CN105936732A - High transparency and high hardness flame retardant ABS composite material and preparation method thereof - Google Patents
High transparency and high hardness flame retardant ABS composite material and preparation method thereof Download PDFInfo
- Publication number
- CN105936732A CN105936732A CN201610405561.9A CN201610405561A CN105936732A CN 105936732 A CN105936732 A CN 105936732A CN 201610405561 A CN201610405561 A CN 201610405561A CN 105936732 A CN105936732 A CN 105936732A
- Authority
- CN
- China
- Prior art keywords
- retardant
- resin
- high transparency
- flame
- high rigidity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a high transparency and high hardness flame retardant ABS composite material and a preparation method thereof. The high transparency and high hardness flame retardant ABS composite material is prepared from the following raw materials by weight: 60-85 parts of resin A, 10-30 parts of PMMA, 10-20 parts of flame retardant masterbatch, and 5-25 parts of a toughening agent, wherein the resin A is MABS. The flame retardant masterbatch is prepared from the following raw materials by weight: 60-90 parts of resin B, 10-30 parts of a phosphorus-nitrogen flame retardant, and 5-20 parts of zinc borate, wherein the resin A is MABS. And the specification of the resin A and the specification of the resin B can be the same or different. According to the high transparency and high hardness flame retardant ABS composite material provided by the invention, a flame retardant is prepared into masterbatch, so that the flame retardant can be dispersed more uniformly in the blend. And by using a flame retardant with small particle size, the material's light transmittance can be improved.
Description
Technical field
The invention belongs to polymeric material field, especially relate to a kind of high transparency, high rigidity flame-proof ABS
Composite and preparation method thereof.
Background technology
Acrylonitrile-butadiene-styrene copolymer (ABS) resin is by styrene, butadiene, propylene
The terpolymer of nitrile composition, has concentrated cinnamic high fluidity, the rubber toughness of butadiene and propylene
The chemicals-resistant characteristic of nitrile, has excellent processing characteristics, resistance to low temperature, electrical insulation capability, resistance toization
Learn corrosive nature and high glaze and excellent plating performance, have that creep resistant is good, dimensional stability simultaneously
The excellent characteristics such as height, molding shrinkage are little, the widest in field application such as military project, automobile, electronic apparatus
General.But on the one hand the oxygen index (OI) of ABS resin only has 18, belongs to combustible material.Therefore, to ABS tree
It is the most conventional a kind of ABS resin method of modifying that fat carries out flame-retardant modified.On the other hand, along with society
Can expanding economy, people are in addition to more and more higher to the requirement of materials'use performance, more to material surface
Aesthetic increasingly favor, therefore develop and not only there is serviceability, have more transparent texture
Material modified is a current trend.There are many macromolecular materials at present without accomplishing before modified
Transparent stage, such as clear polycarbonate, acrylic, transparent ABS (MABS) resin, saturating benzene etc., but
These materials, by after flame-retardant modified, all become non-transparent material.Obtaining it to the requirement of performance
Meanwhile, the aesthetic values of its outward appearance it are lost.
But, the case hardness of common transparent flame-retardant ABS material is relatively low, limits it one
Application in a little fields.Additionally, the flame retardant effect of existing transparent flame-retardant ABS material is poor, thoroughly
Lightness is relatively low.Therefore, develop a kind of high transparency, high rigidity flame-retardant ABS compound material seems particularly
Important, there is the huge market space.
Summary of the invention
In view of this, it is contemplated that propose a kind of high transparency, high rigidity flame-retardant ABS compound material and
Its preparation method, high transparency, high rigidity flame-retardant ABS compound material pencil hardness level >=HB rank, system
Preparation Method is simple, handling ease, with low cost.
For reaching above-mentioned purpose, the technical scheme is that and be achieved in that:
A kind of high transparency, high rigidity flame-retardant ABS compound material, by the raw material system including following weight portion
Become:
Wherein, described Resin A is MABS.
Further, described fire-retardant master granule is made up of the raw material including following weight portion:
Resin B 60-90 part,
Phosphorus-nitrogen containing flame retardant 10-30 part,
Firebrake ZB 5-20 part；
Wherein, described resin B is MABS；Described Resin A identical with the specification of resin B or
Different.
Further, described phosphorus-nitrogen containing flame retardant is the one in Quadrafos, melamine cyanurate
Or the mixture of two kinds；The particle diameter of described Firebrake ZB is 2-4 μm.
Further, the light transmittance of described Resin A > 80%, Izod notched impact strength > 10kJ/m2；
The light transmittance of described resin B > 80%, Izod notched impact strength > 10kJ/m2。
Further, described toughener is MMB methyl methacrylate butadiene styrene copolymer
(MBS) type toughener, acrylonitrile-styrene-acrylic ester graft copolymer (ASA) type toughener,
One or more in ethylene-vinyl acetate copolymer (EVA) type toughener.
Further, the described PMMA melt flow rate (MFR) when 220 DEG C/10KG is
15-35g/10min, pencil hardness is 2H.
Described high transparency, the raw material of high rigidity flame-retardant ABS compound material also include that weight portion is
The auxiliary agent of 0.1-3 part.
Described auxiliary agent is heat stabilizer, light stabilizer, processing aid or pigment.
Described heat stabilizer can improve material heat aging property during processing and use, logical
Often be selected from the complex of phenols, phosphorous acid esters, monothioester class one or more.
Described light stabilizer can improve material light aging resisting property in use, can be to be obstructed
Amine or UV absorbent.
Described processing aid is that low molecule esters stearic acid, metallic soap are (selected from calcium stearate Cast, hard
Fat acid zinc Znst), one or more in stearic acid complex ester or amide-type (erucyl amide).
Described high transparency, the preparation method of high rigidity flame-retardant ABS compound material, comprise the steps:
(1) resin B, phosphorus-nitrogen containing flame retardant and Firebrake ZB are joined in high-temperature mixing machine, at 170-250
Carry out premixing at a temperature of DEG C, after pelletize cooling, obtain fire-retardant master granule；
(2) Resin A, PMMA, fire-retardant master granule, toughener are sufficiently mixed 10-60 at high-speed mixer
Minute, obtain premix material；
(3) premix material is transported in double screw extruder through the pay-off of delicate metering, extrusion
Each section of extruder temperature of machine controls between 180-230 DEG C, and the draw ratio of double screw extruder is 25-40:
1, screw speed is 200-800 rev/min, screw rod shearing, mixing and conveying under, material is able to
Fully fusing, compound, then through extruding pelletization, to be dried to obtain high transparency, high rigidity flame-proof ABS multiple
Condensation material.
Described high transparency, high rigidity flame-retardant ABS compound material join needed for being processed in injection machine
Batten, the barrel temperature of described injection machine 190-240 DEG C, mold temperature 60-70 DEG C, injection pressure
6-10MPa。
Described high transparency, the application of high rigidity flame-retardant ABS compound material, described high transparency, height
Hardness flame-retardant ABS compound material is applied to electrical instrumentation, medical equipment or electron trade.
Relative to prior art, high transparency of the present invention, high rigidity flame-retardant ABS compound material and
Its preparation method has the advantage that
(1) high transparency of the present invention, high rigidity flame-retardant ABS compound material are through test, its resistance
Combustion grade reaches V-2 or V-1 rank, excellent in mechanical performance.
(2) high transparency of the present invention, high rigidity flame-retardant ABS compound material transparency are more than 70%.
(3) high transparency of the present invention, high rigidity flame-retardant ABS compound material pencil hardness level >=HB
Rank.
(4) fire retardant is prepared as by high transparency of the present invention, high rigidity flame-retardant ABS compound material
Master batch, can make fire retardant the most scattered more uniform；Use the fire retardant that particle diameter is little permissible
The light transmittance making material improves.
(5) high transparency of the present invention, the preparation method of high rigidity flame-retardant ABS compound material help
In improving working environment.
(6) high transparency of the present invention, high rigidity flame-retardant ABS compound material preparation method simple
Easy, handling ease, with low cost, it is highly suitable for electrical instrumentation, medical equipment, electron trade etc.
I.e. need fire-retardant, need again the field popularization and application such as certain transparency.
Detailed description of the invention
Unless otherwise indicated, term used herein is respectively provided with containing of those skilled in the art's routine understanding
Terms more used herein, for the ease of understanding the present invention, have been carried out following definitions by justice.
All of Digital ID, such as pH, temperature, time, concentration, including scope, be all approximation
Value.It is to be understood that, although all add term " about " before all of Digital ID of the clearest and the most definite narration.
Simultaneously it will also be understood that, although the clearest and the most definite narration, reagent described herein is only example, its
Equivalent is known in the art.
MABS described in the embodiment of the present invention selects the MABS TE-10S of NEC chemistry；
PMMA described in the embodiment of the present invention selects strange beautiful CM-211；
The MBS EM-500 of Korea S LG chemistry selected by toughener described in the embodiment of the present invention；
Phosphorus-nitrogen containing flame retardant described in the embodiment of the present invention is Quadrafos, and described Quadrafos selects Chinese mugwort
The FP-2200 of enlightening section；
Firebrake ZB described in the embodiment of the present invention selects Chengdu Kai Fei high-energy chemistry Industrial Co., Ltd
ZB-500；
Brominated triazine described in comparative example of the present invention selects the FR-245 of Dead Sea bromine company of Israel；
Fire retarding synergist described in comparative example of the present invention selects the S-05N of Yunnan Mu Liti industry company limited；
Melamine cyanurate described in comparative example of the present invention selects the MC-25 of BASF；
Tetrabromobisphenol A described in comparative example of the present invention selects the FR-1524 of Dead Sea bromine company of Israel；
Brominated epoxy described in comparative example of the present invention selects the CXB-714C that Korea S's space enters；
TDE described in comparative example of the present invention selects the 4010 of Ya Bao company of the U.S.；
The ABS composite material that embodiment of the present invention and comparative example obtain uses iso standard test
Its correlated performance.The UL-94 vertical combustion Yi Shi U.S. ATLAS that test flame retardant rating uses
HVUL-2；Test light transmittance uses Shi Linshang Science and Technology Ltd. LS105A luminous transmittance measuring.
The present invention is described in detail below in conjunction with embodiment.
A kind of high transparency, high rigidity flame-retardant ABS compound material, by the raw material system including following weight portion
Become: MABS 60-85 part, PMMA 10-30 part, fire-retardant master granule 10-20 part, toughener 5-25
Part.
Described fire-retardant master granule is made up of the raw material including following weight portion: MABS 60-90 part, phosphorus
Nitrogenated flame retardant 10-30 part, Firebrake ZB 5-20 part.
Described high transparency, the preparation method of high rigidity flame-retardant ABS compound material, comprise the steps:
(1) MABS, phosphorus-nitrogen containing flame retardant and Firebrake ZB are joined in high-temperature mixing machine, carry out pre-
Mixing, obtains fire-retardant master granule after pelletize cooling；
(2) MABS, PMMA, fire-retardant master granule, toughener are sufficiently mixed 10-60 at high-speed mixer
Minute, obtain premix material；
(3) premix material is transported in double screw extruder, at spiral shell through the pay-off of delicate metering
Under the shearing of bar, mixing and conveying, material fully melted, compound, then through extruding pelletization, dry
Dry obtain high transparency, high rigidity flame-retardant ABS compound material.
The processing conditions that described double screw extruder melt extrudes is as follows: district's temperature 180 DEG C, 2nd district
Temperature 190 DEG C, three district's temperature 200 DEG C, four district's temperature 210 DEG C, five district's temperature 220 DEG C, six district's temperature
220 DEG C, seven district's temperature 220 DEG C, eight district's temperature 220 DEG C, nine district's temperature 220 DEG C, ten district's temperature 220
DEG C, head temperature 230 DEG C；Screw speed is 200-800 rev/min；The draw ratio of double screw extruder
For 40:1, screw speed is 200-800 rev/min.
Described high transparency, the application of high rigidity flame-retardant ABS compound material, described high transparency, height
Hardness flame-retardant ABS compound material is applied to electrical instrumentation, medical equipment or electron trade.
Embodiment 1-4, comparative example 1-4
By after each raw material preparation of weight portion listed in table 1 and table 2 to ABS composite material press
Standard size is molded into the standard batten of test, and carries out each performance test by testing standard.
Each material content (percentage by weight) of table 1 fire-retardant master granule
| Component | A1 | A2 | A3 | A4 |
| MABS resin | 70 | 70 | 65 | 65 |
| Quadrafos | 10 | 20 | / | 15 |
| Melamine cyanurate | / | / | 30 | 10 |
| Firebrake ZB | 20 | 10 | 5 | 10 |
The concrete proportioning of each raw material and performance test data in table 2 embodiment and comparative example
It can be seen that the bromide fire retardant that compares from the embodiment of table 2 with comparative example, the present invention selects
Phosphorus-nitrogen containing flame retardant and Firebrake ZB fire-retardant master granule with MABS resin as carrier are used as fire retardant (i.e.
Fire-retardant master granule), mechanical property is the most excellent, and mobile performance is more excellent than traditional flame-proof ABS.More
It is essential that add PMMA in formula, the more traditional flame-proof ABS of its light transmittance is greatly improved,
Light transmittance can accomplish more than 80%, and, add PMMA after, the pencil hardness of material is also from 2H
Rank brings up to HB rank.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all at this
Within the spirit of invention and principle, any modification, equivalent substitution and improvement etc. made, should be included in
Within protection scope of the present invention.
Claims (8)
1. a high transparency, high rigidity flame-retardant ABS compound material, it is characterised in that: as follows by including
The raw material of weight portion is made:
Wherein, described Resin A is MABS.
High transparency the most according to claim 1, high rigidity flame-retardant ABS compound material, its feature
It is: described fire-retardant master granule is made up of the raw material including following weight portion:
Resin B 60-90 part,
Phosphorus-nitrogen containing flame retardant 10-30 part,
Firebrake ZB 5-20 part；
Wherein, described resin B is MABS；Described Resin A identical with the specification of resin B or
Different.
High transparency the most according to claim 2, high rigidity flame-retardant ABS compound material, its feature
It is: described phosphorus-nitrogen containing flame retardant is one or both in Quadrafos, melamine cyanurate
Mixture；The particle diameter of described Firebrake ZB is 2-4 μm.
High transparency the most according to claim 2, high rigidity flame-retardant ABS compound material, its feature
Be: the light transmittance of described Resin A 80%, Izod notched impact strength > 10kJ/m2；Described
The light transmittance of resin B > 80%, Izod notched impact strength > 10kJ/m2。
High transparency the most according to claim 1, high rigidity flame-retardant ABS compound material, its feature
It is: described toughener is in MBS type toughener, ASA type toughener, EVA type toughener
Plant or two or more.
High transparency the most according to claim 1, high rigidity flame-retardant ABS compound material, its feature
It is: the described PMMA melt flow rate (MFR) when 220 DEG C/10KG is 15-35g/10min, lead
Hardness is 2H.
7. high transparency according to any one of claim 2-6, high rigidity flame-retardant ABS compound material
Preparation method, it is characterised in that: comprise the steps:
(1) resin B, phosphorus-nitrogen containing flame retardant and Firebrake ZB are joined in high-temperature mixing machine, at 170-250
Carry out premixing at a temperature of DEG C, after pelletize cooling, obtain fire-retardant master granule；
(2) Resin A, PMMA, fire-retardant master granule, toughener are sufficiently mixed 10-60 at high-speed mixer
Minute, obtain premix material；
(3) premix material is transported in double screw extruder through the pay-off of delicate metering, extrusion
Each section of extruder temperature of machine controls between 180-230 DEG C, and the draw ratio of double screw extruder is 25-40:
1, screw speed is 200-800 rev/min, screw rod shearing, mixing and conveying under, material is able to
Fully fusing, compound, then through extruding pelletization, to be dried to obtain high transparency, high rigidity flame-proof ABS multiple
Condensation material.
8. high transparency according to any one of claim 1-6, high rigidity flame-retardant ABS compound material
Application, it is characterised in that: described high transparency, high rigidity flame-retardant ABS compound material are applied to electrical equipment
Instrument, medical equipment or electron trade.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610405561.9A CN105936732A (en) | 2016-06-07 | 2016-06-07 | High transparency and high hardness flame retardant ABS composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610405561.9A CN105936732A (en) | 2016-06-07 | 2016-06-07 | High transparency and high hardness flame retardant ABS composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105936732A true CN105936732A (en) | 2016-09-14 |
Family
ID=57151814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610405561.9A Pending CN105936732A (en) | 2016-06-07 | 2016-06-07 | High transparency and high hardness flame retardant ABS composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105936732A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016199A (en) * | 2019-03-25 | 2019-07-16 | 合肥圆融新材料有限公司 | A kind of high-gloss metal texture exempts from spraying, environment friendly flame-proof ABS material and preparation method thereof |
| US20220203189A1 (en) * | 2020-12-29 | 2022-06-30 | East Coast Dyes, Inc. | Clear lacrosse head |
| CN114806067A (en) * | 2022-03-31 | 2022-07-29 | 金发科技股份有限公司 | High-light-transmittance ABS (acrylonitrile butadiene styrene) composite material as well as preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220194A (en) * | 2007-10-15 | 2008-07-16 | 张发饶 | Production method for environment-protection flame-proof ABS system master batch |
| CN103709441A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | Phosphor-nitrogen halogen-free flame-retardant master batch used for engineering plastics, and preparation method thereof |
| CN104371264A (en) * | 2014-11-28 | 2015-02-25 | 苏州银禧科技有限公司 | High-hardness transparent flame-retardant ABS (acrylonitrile butadiene styrene) composite and preparation method thereof |
| CN104403258A (en) * | 2014-12-17 | 2015-03-11 | 天津金发新材料有限公司 | Antiflaming reinforcing ABS composite material and preparation method thereof |
-
2016
- 2016-06-07 CN CN201610405561.9A patent/CN105936732A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220194A (en) * | 2007-10-15 | 2008-07-16 | 张发饶 | Production method for environment-protection flame-proof ABS system master batch |
| CN103709441A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | Phosphor-nitrogen halogen-free flame-retardant master batch used for engineering plastics, and preparation method thereof |
| CN104371264A (en) * | 2014-11-28 | 2015-02-25 | 苏州银禧科技有限公司 | High-hardness transparent flame-retardant ABS (acrylonitrile butadiene styrene) composite and preparation method thereof |
| CN104403258A (en) * | 2014-12-17 | 2015-03-11 | 天津金发新材料有限公司 | Antiflaming reinforcing ABS composite material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 王文广等: "《塑料配方设计》", 31 July 2004, 化学工业出版社 * |
| 陈刚等: "《大型电站 煤堆自燃机理与阻燃技术》", 30 April 2015, 中国电力出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016199A (en) * | 2019-03-25 | 2019-07-16 | 合肥圆融新材料有限公司 | A kind of high-gloss metal texture exempts from spraying, environment friendly flame-proof ABS material and preparation method thereof |
| US20220203189A1 (en) * | 2020-12-29 | 2022-06-30 | East Coast Dyes, Inc. | Clear lacrosse head |
| CN114806067A (en) * | 2022-03-31 | 2022-07-29 | 金发科技股份有限公司 | High-light-transmittance ABS (acrylonitrile butadiene styrene) composite material as well as preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103102669B (en) | Thermal-resistant light-smoke halogen-free flame-retardant PC/ABS alloy material and preparation method thereof | |
| CN101709126B (en) | Flame-retardant and antistatic ABS modified resin | |
| CN102002203B (en) | Flame-retarded ASA (Acrylic ester-Styrene-Acrylonitrile) modified resin and preparation method thereof | |
| CN109608856A (en) | A kind of charging pile shell antiflaming polycarbonate alloy PP Pipe Compound and preparation method thereof | |
| CN103289294B (en) | transparent flame-retardant ABS material, preparation method and application thereof | |
| CN102838825B (en) | High-strength halogen-free flame-retardant long-glass-fiber-reinforced AS (Acrylonitrile-Styrene Copolymer) composite material and preparation method thereof | |
| CN103289293B (en) | Transparent flame-retardant antistatic ABS material, preparation method and application thereof | |
| CN104497531A (en) | Composite material for computer shells | |
| CN103013089A (en) | Flame-retardant glass fiber reinforced PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) composite material and preparation method thereof | |
| CN104744875A (en) | Preparation method of antibacterial flame-retardant ABS material | |
| CN104403258A (en) | Antiflaming reinforcing ABS composite material and preparation method thereof | |
| CN101787190B (en) | Flame-retarding environment-friendly high-intensity PC-AS composite material and preparation method thereof | |
| CN105936732A (en) | High transparency and high hardness flame retardant ABS composite material and preparation method thereof | |
| CN101671470B (en) | Fire-retardant high-ductility composite material and manufacturing method thereof | |
| CN105936731A (en) | Low-smoke transparent flame-retardant ABS material, preparation method and application thereof | |
| CN108912642B (en) | Antistatic, low-smoke, halogen-free and flame-retardant PC/ABS alloy material and preparation process thereof | |
| CN104448673A (en) | Spraying-free high-weather-resistant scratch-resistant halogen-free flame-retardant ABS (acrylonitrile butadiene styrene) preparation and process | |
| CN105936733A (en) | Environment-friendly low-smoke antistatic and transparent flame-retardant ABS material, preparation method and application thereof | |
| CN103044848A (en) | ABS/PMMA composite and preparation method thereof | |
| CN108570205B (en) | Flame-retardant styrene composition and preparation method thereof | |
| CN103642168A (en) | Modified ABS material | |
| CN104448672A (en) | Antioxidant, high flow, halogen-free and flame retardant ABS and preparation process thereof | |
| CN106084622A (en) | A kind of superelevation glossiness transparent flame-retarding ABS composite material and preparation method thereof | |
| CN106398191A (en) | Halogen-free flame-retardant long glass fiber enhanced nylon 6T composite material and preparation method thereof | |
| CN104387742A (en) | High-temperature-resistant PC composite material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160914 |
|
| RJ01 | Rejection of invention patent application after publication |