CN110128812A - A kind of powder puff with can temperature become sponge and its manufacture craft - Google Patents
A kind of powder puff with can temperature become sponge and its manufacture craft Download PDFInfo
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- CN110128812A CN110128812A CN201910403612.8A CN201910403612A CN110128812A CN 110128812 A CN110128812 A CN 110128812A CN 201910403612 A CN201910403612 A CN 201910403612A CN 110128812 A CN110128812 A CN 110128812A
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- sponge
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The embodiment of the invention discloses a kind of powder puffs with that warm can become sponge and its manufacture craft, belongs to technical field of polymer materials.It is described can temperature change powder flutter and be made of first component and second component according to weight ratio 1.5~2.5:0.8~1.2 with sponge, wherein, first component is 35~60% by weight percentage filler, 1~3% surfactant, 0.5~3% emulsifier, 0.5~1% temperature-sensitive toner, surplus are that water forms；Second group is divided into hydrophilic polyurethane performed polymer.Powder puff made from the embodiment of the present invention with can temperature become sponge there is good physical property, oder levels are low, good environmental protection, while having good shape recovery and touch sensitivity, are adapted for use in cosmetics.
Description
Technical field
The present embodiments relate to technical field of polymer materials, and in particular to a kind of powder puff with can temperature become sponge and its system
Make technique.
Background technique
Sponge is one kind of polyurethane foam plastics, belongs to flexible polyurethane foam.Because there is the cellular knot of cellular
Structure has the characteristics that excellent flexibility, elasticity, water imbibition, water resistance, is widely used in sofa, mattress, clothes, flexible package
Etc. industries.
In the synthesis process of sponge, mainly by the processes such as chain length reaction, foaming and crosslinking, point of these reactions and raw material
Minor structure, degree of functionality, molecular weight etc. are related.
Currently, most of in sponge production use the box foaming of a step, under high velocity agitation by various raw materials, add rapidly
Enter shaping box, the reaction such as chain growth, foaming, crosslinking, solidification is completed in forming box, to complete sponge production.
Traditional sponge does not have the function of changing color according to environment temperature, but the appearance of temperature-sensitive toner material, passes through
Temperature-sensitive toner is added in the manufacture craft of sponge, is expected to that the sponge for changing color according to environment temperature is made.
Powder puff is one kind of cosmetic applicators, for picking foundation cream and modification dressing, by being polished to sponge, mesh
It is preceding not yet to occur changing the powder puff of color according to environment temperature on the market.
Summary of the invention
For this purpose, the embodiment of the present invention provide a kind of powder puff with can temperature become sponge and its manufacture craft, to solve the prior art
In not yet there is the problem of changing the powder puff of color according to environment temperature.
To achieve the goals above, the embodiment of the present invention provides the following technical solutions:
According to a first aspect of the embodiments of the present invention, using the embodiment of the invention provides a kind of powder puff warm can become sponge, institute
State can temperature change powder flutter and be made of first component and second component according to weight ratio 1.5~2.5:0.8~1.2 with sponge, wherein first component
By weight percentage be 35~60% filler, 1~3% surfactant, 0.5~3% emulsifier, 0.5~1%
Temperature-sensitive toner, surplus are water composition；Second group is divided into hydrophilic polyurethane performed polymer.
Further, the filler is 400-800 mesh wollastonite in powder.
Further, the surfactant is selected from one of PE6800, PE6200, polyether silicone oil or a variety of.
Further, the emulsifier is 1000NI.
Further, the first component is 35~45% filler, 1.5~2% surface-active by weight percentage
Agent, 0.8~1.2% emulsifier, 0.6~0.8% temperature-sensitive toner, surplus are water composition.
According to a second aspect of the embodiments of the present invention, the embodiment of the invention provides a kind of above-mentioned powder puff use can Wen Bianhai
Continuous manufacture craft, the technique the following steps are included:
1) each raw material of first component is uniformly mixed under normal pressure, under agitation, second component is added, foaming mixing is made
Material；
2) foam mixture made from step 1) is delivered to foaming machine through high-voltage tube and carries out foamable reaction, foaming bubble is made
It is continuous；
3) foam sponge made from step 2) is delivered to dryer and carries out drying and processing, obtained powder puff is used can Wen Bianhai
It is continuous.
Further, in step 1), the temperature of first component is 16~20 DEG C, and the temperature of second component is 30~35 DEG C.
Further, in step 1), mixing speed 3500-5000r/min.
Further, in step 3), the temperature of the dryer is 100~150 DEG C.
Sponge metachromatic principle: sponge shows the color of heat discoloration powder at normal temperature, (hot as held by heat effect
The heat sources such as water), sponge surface partially or fully becomes sponge true qualities, because at a certain temperature because electronics transfer makes temperature-sensitive toner
Molecular structure changes, to realize " colored-colorless " color change.
The embodiment of the present invention has the advantages that
The powder puff of the embodiment of the present invention uses one-step synthesis with that warm can become sponge, i.e., will using low pressure urethane foaming machine
According to the first component (filler, surfactant, emulsifier, temperature-sensitive toner, water) and second component (hydrophilic polyurethane of setting proportion
Performed polymer) it is transported to after head high-speed stirred injects mold through high-voltage tube and reacts foaming and molding, after drying, there is operation
Process is simple, the low feature of production cost,
Powder puff made from the embodiment of the present invention is with that warm can become sponge with good physical property, and oder levels are low, environmental protection
Performance is good, while having good shape recovery and touch sensitivity, is adapted for use in cosmetics.
Specific embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book is understood other advantages and efficacy of the present invention easily, it is clear that described embodiment is the present invention one
Section Example, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not doing
Every other embodiment obtained under the premise of creative work out, shall fall within the protection scope of the present invention.
PE6800 is purchased from BASF Chemical Company；1000NI is purchased from BASF Chemical Company；
PE6200 is purchased from BASF Chemical Company；Wollastonite in powder is purchased from Guangzhou side's benefit chemical industry；Polyether silicone oil activating agent is purchased from river
Men Yiben chemistry；Temperature-sensitive toner is purchased from U.S. LCR.
Embodiment 1
The powder puff of the present embodiment with can temperature become sponge and be made according to weight ratio 1.5:1 of first component and second component, wherein first
800 mesh wollastonites in powder that component is 50% by weight percentage, 0.3% PE6800,0.9% PE6200,0.15%
Polyether silicone oil, 1.2% 1000NI, 0.6% temperature-sensitive toner, surplus are water composition；Second group is divided into hydrophilic polyurethane pre-polymerization
Body.
The powder puff of the present embodiment with can temperature become sponge manufacture craft the following steps are included:
1) each raw material of first component is uniformly mixed under normal pressure and is maintained at 20 DEG C, in the stirring that speed is 3800r/min
Under the conditions of, the second component that temperature is 30 DEG C is added, foam mixture is made；
2) foam mixture made from step 1) is delivered to foaming machine through high-voltage tube and carries out foamable reaction, foaming bubble is made
It is continuous；
3) foam sponge made from step 2) is delivered to dryer, carries out drying and processing at 120 DEG C, powder puff is made and uses
It can temperature change sponge.
Embodiment 2
The powder puff of the present embodiment with can temperature become sponge and be made according to weight ratio 2:1 of first component and second component, wherein first group
Point by weight percentage be 42% 400 mesh wollastonites in powder, 0.25% PE6800,1.2% PE6200,0.2% it is poly-
Ether silicone oil, 1% 1000NI, 0.75% temperature-sensitive toner, surplus are water composition；Second group is divided into hydrophilic polyurethane performed polymer.
The powder puff of the present embodiment with can temperature become sponge manufacture craft the following steps are included:
1) each raw material of first component is uniformly mixed under normal pressure and is maintained at 16 DEG C, in the stirring that speed is 4500r/min
Under the conditions of, the second component that temperature is 30 DEG C is added, foam mixture is made；
2) foam mixture made from step 1) is delivered to foaming machine through high-voltage tube and carries out foamable reaction, foaming bubble is made
It is continuous；
3) foam sponge made from step 2) is delivered to dryer, carries out drying and processing at 100 DEG C, powder puff is made and uses
It can temperature change sponge.
Embodiment 3
The powder puff of the present embodiment with can temperature become sponge and be made according to weight ratio 2.5:0.8 of first component and second component, wherein
600 mesh wollastonites in powder, 0.15% PE6800,1.8% PE6200,0.18% of the first component by weight percentage for 60%
Polyether silicone oil, 1.5% 1000NI, 0.8% temperature-sensitive toner, surplus be water composition；It is pre- that second group is divided into hydrophilic polyurethane
Aggressiveness.
The powder puff of the present embodiment with can temperature become sponge manufacture craft the following steps are included:
1) each raw material of first component is uniformly mixed under normal pressure and is maintained at 18 DEG C, in the stirring that speed is 4500r/min
Under the conditions of, the second component that temperature is 30 DEG C is added, foam mixture is made；
2) foam mixture made from step 1) is delivered to foaming machine through high-voltage tube and carries out foamable reaction, foaming bubble is made
It is continuous；
3) foam sponge made from step 2) is delivered to dryer, carries out drying and processing at 150 DEG C, powder puff is made and uses
It can temperature change sponge.
Embodiment 4
The powder puff of the present embodiment with can temperature become sponge and be made according to weight ratio 2:1 of first component and second component, wherein first group
Point by weight percentage be 35% 400 mesh wollastonites in powder, 0.4% PE6800,1.2% PE6200,0.15% it is poly-
Ether silicone oil, 2.2%% 1000NI, 1% temperature-sensitive toner, surplus are water composition；Second group is divided into hydrophilic polyurethane performed polymer.
The powder puff of the present embodiment with can temperature become sponge manufacture craft the following steps are included:
1) each raw material of first component is uniformly mixed under normal pressure and is maintained at 20 DEG C, in the stirring that speed is 5000r/min
Under the conditions of, the second component that temperature is 30 DEG C is added, foam mixture is made；
2) foam mixture made from step 1) is delivered to foaming machine through high-voltage tube and carries out foamable reaction, foaming bubble is made
It is continuous；
3) foam sponge made from step 2) is delivered to dryer, carries out drying and processing at 130 DEG C, powder puff is made and uses
It can temperature change sponge.
Embodiment 5
The powder puff of the present embodiment with can temperature become sponge and be made according to weight ratio 1.8:1 of first component and second component, wherein first
800 mesh wollastonites in powder that component is 55% by weight percentage, 0.22%PE6800,2.2% PE6200,0.25% it is poly-
Ether silicone oil, 0.8% 1000NI, 0.7% temperature-sensitive toner, surplus are water composition；Second group is divided into hydrophilic polyurethane performed polymer.
The powder puff of the present embodiment with can temperature become sponge manufacture craft the following steps are included:
1) each raw material of first component is uniformly mixed under normal pressure and is maintained at 20 DEG C, in the stirring that speed is 4500r/min
Under the conditions of, the second component that temperature is 35 DEG C is added, foam mixture is made；
2) foam mixture made from step 1) is delivered to foaming machine through high-voltage tube and carries out foamable reaction, foaming bubble is made
It is continuous；
3) foam sponge made from step 2) is delivered to dryer, carries out drying and processing at 120 DEG C, powder puff is made and uses
It can temperature change sponge.
Test case
To powder puff made from embodiment 1-5 with can temperature become sponge physical property test, the results are shown in Table 1.
Table 1
| Group | Density kg/m3 | Voidage/mm | Tensile strength/kgf | Hardness/H | Oder levels |
| Embodiment 1 | 152.5 | 0.095 | 4.3 | 48.3 | ≤2 |
| Embodiment 2 | 145.4 | 0.105 | 4.8 | 54.2 | ≤2 |
| Embodiment 3 | 158.8 | 0.082 | 4.2 | 50.5 | ≤2 |
| Embodiment 4 | 149.2 | 0.116 | 4.5 | 46.7 | ≤2 |
| Embodiment 5 | 156.1 | 0.109 | 4.7 | 52.3 | ≤2 |
As it can be seen from table 1 the powder puff of the embodiment of the present invention has good physical property, while gas with that warm can become sponge
Taste grade is low, and good environmental protection is adapted for use in cosmetics.
To powder puff made from embodiment 1-5 with can temperature become the shape recovery of sponge and and touch sensitivity evaluate.
Shape recovery: rubbing sample in water, it is made sufficiently to absorb water.Then sample is taken out from water, is held in palm
Time after moisture is squeezed out completely, when shape when palm is decontroled in measurement to sample is restored.
It is touch sensitivity: without coarse rough feeling, to indicate touch sensitivity good.
Evaluation result is shown in Table 2.
Table 2
| Group | Shape recovery/second | It is touch sensitivity |
| Embodiment 1 | 2.5 | It is touch sensitivity good |
| Embodiment 2 | 2.8 | It is touch sensitivity good |
| Embodiment 3 | 3.0 | It is touch sensitivity good |
| Embodiment 4 | 3.2 | It is touch sensitivity good |
| Embodiment 5 | 2.8 | It is touch sensitivity good |
From table 2 it can be seen that the powder puff of the embodiment of the present invention, which is used, warm can become sponge with good shape recovery and touching
Perception.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (9)
1. a kind of powder puff with can temperature become sponge, which is characterized in that it is described can temperature change powder flutter with sponge by first component and second component by
Be made according to weight ratio 1.5~2.5:0.8~1.2, wherein first component by weight percentage be 35~60% filler, 1~
3% surfactant, 0.5~3% emulsifier, 0.5~1% temperature-sensitive toner, surplus are water composition；Second group is divided into hydrophilic
Property base polyurethane prepolymer for use as.
2. powder puff according to claim 1, which is used, warm to become sponge, which is characterized in that the filler is 400-800 mesh silicon ash
Mountain flour.
3. powder puff according to claim 1, which is used, warm to become sponge, which is characterized in that the surfactant is selected from
One of PE6800, PE6200, polyether silicone oil are a variety of.
4. powder puff according to claim 1, which is used, warm to become sponge, which is characterized in that the emulsifier is 1000NI.
5. powder puff according to claim 1, which is used, warm to become sponge, which is characterized in that the first component is by weight percentage
For 35~45% filler, 1.5~2% surfactant, 0.8~1.2% emulsifier, 0.6~0.8% temperature-sensitive color
Powder, surplus are water composition.
6. a kind of powder puff described in claim 1 with can temperature become the manufacture craft of sponge, which is characterized in that the technique include with
Lower step:
1) each raw material of first component is uniformly mixed under normal pressure, under agitation, second component is added, foam mixture is made；
2) foam mixture made from step 1) is delivered to polyurethane foaming machine through high-voltage tube and carries out foamable reaction, foaming is made
Bubble is continuous；
3) foam sponge made from step 2) is delivered to dryer and carries out drying and processing, powder puff is made and uses and warm can become sponge.
7. powder puff according to claim 6 with can temperature become the manufacture craft of sponge, which is characterized in that in step 1), first group
The temperature divided is 16~20 DEG C, and the temperature of second component is 30~35 DEG C.
8. powder puff according to claim 6 with can temperature become the manufacture craft of sponge, which is characterized in that in step 1), stirring
Speed is 3500-5000r/min.
9. powder puff according to claim 6 with can temperature become the manufacture craft of sponge, which is characterized in that it is described in step 3)
The temperature of dryer is 100~150 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910403612.8A CN110128812A (en) | 2019-05-15 | 2019-05-15 | A kind of powder puff with can temperature become sponge and its manufacture craft |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910403612.8A CN110128812A (en) | 2019-05-15 | 2019-05-15 | A kind of powder puff with can temperature become sponge and its manufacture craft |
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| CN110128812A true CN110128812A (en) | 2019-08-16 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111303613A (en) * | 2020-03-06 | 2020-06-19 | 广州琪彩化妆工具有限公司 | Cellular large-pore polyurethane sponge and processing method thereof |
| CN113861370A (en) * | 2021-09-16 | 2021-12-31 | 山东一诺威聚氨酯股份有限公司 | Polyurethane composite material for cosmetic cotton and preparation method thereof |
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| CN108484874A (en) * | 2018-03-23 | 2018-09-04 | 惠州市远安新材料有限公司 | A kind of polyurethane material, high-elastic Antibacterial polyurethane class powder puff and preparation method thereof |
| CN108641391A (en) * | 2018-05-07 | 2018-10-12 | 东莞市创继荣高分子材料有限公司 | A kind of non-latex powder puff of bamboo fibre hydrophily and preparation method |
| CN108715629A (en) * | 2018-05-17 | 2018-10-30 | 滁州市赢聚高分子材料有限公司 | The special urethane raw of makeup sponge for liquid foundation |
-
2019
- 2019-05-15 CN CN201910403612.8A patent/CN110128812A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105029981A (en) * | 2015-08-25 | 2015-11-11 | 惠州会德宝实业有限公司 | Pillow |
| CN108484874A (en) * | 2018-03-23 | 2018-09-04 | 惠州市远安新材料有限公司 | A kind of polyurethane material, high-elastic Antibacterial polyurethane class powder puff and preparation method thereof |
| CN108641391A (en) * | 2018-05-07 | 2018-10-12 | 东莞市创继荣高分子材料有限公司 | A kind of non-latex powder puff of bamboo fibre hydrophily and preparation method |
| CN108715629A (en) * | 2018-05-17 | 2018-10-30 | 滁州市赢聚高分子材料有限公司 | The special urethane raw of makeup sponge for liquid foundation |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111303613A (en) * | 2020-03-06 | 2020-06-19 | 广州琪彩化妆工具有限公司 | Cellular large-pore polyurethane sponge and processing method thereof |
| CN113861370A (en) * | 2021-09-16 | 2021-12-31 | 山东一诺威聚氨酯股份有限公司 | Polyurethane composite material for cosmetic cotton and preparation method thereof |
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Application publication date: 20190816 |