CN110157323A - Wear-resisting optical curing of UV anti-static coatings and preparation method thereof - Google Patents
Wear-resisting optical curing of UV anti-static coatings and preparation method thereof Download PDFInfo
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- CN110157323A CN110157323A CN201910339665.8A CN201910339665A CN110157323A CN 110157323 A CN110157323 A CN 110157323A CN 201910339665 A CN201910339665 A CN 201910339665A CN 110157323 A CN110157323 A CN 110157323A
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- static coatings
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- optical curing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to coating technologies more particularly to a kind of wear-resisting optical curing of UV anti-static coatings and preparation method thereof.The technical solution adopted by the present invention is that: wear-resisting optical curing of UV anti-static coatings, it is characterised in that: the raw material including following parts by weight: 35-45 parts of polyurethane acrylate resin；10-20 parts of aqueous unsaturated polyester (UP) acrylate resin；3-7 parts of polyvinyl alcohol；2-5 parts of bortz powder；2-3 parts of photoinitiator；7-10 parts of diluent；0.3-1 parts of defoaming agent；0.3-1 parts of antibacterial mildew inhibitor；5-8 parts of glass fibre；5-8 parts of nanofiller；3-5 parts of antistatic agent；70-80 parts of deionized water.The invention has the advantages that film curing speed is fast, antistatic effect, antibacterial and mouldproof and wearability are good.
Description
Technical field
The present invention relates to coating technologies more particularly to a kind of wear-resisting optical curing of UV anti-static coatings and preparation method thereof.
Background technique
With the development of market economy, great variety is had occurred in paint field, and wherein UV coating is all ultraviolet radiations
Coating material solidified general designation.It has many advantages, such as fast curing rate, normal temperature cure, environmentally protective, film layer brightness height, after dry
Film surface is firm heat-resisting, is widely used to the fields such as chemical industry, household, electronics light industry.Existing optical curing of UV coating still remains
Some disadvantages, for example wear no resistance, a series of defects such as antistatic effect is bad.Seriously affect the usage experience of client.Therefore,
The new technical solution of one kind should be provided to solve the above problems.
Summary of the invention
The purpose of the present invention is: it is directed to disadvantage existing in the prior art, proposes a kind of high wear resistant photo-cured UV antistatic
Coating and preparation method thereof.
To achieve the above object, the technical solution adopted by the present invention is that:
Wear-resisting optical curing of UV anti-static coatings, the raw material including following parts by weight: polyurethane acrylate resin 35-45
Part；10-20 parts of aqueous unsaturated polyester (UP) acrylate resin；3-7 parts of polyvinyl alcohol；2-5 parts of bortz powder；Photoinitiator 2-3
Part；7-10 parts of diluent；0.3-1 parts of defoaming agent；0.3-1 parts of antibacterial mildew inhibitor；5-8 parts of glass fibre；5-8 parts of nanofiller；
3-5 parts of antistatic agent；70-80 parts of deionized water.
Further technical solution:
The photoinitiator is 1- hydroxycyclohexyl phenyl ketone；The defoaming agent is polyethers defoaming agent；The dilution
Agent is acrylate monomer.
The nanofiller includes nano-silver powder and nano antibacterial agent.
It further include 2-5 parts of thickener.
The thickener is at least one of hydroxypropyl methyl cellulose, sodium carboxymethylcellulose, hydroxyethyl cellulose.
The preparation method of wear-resisting optical curing of UV anti-static coatings, includes the following steps:
S1, it prepares filler: ball milling in nano-silver powder and nano antibacterial agent investment ball mill will be included；
S2, it is taken by weight by polyvinyl alcohol, aqueous unsaturated polyester (UP) acrylate resin and urethane acrylate tree
Rouge carries out being mixed to prepare mixture；
S3, filler, photoinitiator, antistatic agent, defoaming agent, antibacterial mildew inhibitor, glass fibre, gold are added in the mixture
1h is stirred after emery.
S4, deionized water is slowly added dropwise with phase inversion and diluent is dispersed into stable emulsion, time for adding 2h.
Due to the application of above-mentioned technical proposal, the invention has the following advantages over the prior art:
1, optical curing of UV coating of the invention passes through polyurethane acrylate resin, aqueous unsaturated polyester (UP) acrylate
Resin, polyvinyl alcohol, diluent, defoaming agent, the interaction between photoinitiator, obtained water-based ultraviolet (UV) curable coating are formed
Film curing speed it is fast, and be not easy to turn yellow.
2, optical curing of UV coating of the invention matches antistatic agent, and the coating to be formed is made to have good antistatic effect；
Meanwhile antibacterial mildew inhibitor is matched, make the coating to be formed, has effects that antibacterial and mouldproof, protection materials are not by microbiological spoilage.
3, optical curing of UV coating of the invention matches bortz powder and glass fibre as abrasion resistant particles, effectively increases
Coating is wear-resisting, scratch-resistant ability.
Specific embodiment
Technical solution of the present invention is further described below with reference to specific embodiment, but the present invention is not limited to
Following embodiments.If the raw material that the present invention uses can be bought on the market without specified otherwise.
Embodiment one
Wear-resisting optical curing of UV anti-static coatings, the raw material including following parts by weight: 35 parts of polyurethane acrylate resin；Water
20 parts of acrylate resin of unsaturated polyester (UP) of property；3 parts of polyvinyl alcohol；5 parts of bortz powder；2 parts of photoinitiator；7 parts of diluent；Disappear
0.5 part of infusion；0.3 part of antibacterial mildew inhibitor；5 parts of glass fibre；5 parts of nanofiller；3 parts of antistatic agent；2 parts of thickener；Go from
70 parts of sub- water.
The photoinitiator is 1- hydroxycyclohexyl phenyl ketone；The defoaming agent is polyethers defoaming agent；The dilution
Agent is acrylate monomer.
The nanofiller includes nano-silver powder and nano antibacterial agent.
The thickener is sodium carboxymethylcellulose.
The preparation method of wear-resisting optical curing of UV anti-static coatings, includes the following steps:
S1, it prepares filler: ball milling in nano-silver powder and nano antibacterial agent investment ball mill will be included；
S2, it is taken by weight by polyvinyl alcohol, aqueous unsaturated polyester (UP) acrylate resin and urethane acrylate tree
Rouge carries out being mixed to prepare mixture；
S3, filler, photoinitiator, antistatic agent, defoaming agent, antibacterial mildew inhibitor, glass fibre, gold are added in the mixture
1h is stirred after emery.
S4, deionized water is slowly added dropwise with phase inversion and diluent is dispersed into stable emulsion, time for adding 2h.
Embodiment two
Wear-resisting optical curing of UV anti-static coatings, the raw material including following parts by weight: 40 parts of polyurethane acrylate resin；Water
15 parts of acrylate resin of unsaturated polyester (UP) of property；7 parts of polyvinyl alcohol；3 parts of bortz powder；3 parts of photoinitiator；10 parts of diluent；
1 part of defoaming agent；0.5 part of antibacterial mildew inhibitor；8 parts of glass fibre；10 parts of nanofiller；4 parts of antistatic agent；3 parts of thickener；Go from
75 parts of sub- water.
The photoinitiator is 1- hydroxycyclohexyl phenyl ketone；The defoaming agent is polyethers defoaming agent；The dilution
Agent is acrylate monomer.
The nanofiller includes nano-silver powder and nano antibacterial agent.
The thickener is hydroxypropyl methyl cellulose.
The preparation method of wear-resisting optical curing of UV anti-static coatings, includes the following steps:
S1, it prepares filler: ball milling in nano-silver powder and nano antibacterial agent investment ball mill will be included；
S2, it is taken by weight by polyvinyl alcohol, aqueous unsaturated polyester (UP) acrylate resin and urethane acrylate tree
Rouge carries out being mixed to prepare mixture；
S3, filler, photoinitiator, antistatic agent, defoaming agent, antibacterial mildew inhibitor, glass fibre, gold are added in the mixture
1h is stirred after emery.
S4, deionized water is slowly added dropwise with phase inversion and diluent is dispersed into stable emulsion, time for adding 2h.
Embodiment three
Wear-resisting optical curing of UV anti-static coatings, the raw material including following parts by weight: 45 parts of polyurethane acrylate resin；Water
10 parts of acrylate resin of unsaturated polyester (UP) of property；4 parts of polyvinyl alcohol；2 parts of bortz powder；2.5 parts of photoinitiator；8 parts of diluent；
0.3 part of defoaming agent；1 part of antibacterial mildew inhibitor；6 parts of glass fibre；7 parts of nanofiller；5 parts of antistatic agent；5 parts of thickener；Go from
80 parts of sub- water.
The photoinitiator is 1- hydroxycyclohexyl phenyl ketone；The defoaming agent is polyethers defoaming agent；The dilution
Agent is acrylate monomer.
The nanofiller includes nano-silver powder and nano antibacterial agent.
The thickener is hydroxyethyl cellulose.
The preparation method of wear-resisting optical curing of UV anti-static coatings, includes the following steps:
S1, it prepares filler: ball milling in nano-silver powder and nano antibacterial agent investment ball mill will be included；
S2, it is taken by weight by polyvinyl alcohol, aqueous unsaturated polyester (UP) acrylate resin and urethane acrylate tree
Rouge carries out being mixed to prepare mixture；
S3, filler, photoinitiator, antistatic agent, defoaming agent, antibacterial mildew inhibitor, glass fibre, gold are added in the mixture
1h is stirred after emery.
S4, deionized water is slowly added dropwise with phase inversion and diluent is dispersed into stable emulsion, time for adding 2h.
Although some specific embodiments of the invention are described in detail by example, the skill of this field
Art personnel it should be understood that example above merely to being illustrated, the range being not intended to be limiting of the invention.The skill of this field
Art personnel are it should be understood that can without departing from the scope and spirit of the present invention modify to above embodiments.This hair
Bright range is defined by the following claims.
Claims (6)
1. wear-resisting optical curing of UV anti-static coatings, it is characterised in that: the raw material including following parts by weight: urethane acrylate tree
35-45 parts of rouge；10-20 parts of aqueous unsaturated polyester (UP) acrylate resin；3-7 parts of polyvinyl alcohol；2-5 parts of bortz powder；Light draws
Agent 2-3 parts of hair；7-10 parts of diluent；0.3-1 parts of defoaming agent；0.3-1 parts of antibacterial mildew inhibitor；5-8 parts of glass fibre；Nanofiller
5-8 parts；3-5 parts of antistatic agent；70-80 parts of deionized water.
2. wear-resisting optical curing of UV anti-static coatings according to claim 1, it is characterised in that: further include 2-5 parts of thickener.
3. wear-resisting optical curing of UV anti-static coatings according to claim 1, it is characterised in that: the photoinitiator is 1- hydroxyl
Butylcyclohexyl phenyl ketone；The defoaming agent is polyethers defoaming agent；The diluent is acrylate monomer.
4. wear-resisting optical curing of UV anti-static coatings according to claim 1, it is characterised in that: the thickener is hydroxypropyl
At least one of methylcellulose, sodium carboxymethylcellulose, hydroxyethyl cellulose.
5. wear-resisting optical curing of UV anti-static coatings according to claim 1, it is characterised in that: the nanofiller includes receiving
Rice silver powder and nano antibacterial agent.
6. the preparation method of the wear-resisting optical curing of UV anti-static coatings such as any one of claim 1-5, it is characterised in that: including such as
Lower step:
S1, it prepares filler: ball milling in nano-silver powder and nano antibacterial agent investment ball mill will be included；
S2, take by weight by polyvinyl alcohol, aqueous unsaturated polyester (UP) acrylate resin and polyurethane acrylate resin into
Row is mixed to prepare mixture；
S3, filler, photoinitiator, antistatic agent, defoaming agent, antibacterial mildew inhibitor, glass fibre, diamond are added in the mixture
1h is stirred after powder.
S4, deionized water is slowly added dropwise with phase inversion and diluent is dispersed into stable emulsion, time for adding 2h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910339665.8A CN110157323A (en) | 2019-04-25 | 2019-04-25 | Wear-resisting optical curing of UV anti-static coatings and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910339665.8A CN110157323A (en) | 2019-04-25 | 2019-04-25 | Wear-resisting optical curing of UV anti-static coatings and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110157323A true CN110157323A (en) | 2019-08-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910339665.8A Pending CN110157323A (en) | 2019-04-25 | 2019-04-25 | Wear-resisting optical curing of UV anti-static coatings and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113278355A (en) * | 2021-06-21 | 2021-08-20 | 漳州市和兴涂料有限公司 | Water-based uv photocureable coating and preparation method thereof |
| CN114716689A (en) * | 2022-04-20 | 2022-07-08 | 安徽沃尔德新材料有限公司 | Processing technology and device for anti-static biomass water-based acrylate raw material |
| CN115851108A (en) * | 2022-12-07 | 2023-03-28 | 惠州市日大实业有限公司 | Water-based high-wear-resistance nano silver ion antibacterial UV coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104673080A (en) * | 2013-11-27 | 2015-06-03 | 李应芝 | Antistatic water-borne UV coating |
| CN108977057A (en) * | 2018-08-22 | 2018-12-11 | 广东昊辉新材料有限公司 | A kind of aqueous photo-curing floor paint and preparation method thereof |
| CN109401612A (en) * | 2018-11-02 | 2019-03-01 | 华容县恒兴建材有限公司 | Wear-resisting optical curing of UV coating |
-
2019
- 2019-04-25 CN CN201910339665.8A patent/CN110157323A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104673080A (en) * | 2013-11-27 | 2015-06-03 | 李应芝 | Antistatic water-borne UV coating |
| CN108977057A (en) * | 2018-08-22 | 2018-12-11 | 广东昊辉新材料有限公司 | A kind of aqueous photo-curing floor paint and preparation method thereof |
| CN109401612A (en) * | 2018-11-02 | 2019-03-01 | 华容县恒兴建材有限公司 | Wear-resisting optical curing of UV coating |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113278355A (en) * | 2021-06-21 | 2021-08-20 | 漳州市和兴涂料有限公司 | Water-based uv photocureable coating and preparation method thereof |
| CN113278355B (en) * | 2021-06-21 | 2022-05-24 | 漳州市和兴涂料有限公司 | Water-based uv photocureable coating and preparation method thereof |
| CN114716689A (en) * | 2022-04-20 | 2022-07-08 | 安徽沃尔德新材料有限公司 | Processing technology and device for anti-static biomass water-based acrylate raw material |
| CN115851108A (en) * | 2022-12-07 | 2023-03-28 | 惠州市日大实业有限公司 | Water-based high-wear-resistance nano silver ion antibacterial UV coating and preparation method thereof |
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Application publication date: 20190823 |
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