CN110144065A - A kind of antibacterial foamed shoe sole and preparation method thereof - Google Patents
A kind of antibacterial foamed shoe sole and preparation method thereof Download PDFInfo
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- CN110144065A CN110144065A CN201910399984.8A CN201910399984A CN110144065A CN 110144065 A CN110144065 A CN 110144065A CN 201910399984 A CN201910399984 A CN 201910399984A CN 110144065 A CN110144065 A CN 110144065A
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- liquid
- shoe sole
- foamed shoe
- raw material
- antibacterial
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0004—Use of compounding ingredients, the chemical constitution of which is unknown, broadly defined, or irrelevant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2307/00—Characterised by the use of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention relates to footwear material fields, a kind of antibacterial foamed shoe sole and preparation method thereof is provided, the foamed shoe sole antibacterial effect for solving the prior art is bad, poor flexibility, the big defect of taste irritation, each raw material including following parts by weight: natural rubber 35-38, butadiene rubber 20-25, anti-wear agent 15-20, mould inhibitor 14-19, talcum powder 40-45, zinc oxide 1.3-1.5, promotor 34-38, titanium dioxide 20-25, color inhibition agent 15-20, oxidant 20-23, foaming agent 12-13, pure water 60-70, kuh-seng liquid 5-8, Cortex Phellodendri liquid 3-7, scutellaria liquid 4-6, polygonum cuspidate liquid 5-8, climbing groundsel 4-6, frutus cnidii liquid 4-6.
Description
Technical field
The present invention relates to footwear material fields more particularly to a kind of antibacterial foamed shoe sole and preparation method thereof.
Background technique
Being widely used of chemical bactericide brings environmental pollution, residual hazard harm, the anti-medicine of germ, safety of human and livestock are on the hazard
A series of problems, such as.It is an effective way for developing harmless boilogical antibacterial agent that Substance is found from plant, with
This alleviates the serious pollution problem of current chemicals.Antibacterial agent currently on the market, mainly with alcohol, the tincture of iodine, acetic acid chloroethene
Pyridine is main component, and irritation is larger, has residual and stability and safety are poor.
Rubber foam soles are that leachy rubber is formed after rubber is foamed, and therefore, are had than non-foamed rubber
Lighter performance.The rubber foam soles of the prior art are easy hair since it does not have antibacterial effect, wearing a period of time rear foot bottom
It is smelly, it is harmful to human health.
Application number 201510447311.7 discloses a kind of antibacterial rubber sole, including anti-slip layer, centre in Chinese patent
Interlayer and antibiotic layer, the anti-slip layer, intermediate course and antibiotic layer are sequentially connected from outside to inside, and the antibiotic layer is by genuine milk
Glue, zinc oxide, sulphur, odium stearate, filler rubber nano active calcium carbonate powder, promotor ZDC, expands nano-titanium dioxide
Powder NF10, inhibitor, calcium carbonate and carbon black, weight percent shared by each ingredient is bacterium layer by natural emulsion in the antibiotic layer
45~55%, nano-titanium dioxide 10~15%, zinc oxide 1.5~2.5%, sulphur 2.5~3.5%, odium stearate 2.5~
5.5%, filler rubber nano active calcium carbonate powder 4.5~6.5%, promotor ZDC1.5~3.5%, diffusion agent N F100.5
~1.5%, inhibitor 2.5~3.5%, calcium carbonate 5~8%, carbon black 2.5~4.5%.The sole is provided with individual one layer and resists
Bacterium layer really plays the only natural emulsion of antibacterial action in antibiotic layer, and therefore, antibacterial effect is limited.
Summary of the invention
Therefore, for the above content, the present invention provides a kind of antibacterial foamed shoe sole and preparation method thereof, solves the prior art
The defect that foamed shoe sole antibacterial effect is bad, poor flexibility, taste irritation are big.
In order to achieve the above objectives, the present invention is achieved by the following technical solutions: a kind of antibacterial foamed shoe sole, including with
Each raw material of lower parts by weight:
A further improvement is that each raw material including following parts by weight:
A kind of preparation method of antibacterial foamed shoe sole, including following processing step:
(1) prepare raw material: each raw material described in claim 1 is weighed according to the ratio；
(2) pre-process major ingredient: by natural rubber, butadiene rubber, anti-wear agent, mould inhibitor, talcum powder, zinc oxide, promotor,
Titanium dioxide, oxidant, foaming agent, is mixed evenly color inhibition agent；
(3) mixing: the major ingredient that step (2) are uniformly mixed is put into the mixer for being preheated to 180 DEG C -185 DEG C in advance, is added
Enter pure water, kuh-seng liquid, Cortex Phellodendri liquid, scutellaria liquid, polygonum cuspidate liquid, climbing groundsel, frutus cnidii liquid, banbury rotating speed is controlled in 80-100r/
Min, mixing to molten condition；
(4) article that step (3) are handled refining glue: is smelt glue sheet；The glue sheet article with a thickness of 5-30mm；
(5) it is put into mold molding: the glue sheet article that step (4) obtains is put into mold, vulcanization is integrally formed, vulcanization
The processing time is 600-680s, and mold temperature is 180 DEG C -185 DEG C；
(6) it demoulds；
(7) it cuts, deburring, obtains antibacterial foamed shoe-pad.
By using preceding solution, the beneficial effects of the present invention are:
Antibacterial foamed shoe sole of the invention, uses formula as below: natural rubber 35-38, butadiene rubber 20-25, wear-resisting
Agent 15-20, mould inhibitor 14-19, talcum powder 40-45, zinc oxide 1.3-1.5, promotor 34-38, titanium dioxide 20-25, color inhibition
Agent 15-20, oxidant 20-23, foaming agent 12-13, pure water 60-70, kuh-seng liquid 5-8, Cortex Phellodendri liquid 3-7, scutellaria liquid 4-6, polygonum cuspidate
Liquid 5-8, climbing groundsel 4-6, frutus cnidii liquid 4-6.Using rubber as major ingredient, the auxiliary agents such as foaming agent, promotor, zinc oxide, oxidation is added
Zinc has the function of promotion each component mobility, and for keeping sole bulk, foam thickness is controlled in 5-30mm, promotor foaming agent
For controlling the dosage of foaming, the realization of foam thickness, pure water, kuh-seng liquid, Cortex Phellodendri liquid, scutellaria liquid, polygonum cuspidate liquid, a thousand li are assisted
Light, frutus cnidii liquid are the composition of Chinese medicine antibacterial liquid, and using the antimicrobial fluid of traditional Chinese medicinal components, good anti-bacterial effect can resist large intestine bar
The strains such as bacterium, golden yellow staphylococcus, the generation of prevention foot odor；It is not added with glue in sole, makes sole integrally and will not have and is pungent
Taste.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and the realization process for reaching technical effect can fully understand and implement.
Unless otherwise specified, the conventional hand that technological means employed in embodiment is well known to those skilled in the art
Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it
Constituent person is indicated on the first occurrence.
Embodiment one
A kind of antibacterial foamed shoe sole, each raw material including following parts by weight:
A kind of preparation method of antibacterial foamed shoe sole, including following processing step:
(1) prepare raw material: above-mentioned each raw material is weighed according to the ratio；
(2) pre-process major ingredient: by natural rubber, butadiene rubber, anti-wear agent, mould inhibitor, talcum powder, zinc oxide, promotor,
Titanium dioxide, oxidant, foaming agent, is mixed evenly color inhibition agent；
(3) mixing: the major ingredient that step (2) are uniformly mixed is put into the mixer for being preheated to 180 DEG C -185 DEG C in advance, is added
Enter pure water, kuh-seng liquid, Cortex Phellodendri liquid, scutellaria liquid, polygonum cuspidate liquid, climbing groundsel, frutus cnidii liquid, banbury rotating speed is controlled in 80-100r/
Min, mixing to molten condition；
(4) article that step (3) are handled refining glue: is smelt glue sheet；The glue sheet article with a thickness of 5-30mm；
(5) it is put into mold molding: the glue sheet article that step (4) obtains is put into mold, vulcanization is integrally formed, vulcanization
The processing time is 600-680s, and mold temperature is 180 DEG C -185 DEG C；
(6) it demoulds；
(7) it cuts, deburring, obtains antibacterial foamed shoe-pad.
By using preceding solution, the beneficial effects of the present invention are:
Antibacterial foamed shoe sole of the invention, uses formula as below: natural rubber 35-38, butadiene rubber 20-25, wear-resisting
Agent 15-20, mould inhibitor 14-19, talcum powder 40-45, zinc oxide 1.3-1.5, promotor 34-38, titanium dioxide 20-25, color inhibition
Agent 15-20, oxidant 20-23, foaming agent 12-13, pure water 60-70, kuh-seng liquid 5-8, Cortex Phellodendri liquid 3-7, scutellaria liquid 4-6, polygonum cuspidate
Liquid 5-8, climbing groundsel 4-6, frutus cnidii liquid 4-6.Using rubber as major ingredient, the auxiliary agents such as foaming agent, promotor, zinc oxide, oxidation is added
Zinc has the function of promotion each component mobility, and for keeping sole bulk, foam thickness is controlled in 5-30mm, promotor foaming agent
For controlling the dosage of foaming, the realization of foam thickness, pure water, kuh-seng liquid, Cortex Phellodendri liquid, scutellaria liquid, polygonum cuspidate liquid, a thousand li are assisted
Light, frutus cnidii liquid are the composition of Chinese medicine antibacterial liquid, and using the antimicrobial fluid of traditional Chinese medicinal components, good anti-bacterial effect can resist large intestine bar
The strains such as bacterium, golden yellow staphylococcus, the generation of prevention foot odor；It is not added with glue in sole, makes sole integrally and will not have and is pungent
Taste.
Each raw material is commercially available in the present embodiment arrives.
Embodiment two
A kind of antibacterial foamed shoe sole, including outsole and the indsole being arranged in outsole composition, the outsole is by following weight
Each raw material composition of part:
Natural rubber 36, butadiene rubber 24, anti-wear agent 18, mould inhibitor 16, talcum powder 42, zinc oxide 1.4, promotor
DM14.5, titanium dioxide 22, captax grain 20, color inhibition agent 18,
Oxidant 20, foaming agent 12.5,10 parts by weight of white pigment, pure water 70, kuh-seng liquid 5, Cortex Phellodendri liquid 5, scutellaria liquid 5,
Polygonum cuspidate liquid 5, climbing groundsel 5, frutus cnidii liquid 5.
The formula of said midsole and outsole have a slightly difference, and pigment is yellow uitramarine and 10 parts by weight, other formulas with
Outsole is consistent.
Preparation method reference implementation example one, the difference with embodiment one are as follows: after step (3) outsole raw material adds directly
Each raw material of indsole is added directly into mixer and carries out mixing, other steps are as embodiment one.
Embodiment three
A kind of antibacterial foamed shoe sole is made of each raw material of following parts by weight:
Natural rubber 38, butadiene rubber 25, anti-wear agent 20, mould inhibitor 19, talcum powder 45, zinc oxide 1.5, promotor 38,
Titanium dioxide 25, color inhibition agent 20, oxidant 23, foaming agent 13, pure water 70, kuh-seng liquid 8, Cortex Phellodendri liquid 7, scutellaria liquid 6, polygonum cuspidate liquid
8, climbing groundsel 4-6, frutus cnidii liquid 4-6.
Preparation method and embodiment one are consistent.
Wherein, sole of the invention can also be that bottom of multilayer shoe structure is directly integrally formed, and the color of each layer sole can
To be designed according to the demand of client.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the patents of this creation opinion, and is not limited to those disclosed embodiments.
Claims (3)
1. a kind of antibacterial foamed shoe sole, which is characterized in that each raw material including following parts by weight:
2. a kind of antibacterial foamed shoe sole, which is characterized in that each raw material including following parts by weight:
3. according to claim 1 a kind of antibacterial foamed shoe sole preparation method, which is characterized in that including following processing walk
It is rapid:
(1) prepare raw material: each raw material described in claim 1 is weighed according to the ratio；
(2) major ingredient is pre-processed: by natural rubber, butadiene rubber, anti-wear agent, mould inhibitor, talcum powder, zinc oxide, promotor, titanium white
Powder, oxidant, foaming agent, is mixed evenly color inhibition agent；
(3) mixing: the major ingredient that step (2) are uniformly mixed is put into the mixer for being preheated to 180 DEG C -185 DEG C in advance, is added pure
Water, kuh-seng liquid, Cortex Phellodendri liquid, scutellaria liquid, polygonum cuspidate liquid, climbing groundsel, frutus cnidii liquid, tea polyphenols and far-infrared powder, banbury rotating speed control
System is in 80-100r/min, mixing to molten condition；
(4) article that step (3) are handled refining glue: is smelt glue sheet；The glue sheet article with a thickness of 5-30mm；
(5) it is put into mold molding: the glue sheet article that step (4) obtains is put into mold, vulcanization is integrally formed, vulcanizing treatment
Time is 600-680s, and mold temperature is 180 DEG C -185 DEG C；
(6) it demoulds；
(7) it cuts, deburring, obtains antibacterial foamed shoe-pad.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910399984.8A CN110144065A (en) | 2019-05-14 | 2019-05-14 | A kind of antibacterial foamed shoe sole and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910399984.8A CN110144065A (en) | 2019-05-14 | 2019-05-14 | A kind of antibacterial foamed shoe sole and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110144065A true CN110144065A (en) | 2019-08-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201910399984.8A Pending CN110144065A (en) | 2019-05-14 | 2019-05-14 | A kind of antibacterial foamed shoe sole and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804241A (en) * | 2019-11-12 | 2020-02-18 | 泉州星竹鞋材有限公司 | Preparation method of high-elastic sole for EVA insole |
| CN112029159A (en) * | 2020-06-03 | 2020-12-04 | 刘晓飞 | Natural rubber traditional Chinese medicine foaming insole, foaming shoe and manufacturing method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120021903A (en) * | 2010-08-20 | 2012-03-09 | 코오롱인더스트리 주식회사 | Composition for outsole and shoes manufactured by the same |
| CN103589031A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial foamed rubber sole material |
| CN103689855A (en) * | 2013-12-27 | 2014-04-02 | 石狮蚂蚁城鞋服有限公司 | Durable leather shoe with sterilization and deodorization effects |
| CN105218884A (en) * | 2015-11-13 | 2016-01-06 | 河南荣光鞋业有限公司 | Wear-resistant sole material and manufacture method thereof |
| CN109233260A (en) * | 2018-07-05 | 2019-01-18 | 李丙礼 | A kind of preparation method of antibacterial and deodouring sole |
-
2019
- 2019-05-14 CN CN201910399984.8A patent/CN110144065A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120021903A (en) * | 2010-08-20 | 2012-03-09 | 코오롱인더스트리 주식회사 | Composition for outsole and shoes manufactured by the same |
| CN103589031A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial foamed rubber sole material |
| CN103689855A (en) * | 2013-12-27 | 2014-04-02 | 石狮蚂蚁城鞋服有限公司 | Durable leather shoe with sterilization and deodorization effects |
| CN105218884A (en) * | 2015-11-13 | 2016-01-06 | 河南荣光鞋业有限公司 | Wear-resistant sole material and manufacture method thereof |
| CN109233260A (en) * | 2018-07-05 | 2019-01-18 | 李丙礼 | A kind of preparation method of antibacterial and deodouring sole |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804241A (en) * | 2019-11-12 | 2020-02-18 | 泉州星竹鞋材有限公司 | Preparation method of high-elastic sole for EVA insole |
| CN112029159A (en) * | 2020-06-03 | 2020-12-04 | 刘晓飞 | Natural rubber traditional Chinese medicine foaming insole, foaming shoe and manufacturing method |
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Application publication date: 20190820 |