CN110154484A - The super antistatic crystal film of one kind and its manufacture craft - Google Patents
The super antistatic crystal film of one kind and its manufacture craft Download PDFInfo
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- CN110154484A CN110154484A CN201910335228.9A CN201910335228A CN110154484A CN 110154484 A CN110154484 A CN 110154484A CN 201910335228 A CN201910335228 A CN 201910335228A CN 110154484 A CN110154484 A CN 110154484A
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- crystal film
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to the super antistatic crystal film of one kind and its manufacture crafts, the super antistatic crystal film of one of which, it is characterized in that, it include: 50-100 parts of makrolon material mass ratio, 20-40 parts of vegetable and animals oils, 15-30 parts of plasticizer, 6-10 parts of stabilizer, 4-8 parts of desiccant, 0.1-1 parts of toner.Picture color is bright-coloured, and color saturation is high, and hierarchy correlation is strong, and rich in stereo concave-convex sense, visual impact is strong；Monofilm solution, product have Water-proof sun-proof performance；Easy sticker easily removes, no residue glue, clears up glass without taking time, and (cover) is glittering and translucent, smooth such as mirror from the inside to surface, has good crystal texture, has the characteristics of waterproof, resistance to Huang, good hand touch, while environmental protection, packs transparent height.
Description
Technical field
The present invention relates to Filming Technology fields, more specifically to the super antistatic crystal film of one kind.
Background technique
Crystal film (also known as crystal chip) is a kind of for manufacturing the proprietary material of crystal photo album, crystal painting etc..The material
The compound and manufactured photograph album of heat is carried out with common laser photo or ink-jet photographic.From the inside to surface (cover) it is glittering and translucent, it is smooth such as
Mirror has good crystal texture.Crystal film is divided into cold mounting and heat mounting and two kinds.Cold mounting can operate at normal temperature, heat
Mounting needs temperature to reach 90 degree or more.The characteristics of PET water epitaxial in crystal film is high temperature resistant.The water of the PET material of import
Epitaxial quality is more stable, and price is high.
In current design, many crystal film transparency interactions are bad, ideal state are not achieved, such as cannot see that StoreFront
The furnishings of inside；Crystal film product, which is attached on glass, is easy to bubble, is not easy periodical poster face；It is also not easy to move when printing under product
It removes, stays residue glue, the picture for needing to take time on manual cleaning glass；The bright-coloured saturation degree of product color is low, and the distortion factor is higher.Also
Crystal film using the time, there is a phenomenon where yellowing not long, material is also excessively thick and solid, and flexibility is bad, though some reach transparent
Effect is spent, is not had also but antistatic and other effects.
Therefore, the prior art is urgently greatly improved.
Summary of the invention
The technical problem to be solved in the present invention is that for the above-mentioned defect of the prior art, on the one hand, the present invention provides
The super antistatic crystal film of one kind, comprising: 50-100 parts of makrolon material mass ratio, 20-40 parts of vegetable and animals oils, plasticizer
15-30 parts, 6-10 parts of stabilizer, 4-8 parts of desiccant, 0.1-1 parts of toner.
Preferably, the makrolon material is substituted by makrolon material.
Preferably, the makrolon material is by diethyl phthalate material substitution.
Preferably, the makrolon material is substituted by acrylic board material.
Preferably, the vegetable and animals oils include epoxidized soybean oil, corn oil.
Preferably, the plasticizer includes dibutyl phthalate material.
On the other hand, the present invention provides one kind super antistatic crystal film manufacture craft, comprising steps of
S11,50-100 parts of raw material makrolon material mass ratio is taken, 20-40 parts of vegetable and animals oils, 15-30 parts of plasticizer,
6-10 parts of stabilizer, 4-8 parts of desiccant, 0.1-1 parts of formation crystal film mixtures of toner are placed 1~3 day in a kettle；
S12, the processing of plastic-coated lamination is carried out to the crystal film mixture formed after step S11；
S13, become crystal film semi-finished product after being bonded to the crystal film mixture by step S12 with PET；
S14, it is made to after the crystal film surface of semi-finished of step S13 is by coating attachment PVC material skin covering of the surface
Obtain crystal film finished product.
Preferably, pass through coating attaching surface in step S14, to the crystal film surface of semi-finished by step S13
After film after finished product further include: layer protecting film is set on the crystal film finished product, and the protective film is arm material.
It preferably, further include by the crystal film mixture high-speed stirred before placing 1~3 day in a kettle.
Preferably, the makrolon material is substituted by makrolon material.
Implement super antistatic crystal film of the invention, has the advantages that picture color is bright-coloured, color saturation
Height, hierarchy correlation is strong, and rich in stereo concave-convex sense, visual impact is strong；Monofilm solution, product have Water-proof sun-proof performance；
Easy sticker easily removes, no residue glue, clears up glass without taking time, and (cover) is glittering and translucent, smooth such as mirror from the inside to surface, has fine
Crystal texture, have the characteristics of waterproof, resistance to Huang, good hand touch, while environmental protection, pack transparent height.
Specific embodiment
The invention discloses the super antistatic crystal films of one kind, include at least, and 50-100 parts of makrolon material mass ratio,
20-40 parts of vegetable and animals oils, 15-30 parts of plasticizer, 6-10 parts of stabilizer, 4-8 parts of desiccant, 0.1-1 parts of toner.Specific implementation
When, antistatic material makrolon material can by acrylic board, pvc material, polyethylene terephthalate or
The substitution such as MC501CDR6.It may include any one in epoxidized soybean oil, corn oil etc. as lubricant vegetable and animals oils.Also
The soap base that can be constituted using synthetic lubricant fluid, semisolid lubricants or lubricating grease such as petroleum base oil and synthetic base oil,
It can also be solid lubricant: graphite, molybdenum disulfide etc..Wherein, fluid lubricant (lubricating oil) is most common lubricant.
Plasticising --- be added higher boiling in high polymer, low volatility, and can with the small-molecule substance of Polymers Phase mixing and
Change the behavior of its mechanical property.Plasticising is an important method of modified-high polymer, for example, PVC flowing temperature close to point
Temperature is solved, 30~50% dibutyl phthalate is commonly incorporated into molding, its flowing temperature and melt can be reduced in this way
Viscosity is easy to process.Its cold-resistant, erosion-resisting characteristics can also be improved, soft plastic product (film, adhesive tape, artificial leather etc.) is made.Polymerization
There are intermolecular interaction between object macromolecular chain, its size is related with the molecular structure performance of polymer.It is intermolecular
Active force make polymer that there is some strength, while also influencing its processing performance, plasticizer is inserted between polymer molecule, is cut
Active force between weak macromolecular, increases the activity of polymer molecule, so as to improve the soft of Polymer Processing and product
Toughness.It is all can and resin uniformly mix, chemical change does not occur for when mixing, but can reduce material glass transition temperature and plastics at
Melt viscosity when type is processed, and remains unchanged in itself, though or it plays a chemical change and can retain for a long time in plastic products and energy
The certain physical properties for changing resin, the solid of liquid organic compound or low melting point with these performances, are referred to as plasticized
Agent.When it is implemented, plasticizer can also be selected as dibutyl phthalate material.
Embodiment one
The present invention provides one kind super antistatic crystal film manufacture craft, comprising steps of
S21,60 parts of raw material makrolon material mass ratio is taken, 35 parts of vegetable and animals oils, 25 parts of plasticizer, stabilizer 7
Part, 7 parts of desiccant, 0.6 part of formation crystal film mixture of toner is sufficiently stirred in high-speed mixer；The purpose done so
It is in order to enable crystal film mixture stirs evenly, reaction is abundant；Desiccant be in order to enable crystal film finished product have it is moisture-proof
Function, toner are in order to enable crystal film finished product is bright in luster, and toner can be selected according to the needs of users.
S22, it places 1~3 day in a kettle, the purpose for the arrangement is that in order to enable the crystal film mixture after stirring is cold
But, it is restored to natural temperature；
S23, the processing of plastic-coated lamination is carried out to the crystal film mixture formed after step S22；
S24, become crystal film semi-finished product after being bonded to the crystal film mixture by step S23 with PET；
S25, it is made to after the crystal film surface of semi-finished of step S24 is by coating attachment PVC material skin covering of the surface
Obtain crystal film finished product；
S26, layer protecting film is set on the crystal film finished product by step S25, protective film can be arm material, this
The purpose that sample is done is in order to moisture-proof dust-proof.
Embodiment two
The present invention provides one kind super antistatic crystal film manufacture craft, comprising steps of
S31, raw material makrolon material mass ratio 50 is taken, 20 parts of vegetable and animals oils, 15 parts of plasticizer, 6 parts of stabilizer,
4 parts of desiccant, 0.1 part of formation crystal film mixture of toner is sufficiently stirred in high-speed mixer；The purpose for the arrangement is that being
Crystal film mixture stirred evenly, reaction is abundant；Desiccant be in order to enable crystal film finished product has moisture-proof function,
Toner is in order to enable crystal film finished product is bright in luster, and toner can be selected according to the needs of users.
S32, it places 1~3 day in a kettle, the purpose for the arrangement is that in order to enable the crystal film mixture after stirring is cold
But, it is restored to natural temperature；
S33, the processing of plastic-coated lamination is carried out to the crystal film mixture formed after step S32；
S34, become crystal film semi-finished product after being bonded to the crystal film mixture by step S33 with PET；
S35, it is made to after the crystal film surface of semi-finished of step S34 is by coating attachment PVC material skin covering of the surface
Obtain crystal film finished product；
S36, layer protecting film is set on the crystal film finished product by step S35, protective film can be arm material, this
The purpose that sample is done is in order to moisture-proof dust-proof.
Embodiment three
The present invention provides one kind super antistatic crystal film manufacture craft, comprising steps of
S41,100 parts of raw material makrolon material mass ratio is taken, 40 parts of vegetable and animals oils, 30 parts of plasticizer, stabilizer 10
Part, 8 parts of desiccant, 1 part of formation crystal film mixture of toner is sufficiently stirred in high-speed mixer；The purpose for the arrangement is that
In order to enable crystal film mixture stirs evenly, reaction is abundant；Desiccant is in order to enable crystal film finished product has moisture-proof function
Can, toner is in order to enable crystal film finished product is bright in luster, and toner can be selected according to the needs of users.
S42, it places 1~3 day in a kettle, the purpose for the arrangement is that in order to enable the crystal film mixture after stirring is cold
But, it is restored to natural temperature；
S43, the processing of plastic-coated lamination is carried out to the crystal film mixture formed after step S42；
S44, become crystal film semi-finished product after being bonded to the crystal film mixture by step S43 with PET；
S45, it is made to after the crystal film surface of semi-finished of step S44 is by coating attachment PVC material skin covering of the surface
Obtain crystal film finished product；
S46, layer protecting film is set on the crystal film finished product by step S45, protective film can be arm material, this
The purpose that sample is done is in order to moisture-proof dust-proof.
Example IV
The present invention provides one kind super antistatic crystal film manufacture craft, comprising steps of
S51,80 parts of raw material makrolon material mass ratio is taken, 30 parts of vegetable and animals oils, 20 parts of plasticizer, stabilizer 8
Part, 6 parts of desiccant, 0.5 part of formation crystal film mixture of toner is sufficiently stirred in high-speed mixer；The purpose done so
It is in order to enable crystal film mixture stirs evenly, reaction is abundant；Desiccant be in order to enable crystal film finished product have it is moisture-proof
Function, toner are in order to enable crystal film finished product is bright in luster, and toner can be selected according to the needs of users.
S52, it places 1~3 day in a kettle, the purpose for the arrangement is that in order to enable the crystal film mixture after stirring is cold
But, it is restored to natural temperature；
S53, the processing of plastic-coated lamination is carried out to the crystal film mixture formed after step S52；
S54, become crystal film semi-finished product after being bonded to the crystal film mixture by step S53 with PET；
S55, it is made to after the crystal film surface of semi-finished of step S54 is by coating attachment PVC material skin covering of the surface
Obtain crystal film finished product；
S56, layer protecting film is set on the crystal film finished product by step S55, protective film can be arm material, this
The purpose that sample is done is in order to moisture-proof dust-proof.
In agio epitaxial finished product Specific construction, by glass water spray cleaning one time before upper periodical, check whether glass surface is smooth,
Whether affixed object is secured；It is printed on product, it is easy for construction convenient；It sprays water poster, product is developed with scraper and whole catches up with bubble；Product is complete
Print complete in portion, overall effect confirmation of taking pictures is kept on file；It is checked before lower periodical in product use with the presence or absence of bubble, contraction and alice etc.
Problem；When lower periodical, residue glue air bubble problem is checked whether there is.
The present invention by the designs of above embodiments, the beneficial effect is that: picture color is bright-coloured, and color saturation is high, layer
Secondary comparison is strong, and rich in stereo concave-convex sense, visual impact is strong；Monofilm solution, product have Water-proof sun-proof performance；Easy sticker is easy
It removing, no residue glue, clears up glass without taking time, glittering and translucent from the inside to surface, smooth such as mirror has good crystal texture,
It has the characteristics of waterproof, resistance to Huang, good hand touch, while environmental protection, packs transparent height.
The present invention is described according to specific embodiment, but it will be understood by those skilled in the art that not departing from this hair
When bright range, various change and equivalent replacement can be carried out.In addition, to adapt to the specific occasion of the technology of the present invention, it can be to the present invention
Many modifications are carried out without departing from its protection scope.Therefore, the present invention is not limited to specific embodiments disclosed herein, and including
All embodiments for dropping into claims.
Claims (10)
1. the super antistatic crystal film of one kind characterized by comprising 50-100 parts of makrolon material mass ratio, animals and plants
It is 20-40 parts oily, 15-30 parts of plasticizer, 6-10 parts of stabilizer, 4-8 parts of desiccant, 0.1-1 parts of toner.
2. super antistatic crystal film according to claim 1, which is characterized in that the makrolon material is by poly- carbonic acid
Ester material substitution.
3. super antistatic crystal film according to claim 1, which is characterized in that the makrolon material is by benzene diformazan
Diethyl phthalate material substitution.
4. super antistatic crystal film according to claim 1, which is characterized in that the makrolon material is by acrylic
Plate material substitution.
5. super antistatic crystal film according to claim 1, which is characterized in that the vegetable and animals oils include epoxy soybean
Oil, corn oil.
6. super antistatic crystal film according to claim 1, which is characterized in that the plasticizer includes phthalic acid
Dibutyl ester material.
7. the super antistatic crystal film manufacture craft of one kind, which is characterized in that comprising steps of
S11,50-100 parts of raw material makrolon material mass ratio is taken, 20-40 parts of vegetable and animals oils, 15-30 parts of plasticizer, stablized
6-10 parts of agent, 4-8 parts of desiccant, 0.1-1 parts of formation crystal film mixtures of toner are placed 1~3 day in a kettle；
S12, the processing of plastic-coated lamination is carried out to the crystal film mixture formed after step S11；
S13, become crystal film semi-finished product after being bonded to the crystal film mixture by step S12 with PET；
S14, to by the crystal film surface of semi-finished of step S13 by coating attaching surface film after be made crystal film at
Product.
8. super antistatic crystal film manufacture craft according to claim 7, which is characterized in that in step S14, to process
After the crystal film surface of semi-finished of step S13 is by finished product after coating attachment PVC material skin covering of the surface further include:
Layer protecting film is set on the crystal film finished product, and the protective film is arm material.
9. super antistatic crystal film manufacture craft according to claim 7, which is characterized in that place 1 in a kettle
It further include by the crystal film mixture high-speed stirred before~3 days.
10. super antistatic crystal film manufacture craft according to claim 7, which is characterized in that the polycarbonate material
Material is substituted by makrolon material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910335228.9A CN110154484A (en) | 2019-04-24 | 2019-04-24 | The super antistatic crystal film of one kind and its manufacture craft |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910335228.9A CN110154484A (en) | 2019-04-24 | 2019-04-24 | The super antistatic crystal film of one kind and its manufacture craft |
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| CN110154484A true CN110154484A (en) | 2019-08-23 |
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| CN109367174A (en) * | 2018-09-05 | 2019-02-22 | 扬州市众和同盛包装材料有限公司 | A kind of heat mounting crystal film and its processing method |
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2019
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302300A (en) * | 2008-01-04 | 2008-11-12 | 上海金浦塑料包装材料有限公司 | Antifog crystal film and preparation thereof |
| CN101758739A (en) * | 2010-01-07 | 2010-06-30 | 朱春生 | Method for producing high wear-resistant interbedded crystalline decorating plate |
| CN101775181A (en) * | 2010-02-11 | 2010-07-14 | 天津宏茂塑胶有限公司 | White-light laminated crystal board and making method thereof |
| CN104356555A (en) * | 2014-11-26 | 2015-02-18 | 天津市天塑科技集团有限公司第四塑料制品厂 | High-elastic polyvinyl chloride weather-resistant flame-retardant super-bright crystal membrane and preparation method thereof |
| CN205853513U (en) * | 2016-05-26 | 2017-01-04 | 佛山美林数码影像材料有限公司 | A kind of sheet material of band crystalline substance steel membrane layer |
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Application publication date: 20190823 |