KR200417096Y1 - transfer paper - Google Patents

transfer paper Download PDF

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Publication number
KR200417096Y1
KR200417096Y1 KR2020060004687U KR20060004687U KR200417096Y1 KR 200417096 Y1 KR200417096 Y1 KR 200417096Y1 KR 2020060004687 U KR2020060004687 U KR 2020060004687U KR 20060004687 U KR20060004687 U KR 20060004687U KR 200417096 Y1 KR200417096 Y1 KR 200417096Y1
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South Korea
Prior art keywords
weight
color
layer
luminous
transfer paper
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KR2020060004687U
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Korean (ko)
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김동현
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김동현
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42—Intermediate, backcoat, or covering layers
    • B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
    • B41M5/443—Silicon-containing polymers, e.g. silicones, siloxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/50—Sympathetic, colour changing or similar inks

Abstract

본 고안은 티셔츠, 모자, 신발, 내의류, 홈패션류, 가방, 축구공, 문구팬시류 등에 전면 또는 부분적으로 적용한 원색그림, 글자, 도형 등이 어두운 실내에서는 칼라야광으로 나타나고, 밝은 실외로 나가게 되면 다양한 칼라로 변색되는 광호환 변색 칼라야광 전사지의 제조방법에 관한 고안으로서, 상면에 이형제 코팅층과 실리콘 투명층 및 색상 잉크층과 불투명 백색층, 접착층을 순차적으로 형성한 원단에 있어서, 상기 실리콘 투명층과 색상 잉크층의 사이에는 칼라 야광층을 더 형성하고, 상기 칼라 야광층의 상측에는 광호환 변색층을 더 형성하는 것을 특징으로 한다.The present invention appears in color luminous in dark interiors such as T-shirts, hats, shoes, underwear, home fashions, bags, soccer balls, stationery fancy, etc. The invention relates to a method for producing a photochromic color-colored luminous transfer paper which is discolored in color, wherein the silicone transparent layer and the color ink are formed in a fabric in which a release agent coating layer, a silicone transparent layer, a color ink layer, an opaque white layer, and an adhesive layer are sequentially formed on an upper surface thereof. A color luminous layer is further formed between the layers, and a photocompatible color change layer is further formed on the color luminous layer.

따라서, 본 고안은 피전사에 전사된 원색그림, 글자, 도형 등의 색상이 어두운 실내 또는 햇빛이 없는 곳에서 실내 또는 햇빛이 있는 곳으로 이동할 시, 다양한 색상으로 변색이 되는 것은 물론, 야간에도 의류에 인쇄된 문자 및 그림 등의 보여지도록 함으로써, 다양한 상품에 사용하여 시각적인 만족도를 극대화할 수 있는 매우 유용한 고안이다.Therefore, the present invention is a color of the primary picture, letters, shapes, etc. transferred to the transfer, when moving from the dark room or the place without sunlight to the room or the place where the sunlight, as well as discolored in various colors, clothing at night By showing the printed characters and pictures, etc., it is a very useful design that can be used for various products to maximize the visual satisfaction.

변색, 칼라, 야광, 전사지 Discoloration, color, luminous, transfer paper

Description

광호환 변색 칼라야광 전사지{transfer paper}Photochromic color-colored luminous transfer paper {transfer paper}

도 1은 일반적인 전사지의 일부 절결 확대 단면도1 is a partially cut-away enlarged cross-sectional view of a typical transfer paper.

도 2a는 본 고안에 따른 광호환 변색층 또는 칼라 야광층이 부분적으로 형성된 상태의 전사지 일부 절결 확대 단면도Figure 2a is a partially cut-out enlarged cross-sectional view of the transfer paper in a state where the photo-compatible color change layer or color luminous layer is formed in accordance with the present invention

도 2b는 본 고안에 따른 광호환 변색층 또는 칼라 야광층이 전체적으로 형성된 상태의 전사지 일부 절결 확대 단면도Figure 2b is an enlarged cross-sectional view of a portion of the transfer paper in a state where the photo-compatible color change layer or the color luminous layer is formed as a whole

도 3은 본 고안에 따른 광호환 변색층과 칼라 야광층이 동시에 전체적으로 형성된 상태의 전사지 일부 절결 확대 단면도3 is a partially cut-away enlarged cross-sectional view of the transfer paper in a state where the photochromic discoloration layer and the color luminous layer are formed at the same time.

도 4는 본 고안에 따른 광호환 변색 칼라야광 전사지의 배면 예시도Figure 4 is an illustration of the back of the photochromic color-colored luminous transfer paper according to the present invention

도 5a는 본 고안에 따른 광호환 변색층을 피전사체에 부분적으로 전사한 상태에서 주간(밝은 실외)에서 보았을 때의 예시도Figure 5a is an exemplary view when viewed in the daytime (bright outdoors) in a state in which the photo-compatible color change layer according to the present invention partially transferred to the transfer target

도 5b는 본 고안에 따른 광호환 변색층을 피전사체에 전체적으로 전사한 상태에서 주간(밝은 실외)에서 보았을 때의 예시도Figure 5b is an exemplary view when viewed in the daytime (bright outdoor) in the state in which the photochromic discoloration layer according to the present invention is entirely transferred to the transfer target

도 6a는 본 고안에 따른 칼라 야광층을 피전사체에 부분적으로 전사한 상태에서 야간(어두운 실내)에서 보았을 때의 예시도Figure 6a is an exemplary view when viewed at night (dark room) in a state in which the color luminous layer in accordance with the present invention partially transferred to the transfer target

도 6b는 본 고안에 따른 칼라 야광층을 피전사체에 전체적으로 전사한 상태 에서 야간(어두운 실내)에서 보았을 때의 예시도Figure 6b is an exemplary view when viewed at night (dark room) in the state in which the color luminous layer according to the present invention is transferred to the transfer object as a whole

＜도면의 주요부분에 대한 부호설명＞<Code Description of Main Parts of Drawing>

10 : 전사원지 11: 이형제 코팅층10: transcription base 11: release agent coating layer

12 : 실리콘 투명층 13 : 광호환 변색층12 silicon transparent layer 13 photocompatible color change layer

14 : 칼라 야광층 15 : 색상 잉크층14 color luminous layer 15 color ink layer

16 : 불투명 백색층 17 : 접착층 16: opaque white layer 17: adhesive layer

20 : 피전사체20: subject

본 고안은 광호환 변색 칼라야광 전사지에 관한 것으로서, 특히 티셔츠, 모자, 신발, 내의류, 홈패션류, 가방, 축구공, 문구팬시류 등에 전면 또는 부분적으로 적용한 원색그림, 글자, 도형 등이 어두운 실내에서는 칼라야광으로 나타나고, 밝은 실외로 나가게 되면 다양한 칼라로 변색되는 광호환 변색 칼라야광 전사지에 관한 고안이다.The present invention relates to a photochromic color luminous transfer paper which is optically compatible, and particularly in a room where primary colors, letters, shapes, etc., which are completely or partially applied to T-shirts, hats, shoes, underwear, home fashions, bags, soccer balls, stationery fancy, etc. It is a design for a photo-compatible discolored color luminous transfer paper which appears as color luminous and changes color to various colors when going to a bright outdoor.

일반적으로 문자, 그림, 모양 등의 도안을 의류, 모자, 가방, 문구 등(이하, 피전사체라 함)에 표시 및 장식하기 위하여 전사지가 사용되고 있으며, 이러한 전사지는 종이 또는 플라스틱 필름의 지지체 상에 인쇄를 위한 다수의 층을 형성한 후 이를 피전사체의 표면에 가열 압착하여 전사한다.In general, transfer papers are used to display and decorate letters, drawings, shapes, etc. on clothing, hats, bags, stationery, etc. (hereinafter referred to as transfer subjects), which are printed on a support of paper or plastic film. After forming a plurality of layers for it is transferred by heat pressing on the surface of the transfer object.

특허공보 제95-4333호에는, “분산염료를 이용한 면직물용 전사지”가 기재되어 있으며, 이는 대지 위에 분산염료 인쇄층을 형성하고, 상기 분산염료 인쇄층 위에는 용융성 투명 유기질 왁스층을 형성하며, 유기질 왁스층 위에는 축광분말이 혼합된 투명우레탄 수지층을 피복하여 전사지를 구성한 다음, 그 전사지를 이용하여 전사 인쇄를 행한다.Patent Publication No. 95-4333 discloses "transfer paper for cotton fabric using a disperse dye", which forms a disperse dye printing layer on the earth, and forms a melt transparent transparent organic wax layer on the disperse dye printing layer, On the wax layer, the transparent urethane resin layer mixed with the phosphorescent powder is coated to form a transfer paper, and then transfer printing is performed using the transfer paper.

그러나, 상기와 같은 방법은 분산염료 인쇄층과 투명우레탄 수지층 사이에 유기질 왁스층이 형성되어 있는 3단구조를 가지고 있어서 야광을 위한 구조가 복잡하고, 상기 전사지의 하부 또는 가장자리에 부분적으로 야광층이 인쇄됨으로 인해 야광효과가 상당부분 감소되는 문제점이 있었다. However, the above method has a three-stage structure in which an organic wax layer is formed between the disperse dye printing layer and the transparent urethane resin layer, so that the structure for luminous is complicated, and the luminous layer is partially at the bottom or the edge of the transfer paper. There was a problem that the luminous effect is substantially reduced due to the printing.

또한, 특허공개공보 제2000-0059326호에는 유리나 필름 코팅재인 “광발색형 코팅재”에 관한 기술이 제시되어 있으며, 이는 햇빛(자외선)을 받으면 발색되어 일정량의 햇빛이 차단되고, 햇빛을 받지 않으면 가역적으로 다시 투명해져 광선을 모두 투과시키는 광호변성, 포토크로믹 코팅재이다. 특히, 포토크로믹화합물을 모노머에 첨가하여 중합하는 방법, 포토크로믹 화합물을 직접 고분자에 섞어서 용융성형하는 방법, 포토크로믹화합물을 고분자로 마이크로 캡슐화하여 포토크로믹 캡슐잉크를 제조하는 방법이 기재되어 있는데, 상기와 같이 화합물을 이용한 방법은 마이크로 단위의 포토크로믹 화합물을 중합, 용융성형, 캡슐레이션하여 코팅제로 사용함에 일조량에 따른 내구성 부족, 균일화된 상품제조, 안정적인 코팅제를 만들 수 없는 단점이 있었다. 또한, 안료타입의 마이크로 포토크로믹 화합물을 5％~10％ 정도 투입하므로 물성이 변질되어, 햇빗 차단시 종전의 색상으로 되돌아오는데 시간이 오래 걸리는 문제점도 있었다.In addition, Japanese Patent Application Laid-Open No. 2000-0059326 discloses a technology related to a "photochromic coating material", which is a glass or film coating material, which is colored when it receives sunlight (ultraviolet rays), blocks a certain amount of sunlight, and reversible when it does not receive sunlight. This is a photochromic, photochromic coating material that becomes transparent again and transmits all light rays. In particular, a method of adding a photochromic compound to a monomer to polymerize, a method of directly mixing a photochromic compound with a polymer, and molding the polymer, and a method of preparing a photochromic capsule ink by microencapsulating the photochromic compound into a polymer are described. However, the method using the compound as described above has the drawbacks of lack of durability, uniform product manufacturing, and stable coating agent according to the amount of sunlight due to polymerization, melt molding, encapsulation of the micro unit of the photochromic compound used as a coating agent there was. In addition, since about 5% to 10% of the pigment-type micro photochromic compound is added, physical properties are deteriorated, and there is a problem that it takes a long time to return to the previous color at the time of blocking the hatbit.

따라서, 본 고안은 다양한 색상으로 인쇄된 실제의 무늬가 햇빛(자외선)의 농도에 따라 색상이 달리 변색되도록 하며, 야간에도 보일 수 있도록 하는 것은 물론, 내구성이 좋으면서도 햇빛에 대응하는 속도가 양호한 광호환 변색 칼라야광 전사지를 제공하는데 목적이 있다.Therefore, the present invention allows the actual pattern printed in various colors to be discolored according to the concentration of sunlight (ultraviolet rays), so that it can be seen at night, as well as good durability and good speed to respond to sunlight The purpose is to provide a compatible color fading color luminous transfer paper.

본 고안은 상면에 이형제 코팅층과 실리콘 투명층 및 색상 잉크층과 불투명 백색층, 접착층을 순차적으로 형성한 원단에 있어서, 상기 실리콘 투명층과 색상 잉크층의 사이에는 칼라 야광층을 더 형성하고, 상기 칼라 야광층의 상측에는 광호환 변색층을 더 형성하는 것을 특징으로 한다.In the present invention, a release agent coating layer, a silicon transparent layer, a color ink layer, an opaque white layer, and an adhesive layer are sequentially formed on a top surface, and a color luminous layer is further formed between the silicon transparent layer and the color ink layer. On the upper side of the layer is characterized by further forming a photo-compatible color change layer.

또한, 본 고안의 칼라 야광층은 폴리에스테르 수지 15중량％와, 이소포론 15중량％와, 건조지연제 3중량％와, 디옥틸프탈레이트(DOP) 4.8중량％와, 1~5마이크론의 칼라 축광안료 16중량％와, 분산제 0.1중량％와, 습윤제 0.1중량％를 혼합하여 제분기에서 1시간 밀링작업을 하는 단계와; 다시 메틸 이소부틸케톤(MIBK) 27중량％와, 40％의 염화파라핀 용액 3중량％와, 폴리에스테르 수지 3중량％와, 폴리우레탄 수지 2중량％와, 크실렌 8중량％와, 사이크로헥사논(Cyclohexanone) 3중량％를 혼합하여 2시간 동안 밀링하는 단계;로 이루어지는 것을 특징으로 한다.In addition, the color luminous layer of the present invention is 15% by weight of polyester resin, 15% by weight of isophorone, 3% by weight of drying retardant, 4.8% by weight of dioctylphthalate (DOP), and color luminous flux of 1 to 5 microns. Mixing 16% by weight of the pigment, 0.1% by weight of the dispersant, and 0.1% by weight of the humectant, and milling for 1 hour in a mill; Again 27 wt% methyl isobutyl ketone (MIBK), 3 wt% 40% paraffin chloride solution, 3 wt% polyester resin, 2 wt% polyurethane resin, 8 wt% xylene, and cyclohexanone (Cyclohexanone) 3% by weight of the mixing step of milling; characterized in that consisting of.

그리고, 본 고안은 상면에 이형제 코팅층과 실리콘 투명층 및 색상 잉크층과 불투명 백색층, 접착층을 순차적으로 형성한 원단에 있어서, 상기 층과 층의 사이 에는 광호환 변색층을 더 형성하는 것을 특징으로 한다.In addition, the present invention is characterized in that in the fabric formed by sequentially forming a release agent coating layer, a silicon transparent layer, a color ink layer, an opaque white layer, an adhesive layer on the upper surface, between the layer and the layer is characterized by further forming a photo-compatible color change layer .

아울러, 상기 광호환 변색층은, 톨루엔 5중량％에 200나노 광호환 변색 분산염료 0.01중량％를 분산 용해시키는 단계와; 폴리에스테르 수지 3중량％와 폴리우레탄 수지 2중량％와 메틸 이소부틸케톤(MIBK) 27중량％와 40％의 염화파라핀 용액 3중량％와 건조지연제 2중량％와 이소포론 12.8중량％를 혼합하여 제분기에서 1시간 동안 교반하는 단계와; 사이크로헥사논(Cyclohexanone) 25중량％와 폴리에스테르 수지 15중량％와 폴리우레탄 수지 5중량％와 색분리방지제 0.19중량％를 혼합하고 2시간 동안 교반하는 단계;로 이루어지는 것을 특징으로 한다.In addition, the photochromic discoloration layer, dispersing and dissolving 0.01% by weight of 200 nanophotochromic disperse dyes in 5% by weight of toluene; 3% by weight of polyester resin, 2% by weight of polyurethane resin, 27% by weight of methyl isobutyl ketone (MIBK), 3% by weight of 40% paraffin chloride solution, 2% by weight of drying retardant, and 12.8% by weight of isophorone Stirring in the mill for 1 hour; And mixing 25% by weight of cyclohexanone, 15% by weight of polyester resin, 5% by weight of polyurethane resin, and 0.19% by weight of color separation inhibitor and stirring for 2 hours.

이하, 본 고안의 가장 바람직한 일실시예의 구성을 첨부한 도면에 의거하여 상세히 설명하면 다음과 같다.Hereinafter, with reference to the accompanying drawings, the configuration of the most preferred embodiment of the present invention in detail as follows.

본 고안은 전사원지(20)의 위에 이형제 코팅층(11)을 형성하고, 그 위에는 실리콘 투명층(12)을 형성하며, 실리콘 투명층(12) 위에는 칼라 야광층(14) 또는 광호환 변색층(13)을 형성하고, 그 위에 색상 잉크층(15)과 불투명 백색층(16) 및 접착층(17)을 순서대로 형성한다. 물론, 상기 실리콘 투명층(12)과 색상 잉크층(15) 사이에 칼라 야광층(14)과 광호환 변색층(13)을 모두 형성하는 것도 가능하며, 상기 칼라 야광층(14)과 광호환 변색층(13)을 일부분 또는 전체적으로 형성하는 것도 가능하다.The present invention forms a release agent coating layer 11 on the transfer paper 20, a silicon transparent layer 12 is formed thereon, a color luminous layer 14 or a photo-compatible color change layer 13 on the silicon transparent layer 12 And the color ink layer 15, the opaque white layer 16, and the adhesive layer 17 are sequentially formed thereon. Of course, it is also possible to form both the color luminous layer 14 and the photochromic discoloration layer 13 between the silicon transparent layer 12 and the color ink layer 15, and the color luminous layer 14 and the photochromic discoloration It is also possible to form part 13 in whole or in part.

본 고안의 이형제 코팅층(11)은 유효성분함량 45％인 실리콘폴리머 100중량％에 톨루엔과 사이크로헥사논 (Cyclohexanone)을 1 : 1비율로 혼합한 용제 500~600중량％정도 혼합하여 희석한 후, 실록산폴리머 1중량％와 촉매(수석계 유기물) 2중량％와 지류보호제 3중량％를 첨가 혼합하여 실크인쇄 또는 그라비아 인쇄한후 110℃에서 5~10초간 건조 경화시켜 형성한다.The release agent coating layer 11 of the present invention was diluted by mixing about 500-600% by weight of a solvent in which the toluene and cyclohexanone were mixed at a ratio of 1: 1 by 100% by weight of the silicone polymer having an active ingredient content of 45%. It is formed by adding 1% by weight of siloxane polymer, 2% by weight of catalyst (sensitivity organic material), and 3% by weight of tributary protective agent by silk or gravure printing, followed by dry curing at 110 ° C. for 5 to 10 seconds.

그리고, 상기 실리콘 투명층(12)은 메틸 이소부틸케톤(MIBK) 28중량％와 40％의 염화파라핀 용액 3중량％와 이소포론 12중량％, 그리고, 사이크로헥사논 (Cyclohexanone) 33중량％와 폴리에스테르 수지 15중량％와 폴리우레탄 수지 7중량％를 혼합하고 2시간 동안 교반하여 얻는다.The silicon transparent layer 12 is composed of 28% by weight of methyl isobutyl ketone (MIBK), 3% by weight of 40% paraffin chloride solution, 12% by weight of isophorone, 33% by weight of cyclohexanone and poly 15 weight% of ester resin and 7 weight% of polyurethane resin are mixed and obtained by stirring for 2 hours.

또한, 상기 칼라 야광층(14)은 1~5마이크론의 축광안료를 색상 분산염료에 혼합하여 착색시켜 폴리에스테르수지(SCHATTI사의 Copolyester 376)를 공중합하여 야간에도 칼라가 인식되도록 하며, 색상 잉크층(이 인쇄되는 실리콘 투명층에 인쇄하면 밝은 주간에 보았던 피인쇄물의 색상과 더불어 실제의 피인쇄물이 야간에도 야광의 효과와 함께 인식할 수 있게 되며, 접착시 공지의 Co-PE핫멜트(SCHATTI사의 Copolyester 373)나 폴리우레탄(DACOTA사의 TPU8060)핫멜트 등의 접착수지로 130℃정도에서 5초~10초정도면 이형(박리)처리되어 면은 물론, 폴리에스테르 원단 및 나일론원단에 사용하기에 원활하게 된다.In addition, the color luminous layer 14 is mixed by coloring a 1-5 micron photoluminescent pigment in a color dispersion dye to copolymerize a polyester resin (Copolyester 376 Co., Ltd. of Schatti) so that color is recognized at night, color ink layer ( Printing on this printed silicone transparent layer allows the actual prints to be recognized with the luminous effect at night, as well as the color of the prints seen during the bright day, and known Co-PE hot melts at the time of bonding (Copolyester 373 from Schatti) B. Polyurethane (DAPUTA TPU8060) Hot Melt Adhesive Resin (released) for 5 ~ 10 seconds at 130 ° C for smooth cotton, as well as polyester fabric and nylon fabric.

이때, 상기 칼라 야광층(14)은 폴리에스테르 수지 15중량％에 이소포론 15중량％와, 건조지연제 3중량％와, 디옥틸프탈레이트(DOP) 4.8중량％와, 1~5마이크론의 칼라 축광안료 16중량％와, 분산제 0.1중량％와, 습윤제 0.1중량％를 혼합하여 제분기에서 1시간 밀링작업을 하고, 다시 메틸 이소부틸케톤(MIBK) 27중량％와, 40％의 염화파라핀 용액 3중량％와, 폴리에스테르 수지 3중량％와, 폴리우레탄 수지 2중량％와, 크실렌 8중량％와, 사이크로헥사논(Cyclohexanone) 3중량％를 혼합하여 2시간 동안 밀링하여 6마이크론이하의 혼합물을 얻는다.At this time, the color luminous layer 14 is 15% by weight of polyester resin, 15% by weight of isophorone, 3% by weight of drying retardant, 4.8% by weight of dioctylphthalate (DOP), and color luminous flux of 1 to 5 microns. 16% by weight of the pigment, 0.1% by weight of the dispersant, and 0.1% by weight of the wetting agent were mixed for 1 hour in the mill, and again 27% by weight of methyl isobutyl ketone (MIBK) and 3% by weight of a 40% paraffin chloride solution. %, 3% by weight of polyester resin, 2% by weight of polyurethane resin, 8% by weight of xylene, and 3% by weight of cyclohexanone are mixed and milled for 2 hours to obtain a mixture of 6 microns or less. .

또한, 상기 광호환 변색층(13)은 200나노의 입도를 가진 미세한 분말형태의 분산성 광호환 분산염료(예를들어 영국 James Robinson사의 Reversacol Photochromic Dyes)를 톨루엔 및 솔벤트에 분산시켜 점도가 50,000cps를 가지도록 하며, 120℃~130℃에서 경화되는 폴리에스테르수지(예를들어 SWISS SCHATTI사의 Co-polyester 376)를 공중합하여 얻는다. In addition, the photochromic discoloration layer 13 is dispersed in toluene and solvent by dispersing a fine powder dispersible photocompatible disperse dye having a particle size of 200 nanometer (for example, James Robinson UK Reversacol Photochromic Dyes) in toluene and solvent Obtained by copolymerizing a polyester resin (for example, Co-polyester 376 of SWISS SCHATTI Co., Ltd.) cured at 120 ℃ ~ 130 ℃.

이를 구체적으로 설명하면, 톨루엔 5중량％에 200나노 광호환 변색 분산염료 0.01중량％를 분산 용해시키고, 폴리에스테르 수지 3중량％와 폴리우레탄 수지 2중량％와 메틸 이소부틸케톤(MIBK) 27중량％와 40％의 염화파라핀 용액 3중량％와 건 조지연제 2중량％와 이소포론 12.8중량％를 혼합하여 제분기에서 1시간 동안 교반하며, 사이크로헥사논(Cyclohexanone) 25중량％와 폴리에스테르 수지 15중량％와 폴리우레탄 수지 5중량％와 색분리방지제 0.19중량％를 혼합하고 2시간 동안 교반한다.Specifically, 0.01% by weight of 200 nano-photochromic disperse dyes are dispersed and dissolved in 5% by weight of toluene, 3% by weight of polyester resin, 2% by weight of polyurethane resin and 27% by weight of methyl isobutyl ketone (MIBK) And 3% by weight of 40% paraffin chloride solution, 2% by weight of dry delay agent, and 12.8% by weight of isophorone, were stirred for 1 hour in a mill, 25% by weight of cyclohexanone and polyester resin 15 The weight percent, 5 weight percent polyurethane resin, and 0.19 weight percent color separation inhibitor are mixed and stirred for 2 hours.

이때, 상기 분산성 광호환 변색 염료는 기본적인 칼라가 28가지 칼라로 이루어져 있으며 다음과 같이 자외선에 따른 화학구조식의 변화로 인해 다양한 칼라로 변색된다.In this case, the dispersible photo-compatible color change dye has a basic color of 28 colors and changes color as a variety of colors due to the change in chemical structure according to the ultraviolet rays as follows.

아래 화학구조식은 RED 칼라의 광호환 변색 염료(Photocromic Dye)가 자외선(UV)에 노출 시 무색에서 유색으로, 유색에서 무색으로 착색되는 과정을 보이고 있다.The chemical formula below shows the process of color photochromic dye of RED color being colorless to colored and colored to colorless when exposed to ultraviolet (UV) light.

Figure 112006501499840-utm00001
Figure 112006501499840-utm00001

또한, 아래 화학구조식은 Grey 칼라의 광호환 변색 염료(Photocromic Dye)가 자외선(UV)에 노출 시 무색에서 유색으로, 유색에서 무색으로 착색되는 과정을 보 이고 있다.In addition, the following chemical structure shows the process of the color-chromic dye (Photocromic Dye) of the gray color is colorless to color, color to colorless when exposed to ultraviolet (UV).

Figure 112006501499840-utm00002
Figure 112006501499840-utm00002

상기 색상 잉크층(15)은 단일칼라 또는 다색의 칼라를 단독으로 사용 시에 혼합시키는 조성물로서, 금, 은, 동, 펄, 메탈, 비드, 반짝이, 형광, 알루미늄박 등 다양한 소재를 함께 혼합하여 실크스크린 인쇄하며, 원색그림 인쇄시는 Off-set을 이용한 특수불면 인쇄 잉크를 사용한다. 색상 잉크층(15)은 폴리에스테르 수지 5중량％와 폴리우레탄 수지 15중량％, 염화비닐수지 2중량％와 사이클론헥산 60중량％ 및 메틸 이소부틸케톤(MIBK) 16중량％와 색상안료 1.85와 색분리방지제(BYK 300) 0.15중량％를 혼합하여 얻는다.The color ink layer 15 is a composition in which a single color or a multicolored color is mixed alone when used, and various materials such as gold, silver, copper, pearl, metal, beads, glitter, fluorescent, and aluminum foil are mixed together. Silk-screen printing, special color printing ink using off-set is used for primary color printing. The color ink layer 15 includes 5% by weight of polyester resin, 15% by weight of polyurethane resin, 2% by weight of vinyl chloride resin, 60% by weight of cyclonehexane, 16% by weight of methyl isobutyl ketone (MIBK), color pigment 1.85 and color Obtained by mixing 0.15% by weight of a separation inhibitor (BYK 300).

그리고, 불투명 백색층(16)은 사이크로헥사논 (Cyclohexanone) 40중량％와 폴리에스테르 수지 7중량％ 및 폴리우레탄 수지 10중량％, 염화비닐수지 2중량％와 색분리방지제(BYK 300) 0.2중량％, 또한, 건조지연제 0.8중량％와 Titan백색안료 40중량％를 혼합하고 2시간 동안 밀링하여 얻는다.The opaque white layer 16 is 40% by weight of cyclohexanone, 7% by weight of polyester resin, 10% by weight of polyurethane resin, 2% by weight of vinyl chloride resin, and 0.2% by weight of color separation inhibitor (BYK 300). %, And 0.8% by weight of the drying retardant and 40% by weight of Titan white pigment are mixed and obtained by milling for 2 hours.

상기 접착층(17)은 코폴리에스테르(SWISS SCHATTI사의 Copolyester 376) 20중량％와 폴리우레탄(DACOTA사의 TPU8060) 20중량％와 사이클론헥사논 60중량％를 첨가제와 함께 열탕혼합하여 교반 및 냉각시킨 후, 핫멜트(SWISS SCHATTI사의 Copolyester 373)나 폴리우레탄(DACOTA사의 TPU8060)을 30％중량부로 혼합하여 사용한다.The adhesive layer 17 was heated and mixed with 20% by weight of copolyester (Copolyester 376 of SWISS SCHATTI Co., Ltd.), 20% by weight of polyurethane (TPU8060 of DACOTA) and 60% by weight of cyclonehexanone with an additive, followed by stirring and cooling. Hot melt (Copolyester 373 from SWISS SCHATTI Co., Ltd.) or polyurethane (TPU8060 from DACOTA Co., Ltd.) is used by mixing at 30% by weight.

따라서, 본 고안은 상기와 같이 제조된 전사지를 이용하여 피전사체(20)에 공지의 방법으로 전사를 하며, 피전사체(20)의 원색그림, 글자, 도형 등이 어두운 실내에서 밝은 실외(햇빛) 측으로 이동하면 광호환 변색층(13)에 의해 다양한 칼라로 변색되고, 야간에는 야광에 의해 피전사체(20)에 인쇄된 그대로의 형태가 보여지도록 하는 전사지의 제조방법에 관한 것으로서, 색상의 인쇄 전에 광호환 변색층(13)과 칼라 야광층(14)을 부분 또는 전체적으로 인쇄하여 다양한 제품에 적용하며, 접착시 낮은 온도에서도 이형(박리)처리가 되도록 하여 다양한 소재에 사용할 수 있는 특징을 가지고 있다.Therefore, the present invention transfers to the transfer target 20 by a known method using the transfer paper prepared as described above, the primary color pictures, letters, figures, etc. of the transfer target 20 is bright outdoors (sunlight) Moving to the side is changed to various colors by the photochromic discoloration layer 13, and relates to a manufacturing method of the transfer paper so that the form as it is printed on the transfer object 20 by night luminous is visible, before printing the color The photochromic layer 13 and the color luminous layer 14 are partially or entirely printed and applied to a variety of products, and they can be used for various materials by being released (peeled) even at low temperatures during adhesion.

상기와 같이 본 고안은 피전사에 전사된 원색그림, 글자, 도형 등의 색상이 어두운 실내 또는 햇빛이 없는 곳에서 실내 또는 햇빛이 있는 곳으로 이동할 시, 다양한 색상으로 변색이 되는 것은 물론, 야간에도 의류에 인쇄된 문자 및 그림 등의 보여지도록 함으로써, 다양한 상품에 사용하여 시각적인 만족도를 극대화할 수 있는 매우 유용한 고안이다.As described above, the present invention can be discolored in various colors as well as at night when moving from indoors to sunlight or indoors where there are no colors such as primary colors, letters, and figures transferred to the transferee, or where there is no sunlight. By displaying the printed characters and pictures on the clothing, it is a very useful design that can be used in a variety of products to maximize the visual satisfaction.

또한, 피전사체에 전사된 전사지의 내구성이 양호하여 변형의 염려가 줄어들고, 햇빛에 대한 반응속도가 빨라 양호한 광호환 변색이 이루어지는 장점이 있다.In addition, the durability of the transfer paper transferred to the transfer target is reduced, there is a fear of deformation, there is an advantage that a good photo-compatible color change is achieved due to the fast response to sunlight.

Claims (5)

상면에 이형제 코팅층과 실리콘 투명층 및 색상 잉크층과 불투명 백색층, 접Top release agent coating layer, silicone transparent layer, color ink layer, opaque white layer, contact 착층을 순차적으로 형성한 전사지에 있어서,In the transfer paper in which the contact layer was formed sequentially, 상기 실리콘 투명층과 색상 잉크층의 사이에는 칼라 야광층을 더 형성하는 A color luminous layer is further formed between the silicon transparent layer and the color ink layer. 것을 특징으로 하는 광호환 변색 칼라야광 전사지.Photochromic color-colored luminous transfer paper, characterized in that. 제 1항에 있어서,The method of claim 1, 상기 칼라 야광층의 상측에는 광호환 변색층을 더 형성하는 것을 특징으로 하는 광호환 변색 칼라야광 전사지.The photochromic color-colored luminous transfer paper, characterized in that further forming a photo-compatible color change layer on the upper side of the color luminous layer. 제 1항 또는 제 2항의 칼라 야광층은The color luminous layer of claim 1 or 2 폴리에스테르 수지 15중량％와, 이소포론 15중량％와, 건조지연제 3중량％와, 디옥틸프탈레이트(DOP) 4.8중량％와, 1~5마이크론의 칼라 축광안료 16중량％와, 분산제 0.1중량％와, 습윤제 0.1중량％를 혼합하여 제분기에서 1시간 밀링작업을 하고, 다시 메틸 이소부틸케톤(MIBK) 27중량％와, 40％의 염화파라핀 용액 3중량％와, 폴리에스테르 수지 3중량％와, 폴리우레탄 수지 2중량％와, 크실렌 8중량％와, 사이크로헥사논(Cyclohexanone) 3중량％를 혼합하여 2시간 동안 밀링하여 얻 는 것을 특징으로 하는 광호환 변색 칼라야광 전사지.15% by weight of polyester resin, 15% by weight of isophorone, 3% by weight of drying retardant, 4.8% by weight of dioctylphthalate (DOP), 16% by weight of 1-5 micron color photoluminescent pigment, and 0.1% of dispersant %, 0.1 wt% of the wetting agent was mixed and milled for 1 hour in a mill, and again 27 wt% of methyl isobutyl ketone (MIBK), 3 wt% of a 40% paraffin chloride solution, and 3 wt% of a polyester resin And 2% by weight of polyurethane resin, 8% by weight of xylene, and 3% by weight of cyclohexanone, which are obtained by milling for 2 hours. 상면에 이형제 코팅층과 실리콘 투명층 및 색상 잉크층과 불투명 백색층, 접착층을 순차적으로 형성한 전사지에 있어서, In the transfer paper formed by sequentially forming a release agent coating layer, a silicon transparent layer, a color ink layer, an opaque white layer, an adhesive layer on the upper surface, 상기 실리콘 투명층과 색상 잉크층의 사이에는 광호환 변색층을 더 형성하는 광호환 변색 칼라야광 전사지.The photocompatible color change color luminous transfer paper further forming a photocompatible color change layer between the silicon transparent layer and the color ink layer. 제 2항 또는 제 4항에 있어서, The method according to claim 2 or 4, 상기 광호환 변색층은,The photocompatible color change layer, 톨루엔 5중량％에 200나노 광호환 변색 분산염료 0.01중량％를 분산 용해시키고; 폴리에스테르 수지 3중량％와 폴리우레탄 수지 2중량％와 메틸 이소부틸케톤(MIBK) 27중량％와 40％의 염화파라핀 용액 3중량％와 건조지연제 2중량％와 이소포론 12.8중량％를 혼합하여 제분기에서 1시간 동안 교반하며; 사이크로헥사논(Cyclohexanone) 25중량％와 폴리에스테르 수지 15중량％와 폴리우레탄 수지 5중량％와 색분리방지제 0.19중량％를 혼합하고 2시간 동안 교반하여; 얻는 것을 특징으로 하는 광호환 변색 칼라야광 전사지.Dispersing and dissolving 0.01% by weight of 200 nanophotochromic disperse dyes in 5% by weight of toluene; 3% by weight of polyester resin, 2% by weight of polyurethane resin, 27% by weight of methyl isobutyl ketone (MIBK), 3% by weight of 40% paraffin chloride solution, 2% by weight of drying retardant, and 12.8% by weight of isophorone Stirring in the mill for 1 hour; 25% by weight of cyclohexanone, 15% by weight of polyester resin, 5% by weight of polyurethane resin, and 0.19% by weight of color separation agent were mixed and stirred for 2 hours; Photochromic color-colored luminous transfer paper, characterized in that the obtained.
KR2020060004687U 2006-02-21 2006-02-21 transfer paper KR200417096Y1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101515322B1 (en) * 2014-01-27 2015-04-24 정호연 Method for textile printing
KR102263710B1 (en) * 2020-11-25 2021-06-09 고경열 Transfer sheet sticker usable on mask

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101515322B1 (en) * 2014-01-27 2015-04-24 정호연 Method for textile printing
KR102263710B1 (en) * 2020-11-25 2021-06-09 고경열 Transfer sheet sticker usable on mask

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