CN104497425A - Antibacterial deodorant sponge insole and manufacture method thereof - Google Patents
Antibacterial deodorant sponge insole and manufacture method thereof Download PDFInfo
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- CN104497425A CN104497425A CN201410713048.7A CN201410713048A CN104497425A CN 104497425 A CN104497425 A CN 104497425A CN 201410713048 A CN201410713048 A CN 201410713048A CN 104497425 A CN104497425 A CN 104497425A
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- pad
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- shoe
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention relates to an antibacterial deodorant insole and a manufacture method thereof, belonging to the technical field of shoemaking. The manufacture method disclosed by the invention comprises preparation of antibacterial deodorant silica sol and preparation of an antibacterial deodorant silica sol insole. The manufacture method comprises the following steps of: doping an organic antibacterial component, namely a silver zeolite antibacterial agent, in silica sol at first time, and then, dispersing silica soil carrying silver zeolite dispersion liquid in a rubber sponge insole. The insole manufactured by the manufacture method not only has rubber sponge resilience and breathability but also has an obvious antibacterial effect to escherichia coli and staphylococcus aureus.
Description
Technical field
The present invention relates to a kind of shoe-pad, particularly relate to a kind of antibacterial deodourizing foamed shoe-pad and preparation method thereof, belong to shoemaking production technical field.
Background technology
Shoe-pad, as the traditional product of China, has the history of several thousand.In modern society, along with scientific-technical progress, this product closely bound up with life of shoe-pad, has broken away from the simple function of the size of adjustment shoes, has progressively developed into foodcare product; Join product from simple footwear, develop into an emerging independently industry, being one has present flourish vital, vigorous sunrise industry.
Along with the enhancing of the development of science and technology, the raising of people's living standard and health environment-friendly consciousness, people to the requirement of footwear also gradually, windproof and rain proof ventilative from soft comfortable, moisture absorption etc. expand to the aspects such as anti-mould and anti-moth, deodorization, health care be nontoxic.Footwear are daily necessitiess that everyone will wear, and all one's life of people has the time of 2/3 to wear shoes.Most people is in the process wearing footwear boots, especially after summer and motion, because sweat secretion amount increases severely, microorganism is breeding at a high speed, organism in a large amount of decomposition sweat and produce stench, if things go on like this even cause a series of illness such as pin is smelly, the ringworm of the foot, tinea pedis, beriberi, directly affect the physical and mental health of people.
Shoe-pad is along with the progress of science and technology, scientific and technological content improves day by day, human physilogical characteristic and body mechanics and sport dynamics principle, area of computer aided are more and more applied to insole design and in producing, the traditional Chinese medical science " plantar reflecting region is theoretical " is widely used in insole products, and the novel materials such as nano material, cushioning material, magnetic therapy material, sorbing material, anti-antibacterial material are also applied in insole products by a large amount of.
Vola is considered as " the second heart " " root of essence and blood " " foundation stone of HUMAN HEALTH " by current medical circle, and one has started to become one of chief-criminal affecting state's living quality of patients to unvalued foot affliction.As, quotidian beriberi, pin are smelly, pin sweat; The foot of the generation often worn high heels is uncomfortable, long pin cocoon or foot's distortion; Be engaged in for a long time stand, shoe-pad that the crowd of work of walking and the elderly also need a pair of comfortable, soft; Diabetic foot is the crippling complication of diabetes chronic, and current sickness rate is high etc., all becomes the ample scope for abilities of this healthcare products of shoe-pad.
Utilize method one class of antiseptic-germicide deodorizing to be in shoe-pad, spray some volatile medicine in current shoe products, the fragrance distributed with it is to suppress the stench produced in footwear; Another kind of is adsorbed form material, the surface-area utilizing material huge and intrinsic high surface energy thereof to ambient substance produce powerful adsorptive power.But these methods can only simply deodorizing, and can not play to the bacterium grown in footwear, fungi the effect killed, and then brings out the disease such as beriberi, the ringworm of the foot.
Chinese invention: 03115625.8 discloses a kind of antibacterial deodorization insole, this shoe-pad is on the basis of traditional sock, being have employed by the positive layer of shoe-pad by bamboo fibers is the fabric that raw material is made, or all to adopt by bamboo fibers by the positive layer of shoe-pad and bottom surface layer be the fabric that raw material is made.This patent of invention utilizes bamboo fibers to have natural antibacterial, and it all has good anti-microbial effect to tinea alba bacterium, staphylococcus aureus, MRSA bacterium, intestinal bacteria etc., is to adopt the method for physics to reach antibacterial deodourizing effect.
Summary of the invention
The object of this invention is to provide a kind of antibacterial deodourizing foamed shoe-pad and preparation method thereof, not only there is with the shoe-pad that the method makes rebound resilience and the ventilation property of rubber pange, significant antibacterial effect can also be played to intestinal bacteria and streptococcus aureus.
In order to reach above object, the present invention by the following technical solutions:
A kind of antibacterial deodourizing foamed shoe-pad, described foamed shoe-pad comprises the material of following weight part:
Terpolymer EP rubber: 100 parts
Vulcanizing agent: 1-5 part
Tune fills agent: 80-150 part
Softening agent: 40-68 part
Whipping agent: 1-5 part
Silver zeolite: 0.5-2.5 part
Silica gel: 2-8 part.
A making method for antibacterial deodourizing foamed shoe-pad, comprises the steps:
(1) preparation of load silver zeolite liquid: 30-50g CMC-Na adds in the beaker of the 40-50mL1-5% zeolite with carrying silver aqueous solution, regulation system pH value is 8.0-10.5, then with the rotating speed high speed shear 30min of 4000rpm, stand-by;
(2) 10-25g organism, adds 20-35g anhydrous sodium carbonate after mixing, stirring and using concentration to be the hydrochloric acid conditioning solution pH of the NaOH and 10% of 0.2mol/L is 1.5-3.5, then at 30 DEG C, 2-6 hour is stirred with motor stirrer, make it peptization, obtained transparent colloidal sol, stand-by;
(3) above-mentioned (1) and (2) liquid be uniformly mixed and regulate pH to be 1.0-3.5, vibrating 2-15min with ultrasonic cleaner;
(4) terpolymer EP rubber is joined in banburying chamber the 2-5min that plasticates, plasticating temperature 65-85 DEG C;
(5) then weighting agent, to 95-120 DEG C, is dropped into banburying 2-10min in banburying chamber by raised temperature, obtains refining glue;
(6) by vulcanizing agent, whipping agent and softening agent mixing 1.5:1:1(mass ratio) grind afterwards and make paste, grinding temperature <50 DEG C;
(7) the refining glue (5) obtained and mixing with the paste arrived of (6), and the mixture 200r/min obtained with (3), mixing 10-50min;
(8) the refining glue (7) obtained drops into pressure roller 4-7mm in mill, and it is shaping to carry out cut-parts to gum stock by shoe-pad model cavity size;
(9) film cut out in (8) is loaded matched moulds sulfuration in mold cavity, curing temperature is 150-250 DEG C, pressure 5-15mPa, and curing time is 5-35min;
(10) hot demoulding, deburring obtains object product.
The invention has the beneficial effects as follows: the shoe-pad that this method makes not only has rebound resilience and the ventilation property of rubber pange, can also play significant antibacterial effect to intestinal bacteria and streptococcus aureus.
Accompanying drawing explanation
Fig. 1 is the fabrication processing figure of antibacterial deodourizing foamed shoe-pad.
Embodiment
Be described in further details the present invention below by example, these examples are only used for the present invention is described, do not limit the scope of the invention.
Embodiment 1
A kind of antibacterial deodourizing foamed shoe-pad, described foamed shoe-pad comprises the material of following weight part:
Terpolymer EP rubber: 100 parts
Vulcanizing agent: 1 part
Tune fills agent: 80 parts
Softening agent: 40 parts
Whipping agent: 1 part
Silver zeolite: 0.5 part
Silica gel: 2 parts;
Its making method is as follows:
(1) preparation of load silver zeolite liquid: 30g CMC-Na adds in the beaker of the 50mL 3% zeolite with carrying silver aqueous solution, and regulation system pH value is 8.5, then with the rotating speed high speed shear 30min of 4000rpm, stand-by;
(2) 20g organism, adds 20g anhydrous sodium carbonate after mixing, stirring and using concentration to be the hydrochloric acid conditioning solution pH of the NaOH and 10% of 0.2mol/L is 2.5, then at 30 DEG C, 3 hours are stirred with motor stirrer, make it peptization, obtained transparent colloidal sol, stand-by;
(3) above-mentioned (1) and (2) liquid be uniformly mixed and regulate pH to be 2.5, vibrating 8min with ultrasonic cleaner;
(4) terpolymer EP rubber is joined in banburying chamber the 3min that plasticates, plasticating temperature 75 DEG C;
(5) then raised temperature to 100 DEG C, drops into banburying 6min in banburying chamber by weighting agent, obtain refining glue;
(6) by vulcanizing agent, whipping agent and softening agent mixing 1.5:1:1(mass ratio) grind afterwards and make paste, grinding temperature <50 DEG C;
(7) the refining glue (5) obtained and mixing with the paste arrived of (6), and the mixture 200r/min obtained with (3), mixing 30min;
(8) the refining glue (7) obtained drops into pressure roller 7mm in mill, and it is shaping to carry out cut-parts to gum stock by shoe-pad model cavity size;
(9) film cut out in (8) is loaded matched moulds sulfuration in mold cavity, curing temperature is 250 DEG C, pressure 10mPa, and curing time is 15min;
(10) hot demoulding, deburring obtains object product.
Embodiment 2
A kind of antibacterial deodourizing foamed shoe-pad, described foamed shoe-pad comprises the material of following weight part:
Terpolymer EP rubber: 100 parts
Vulcanizing agent: 5 parts
Tune fills agent: 150 parts
Softening agent: 68 parts
Whipping agent: 5 parts
Silver zeolite: 2.5 parts
Silica gel: 8 parts;
Its making method is as follows:
(1) preparation of load silver zeolite liquid: 50g CMC-Na adds in the beaker of the 50mL 5% zeolite with carrying silver aqueous solution, and regulation system pH value is 9.5, then with the rotating speed high speed shear 30min of 4000rpm, stand-by;
(2) 15g organism, adds 25g anhydrous sodium carbonate after mixing, stirring and using concentration to be the hydrochloric acid conditioning solution pH of the NaOH and 10% of 0.2mol/L is 2.5, then at 30 DEG C, 4 hours are stirred with motor stirrer, make it peptization, obtained transparent colloidal sol, stand-by;
(3) above-mentioned (1) and (2) liquid be uniformly mixed and regulate pH to be 2.5, vibrating 10min with ultrasonic cleaner;
(4) terpolymer EP rubber is joined in banburying chamber the 5min that plasticates, plasticating temperature 75 DEG C;
(5) then raised temperature to 95 DEG C, drops into banburying 8min in banburying chamber by weighting agent, obtain refining glue;
(6) by vulcanizing agent, whipping agent and softening agent mixing 1.5:1:1(mass ratio) grind afterwards and make paste, grinding temperature <50 DEG C;
(7) the refining glue (5) obtained and mixing with the paste arrived of (6), and the mixture 200r/min obtained with (3), mixing 30min;
(8) the refining glue (7) obtained drops into pressure roller 6mm in mill, and it is shaping to carry out cut-parts to gum stock by shoe-pad model cavity size;
(9) film cut out in (8) is loaded matched moulds sulfuration in mold cavity, curing temperature is 200 DEG C, pressure 10mPa, and curing time is 25min;
(10) hot demoulding, deburring obtains object product.
Embodiment 3
A kind of antibacterial deodourizing foamed shoe-pad, described foamed shoe-pad comprises the material of following weight part:
Terpolymer EP rubber: 100 parts
Vulcanizing agent: 3 parts
Tune fills agent: 110 parts
Softening agent: 55 parts
Whipping agent: 3 parts
Silver zeolite: 1.5 parts
Silica gel: 6 parts;
Its making method is as follows:
(1) preparation of load silver zeolite liquid: 48g CMC-Na adds in the beaker of the 40mL 6% zeolite with carrying silver aqueous solution, and regulation system pH value is 8.5, then with the rotating speed high speed shear 30min of 4000rpm, stand-by;
(2) 17g organism, adds 23g anhydrous sodium carbonate after mixing, stirring and using concentration to be the hydrochloric acid conditioning solution pH of the NaOH and 10% of 0.2mol/L is 2.5, then at 30 DEG C, 4 hours are stirred with motor stirrer, make it peptization, obtained transparent colloidal sol, stand-by;
(3) above-mentioned (1) and (2) liquid be uniformly mixed and regulate pH to be 3.5, vibrating 10min with ultrasonic cleaner;
(4) terpolymer EP rubber is joined in banburying chamber the 6min that plasticates, plasticating temperature 75 DEG C;
(5) then raised temperature to 95 DEG C, drops into banburying 8min in banburying chamber by weighting agent, obtain refining glue;
(6) by vulcanizing agent, whipping agent and softening agent mixing 1.5:1:1(mass ratio) grind afterwards and make paste, grinding temperature <50 DEG C;
(7) the refining glue (5) obtained and mixing with the paste arrived of (6), and the mixture 200r/min obtained with (3), mixing 30min;
(8) the refining glue (7) obtained drops into pressure roller 5mm in mill, and it is shaping to carry out cut-parts to gum stock by shoe-pad model cavity size;
(9) film cut out in (8) is loaded matched moulds sulfuration in mold cavity, curing temperature is 220 DEG C, pressure 15mPa, and curing time is 15min;
(10) hot demoulding, deburring obtains object product.
Claims (4)
1. an antibacterial deodourizing foamed shoe-pad, is characterized in that: described foamed shoe-pad comprises the material of following weight part:
Terpolymer EP rubber: 100 parts
Vulcanizing agent: 1-5 part
Tune fills agent: 80-150 part
Softening agent: 40-68 part
Whipping agent: 1-5 part
Silver zeolite: 0.5-2.5 part
Silica gel: 2-8 part.
2. a making method for antibacterial deodourizing foamed shoe-pad, is characterized in that: comprise the following steps:
(1) preparation of load silver zeolite liquid: 3-5g Xylo-Mucine CMC-Na adds in the beaker of the 40-50mL1-5% zeolite with carrying silver aqueous solution, regulation system pH value is 8.0-10.5, then with the rotating speed high speed shear 30min of 4000rpm, stand-by;
(2) 10-25g organism, adds 200-350g anhydrous sodium carbonate after mixing, stirring and using concentration to be the hydrochloric acid conditioning solution pH of the NaOH and 10% of 0.2mol/L is 1.5-3.5, then use at 30 DEG C and stir 2-6 hour, make it peptization, obtained transparent colloidal sol, stand-by;
(3) (1) and (2) liquid be uniformly mixed and regulate pH to be 1.0-3.5, vibrating 2-15min with ultrasonic cleaner;
(4) terpolymer EP rubber is joined in banburying chamber the 2-5min that plasticates, plasticating temperature 65-85 DEG C;
(5) then weighting agent, to 95-120 DEG C, is dropped into banburying 2-10min in banburying chamber by raised temperature, obtains refining glue;
(6) by vulcanizing agent, whipping agent and softening agent mixing 1.5:1:1(mass ratio) grind afterwards and make paste, grinding temperature <50 DEG C;
(7) the refining glue (5) obtained and mixing with the paste arrived of (6), and the mixture 200r/min obtained with (3), mixing 10-50min;
(8) the refining glue (7) obtained drops into pressure roller 4-7mm in mill, and it is shaping to carry out cut-parts to gum stock by shoe-pad model cavity size;
(9) film cut out in (8) is loaded matched moulds sulfuration in mold cavity, curing temperature is 150-250 DEG C, pressure 5-15mPa, and curing time is 5-35min;
(10) hot demoulding, deburring, obtains object product.
3. power requires the making method of a kind of antibacterial deodourizing foamed shoe-pad described in 2 according to profit, it is characterized in that: the Xylo-Mucine of 10-20% joins in the zeolite with carrying silver aqueous solution, and regulates pH8.0-10.5.
4. power requires a kind of antibacterial deodourizing foamed shoe-pad described in 2 and preparation method thereof according to profit, it is characterized in that: load silver zeolite sol solutions mixes with the rubber after banburying and additive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410713048.7A CN104497425A (en) | 2014-12-02 | 2014-12-02 | Antibacterial deodorant sponge insole and manufacture method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410713048.7A CN104497425A (en) | 2014-12-02 | 2014-12-02 | Antibacterial deodorant sponge insole and manufacture method thereof |
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| Publication Number | Publication Date |
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| CN104497425A true CN104497425A (en) | 2015-04-08 |
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| CN201410713048.7A Pending CN104497425A (en) | 2014-12-02 | 2014-12-02 | Antibacterial deodorant sponge insole and manufacture method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273319A (en) * | 2015-12-01 | 2016-01-27 | 吴江市风尚鞋厂 | Wear-resistant antibacterial shoe material and preparation method thereof |
| CN105295204A (en) * | 2015-11-18 | 2016-02-03 | 吴江市风尚鞋厂 | Antibacterial and deodorant composite shoe material and preparation method thereof |
| CN105295207A (en) * | 2015-12-01 | 2016-02-03 | 吴江市风尚鞋厂 | Anti-bacterium and deodorization insole material and preparation method thereof |
| CN105924806A (en) * | 2016-05-25 | 2016-09-07 | 广州聚注专利研发有限公司 | Ethylene-propylene-diene monomer rubber foam material and preparation method thereof |
| CN106188725A (en) * | 2016-07-06 | 2016-12-07 | 赵小雷 | A kind of sole with antibiotic effect |
-
2014
- 2014-12-02 CN CN201410713048.7A patent/CN104497425A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295204A (en) * | 2015-11-18 | 2016-02-03 | 吴江市风尚鞋厂 | Antibacterial and deodorant composite shoe material and preparation method thereof |
| CN105273319A (en) * | 2015-12-01 | 2016-01-27 | 吴江市风尚鞋厂 | Wear-resistant antibacterial shoe material and preparation method thereof |
| CN105295207A (en) * | 2015-12-01 | 2016-02-03 | 吴江市风尚鞋厂 | Anti-bacterium and deodorization insole material and preparation method thereof |
| CN105924806A (en) * | 2016-05-25 | 2016-09-07 | 广州聚注专利研发有限公司 | Ethylene-propylene-diene monomer rubber foam material and preparation method thereof |
| CN106188725A (en) * | 2016-07-06 | 2016-12-07 | 赵小雷 | A kind of sole with antibiotic effect |
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Application publication date: 20150408 |