CN105218884A - Wear-resistant sole material and manufacture method thereof - Google Patents
Wear-resistant sole material and manufacture method thereof Download PDFInfo
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Abstract
The invention provides a kind of Wear-resistant sole material, does according to listed as parts by weight, it comprise following raw material: No. 3 smoked sheet 40-60 parts, cis-1,4-polybutadiene rubber 40-60 part, zinc oxide 3-5 part, stearic acid 0.7-1.3 part, glycol ether 4-6 part, promotor 3-4.2 part, anti-aging agent RD Z? 0.8-1.2 part, heat resistanceheat resistant oxygen agent RF? 1.7-2.4 part, sulphur 1.7-2.3 part, machinery oil 12-22 part and white carbon black 42-56 part.The present invention also provides a kind of manufacture method of above-mentioned Wear-resistant sole material.Above-mentioned Wear-resistant sole material in the fabrication process environmental friendliness, pollute smaller.
Description
Technical field
The present invention relates to a kind of Wear-resistant sole material and manufacture method thereof.
Background technology
At present, the body material of material for sole of shoe mainly comprises TPR(thermoplastic elastomer), one or more in EVA, rubber, urethane etc.Material for sole of shoe mainly comprises main gel, promotor, promoting agent, weighting agent, strengthening agent, anti-aging agent, oxidation inhibitor, softening agent and sulphonating agent etc.The wear resistance of material for sole of shoe is the important factor affecting sole quality, especially makes to instruct the sole of special purpose shoes as military products People's Armed Police most important.
Summary of the invention
In view of this, the present invention is necessary provides the reasonable Wear-resistant sole material of a kind of wear resistance and manufacture method thereof.
Particularly, the invention provides a kind of Wear-resistant sole material, according to listed as parts by weight, it comprises following raw material: No. 3 smoked sheet 40-60 parts, cis-1,4-polybutadiene rubber 40-60 part, zinc oxide 3-5 part, stearic acid 0.7-1.3 part, glycol ether 4-6 part, promotor 3-4.2 part, anti-aging agent RD Z0.8-1.2 part, heat resistanceheat resistant oxygen agent RF1.7-2.4 part, sulphur 1.7-2.3 part, machinery oil 12-22 part and white carbon black 42-56 parts.
Based on above-mentioned, it is also comprising toner 15-25 part.
Based on above-mentioned, described tinting material is the various pigment such as black masterbatch or ultramarine.
Based on above-mentioned, it also comprises paraffin 0.22-0.38 part.
Based on above-mentioned, described promotor is promotor PX, altax, vulkacit D or M.Wherein, promotor mainly in order to the complex reaction such as zinc oxide, stearic acid and glycol ether, generate the material that sulphur and No. 3 smoked sheets and cis-1,4-polybutadiene rubber can be impelled crosslinked.
Based on above-mentioned, the weight part of described white carbon black is 48-52 part.
The present invention also provides a kind of manufacture method of above-mentioned Wear-resistant sole material, and it comprises the following steps:
Plasticate: No. 3 smoked sheets being placed in process to the Wei Shi plasticity number of plasticating of thin-pass in mill by above-mentioned weight part is 0.42-0.45, obtained smoked sheet of plasticating;
Close refining: by the described smoked sheet and first close refining by the cis-1,4-polybutadiene rubber of above-mentioned weight part in described mill of plasticating, then thin-pass is plasticated 2-3 time, then plays triangle bag 2-4 time, form conjunction and refine glue;
Mixing: to close refining glue by described and join in Banbury mixer by the zinc oxide of above-mentioned weight part, stearic acid, glycol ether, promotor, anti-aging agent, oxidation inhibitor, machinery oil and white carbon black, mixingly prepare rubber unvulcanizate at 80-90 DEG C, described rubber unvulcanizate is made film;
Sulfuration: by above-mentioned weight part sulphur joined on described film and carry out sulfidizing.
Based on above-mentioned, described mixing step also comprise tinting material and paraffin joined in described Banbury mixer by weight carry out mixing to prepare described rubber unvulcanizate.
Based on above-mentioned, the step of described sulfuration comprises: join on described film by above-mentioned weight part by sulphur, then adopts mould compression moulding, then carries out sulfidizing, obtain sole product.
Compared with prior art, Wear-resistant sole material provided by the invention adopts No. 3 smoked sheets and cis-1,4-polybutadiene rubber and uses, described material for sole of shoe is made to have good hardness, elasticity, wear resistance and snappiness, and heating is few under dynamic load, ageing resistance is good, thus makes described material for sole of shoe can be used as the sole of the training shoes of military products and People's Armed Police; Adopt zinc oxide, stearic acid and glycol ether jointly as the activator of cis-1,4-polybutadiene rubber; Activator coordinates with described promotor and forms linking agent, impels sulphur and cis-1,4-polybutadiene rubber and No. 3 smoked sheets to be cross-linked; Anti-aging agent RD Z and heat resistanceheat resistant oxygen agent RF use, can improve the anti-aging of cis-1,4-polybutadiene rubber and the performance of thermo oxidative aging; Machinery oil, as softening agent, can soften cis-1,4-polybutadiene rubber to improve the snappiness of material for sole of shoe, be easy to manufacture described material for sole of shoe; White carbon black, as the filler of cis-1,4-polybutadiene rubber, has again certain strengthening action, can strengthen intensity and the wear resistance of material for sole of shoe, and simultaneously white carbon black is as transparent material, can not pollute product shoes upper outward appearance after sulfuration; Sulphur, as the vulcanizing agent of cis-1,4-polybutadiene rubber and No. 3 smoked sheets, is conducive to improving the flexible resistance of material for sole of shoe, wear resistance and winter hardiness.Therefore, because the various raw materials such as No. 3 smoked sheets, cis-1,4-polybutadiene rubber, white carbon black, zinc oxide, stearic acid, glycol ether, promotor, anti-aging agent and heat resistanceheat resistant oxygen agent RF are according to certain proportioning, cooperatively interact, thus make Wear-resistant sole material provided by the invention and the Wear-resistant sole material that manufactured by method provided by the invention has excellent hardness, elasticity, wear resistance, snappiness, winter hardiness and the characteristic such as anti-aging, can ordnance be used as.
Further, Wear-resistant sole material provided by the invention is also comprising toner, and because white carbon black is transparent material, so the color of Wear-resistant sole material determines primarily of the color of tinting material, therefore, Wear-resistant sole material provided by the invention can be colored.
Further, Wear-resistant sole material provided by the invention can also comprise the paraffin as protective agent, for forming protective layer on described Wear-resistant sole material, this Wear-resistant sole material is avoided impaired.
The white carbon black adopted in above-mentioned manufacture method provided by the invention normally utilizes industrial tail gas to prepare, and substantially can not pollute when mixing, also can not all cause larger impact to work human and environment.In addition, simpler provided by the invention, is easy to realize.
Test proves: the method adopting national sector standard HG/T2495-2007 specify carries out detection analysis to the hardness of above-mentioned Wear-resistant sole material provided by the invention, tensile strength at yield, tensile yield and abrasion, after testing, above-mentioned high-abrasive material continue that your A hardness is 57-65, tensile strength at yield is 12-15MPa, tensile yield 420%-540%, abrasion 0.28-0.42cm
3/ 1.61Km.Prove that Wear-resistant sole material provided by the invention reaches the standard of ordnance thus.
Embodiment
Below by embodiment, technical scheme of the present invention is described in further detail.
The invention provides a kind of Wear-resistant sole material, according to listed as parts by weight, it comprises following raw material: No. 3 smoked sheet 40-60 parts, cis-1,4-polybutadiene rubber 40-60 part, zinc oxide 3-5 part, stearic acid 0.7-1.3 part, two sweet sour 4-6 parts, promotor 3-4.2 part, anti-aging agent RD Z0.8-1.2 part, heat resistanceheat resistant oxygen agent RF1.7-2.4 part, sulphur 1.7-2.3 part, machinery oil 12-22 part and white carbon black 42-56 parts.Wherein, described promotor is promotor PX, altax, vulkacit D or M.Wherein, promotor mainly in order to the complex reaction such as zinc oxide, stearic acid and glycol ether, generate the cross-linked material that can impel sulphur and No. 3 smoked sheets and cis-1,4-polybutadiene rubber and No. 3 cigarettes.
No. 3 smoked sheets in above-mentioned Wear-resistant sole material and cis-1,4-polybutadiene rubber are as main gel, this material for sole of shoe can be made to have good hardness, elasticity, wear resistance and snappiness, and heating is few under dynamic load, ageing resistance is good, thus makes described material for sole of shoe can be used as the sole of the training shoes of military products and People's Armed Police.Above-mentioned zinc oxide, stearic acid and glycol ether are jointly as the activator of cis-1,4-polybutadiene rubber, and activator coordinates with described promotor and forms linking agent, impel sulphur and cis-1,4-polybutadiene rubber and No. 3 smoked sheets to be cross-linked.Anti-aging agent RD Z and heat resistanceheat resistant oxygen agent RF use, can improve the anti-aging of cis-1,4-polybutadiene rubber and the performance of thermo oxidative aging; Machinery oil, as softening agent, can soften cis-1,4-polybutadiene rubber to improve the snappiness of material for sole of shoe, be easy to manufacture described material for sole of shoe.White carbon black, as the filler of cis-1,4-polybutadiene rubber, has again certain strengthening action, can strengthen intensity and the wear resistance of material for sole of shoe, and simultaneously white carbon black is as transparent material, can not pollute product shoes upper outward appearance after sulfuration; Preferably, the weight part of described white carbon black is 48-52 part.Sulphur, as the vulcanizing agent of cis-1,4-polybutadiene rubber and No. 3 smoked sheets, is conducive to improving the flexible resistance of material for sole of shoe, wear resistance and winter hardiness.Therefore, Wear-resistant sole material provided by the invention and the Wear-resistant sole material manufactured by method provided by the invention have excellent hardness, elasticity, wear resistance, snappiness, winter hardiness and the characteristic such as anti-aging, can be used as ordnance.
Above-mentioned Wear-resistant sole material provided by the invention is also comprising toner 15-25 part.Described tinting material can be the various pigment such as black masterbatch or ultramarine.Because white carbon black is transparent material, so the color of Wear-resistant sole material determines primarily of the color of tinting material, therefore, Wear-resistant sole material provided by the invention can be colored.
Wear-resistant sole material described above provided by the invention can further include paraffin 0.22-0.38 part.Paraffin, as protective agent, can form protective layer, this Wear-resistant sole material be avoided impaired on described Wear-resistant sole material.
The present invention also provides a kind of manufacture method of above-mentioned Wear-resistant sole material, and it comprises the following steps:
Plasticate: No. 3 smoked sheets being placed in process to the Wei Shi plasticity number of plasticating of thin-pass in mill by above-mentioned weight part is 0.42-0.45, then leaves standstill 20-28 hour, obtains smoked sheet of plasticating;
Close refining: by the described smoked sheet and first carry out conjunctions refining process by the cis-1,4-polybutadiene rubber of above-mentioned weight part in described mill of plasticating, then carry out thin-pass and plasticate 2-3 time, then play triangle bag 2-4 time, afterwards standing 20-28 hour, obtain conjunction and refine glue;
Mixing: to close refining glue by described and join in Banbury mixer by the zinc oxide of above-mentioned weight part, stearic acid, glycol ether, promotor, anti-aging agent, oxidation inhibitor, machinery oil and white carbon black, carrying out mixing at 80-90 DEG C, the rubber unvulcanizate be uniformly mixed; Adopt described mill that described rubber unvulcanizate is made film, then leave standstill 20-28 hour; Wherein, this step can also comprise tinting material and paraffin joined in described Banbury mixer by weight carry out mixing to prepare described rubber unvulcanizate;
Shaping: by above-mentioned weight part sulphur to be joined on described film and carry out sulfidization molding process, obtain sole product.Wherein, the step of described sulfuration comprises: join on described film by above-mentioned weight part by sulphur, then adopts mould compression moulding, then carries out sulfidizing, obtain sole product.
With specific embodiment, technical scheme provided by the invention will be further elaborated below.
Embodiment 1
The present embodiment provides a kind of Wear-resistant sole material, and it comprises following raw material: No. 3 smoked sheet 42kg, cis-1,4-polybutadiene rubber 42kg, zinc oxide 3kg, stearic acid 0.7kg, two sweet sour 4kg, altax 3kg, anti-aging agent RD Z0.8kg, heat resistanceheat resistant oxygen agent RF1.7kg, sulphur 1.7kg, machinery oil 12kg and white carbon black 42kg.The manufacture method of this Wear-resistant sole material comprises the following steps:
Plasticate: 42kg No. 3 smoked sheets are placed in mill, adopt the roll spacing thin-pass of 0.1mm to plasticate process 12 times, and open sufficient water coolant, until the Wei Shi plasticity number of No. 3 smoked sheets reaches 0.42-0.45, then park 20 hours, obtain smoked sheet of plasticating;
Close refining: the cis-1,4-polybutadiene rubber of plasticate smoked sheet and the 42kg of above-mentioned quality is carried out in described mill conjunction refining, after closing refining evenly, then plasticate 2 times with the roll spacing thin-pass of 0.1mm, then play triangle bag 2 times, park 20 hours afterwards, obtain closing refining glue;
Mixing: the conjunction of above-mentioned quality refining glue, zinc oxide 3kg, stearic acid 0.7kg, glycol ether 4kg, altax 3kg, anti-aging agent RD Z0.8kg, heat resistanceheat resistant oxygen agent RF1.7kg, machinery oil 12kg and white carbon black 42kg are joined in Banbury mixer, carry out mixing 6 minutes at 80 DEG C, make the various medicaments in this Banbury mixer be mixed to form rubber unvulcanizate all equably; Described rubber unvulcanizate is discharged from this Banbury mixer, and slice, cooling in described mill, then park 20 hours, obtained film;
Shaping: the sulphur of 1.7kg to be joined on above-mentioned film, then adopt particular manufacturing craft to be pressed into sole, after sulfuration, park 20 hours, obtain sole product.
Embodiment 2
The present embodiment provides a kind of Wear-resistant sole material, and it comprises following raw material: No. 3 smoked sheet 50kg, cis-1,4-polybutadiene rubber 50kg, zinc oxide 4kg, stearic acid 1kg, two sweet sour 5kg, captax 3.7kg, anti-aging agent RD Z1kg, heat resistanceheat resistant oxygen agent RF2kg, sulphur 2kg, machinery oil 16kg, white carbon black 50kg, black masterbatch 20kg and paraffin 0.3kg.The manufacture method of this Wear-resistant sole material comprises the following steps:
Plasticate: 50kg No. 3 smoked sheets are placed in mill, adopt the roll spacing thin-pass of 0.1mm to plasticate process 15 times, and open sufficient water coolant, until the Wei Shi plasticity number of No. 3 smoked sheets reaches 0.42-0.45, then park 24 hours, obtain smoked sheet of plasticating;
Close refining: the cis-1,4-polybutadiene rubber of plasticate smoked sheet and the 50kg of above-mentioned quality is carried out in described mill conjunction refining, after closing refining evenly, then plasticate 3 times with the roll spacing thin-pass of 0.1mm, then play triangle bag 3 times, park 24 hours afterwards, obtain closing refining glue;
Mixing: the conjunction of above-mentioned quality refining glue, zinc oxide 4kg, stearic acid 1kg, glycol ether 5kg, captax 3.7kg, anti-aging agent RD Z1kg, heat resistanceheat resistant oxygen agent RF2kg, machinery oil 16kg, white carbon black 50kg, black masterbatch 20kg and paraffin 0.3kg are joined in Banbury mixer, carry out mixing 7 minutes at 85 DEG C, make the various medicaments in this Banbury mixer be mixed to form rubber unvulcanizate all equably; Described rubber unvulcanizate is discharged from this Banbury mixer, and slice, cooling in described mill, then park 24 hours, obtained film;
Shaping: the sulphur of 2kg to be joined on above-mentioned film, then adopt particular manufacturing craft to be pressed into sole, after sulfuration, park 24 hours, obtain sole product.
Embodiment 3
The present embodiment provides a kind of Wear-resistant sole material, and it comprises following raw material: No. 3 smoked sheet 52kg, cis-1,4-polybutadiene rubber 48kg, zinc oxide 4.2kg, stearic acid 0.9kg, glycol ether 6kg, altax 3.9kg, anti-aging agent RD Z1.05kg, heat resistanceheat resistant oxygen agent RF1.9kg, sulphur 1.9kg, machinery oil 19kg, white carbon black 51kg, black masterbatch 18kg and paraffin 0.28kg.The manufacture method of the Wear-resistant sole material that the present embodiment provides is substantially identical with the manufacture method that embodiment 2 provides, and difference is just that the quality of each component in the raw material of Wear-resistant sole material is different.
Embodiment 4
The present embodiment provides a kind of Wear-resistant sole material, and it comprises following raw material: No. 3 smoked sheet 56kg, cis-1,4-polybutadiene rubber 44kg, zinc oxide 5kg, stearic acid 1.3kg, glycol ether 6kg, TM monex 4.2kg, anti-aging agent RD Z1.2kg, heat resistanceheat resistant oxygen agent RF2.4kg, sulphur 2.3kg, machinery oil 22kg, white carbon black 56kg, ultramarine 25kg and paraffin 0.38kg.The manufacture method of this Wear-resistant sole material comprises the following steps:
Plasticate: 56kg No. 3 smoked sheets are placed in mill, adopt the roll spacing thin-pass of 0.1mm to plasticate process 15 times, and open sufficient water coolant, until the Wei Shi plasticity number of No. 3 smoked sheets reaches 0.42-0.45, then park 28 hours, obtain smoked sheet of plasticating;
Close refining: the cis-1,4-polybutadiene rubber of plasticate smoked sheet and the 44kg of above-mentioned quality is carried out in described mill conjunction refining, after closing refining evenly, then plasticate 3 times with the roll spacing thin-pass of 0.1mm, then play triangle bag 5 times, park 28 hours afterwards, obtain closing refining glue;
Mixing: the conjunction of above-mentioned quality refining glue, zinc oxide 5kg, stearic acid 1.3kg, glycol ether 6kg, captax 4.2kg, anti-aging agent RD Z1.2kg, heat resistanceheat resistant oxygen agent RF2.4kg, machinery oil 22kg, white carbon black 56kg, ultramarine 25kg and paraffin 0.38kg are joined in Banbury mixer, carry out mixing 7 minutes at 90 DEG C, make the various medicaments in this Banbury mixer be mixed to form rubber unvulcanizate all equably; Described rubber unvulcanizate is discharged from this Banbury mixer, and slice, cooling in described mill, then park 28 hours, obtained film;
Shaping: the sulphur of 2.3kg to be joined on above-mentioned film, then adopt particular manufacturing craft to be pressed into sole, after sulfuration, park 28 hours, obtain sole product.
Embodiment 5
The present embodiment provides a kind of Wear-resistant sole material, and it comprises following raw material: No. 3 smoked sheet 44kg, cis-1,4-polybutadiene rubber 56kg, zinc oxide 3.8kg, stearic acid 1kg, glycol ether 5.5kg, captax 4kg, anti-aging agent RD Z1kg, heat resistanceheat resistant oxygen agent RF1.8kg, sulphur 1.9kg, machinery oil 12kg, white carbon black 50kg, black masterbatch 20kg and paraffin 0.3kg.The manufacture method of the Wear-resistant sole material that the present embodiment provides is substantially identical with the manufacture method that embodiment 4 provides, and difference is just that the quality of each component in the raw material of Wear-resistant sole material is different.
The method adopting national sector standard HG/T2495-2007 specify carries out detections analysis to performances such as the hardness of the Wear-resistant sole material that embodiment 1-5 provides, tensile strength at yield, tensile yield and abrasion, and result is as shown in the table: the performance test results showing Wear-resistant sole material
| Performance perameter | Military products standard | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Hardness (continue that A) | 55-65 | 57 | 62 | 63 | 69 | 65 |
| Tensile strength at yield (MPa) | ≥12 | 12.1 | 13.5 | 13.2 | 14 | 15 |
| Tensile yield (%) | ≥400 | 420 | 480 | 460 | 540 | 430 |
| Abrasion (cm 3/1.61 K·m) | ≤0.8 | 0.42 | 0.38 | 0.28 | 0.32 | 0.41 |
As can be seen from the above table: the physicals of the Wear-resistant sole material that embodiment of the present invention 1-5 provides meets the specification of quality index of national military products footwear, the sole manufacturing military footwear can be used as.
Finally should be noted that: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the field are to be understood that: still can modify to the specific embodiment of the present invention or carry out equivalent replacement to portion of techniques feature; And not departing from the spirit of technical solution of the present invention, it all should be encompassed in the middle of the technical scheme scope of request of the present invention protection.
Claims (8)
1. a Wear-resistant sole material, it is characterized in that, according to listed as parts by weight, it comprises following raw material: No. 3 smoked sheet 40-60 parts, cis-1,4-polybutadiene rubber 40-60 part, zinc oxide 3-5 part, stearic acid 0.7-1.3 part, glycol ether 4-6 part, promotor 3-4.2 part, anti-aging agent RD Z0.8-1.2 part, heat resistanceheat resistant oxygen agent RF1.7-2.4 part, sulphur 1.7-2.3 part, machinery oil 12-22 part and white carbon black 42-56 parts.
2. Wear-resistant sole material according to claim 1, is characterized in that, it is also comprising toner 15-25 part.
3. Wear-resistant sole material according to claim 2, is characterized in that, described tinting material is black masterbatch or ultramarine.
4. the Wear-resistant sole material according to any one of claim 1-3, is characterized in that, it also comprises paraffin 0.22-0.38 part.
5. Wear-resistant sole material according to claim 4, is characterized in that, the weight part of described white carbon black is 48-52 part.
6. a manufacture method for Wear-resistant sole material, it comprises the following steps:
Plasticate: No. 3 smoked sheets being placed in process to the Wei Shi plasticity number of plasticating of thin-pass in mill by weight part according to claim 1 is 0.42-0.45, obtained smoked sheet of plasticating;
Close refining: by the described smoked sheet and first close refining by the cis-1,4-polybutadiene rubber of weight part according to claim 1 in described mill of plasticating, then thin-pass is plasticated 2-3 time, then plays triangle bag 2-4 time, form conjunction and refine glue;
Mixing: to close refining glue by described and join in Banbury mixer by the zinc oxide of weight part according to claim 1, stearic acid, glycol ether, promotor, anti-aging agent, oxidation inhibitor, machinery oil and white carbon black, mixingly prepare rubber unvulcanizate at 80-90 DEG C, described rubber unvulcanizate is made film;
Sulfuration: by weight part according to claim 1 sulphur joined on described film and carry out sulfidizing.
7. the manufacture method of Wear-resistant sole material according to claim 6, is characterized in that, described mixing step also comprise tinting material and paraffin joined in described Banbury mixer by weight carry out mixing to prepare described rubber unvulcanizate.
8. the manufacture method of the Wear-resistant sole material according to claim 6 or 7, it is characterized in that, the step of described sulfuration comprises: join on described film by weight part according to claim 1 by sulphur, then adopts mould compression moulding, carry out sulfidizing again, obtain sole product.
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| CN201510773970.XA CN105218884A (en) | 2015-11-13 | 2015-11-13 | Wear-resistant sole material and manufacture method thereof |
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| CN107573554A (en) * | 2017-09-26 | 2018-01-12 | 鹤山市名鹤鞋材有限公司 | Wear-resisting sole rubber mass and preparation method thereof |
| CN107722872A (en) * | 2017-11-06 | 2018-02-23 | 陈沛栋 | White gasoline slurry |
| CN108158129A (en) * | 2017-11-22 | 2018-06-15 | 海盐县硕创服装研究所 | A kind of light wear-resistant sole material |
| CN110144065A (en) * | 2019-05-14 | 2019-08-20 | 林建辉 | A kind of antibacterial foamed shoe sole and preparation method thereof |
| CN111849043A (en) * | 2020-08-15 | 2020-10-30 | 温州市鹿城金米莉金足皮鞋厂 | Wear-resistant sole and production process thereof |
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