CN106188725A - A kind of sole with antibiotic effect - Google Patents
A kind of sole with antibiotic effect Download PDFInfo
- Publication number
- CN106188725A CN106188725A CN201610528649.XA CN201610528649A CN106188725A CN 106188725 A CN106188725 A CN 106188725A CN 201610528649 A CN201610528649 A CN 201610528649A CN 106188725 A CN106188725 A CN 106188725A
- Authority
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- China
- Prior art keywords
- powder
- sole
- zinc oxide
- silver ion
- curcumin
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of sole with antibiotic effect, it is characterized in that, be made up of the composition of following weight: thermoplastic rubber material 200 300g, polylactic acid 15 25g, macroporous adsorbent resin 10 20g, AKD emulsion 15 25g, plasticizer 1.5 2.5g, silver ion 0.2 0.5g, antioxidant 0.5 1g, curcumin 1 4g, surfactant 1 3g, zinc oxide 0.3 1g, nano-tourmaline powder 2 4g, dry cow glue powder 1 3g, copper sulfate 0.2 0.5g, hydroxy silicon oil 0.5 1.8g, activated calcium 2 4g, tea polyphenols 0.3 1.6g, Os Caprae seu Ovis powder 0.5 2g.Add the raw materials such as AKD emulsion, silver ion and zinc oxide, it is possible to discharging its antibiotic effect slowly, penetration is strong, sole can be directly acted on, reach antibacterial, biocidal efficacies, meet people's demand to antibiosis and health-care shoes boots, expand the antibacterial range of application in footwear material field.
Description
Technical field
The present invention relates to household articles technical field, be specifically related to a kind of sole with antibiotic effect.
Background technology
Shoes are that in people's daily life, institute is indispensable, as the saying goes: a thousand miles begins with a single step.Therefore, footwear are produced
The producer of son is the most numerous, and shoes miscellaneous are complete, and can need to produce at any time difference according to user
The footwear of style, to meet different age group, different operating character and the needs of men and women.Conventional footwear are difficult to breathe freely, and are easily generated different
Taste, wears Jiu Liao foot comfort poor.Biological hologram medical evidence, it is tens of that vola arranges the heart of human body, lung, liver, kidney, gastrointestinal etc.
The specific reflection district of individual organ, stimulates these corresponding echo areas by massage, just energy dredging the meridian, regulates internal organs function, promotees
Air inlet blood flow is smooth, adjusts body de-synchronization state, reaches the purpose for the treatment of, diseases prevention, health care.This just requires that sole not only to have well
Warmth retention property, but also breathability to be had, thermal diffusivity, it is possible to rapid perspiration prevents growing of antibacterial.
On domestic and international market, existing antibiosis and health-care shoes substantially uses medicine or nano material to be made at present, and all
Simply make an issue of on the surfacing of shoe pad, or be equipped with antibacterial medicinal liquid medicated powder or by the special system to sole at shoe lining
Reaching ventilative circulation etc., do so, the antibacterial footwear not only safety of production is low, persistency, water-wash resistance and antibacterial wide spectrum
Property poor, and do not meet following health promoting shoe development trend the most widely.
Summary of the invention
The technical problem to be solved is that providing one to have kills pathogenic bacteria, improves footwear chamber internal medium, controls
More the sole of tinea pedis.
The technical problem to be solved realizes by the following technical solutions:
A kind of sole with antibiotic effect, is made up of the composition of following weight: TPR (thermoplastic rubber material) 200-
300g, polylactic acid 15-25g, macroporous adsorbent resin 10-20g, AKD emulsion 15-25g, plasticizer 1.5-2.5g, silver ion 0.2-
0.5g, antioxidant 0.5-1g, curcumin 1-4g, surfactant 1-3g, zinc oxide 0.3-1g, nano-tourmaline powder 2-4g, dry
Cow glue powder 1-3g, copper sulfate 0.2-0.5g, hydroxy silicon oil 0.5-1.8g, activated calcium 2-4g, tea polyphenols 0.3-1.6g, Os Caprae seu Ovis powder
0.5-2g；
The preferable weight of each component is: TPR (thermoplastic rubber material) 250g, polylactic acid 20g, macroporous adsorbent resin 15g,
AKD emulsion 20g, plasticizer 2g, silver ion 0.3g, antioxidant 0.7g, curcumin 2g, surfactant 2g, zinc oxide 0.5g, receive
Rice tourmaline powder 3g, dry cow glue powder 2g, copper sulfate 0.4g, hydroxy silicon oil 1g, activated calcium 3g, tea polyphenols 0.6g, Os Caprae seu Ovis powder 1g；
The preparation method of above-mentioned sole is as follows:
(1) in thermoplastic rubber material, first add macroporous adsorbent resin, hydroxy silicon oil and dry cow glue powder, pinching
In conjunction machine mixing uniformly；
(2) AKD emulsion is warming up to about 60 DEG C, adds zinc oxide, antioxidant, curcumin, nano-tourmaline powder, sulphuric acid
Copper, activated calcium, tea polyphenols each Os Caprae seu Ovis powder, continuous stirring about 10 minutes, then take out, put in the kneader in step (1)
Mixing 15-20 minute；
(3) adding polylactic acid and silver ion in the raw material mixed in step (2), at 130-180 DEG C, heat is mixed 2 little
Time, it is subsequently adding surfactant and plasticizer, is made into sizing material, send into injection machine injection mo(u)lding and prepare sole.
A kind of antibacterial shoe using above-mentioned sole to prepare, has significant antibacterial effect, it is possible to improve, treat tinea pedis, change
Kind footwear chamber interior condition.
It is generally acknowledged that anti-biotic material is only used for material surface, do not possess great oozing in view of some anti-biotic material
Ability thoroughly, say, that can penetrate some material, its antibiotic effect can be through material in material in the case of by material barrier film
Surface shows, possesses powerful penetration.The application adds AKD emulsion, copper sulfate, activated calcium, silver ion and zinc oxide
Deng raw material, it is possible to discharge its antibiotic effect slowly, penetration is strong, it is possible to directly act on sole, reaches antibacterial, sterilization merit
Effect, meets people's demand to antibiosis and health-care shoes boots, expands the antibacterial range of application in footwear material field.
The invention has the beneficial effects as follows: the present invention uses thermoplastic rubber material and polylactic acid to carry out coordinating as major ingredient,
Nonirritant, having no side effect, to human height's safety, environmentally friendly, plasticity is good, and stability is strong, and the sole of preparation is fitted
Close and make various playshoes, it is possible to effectively prevention, treatment tinea pedis, increase the breathability in footwear chamber, more comfortable when making to wear, reduce
Perspiration is discharged.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot
Close specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of sole with antibiotic effect, is made up of the composition of following weight: thermoplastic rubber material 250g, polylactic acid
Live in 20g, macroporous adsorbent resin 15g, AKD emulsion 20g, plasticizer 2g, silver ion 0.3g, antioxidant 0.7g, curcumin 2g, surface
Property agent 2g, zinc oxide 0.5g, nano-tourmaline powder 3g, dry cow glue powder 2g, copper sulfate 0.4g, hydroxy silicon oil 1g, activated calcium 3g,
Tea polyphenols 0.6g, Os Caprae seu Ovis powder 1g；
The preparation method of above-mentioned sole is as follows:
(1) in thermoplastic rubber material, first add macroporous adsorbent resin, hydroxy silicon oil and dry cow glue powder, pinching
In conjunction machine mixing uniformly；
(2) AKD emulsion is warming up to about 60 DEG C, adds zinc oxide, antioxidant, curcumin, nano-tourmaline powder, sulphuric acid
Copper, activated calcium, tea polyphenols each Os Caprae seu Ovis powder, continuous stirring about 10 minutes, then take out, put in the kneader in step (1)
Mixing 15-20 minute；
(3) adding polylactic acid and silver ion in the raw material mixed in step (2), at 130-180 DEG C, heat is mixed 2 little
Time, it is subsequently adding surfactant and plasticizer, is made into sizing material, send into injection machine injection mo(u)lding and prepare sole.
Embodiment 2
A kind of sole with antibiotic effect, is made up of the composition of following weight: TPR (thermoplastic rubber material) 300g,
Polylactic acid 25g, macroporous adsorbent resin 20g, AKD emulsion 25g, plasticizer 2.5g, silver ion 0.5g, antioxidant 1g, curcumin 4g,
Surfactant 3g, zinc oxide 1g, nano-tourmaline powder 2g, dry cow glue powder 3g, copper sulfate 0.5g, hydroxy silicon oil 1.8g, work
Property calcium 4g, tea polyphenols 1.6g, Os Caprae seu Ovis powder 2g；
The preparation method of above-mentioned sole is as follows:
(1) in thermoplastic rubber material, first add macroporous adsorbent resin, hydroxy silicon oil and dry cow glue powder, pinching
In conjunction machine mixing uniformly；
(2) AKD emulsion is warming up to about 60 DEG C, adds zinc oxide, antioxidant, curcumin, nano-tourmaline powder, sulphuric acid
Copper, activated calcium, tea polyphenols each Os Caprae seu Ovis powder, continuous stirring about 10 minutes, then take out, put in the kneader in step (1)
Mixing 15-20 minute；
(3) adding polylactic acid and silver ion in the raw material mixed in step (2), at 130-180 DEG C, heat is mixed 2 little
Time, it is subsequently adding surfactant and plasticizer, is made into sizing material, send into injection machine injection mo(u)lding and prepare sole.
Embodiment 3
A kind of sole with antibiotic effect, is made up of the composition of following weight: TPR (thermoplastic rubber material) 200g,
Polylactic acid 15g, macroporous adsorbent resin 10g, AKD emulsion 15g, plasticizer 1.5g, silver ion 0.2g, antioxidant 0.5g, curcumin
1g, surfactant 1g, zinc oxide 0.3g, nano-tourmaline powder 2g, dry cow glue powder 1g, copper sulfate 0.2g, hydroxy silicon oil
0.5g, activated calcium 2g, tea polyphenols 0.3g, Os Caprae seu Ovis powder 0.5g；
The preparation method of above-mentioned sole is as follows:
(1) in thermoplastic rubber material, first add macroporous adsorbent resin, hydroxy silicon oil and dry cow glue powder, pinching
In conjunction machine mixing uniformly；
(2) AKD emulsion is warming up to about 60 DEG C, adds zinc oxide, antioxidant, curcumin, nano-tourmaline powder, sulphuric acid
Copper, activated calcium, tea polyphenols each Os Caprae seu Ovis powder, continuous stirring about 10 minutes, then take out, put in the kneader in step (1)
Mixing 15-20 minute；
(3) adding polylactic acid and silver ion in the raw material mixed in step (2), at 130-180 DEG C, heat is mixed 2 little
Time, it is subsequently adding surfactant and plasticizer, is made into sizing material, send into injection machine injection mo(u)lding and prepare sole.
Embodiment 4
A kind of sole with antibiotic effect, is made up of the composition of following weight: TPR (thermoplastic rubber material) 300g,
Polylactic acid 15g, macroporous adsorbent resin 20g, AKD emulsion 15g, plasticizer 2.5g, silver ion 0.2g, antioxidant 1g, curcumin 1g,
Surfactant 3g, zinc oxide 0.3g, nano-tourmaline powder 4g, dry cow glue powder 1g, copper sulfate 0.5g, hydroxy silicon oil 0.5g,
Activated calcium 4g, tea polyphenols 0.3g, Os Caprae seu Ovis powder 2g；
The preparation method of above-mentioned sole is as follows:
(1) in thermoplastic rubber material, first add macroporous adsorbent resin, hydroxy silicon oil and dry cow glue powder, pinching
In conjunction machine mixing uniformly；
(2) AKD emulsion is warming up to about 60 DEG C, adds zinc oxide, antioxidant, curcumin, nano-tourmaline powder, sulphuric acid
Copper, activated calcium, tea polyphenols each Os Caprae seu Ovis powder, continuous stirring about 10 minutes, then take out, put in the kneader in step (1)
Mixing 15-20 minute；
(3) adding polylactic acid and silver ion in the raw material mixed in step (2), at 130-180 DEG C, heat is mixed 2 little
Time, it is subsequently adding surfactant and plasticizer, is made into sizing material, send into injection machine injection mo(u)lding and prepare sole.
Antimicrobial long-acting experiment (utilizing antibacterial shoe prepared by anti-biotic material of the present invention)
By 100 ages 15-35 year between bifurcation without foot fester, but the patient suffering from tinea pedis separate at random test group and
Matched group, often organizes 50 people.
Test group everyone issue the product shoes 2 pairs that sample is prepared by anti-bacteria shoe sole, matched group issues commercial antimicrobial shoe pad 2 pairs.
Mainly use by test footwear in the trial employment period for participating in the personnel of test, within every 3 days, change another a pair of shoes, the footwear passed are placed
In ventilation, wait that next time, circulation was worn.
No longer medication during test, collects the data (to the about the 60th day) of latter 30 days continuously after using 30 days.
Result of the test is: having 3 people rear feet of taking off one's shoes from the 30th day to have slight abnormal flavour in test group, 1 people was from the 50th day
Rear feet of taking off one's shoes has slight abnormal flavour, and remaining is free from extraneous odour, unmanned foot bifurcation pruritus；
Having 38 people rear feet of taking off one's shoes from the 30th day to have abnormal flavour in matched group, 4 people rear feet of taking off one's shoes from the 50th day has different
Taste, remaining is free from extraneous odour, wherein has 8 people's foot bifurcation prurituss.
As can be seen here, the antibacterial effect of antibacterial shoe prepared by the present invention has the most excellent than antibacterial insoles of the prior art
Gesture.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry
Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and
Equivalent defines.
Claims (6)
1. a sole with antibiotic effect, it is characterised in that be made up of the composition of following weight: thermoplastic rubber material
200-300g, polylactic acid 15-25g, macroporous adsorbent resin 10-20g, AKD emulsion 15-25g, plasticizer 1.5-2.5g, silver ion
0.2-0.5g, antioxidant 0.5-1g, curcumin 1-4g, surfactant 1-3g, zinc oxide 0.3-1g, nano-tourmaline powder 2-
4g, dry cow glue powder 1-3g, copper sulfate 0.2-0.5g, hydroxy silicon oil 0.5-1.8g, activated calcium 2-4g, tea polyphenols 0.3-1.6g,
Os Caprae seu Ovis powder 0.5-2g.
A kind of sole with antibiotic effect the most according to claim 1, it is characterised in that by the composition system of following weight
Become: thermoplastic rubber material 250g, polylactic acid 20g, macroporous adsorbent resin 15g, AKD emulsion 20g, plasticizer 2g, silver ion
0.3g, antioxidant 0.7g, curcumin 2g, surfactant 2g, zinc oxide 0.5g, nano-tourmaline powder 3g, dry cow glue powder 2g,
Copper sulfate 0.4g, hydroxy silicon oil 1g, activated calcium 3g, tea polyphenols 0.6g, Os Caprae seu Ovis powder 1g.
A kind of sole with antibiotic effect the most according to claim 1, it is characterised in that by the composition system of following weight
Become: thermoplastic rubber material 300g, polylactic acid 25g, macroporous adsorbent resin 20g, AKD emulsion 25g, plasticizer 2.5g, silver ion
0.5g, antioxidant 1g, curcumin 4g, surfactant 3g, zinc oxide 1g, nano-tourmaline powder 2g, dry cow glue powder 3g, sulphuric acid
Copper 0.5g, hydroxy silicon oil 1.8g, activated calcium 4g, tea polyphenols 1.6g, Os Caprae seu Ovis powder 2g.
A kind of sole with antibiotic effect the most according to claim 1, it is characterised in that by the composition system of following weight
Become: thermoplastic rubber material 200g, polylactic acid 15g, macroporous adsorbent resin 10g, AKD emulsion 15g, plasticizer 1.5g, silver ion
0.2g, antioxidant 0.5g, curcumin 1g, surfactant 1g, zinc oxide 0.3g, nano-tourmaline powder 2g, dry cow glue powder 1g,
Copper sulfate 0.2g, hydroxy silicon oil 0.5g, activated calcium 2g, tea polyphenols 0.3g, Os Caprae seu Ovis powder 0.5g.
5. prepare the method for sole described in any one of claim 1-4 for one kind, it is characterised in that step is as follows:
(1) in thermoplastic rubber material, macroporous adsorbent resin, hydroxy silicon oil and dry cow glue powder are first added, at kneader
In mixing uniformly；
(2) AKD emulsion is warming up to about 60 DEG C, add zinc oxide, antioxidant, curcumin, nano-tourmaline powder, copper sulfate,
Activated calcium, tea polyphenols each Os Caprae seu Ovis powder, continuous stirring about 10 minutes, then take out, put in the kneader in step (1) mixing
15-20 minute；
(3) raw material mixed in step (2) adds polylactic acid and silver ion, mixed 2 hours of heat at 130-180 DEG C, so
Rear addition surfactant and plasticizer, be made into sizing material, sends into injection machine injection mo(u)lding and prepares sole.
6. the application in preparation antibacterial shoe of the sole described in an any one of claim 1-4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610528649.XA CN106188725A (en) | 2016-07-06 | 2016-07-06 | A kind of sole with antibiotic effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610528649.XA CN106188725A (en) | 2016-07-06 | 2016-07-06 | A kind of sole with antibiotic effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106188725A true CN106188725A (en) | 2016-12-07 |
Family
ID=57465620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610528649.XA Pending CN106188725A (en) | 2016-07-06 | 2016-07-06 | A kind of sole with antibiotic effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106188725A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109851371A (en) * | 2019-04-10 | 2019-06-07 | 肇庆市盛浩新材料科技有限公司 | A kind of high-efficiency antimicrobial new material and preparation method thereof for ceramics and quartz plate |
| CN111290051A (en) * | 2020-04-08 | 2020-06-16 | 中国科学院西北生态环境资源研究院 | Desert meteorological monitoring device and monitoring method thereof |
| CN112592568A (en) * | 2020-12-15 | 2021-04-02 | 衡阳丰泰鞋业有限公司 | Light-weight high-wear-resistance sports shoe sole material and preparation method thereof |
| CN114133747A (en) * | 2021-12-31 | 2022-03-04 | 浙江恒诚鞋业有限公司 | Antibacterial insole and preparation method thereof |
| CN115011060A (en) * | 2022-05-06 | 2022-09-06 | 茂泰(福建)鞋材有限公司 | Semitransparent thermoplastic rubber sole, semitransparent thermoplastic elastomer composition for sole and preparation method thereof |
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| CN2599953Y (en) * | 2002-12-10 | 2004-01-21 | 上海蓝戈科技发展有限公司 | Multifunctional health-care slippers with bactericidal and deodorization function |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109851371A (en) * | 2019-04-10 | 2019-06-07 | 肇庆市盛浩新材料科技有限公司 | A kind of high-efficiency antimicrobial new material and preparation method thereof for ceramics and quartz plate |
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| CN111290051A (en) * | 2020-04-08 | 2020-06-16 | 中国科学院西北生态环境资源研究院 | Desert meteorological monitoring device and monitoring method thereof |
| CN112592568A (en) * | 2020-12-15 | 2021-04-02 | 衡阳丰泰鞋业有限公司 | Light-weight high-wear-resistance sports shoe sole material and preparation method thereof |
| CN112592568B (en) * | 2020-12-15 | 2022-09-02 | 莆田市城厢区恒鑫鞋材有限公司 | Light-weight high-wear-resistance sports shoe sole material and preparation method thereof |
| CN114133747A (en) * | 2021-12-31 | 2022-03-04 | 浙江恒诚鞋业有限公司 | Antibacterial insole and preparation method thereof |
| CN115011060A (en) * | 2022-05-06 | 2022-09-06 | 茂泰(福建)鞋材有限公司 | Semitransparent thermoplastic rubber sole, semitransparent thermoplastic elastomer composition for sole and preparation method thereof |
| CN115011060B (en) * | 2022-05-06 | 2024-05-10 | 茂泰(福建)新材料科技有限公司 | Semitransparent thermoplastic rubber sole, semitransparent thermoplastic elastomer composition for sole and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20161207 |