3 - 501, zip code: 310013 Co-patentee before: Chen Bochuan Patentee before: Pan Pu town |
|
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: Hangzhou City, Zhejiang province 311106 Xinlu Kang Linping Qianjiang Economic Development Zone No. 600 Patentee after: Hangzhou Todaytec Corporation Address before: 310053 building, five hi tech software park, Zhijiang science and Technology Industrial Zone, Hangzhou hi tech Zone, Zhejiang Patentee before: Hangzhou Todaytec Digital Co., Ltd. |
|
| CX01 | Expiry of patent term |
Granted publication date: 20031119 |
|
| CX01 | Expiry of patent term |