CN110128775A - A kind of high durable high-temperature resistant ABS deflagration Masterbatch - Google Patents
A kind of high durable high-temperature resistant ABS deflagration Masterbatch Download PDFInfo
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- CN110128775A CN110128775A CN201910308437.4A CN201910308437A CN110128775A CN 110128775 A CN110128775 A CN 110128775A CN 201910308437 A CN201910308437 A CN 201910308437A CN 110128775 A CN110128775 A CN 110128775A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2477/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2477/06—Polyamides derived from polyamines and polycarboxylic acids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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Abstract
The invention discloses a kind of high durable high-temperature resistant ABS deflagration Masterbatch, belong to coloring plastic technical field.The ABS deflagration Masterbatch is composed of the following components by weight: polyamide 10%~35%, ABS 10%~70%, toner 0.001~75%, weather resisting agent 1%~20%, fire retardant 2%~30%, antioxidant 0.05%~3%, dispersing agent 0%~10%.Masterbatch of the invention has high-temperature resistant, when being molded big product, and product color is uniform, does not occur the problems such as yellow line and xanthochromia；When being used for ABS color articles simultaneously, the burn rate of product not only meets UL94HB requirement, and product is also able to satisfy fire retardant Halogen, and product is in 313nm ultraviolet radioactive 96H, chromatic aberration (Δ E)≤8.ABS deflagration Masterbatch of the invention and ABS compatibility are good, and color divergence is excellent, it is small to influence on the impact strength of product.
Description
Technical field
The invention belongs to coloring plastic technical field, in particular to a kind of high durable high-temperature resistant ABS deflagration Masterbatch.
Background technique
ABS resin is the terpolymer of acrylonitrile, butadiene and styrene, at present the production method of ABS have copolymerization method,
Emulsion graft polymerization method and blending method three categories.It, can processability is different, the trade mark is different tree by adjusting the proportion of three kinds of monomers
Rouge.ABS resin is nontoxic, tasteless, not only and with toughness, hardness, the excellent mechanical property of rigidity equilibrium, also has preferable resistance to
The performances such as chemical property, dimensional stability, surface gloss, lower temperature resistance, tinctorial property., application maximum as current production rate
One of big general engineering plastic of most wide five, is widely used in the numerous areas such as automobile, utensil, electronic device, household electrical appliance.
But as ABS application surface is more and more wider, product safety problem caused by defect is more and more, for example pure ABS weatherability is poor, note
Plastic, which is not added after the auxiliary agents such as weather resisting agent place a period of time, will appear xanthochromia；The combustibility of pure ABS resin meets UL94HB
Grade standard, but when colorant, dispersing agent, weather resisting agent and antioxidant etc. to be added in pure ABS, it realizes ABS coloring and improves resistance to
When the performances such as time, horizontal burn rate is greatly improved, and is not able to satisfy the requirement of UL94HB；Pure ABS is being greater than 240 DEG C of injection moldings,
When being especially molded components with large size plastic jetting-moulding device, the problems such as moulding is easy to appear yellow line.
Patent ZL99122333.0 has invented a kind of black fire-retarding mother particles, using organic halogen fire retardant as main flame retardant and
Phosphate, zinc borate etc. are auxiliary flame retardant and other additive compounds, are obtained using resins such as EVA and PE as carrier a kind of efficient
Flame-retardant compounds.Fire-retarding mother particles made from the invention are on 4~10% additive amount to the Effect on Mechanical Properties of matrix ABS resin
Less, have efficient anti-flammability and a good mobility, and product surface it is bright and clean, without bad orders such as the current marks visually shown
Problem, but the invention uses the resins such as EVA and PE as carrier, and carrier is readily burned, and for the flame retardant property for improving master batch, need to be added
Increasing amount halogen containing flame-retardant influences the injection molding heat resistance of color masterbatch and the weatherability of moulding, and carrier and ABS compatibility be not good enough,
When color masterbatch additive amount being caused to be greater than 4%, the problems such as being easy to appear layering.
104194302 A of patent CN has invented a kind of ABS deflagration grade Masterbatch, wherein being lower than 150 DEG C of phosphoric acid with fusing point
Ester, phosphite ester etc. are fire retardant, using amino-compound or 80~105 DEG C of softening point of linear phenolic resin as fire-retardant synergistic
Agent, organosilicon compound are dispersing agent, obtain a kind of ABS deflagration Masterbatch using PC as color masterbatch carrier.The invention is made
Deflagration Masterbatch and ABS basis material compatibility it is good, have efficient flame retardant property and mobility, product is not layered,
And product surface is bright and clean, the bad orders phenomenon such as no current mark.But the patent of invention uses PC resin for carrier, amino-compound or
Linear phenolic resin is easy xanthochromia, weatherability as fire retarding synergist, such carrier and fire retarding synergist under ultraviolet light
It is very poor；Fire retarding synergist is easy xanthochromia, causes the color difference of moulding more difficult to control, be especially molded in the case where being greater than 230 DEG C of processing
The plastic parts such as big air conditioner housing are easier to yellow line etc. occur.Therefore, the flame retardant property for seeking a kind of halogen-free flame retardants compounding is good
It is good, it is good with ABS compatibility, there is uvioresistant xanthochromia and Masterbatch resistant to high temperature is still this field technical problem urgently to be solved.
Summary of the invention
The purpose of the present invention is to overcome the shortcomings of the existing technology and deficiency, provides a kind of high durable high-temperature resistant ABS deflagration
Masterbatch, when which is used for ABS color articles, the flame retardant property of product is not only able to satisfy UL94HB related request, and
Product has excellent uvioresistant xanthochromia performance and product color controllable, and color is uniform, good mechanical performance etc..
The purpose of the present invention is what is be achieved by following technical solution:
A kind of high durable high-temperature resistant ABS deflagration Masterbatch, composed of the following components by weight: polyamide 10%~35%,
ABS 10%~70%, toner 0.001~75%, weather resisting agent 1%~20%, fire retardant 2%~30%, antioxidant 0.05%~
3%, dispersing agent 0%~10%.
Preferably, the high durable high-temperature resistant ABS deflagration Masterbatch, it is composed of the following components by weight: polyamide
10%~35%, ABS 20%~70%, toner 2~35%, weather resisting agent 8%~9%, fire retardant 15%~20%, antioxidant
1%, dispersing agent 3%~5%.
The present invention selects the carrier of polyamide and ABS mixture as ABS color masterbatch, this is because polyamide contains largely
Oxygen-containing group and amino, with Halogen phosphorus flame retardant and the used time can play the purpose of cooperative flame retardant, and pass through addition antioxidant, energy
Effectively solve the risk that polyamide generates yellow line in high-temperature injection.
Preferably, the polyamide be fusing point lower than 180 DEG C and greater than 130 DEG C copolyamide, nylon 6, nylon 12,
One of nylon 11, nylon 1212, Nylon 1012, nylon66 fiber 6, nylon 612 are a variety of；Further contain for the oxygen of raising system
Amount etc., copolyamide, nylon 6, nylon66 fiber 6 and nylon 612 of the further preferred fusing point lower than 180 DEG C and greater than 130 DEG C,
It is more excellent with the cooperative flame retardant effect of fire retardant.
Preferably, the toner is that the pigment such as inorganic pigment, organic pigment are compounded, and preferably heatproof is greater than 250 DEG C
Inorganic pigment and organic pigment are compounded, and further preferred heatproof is greater than 250 DEG C of inorganic pigment, and inorganic pigment has coloring
While function, the flame retardant property of product is influenced minimum.
Preferably, the weather resisting agent is hindered amine light stabilizer, benzotriazole ultraviolet absorber, triazines UV absorption
One of one of agent or a variety of mixtures, preferably hindered amine light stabilizer, triazines ultraviolet absorber are a variety of；
The hindered amine light stabilizer, benzotriazole ultraviolet absorber and triazines ultraviolet absorber contain a large amount of nitrogen, are closing
In the case where suitable additive amount, excellent synergistic effect can be played together with polyamide, can not only significantly improve the resistance to of product
Ultraviolet xanthochromia performance, is also remarkably improved the flame retardant property of product.
Preferably, the fire retardant be halogen-free flame retardants, preferably 9, -10 phospho hetero phenanthrene -10- oxide of -9 oxa- of 10- dihydro,
- 10 hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxide of 10- (2,5- dihydroxy phenyl), [(6- oxygen-(6H)-dibenzo-(CE)
(1,2)-oxygen phospha ring -6- ketone) methyl]-succinic acid, melamine aminuria cyanate, ammonium polyphosphate, melamine poly phosphorus
One of hydrochlorate, melamine, phosphate ester flame retardants etc. are a variety of, further preferred [(6- oxygen-(6H)-dibenzo-
(CE) (1,2)-oxygen phospha ring -6- ketone) methyl]-succinic acid, melamine aminuria cyanate, ammonium polyphosphate, melamine be more
One of Quadrafos, phosphate ester flame retardants are a variety of, which more can effectively cooperate with polyamide, weather resisting agent formation
Effect improves the flame retardant property and weather resistance of product, meets the demand for the color masterbatch product that client requires two kinds of performances.
Preferably, the antioxidant is inorganic phosphate kind antioxidant BRUGGOLEN H10, amine antioxidants and special
The mixture of Synergistic stabilizerThe Synergistic blend of H20, hindered phenol antioxygen and phosphonate
One of BRUGGOLEN H161 or a variety of, which can not only significantly improve the yellowing resistance energy of color masterbatch, with nothing
Halogen phosphorus flame retardant has certain synergistic effect, will not be small molecule because of it, reduce the flame retardant property of product.
Preferably, the dispersing agent be titante coupling agent, it is phosphoric acid ester dispersing agent, chelating type dispersing agent, hyperbranched
One of polyhydroxy polycarboxylic esters dispersing agent or a variety of mixtures；Titante coupling agent and phosphoric acid ester dispersing agent not only not shadow
The flame retardant property of product is rung, also has the flame retardant property for the product that improves；Metal ion in chelating type dispersing agent can have
Effect promotes flame-retardant system at carbon, improves the flame retardant property of system to a certain degree；Hyperbranched polyhydroxy polycarboxylic esters dispersing agent and phosphorus-nitrogen
Flame-retardant system is used in compounding, and can also promote flame-retardant system at carbon, the flame retardant property of system is improved to a certain degree, to meet client
Requirement to flame retardant property.
High durable high-temperature resistant ABS deflagration Masterbatch provided by the invention can be using routines such as double screw extruder granulations
The preparation of master batch manufacturing technology.
Compared with prior art, the invention has the following beneficial effects: the present invention is made using polyamide and ABS hybrid resin
For the vector resin of Masterbatch, and it is resistance to by addition weather resisting agent, antioxidant, dispersing agent and pigment etc. high durable to be prepared jointly
High temperature ABS deflagration Masterbatch, the product being prepared with the Masterbatch, weather resistance meet 313nm wavelength, 0.55mw/cm2
Uv energy under irradiate 96H, chromatic aberration Δ E≤8, the flame retardant property of product meets UL94HB, and color is uniform, and this color
Mother does not occur the problems such as xanthochromia, yellow line in 250 DEG C or so lower injection molding resulting products, on Mechanical Properties of Products substantially without influence.This
The ABS deflagration Masterbatch of invention and ABS compatibility are good, and color divergence is excellent, it is small to influence on the impact strength of product.
Specific embodiment
Explanation that the present invention will be further explained combined with specific embodiments below, but specific embodiment is not to the present invention
It is limited in any way.Unless stated otherwise, material, method involved in embodiment are material and method commonly used in the art.
In following embodiment, the percentage composition is weight percentage.
Embodiment 1
At normal temperatures and pressures, by following component and weight percent: PA6 15%, ABS powder 20%, titanium dioxide 35%,
UV770 9%, ammonium polyphosphate 15%, BRUGGOLEN H10 1%, morning source branching lubricant CYD-C600:5%, in high speed
Mixed at high speed 10min is carried out in mixing machine, and melt blending, extrusion, pelletizing, drying, packaging, system are carried out using double screw extruder
Obtain high durable, high temperature resistant ABS deflagration Masterbatch.
Embodiment 2
At normal temperatures and pressures, by following component and weight percent: PA666 15%, ABS powder 21%, ultramarine 5%, titanium white
Powder 30%, poly-succinic (4- hydroxyl -2,2,6,6- tetramethyl -1- piperidine ethanol) ester 8%, [(6- oxygen-(6H)-dibenzo -
(CE) (1,2)-oxygen phospha ring -6- ketone) methyl]-succinic acid 15%, BRUGGOLEN H10 1%, morning source branching lubricant
CYD-C600:5% carries out mixed at high speed 10min in a high speed mixer, carries out melt blending using double screw extruder, squeezes
Out, high durable, high temperature resistant ABS deflagration Masterbatch is made in pelletizing, drying, packaging.
Embodiment 3
At normal temperatures and pressures, by following component and weight percent: PA612 15%, ABS powder 39.9%, carbon black 0.1%,
Iron oxide red 15%, 2,2' methylene bis (4- t-octyl -6- benzotriazole phenol) 2%, UV 770 7%, [(6- oxygen-(6H)-two
Benzo-(CE) (1,2)-oxygen phospha ring -6- ketone) methyl]-succinic acid 15%, 1%, two (octyl benzene of BRUGGOLEN H10
Phenol polyethenoxy ether) phosphide 5%, mixed at high speed 10min is carried out in a high speed mixer, is melted using double screw extruder
It is blended, extrusion, pelletizing, drying, packaging, high durable, high temperature resistant ABS deflagration Masterbatch is made.
Embodiment 4
At normal temperatures and pressures, by following component and weight percent: PA666 35%, ABS powder 29.9%, phthalocyanine blue
0.1%, solvent violet 2%, 2,2' methylene bis (4- t-octyl -6- benzotriazole phenol) 2%, UV 770 7%, polyphosphoric acids
Ammonium 20%, BRUGGOLEN H10 1%, two (octyl phenol polyoxyethylene ether) phosphide 3% carry out high in a high speed mixer
Speed mixing 10min carries out melt blending using double screw extruder, and high durable, resistance to height is made in extrusion, pelletizing, drying, packaging
Warm ABS deflagration Masterbatch.
Embodiment 5
At normal temperatures and pressures, by following component and weight percent: PA666 10%, ABS powder 53.99%, phthalocyanine blue
3%, solvent is black 0.01%, 2,2' methylene bis (4- t-octyl -6- benzotriazole phenol) 2%, UV 770 7%, poly phosphorus
Sour ammonium 20%, BRUGGOLEN H10 1%, chelating polyacrylic acid dispersant 3%, carry out mixed at high speed in a high speed mixer
10min carries out melt blending using double screw extruder, and it is slow that high durable, high temperature resistant ABS is made in extrusion, pelletizing, drying, packaging
Fire Masterbatch.
Comparative example 1
At normal temperatures and pressures, by following component and weight percent: ABS powder 35%, titanium dioxide 35%, UV770 9%, more
Ammonium polyphosphate 15%, BRUGGOLEN H10 1%, morning source branching lubricant CYD-C600:5%, carry out in a high speed mixer
Mixed at high speed 10min carries out melt blending using double screw extruder, and comparative example color masterbatch is made in extrusion, pelletizing, drying, packaging
Grain.
Comparative example 2
At normal temperatures and pressures, by following component and weight percent: ABS powder 70%, phthalocyanine blue 3%, solvent be black 0.01%,
2,2' methylene bis (4- t-octyl -6- benzotriazole phenol) 2%, UV 770 7%, BRUGGOLEN H10 1%, PE wax
16.99%, mixed at high speed 10min is carried out in a high speed mixer, and melt blending is carried out using double screw extruder, squeezes out, cut
Grain, dry, packaging, are made comparative example Masterbatch.
Comparative example 3
At normal temperatures and pressures, by following component and weight percent: PA666 35%, ABS powder 30.9%, phthalocyanine blue
0.1%, solvent violet 2%, 2,2' methylene bis (4- t-octyl -6- benzotriazole phenol) 2%, UV 770 7%, polyphosphoric acids
Ammonium 20%, two (octyl phenol polyoxyethylene ether) phosphide 3% carries out mixed at high speed 10min, using double in a high speed mixer
Screw extruder carries out melt blending, and high durable, high temperature resistant ABS deflagration Masterbatch is made in extrusion, pelletizing, drying, packaging.
Comparative example 4
At normal temperatures and pressures, by following component and weight percent: PA612 15%, ABS powder 43.9%, carbon black 0.1%,
Iron oxide red 15%, ammonium polyphosphate 20%, BRUGGOLEN H10 1%, two (octyl phenol polyoxyethylene ether) phosphide 5%,
Mixed at high speed 10min is carried out in high-speed mixer, and melt blending, extrusion, pelletizing, drying, packet are carried out using double screw extruder
High durable, high temperature resistant ABS deflagration Masterbatch is made in dress.
Comparative example 5
At normal temperatures and pressures, by following component and weight percent: PE resin 20, EVA resin 38.9, carbon black 0.1%, iron
Red 15%, ammonium polyphosphate 20%, BRUGGOLEN H10 1%, two (octyl phenol polyoxyethylene ether) phosphide 5%, in height
In fast mixing machine carry out mixed at high speed 10min, using double screw extruder carry out melt blending, extrusion, pelletizing, drying, packaging,
High durable, high temperature resistant ABS deflagration Masterbatch is made.
Masterbatch prepared by Examples 1 to 5 and comparative example 1~5 adds 4phr injection molding colour table, burning in ABS plastic
Batten and impact batten, specific comparing result are as shown in table 1.
The performance evaluation of table 1 each embodiment and comparative example:
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (9)
1. a kind of high durable high-temperature resistant ABS deflagration Masterbatch, it is characterised in that: composed of the following components by weight: polyamide
10%~35%, ABS 10%~70%, toner 0.001~75%, weather resisting agent 1%~20%, fire retardant 2%~30%, anti-
Oxygen agent 0.05%~3%, dispersing agent 0%~10%.
2. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 1, it is characterised in that: by weight by with the following group
It is grouped as: polyamide 10%~35%, ABS 20%~70%, toner 2~35%, weather resisting agent 8%~9%, fire retardant 15%
~20%, antioxidant 1%, dispersing agent 3%~5%.
3. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 1, it is characterised in that: the polyamide is molten
Copolyamide, nylon 6, nylon 12, nylon 11, nylon 1212, Nylon 1012, nylon of the point lower than 180 DEG C and greater than 130 DEG C
666, one of nylon 612 or a variety of.
4. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 1, it is characterised in that: the toner is heatproof
Inorganic pigment and organic pigment greater than 250 DEG C are compounded.
5. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 1, it is characterised in that: the weather resisting agent be by
Hinder one of amine light stabilizer, benzotriazole ultraviolet absorber, triazines ultraviolet absorber or a variety of mixtures.
6. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 1, it is characterised in that: the fire retardant is nothing
Halogen fire retardant.
7. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 6, it is characterised in that: the halogen-free flame retardants
For -10 phospho hetero phenanthrene -10- oxide of 9, -9 oxa- of 10- dihydro, -10 hydrogen -9- oxa- -10- phospha of 10- (2,5- dihydroxy phenyl)
Phenanthrene -10- oxide, [(6- oxygen-(6H)-dibenzo-(CE) (1,2)-oxygen phospha ring -6- ketone) methyl]-succinic acid, melamine
One of aminuria cyanate, ammonium polyphosphate, Melamine Polyphosphate, melamine, phosphate ester flame retardants etc. or
It is a variety of.
8. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 1, it is characterised in that: the antioxidant is nothing
The mixture of machine phosphoric acid salt antioxidant BRUGGOLEN H10, amine antioxidants and special Synergistic stabilizerOne of Synergistic blend BRUGGOLEN H161 of H20, hindered phenol antioxygen and phosphonate or
It is a variety of.
9. high durable high-temperature resistant ABS deflagration Masterbatch according to claim 1, it is characterised in that: the dispersing agent is titanium
One of esters of gallic acid coupling agent, phosphoric acid ester dispersing agent, chelating type dispersing agent, hyperbranched polyhydroxy polycarboxylic esters dispersing agent are more
Kind mixture.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113999497A (en) * | 2021-10-25 | 2022-02-01 | 金发科技股份有限公司 | Organic black powder composition and preparation method and application thereof |
| CN116355350A (en) * | 2023-04-13 | 2023-06-30 | 清远市一丞阻燃材料有限公司 | High-toughness halogen-free flame-retardant ABS composition and preparation method thereof |
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| CN113999497B (en) * | 2021-10-25 | 2023-09-26 | 金发科技股份有限公司 | Organic black powder composition and preparation method and application thereof |
| CN116355350A (en) * | 2023-04-13 | 2023-06-30 | 清远市一丞阻燃材料有限公司 | High-toughness halogen-free flame-retardant ABS composition and preparation method thereof |
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