CN105647100B - A kind of high black highlighted ABS flame-retardant color master batch grain and its preparation method and application method - Google Patents
A kind of high black highlighted ABS flame-retardant color master batch grain and its preparation method and application method Download PDFInfo
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- CN105647100B CN105647100B CN201610123994.5A CN201610123994A CN105647100B CN 105647100 B CN105647100 B CN 105647100B CN 201610123994 A CN201610123994 A CN 201610123994A CN 105647100 B CN105647100 B CN 105647100B
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 113
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 239000004595 color masterbatch Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 132
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 230000000979 retarding effect Effects 0.000 claims abstract description 25
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical group [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 10
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 claims description 10
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 239000011256 inorganic filler Substances 0.000 claims description 10
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 10
- 239000000779 smoke Substances 0.000 claims description 9
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 6
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 claims description 6
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 150000003918 triazines Chemical class 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 238000001746 injection moulding Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002861 polymer material Substances 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 6
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 4
- 239000000347 magnesium hydroxide Substances 0.000 description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2425/02—Homopolymers or copolymers of hydrocarbons
- C08J2425/04—Homopolymers or copolymers of styrene
- C08J2425/08—Copolymers of styrene
- C08J2425/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The present invention relates to technical field of polymer materials, more particularly to a kind of high black highlighted ABS flame-retardant color master batch grain and its preparation method and application method, the black highlighted ABS flame-retardant color master batch grain of the height is made of the raw material of following parts by weight: 10-30 parts of ABS resin, 5-15 parts of bloom black race, 50-60 parts of fire retardant, 10-18 parts of fire retarding synergist, 2-8 parts of processing aid, 2-5 parts of finishing agent.Production process of the invention is short, at low cost, and flame-retardant color master batch grain obtained can be molded use directly on injection molding machine after being blended with ABS raw material, product surface glossiness obtained is high, and blackness is high, while can get flame retardant effect.
Description
Technical field
The present invention relates to technical field of polymer materials, and in particular to a kind of high black highlighted ABS flame-retardant color master batch grain and its system
Preparation Method and methods for using them.
Background technique
With the development of society and the progress of the mankind, people are also higher and higher to the definition and requirement of beauty.For example, selecting
When household electrical appliances, OA equipment, it is no longer limited only to its functionality, more attentions are concentrated in product appearance.It is high black highlighted
OA equipment more and more receive the favor of people because of its included deep, generous effect.ABS is butadiene, benzene
The characteristics of ethylene, acrylonitrile terpolymer, have that glossiness is high at the advantages of having gathered three kinds of materials, easily molded, good toughness,
It dyes ABS and its flame-retardant modified ABS material is common OA equipment raw material.
In modified enterprise, such common manufacturing method of material are as follows: high by ABS raw material, function additive and bloom black race
After speed is puddled, use double-screw extruding pelletizing, although using raw material made from such method can obtain excellent performance with
Appearance, but energy consumption is high for such method, and Workshop Production environment is poor, and process is long, at high cost.
Summary of the invention
The purpose of the present invention is being directed to above-mentioned deficiency in the prior art, a kind of high black highlighted ABS flame-retardant color master batch grain is provided
And its preparation method and application method, production process is short, at low cost, after flame-retardant color master batch grain obtained is blended with ABS raw material
Use can be molded directly on injection molding machine, product surface glossiness obtained is high, and blackness is high, while can get flame retardant effect.
The purpose of the present invention is achieved through the following technical solutions.
A kind of high black highlighted ABS flame-retardant color master batch grain, is made of the raw material of following parts by weight:
10-30 parts of ABS resin
5-15 parts of bloom black race
50-60 parts of fire retardant
10-18 parts of fire retarding synergist
2-8 parts of processing aid
2-5 parts of finishing agent.
Preferably, a kind of high black highlighted ABS flame-retardant color master batch grain, is made of the raw material of following parts by weight:
10-20 parts of ABS resin
5-10 parts of bloom black race
50-60 parts of fire retardant
11-15 parts of fire retarding synergist
3-5 parts of processing aid
2-3 parts of finishing agent.
Wherein, the ABS resin is the ABS resin of high flowing, under 220 DEG C/10KG test condition, material flowability
Index >=40g/10min.High stir-in resin is conducive to the dispersion of black race, it is ensured that the compatibility of ABS resin and bloom black race.
Wherein, the bloom black race is the mass percent of black smoke in black race using height flowing AS or ABS as the black race of carrier
For 70-90%, the mass percent of carrier is 10-30%.
Bloom black race in the present invention is that high flowing AS or ABS is added on the basis of black smoke to make carrier, can be increased
The compatibility of black smoke and matrix resin (ABS resin).Be conducive to avoid the difference because of compatibility, generate current mark in injection moulding process,
The surface defects such as shade.
Wherein, in the carrier, height flowing AS resin is under 220 DEG C/10KG test condition, material flowability >=50g/
10min；In the carrier, height flowing ABS resin is under 220 DEG C/10KG test condition, material flowability >=40g/10min.
Wherein, the fire retardant is at least one of brominated triazine, tetrabromobisphenol A, brominated epoxy resin；It is described fire-retardant
Synergist is compounded by antimony oxide based flame retardant and inorganic filler with mass ratio for the ratio of 1-3:1, the fire retardant with
The mass ratio of the fire retarding synergist is 3:1-4:1.
Fire retarding synergist is compounded by antimony oxide based flame retardant with inorganic filler, advantageously reduces cost, and fire-retardant
The synergy of agent is good.Bromine antimony compositional flame-retardant is most common flame-retardant system in current ABS, and flame retarding efficiency is high, moderate,
Influence performance to material is small；And traditional halogen-free flame retardants flame retarding efficiency is lower, needs to add more amount, price is more expensive,
It is affected to material, is unsuitable for commercialization and uses.
Wherein, the antimony oxide based flame retardant be at least one of antimony trioxide, antimony pentoxide, sodium antimonate, it is described
Inorganic filler is at least one of barium sulfate, talcum powder, magnesium hydroxide.Preferably, the antimony oxide based flame retardant is three
Antimony oxide, antimony pentoxide, sodium antimonate are the mixture of 1-2:0.5-0.8:1.2-1.5, the inorganic filler with mass ratio
It with mass ratio is the mixture of 2-3:1-1.5:0.8-1.2 for barium sulfate, talcum powder, magnesium hydroxide.
Wherein, the finishing agent is one or both of the wax of low molecular weight, silicone oil substance.Low molecular weight
Wax, for molecular weight in 2000-5000 or so, fusing point is relatively low, and in injection moulding process, the wax of low molecular weight can precipitate into product table
Face increases surface-brightening effect.Preferably, the wax of the low molecular weight is PE wax, the molecular weight of PE wax in 1500-5000, with
ABS raw material can precipitate into product surface when being blended, increase surface-brightening effect.
Preferably, it is mixture that 1:1 is compounded that the finishing agent, which is PE wax with silicone oil substance with mass ratio,.
The silicone oil substance is dimethicone.
Wherein, the processing aid is the mixture of antioxidant and lubricant with mass ratio for 1-2:2:3；Preferably, institute
Stating processing aid is the mixture of antioxidant and lubricant with mass ratio for 1:3.The antioxidant is BASF IRGANOX
1010 and IRGANOX 168 is the mixture of 1:1 with mass ratio；The lubricant be WWRC Group chemical industry EBS and magnesium stearate with
Mass ratio is the mixture of 1:1.
A kind of preparation method of high black highlighted ABS flame-retardant color master batch grain, comprising the following steps:
(1) the above-mentioned ABS resin of precise, bloom black race, fire retardant, fire retarding synergist in proportion, processing aid and table
Face brightener puts it into high-speed mixer and is sufficiently stirred 5-10 minutes；
(2) above-mentioned mixed material is added to double screw extruder, by melting, extrusion, granulation, dry obtained height
Black highlighted ABS flame-retardant color master batch grain, wherein processing temperature range are as follows: 170-180 DEG C, vacuum degree >=0.08MPa, the major diameter of extruder
Than for 25-40, screw speed range is 300-600 revs/min.
A kind of application method of high black highlighted ABS flame-retardant color master batch grain, the black highlighted ABS fire-retardant master granule of above-mentioned height and ABS is former
It after material mixing, is directly molded, high black highlighted ABS composite material, the quality of high black highlighted ABS fire-retardant master granule and ABS raw material is made
Than for 2-3:7-8.
Wherein, the ABS raw material are general ABS material.ABS raw material and Masterbatch are using preceding shaking up, in injection molding machine
Under the action of temperature and screw rod shearing, the Masterbatch of height flowing significantly more efficient can disperse in the base, so that matrix has
The shiny black effect of fire-retardant function and surface.
Utilize the finished surface light of the black highlighted ABS composite material of height made from the black highlighted ABS fire-retardant master granule of height of the invention
Bright, glossiness can achieve on 86, and blackness L value can achieve 26.5 ~ 29.5, and flame retardant rating (3.2mm) can achieve V-0
Grade.
ABS bloom bittern-free flame-proof material in the prior art is directly produced by modified factory, and client, which directly buys, to be made
With price is more expensive.For modified factory, high production cost.The black highlighted ABS fire-retardant master granule of height provided by the invention can be with
Reach the flame-retardant color master batch grain of common class effect, common class effect can be reached after need to only mixing with ABS raw material after client's purchase, used
It is convenient, it is at low cost.
Beneficial effects of the present invention:
Color kind (bloom black race) function and flame retardant efficiency are combined by special selection, are prepared for one kind by the present invention
It can be used for the black highlighted ABS flame-retardant color master batch grain of height of OA equipment, and provide the preparation method of this flame-retardant color master batch grain.Client
Can be used it is high it is black highlight fire-retardant color kind master batch and raw material simple blend after, use can be molded directly on injection molding machine, it is obtained
Product surface glossiness it is high, blackness is high, while can get flame retardant effect.
Utilize the finished surface light of the black highlighted ABS composite material of height made from the black highlighted ABS fire-retardant master granule of height of the invention
Bright, glossiness can achieve on 86, and blackness L value can achieve 27.5 ~ 28.5, and flame retardant rating can achieve 3.2 V-0 grades.
Specific embodiment
The invention will be further described with the following Examples.
Embodiment 1
A kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, is made of the raw material of following parts by weight:
10 parts of ABS resin
15 parts of bloom black race
50 parts of fire retardant
10 parts of fire retarding synergist
2 parts of processing aid
2 parts of finishing agent.
Wherein the ABS resin is high flowing ABS 756S, and bloom black race is AS carrier black race, black smoke mass percent
Ratio is 90%, and the mass percent of carrier is 10%, and fire retardant is brominated triazine, and fire retarding synergist is antimony oxide and hydrogen-oxygen
Change magnesium according to the ratio compound of 3:1, processing aid is the mixture of antioxidant and lubricant 1:3, and finishing agent is PE wax
With the mixture of dimethyl-silicon oily substance 1:1, the molecular weight of PE wax is 1500.
A kind of preparation method of the high black highlighted ABS flame-retardant color master batch grain of the present embodiment, comprising the following steps:
(1) the above-mentioned ABS resin of precise, bloom black race, fire retardant, fire retarding synergist in proportion, processing aid and table
Face brightener puts it into high-speed mixer and is sufficiently stirred 5 minutes；
(2) above-mentioned mixed material is added to double screw extruder, by melting, extrusion, granulation, dry obtained height
Black highlighted ABS flame-retardant color master batch grain, wherein processing temperature range are as follows: 170 DEG C, the draw ratio of vacuum degree >=0.08MPa, extruder is
25, screw speed range is 600 revs/min.
The application method of a kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, by the black highlighted fire-retardant mother of ABS of above-mentioned height
It after grain is mixed with ABS raw material, is directly molded, high black highlighted ABS composite material is made, high black highlighted ABS fire-retardant master granule and ABS are former
The mass ratio of material is 2:8.
Embodiment 2
A kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, is made of the raw material of following parts by weight:
20 parts of ABS resin
11 parts of bloom black race
50 parts of fire retardant
12 parts of fire retarding synergist
4 parts of processing aid
3 parts of finishing agent.
Wherein the ABS resin is high flowing ABS 756H, and bloom black race is ABS carrier black race, black smoke mass percent
It is 80%, the mass percent of carrier is 20%, and fire retardant is brominated epoxy, and fire retarding synergist is that antimony pentoxide is pressed with barium sulfate
According to the ratio compound of 3:1, processing aid is the mixture of antioxidant and lubricant 1:2, and finishing agent is PE wax and diformazan
The mixture of base silicone oil substance 1:1, the molecular weight of PE wax are 1800.
A kind of preparation method of the high black highlighted ABS flame-retardant color master batch grain of the present embodiment, comprising the following steps:
(1) the above-mentioned ABS resin of precise, bloom black race, fire retardant, fire retarding synergist in proportion, processing aid and table
Face brightener puts it into high-speed mixer and is sufficiently stirred 6 minutes；
(2) above-mentioned mixed material is added to double screw extruder, by melting, extrusion, granulation, dry obtained height
Black highlighted ABS flame-retardant color master batch grain, wherein processing temperature range are as follows: 172 DEG C, the draw ratio of vacuum degree >=0.08MPa, extruder is
26, screw speed range is 580 revs/min.
The application method of a kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, by the black highlighted fire-retardant mother of ABS of above-mentioned height
It after grain is mixed with ABS raw material, is directly molded, high black highlighted ABS composite material is made, high black highlighted ABS fire-retardant master granule and ABS are former
The mass ratio of material is 2.5:7.5.
Embodiment 3
A kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, is made of the raw material of following parts by weight:
16 parts of ABS resin
5 parts of bloom black race
50 parts of fire retardant
15 parts of fire retarding synergist
5 parts of processing aid
2 parts of finishing agent.
Wherein the ABS resin is high flowing ABS 756H, and bloom black race is ABS carrier black race, the quality percentage of black smoke
It is frequently 85%, the mass percent of carrier is 15%, and fire retardant is tetrabromobisphenol A, and fire retarding synergist is sodium antimonate and talcum powder
According to the ratio compound of 2:1, processing aid is the mixture of antioxidant and lubricant 2:3, and finishing agent is PE wax and two
The mixture of methyl-silicone oil substance 1:1, the molecular weight of PE wax is 2000.
A kind of preparation method of the high black highlighted ABS flame-retardant color master batch grain of the present embodiment, comprising the following steps:
(1) the above-mentioned ABS resin of precise, bloom black race, fire retardant, fire retarding synergist in proportion, processing aid and table
Face brightener puts it into high-speed mixer and is sufficiently stirred 8 minutes；
(2) above-mentioned mixed material is added to double screw extruder, by melting, extrusion, granulation, dry obtained height
Black highlighted ABS flame-retardant color master batch grain, wherein processing temperature range are as follows: 1750 DEG C, vacuum degree >=0.08MPa, the draw ratio of extruder
It is 30, screw speed range is 500 revs/min.
The application method of a kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, by the black highlighted fire-retardant mother of ABS of above-mentioned height
It after grain is mixed with ABS raw material, is directly molded, high black highlighted ABS composite material is made, high black highlighted ABS fire-retardant master granule and ABS are former
The mass ratio of material is 3:7.
Embodiment 4
A kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, is made of the raw material of following parts by weight:
25 parts of ABS resin
8 parts of bloom black race
53 parts of fire retardant
17 parts of fire retarding synergist
6 parts of processing aid
4 parts of finishing agent.
Wherein the ABS resin is high flowing ABS 756S, and bloom black race is ABS carrier black race, the quality percentage of black smoke
Than being 70%, the mass percent of carrier is 30%, and fire retardant is the ratio that brominated triazine and tetrabromobisphenol A are 3:1 according to mass ratio
Example compound, the fire retarding synergist by antimony oxide based flame retardant and inorganic filler with mass ratio for 1:1 ratio compounding and
At the antimony oxide based flame retardant is the mixing of antimony trioxide, antimony pentoxide, sodium antimonate with mass ratio for 2:0.8:1.5
Object, the inorganic filler are the mixture of barium sulfate, talcum powder, magnesium hydroxide with mass ratio for 3:1:1.2, and processing aid is
The mixture of antioxidant and lubricant 1:1, finishing agent are the mixture of PE wax and dimethyl-silicon oily substance 1:1, PE wax
Molecular weight 2500.
A kind of preparation method of the high black highlighted ABS flame-retardant color master batch grain of the present embodiment, comprising the following steps:
(1) the above-mentioned ABS resin of precise, bloom black race, fire retardant, fire retarding synergist in proportion, processing aid and table
Face brightener puts it into high-speed mixer and is sufficiently stirred 9 minutes；
(2) above-mentioned mixed material is added to double screw extruder, by melting, extrusion, granulation, dry obtained height
Black highlighted ABS flame-retardant color master batch grain, wherein processing temperature range are as follows: 178 DEG C, the draw ratio of vacuum degree >=0.08MPa, extruder is
35, screw speed range is 400 revs/min.
The application method of a kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, by the black highlighted fire-retardant mother of ABS of above-mentioned height
It after grain is mixed with ABS raw material, is directly molded, high black highlighted ABS composite material is made, high black highlighted ABS fire-retardant master granule and ABS are former
The mass ratio of material is 3:7.
Embodiment 5
A kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, is made of the raw material of following parts by weight:
30 parts of ABS resin
12 parts of bloom black race
60 parts of fire retardant
18 parts of fire retarding synergist
8 parts of processing aid
2 parts of finishing agent.
Wherein the ABS resin is high flowing ABS 756H, and bloom black race is ABS carrier black race, the quality percentage of black smoke
It is frequently 75%, the mass percent of carrier is 25%, and fire retardant is brominated epoxy, and the fire retarding synergist is fire-retardant by antimony oxide class
Agent and inorganic filler are compounded with mass ratio for the ratio of 1:1, and the antimony oxide based flame retardant is antimony trioxide, five oxidations
Two antimony, sodium antimonate are the mixture of 1:0.5:1.2 with mass ratio, and the inorganic filler is barium sulfate, talcum powder, magnesium hydroxide
It is the mixture of 2:1:0.8 with mass ratio, processing aid is the mixture of antioxidant and lubricant 1:3, finishing agent PE
The mixture of wax and dimethyl-silicon oily substance 1:1, the molecular weight of PE wax is 3000.
A kind of preparation method of the high black highlighted ABS flame-retardant color master batch grain of the present embodiment, comprising the following steps:
(1) the above-mentioned ABS resin of precise, bloom black race, fire retardant, fire retarding synergist in proportion, processing aid and table
Face brightener puts it into high-speed mixer and is sufficiently stirred 5-10 minutes；
(2) above-mentioned mixed material is added to double screw extruder, by melting, extrusion, granulation, dry obtained height
Black highlighted ABS flame-retardant color master batch grain, wherein processing temperature range are as follows: 180 DEG C, vacuum degree >=0.08MPa, the draw ratio of extruder
It is 40, screw speed range is 600 revs/min.
The application method of a kind of high black highlighted ABS flame-retardant color master batch grain of the present embodiment, by the black highlighted fire-retardant mother of ABS of above-mentioned height
It after grain is mixed with ABS raw material, is directly molded, high black highlighted ABS composite material is made, high black highlighted ABS fire-retardant master granule and ABS are former
The mass ratio of material is 3:7.
The black highlighted ABS composite material of height made from the black highlighted ABS fire-retardant master granule of height using the present embodiment 1-5 of the invention
Physical function parameter it is as follows:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Blackness | 27 | 28.5 | 26.5 | 29.5 | 29.5 |
| Glossiness | 91 | 88 | 92 | 86 | 86 |
| Fire-retardant (3.2mm) | V-0 | V-0 | V-0 | V-0 | V-0 |
Color kind (bloom black race) function and flame retardant efficiency are combined by special selection, are prepared for one kind by the present invention
It can be used for the black highlighted ABS flame-retardant color master batch grain of height of OA equipment, and provide the preparation method of this flame-retardant color master batch grain.Client
Can be used it is high it is black highlight fire-retardant color kind master batch and raw material simple blend after, use can be molded directly on injection molding machine, it is obtained
Product surface glossiness it is high, blackness is high, while can get flame retardant effect.
Utilize the finished surface light of the black highlighted ABS composite material of height made from the black highlighted ABS fire-retardant master granule of height of the invention
Bright, glossiness can achieve 86-92, and blackness L value can achieve 26.5 ~ 29.5, and flame retardant rating can achieve V-0 grades.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered
Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (4)
1. a kind of high black highlighted ABS flame-retardant color master batch grain, it is characterised in that: be made of the raw material of following parts by weight:
The ABS resin is the ABS resin of high flowing, under 220 DEG C/10KG test condition, material flowability index >=
40g/10min；
The bloom black race is using height flowing AS or ABS as the black race of carrier, and the mass percent of black smoke is 70- in black race
90%, the mass percent of carrier is 10-30%；In the carrier, height flows AS resin under 220 DEG C/10KG test condition,
Material flowability >=50g/10min；In the carrier, height flowing ABS resin is under 220 DEG C/10KG test condition, material flowing
Property >=40g/10min；
The fire retardant is at least one of brominated triazine, tetrabromobisphenol A, brominated epoxy resin；The fire retarding synergist by
Antimony oxide based flame retardant and inorganic filler are compounded with mass ratio for the ratio of 1-3:1；
The finishing agent is one or both of the wax of low molecular weight, silicone oil substance；
The processing aid is the mixture of antioxidant and lubricant with mass ratio for 1-2:2:3；The antioxidant is BASF
IRGANOX 1010 and IRGANOX 168 is the mixture of 1:1 with mass ratio；The lubricant is the EBS of WWRC Group chemical industry and hard
Fatty acid magnesium is the mixture of 1:1 with mass ratio.
2. a kind of high black highlighted ABS flame-retardant color master batch grain according to claim 1, it is characterised in that: the antimony oxide class resistance
Combustion agent is at least one of antimony trioxide, antimony pentoxide, sodium antimonate, and the inorganic filler is barium sulfate, talcum powder, hydrogen
At least one of magnesia.
3. a kind of preparation method of high black highlighted ABS flame-retardant color master batch grain, feature described in claim 1-2 any one exist
In: including following procedure of processing:
(1) the above-mentioned ABS resin of precise, bloom black race, fire retardant, fire retarding synergist in proportion, processing aid and surface light
It bright dose, puts it into high-speed mixer and is sufficiently stirred 5-10 minutes；
(2) above-mentioned mixed material is added to double screw extruder, by melting, extrusion, granulation, dry obtained Gao Heigao
Bright ABS flame-retardant color master batch grain, wherein processing temperature range are as follows: 170-180 DEG C, the draw ratio of vacuum degree >=0.08MPa, extruder is
25-40, screw speed range are 300-600 revs/min.
4. a kind of application method of high black highlighted ABS flame-retardant color master batch grain, feature described in claim 1-2 any one exist
In: it after the black highlighted ABS flame-retardant color master batch grain of above-mentioned height is mixed with ABS raw material, is directly molded, high black highlighted ABS composite wood is made
The mass ratio of material, high black highlighted ABS flame-retardant color master batch grain and ABS raw material is 2-3:7-8.
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| CN107216484A (en) * | 2017-06-16 | 2017-09-29 | 惠州市东旭塑胶有限公司 | A kind of preparation method of fire-retardant black masterbatch |
| CN107936446A (en) * | 2017-12-22 | 2018-04-20 | 铜陵市远维线缆有限公司 | A kind of electric wire processing method for improving flame-retardant insulating electric wire moisture resistance |
| CN111500011A (en) * | 2019-12-12 | 2020-08-07 | 重庆会通科技有限公司 | Household flame-retardant weather-resistant high-gloss ABS material and preparation method thereof |
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| CN101787174B (en) * | 2009-11-05 | 2013-05-08 | 上海锦湖日丽塑料有限公司 | Low-L value inflaming retarding ABS modified resin and preparation method thereof |
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