CN110126373A - 一种阻燃壁布及制备方法 - Google Patents

一种阻燃壁布及制备方法 Download PDF

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CN110126373A
CN110126373A CN201910499695.5A CN201910499695A CN110126373A CN 110126373 A CN110126373 A CN 110126373A CN 201910499695 A CN201910499695 A CN 201910499695A CN 110126373 A CN110126373 A CN 110126373A
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fire
wall cloth
woven
retardant wall
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熊自量
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Hangzhou Seeino Wall Cloth Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/002Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/02Coating on the layer surface on fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Fireproofing Substances (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

本发明公开了一种阻燃壁布及制备方法,涉及壁布制备技术领域。其技术要点是:一种阻燃壁布,所述阻燃壁布由表层织物和底衬织物组成,所述表层织物由经线和纬线上下交错编织而成,所述底衬织物由具有防火性能的混纺布料制成;其中所述经线和纬线均采用不燃单丝制成,所述不燃单丝为玻璃纤维或金属丝;所述混纺布料由浸泡过阻燃液的无纺布或纱线织布制成,其中底衬织物粘贴于墙壁上,本发明中的阻燃壁布具有阻燃性高和防潮防霉的优点。

Description

一种阻燃壁布及制备方法
技术领域
本发明涉及壁布制备技术领域,更具体地说,它涉及一种阻燃壁布及制备方法。
背景技术
传统贴墙装饰品大致分为墙纸和壁布两类,墙纸是用漂白化学木浆生产原纸,再经不同工序的加工处理,印上各种装饰图案而成,这种纯木浆制杖壁纸易发生褪色和翘边的情况,收缩不易控制,耐潮和耐擦洗性差,所以现有技术中多用壁布来代替壁纸。
壁布是一种室内墙面装饰材料,是通过运用材料、设备与工艺手法,以色彩与图纹设计组合为特征,表现力无限丰富、可便捷满足多样性个性审美要求与时尚需求,因此也被称为墙上的时装,具有艺术与工艺附加值。壁布实际上是壁纸的另一种形式,一样有着变幻多彩的图案、瑰丽无比的色泽,但在质感上则比壁纸更胜一筹。壁布本身的柔韧性、无毒、无味等特点,使其既适合铺装在人多热闹的客厅或餐厅,也更适合铺装在儿童房或有老人的居室里。
现有技术中,壁布多采用纸和布为原料,两者复合后再经涂胶粘贴使用于装饰墙面的表面,但是壁布的材料本身不具备防火阻燃的性能,从而使得壁布具有较大的安全隐患,并且由于壁布的防霉防潮效果差,使用寿命也相应较低。
因此,需要提出一种新的方案来解决上述问题。
发明内容
针对现有技术存在的不足,本发明的目的一在于提供一种阻燃壁布,通过复合不燃的表层织物和高阻燃性的底衬织物,使得制成的阻燃壁布具有高阻燃性、防潮防霉的优点。
为实现上述目的一,本发明提供了如下技术方案:
一种阻燃壁布,所述阻燃壁布由表层织物和底衬织物组成,所述表层织物由经线和纬线上下交错编织而成,所述底衬织物由具有防火性能的混纺布料制成;
其中所述经线和纬线均采用不燃单丝制成,所述不燃单丝为玻璃纤维或金属丝;
所述混纺布料由浸泡过阻燃液的无纺布或纱线织布制成。
通过采用上述技术方案,玻璃纤维本身具有不燃性,此外还具有隔热、阻燃的效果,在遇到火焰燃烧时能够吸收大量热量并能阻止火焰穿过和隔绝空气;金属丝本身硬度和韧性较好,用作不燃的表层织物时,可进行织成不同的图案纹理,具有一定的金属光泽,提高观赏性。
进一步优选为,所述金属丝的直径为0.08~0.2mm。
通过采用上述技术方案,将金属丝的直径控制在0.08~0.2mm之间,便于金属丝的编织,且编织后的表层织物柔软度高,易于加工。
进一步优选为,所述金属丝采用金丝或银丝。
通过采用上述技术方案,金属丝采用金丝或银丝,其光泽度高,品质高,但其成本高,可用于一些富丽堂皇的高等建筑内。
进一步优选为,所述金属丝采用不锈钢丝。
通过采用上述技术方案,金属丝采用不锈钢丝,其造价和成本较低,且不易生锈,耐腐蚀性能好,适用范围广,使用寿命长。
进一步优选为,所述玻璃纤维制成的表层织物表面涂覆有阻燃树脂,所述阻燃树脂为聚氯乙烯树脂。
通过采用上述技术方案,通过涂覆聚氯乙烯树脂来改善玻璃纤维的性能,降低玻璃纤维的易脆性,提高其韧性,以提高玻璃纤维的使用寿命,由于聚氯乙烯树脂中氯含量高达56%,极限氧指数可达50,是阻燃性能优良的材料,其涂覆到玻璃纤维表面,使得表层织物具有高阻燃性。
进一步优选为,所述阻燃液为磷酸三苯酯、甲基膦酸二甲酯和六溴环十二烷中的一种。
本发明的目的二在于提供一种阻燃壁布的制备方法,采用该方法制备的阻燃壁布具有高阻燃性和防潮防霉的优点。
为实现上述目的二,本发明提供了如下技术方案:
一种阻燃壁布的制备方法,包括以下步骤:
a、采用专用的编织机对玻璃纤维进行经、纬线编织,并对其表面进行涂覆阻燃树脂,然后喷漆形成特定图案,得到表层织物;
b、将底衬织物反复浸泡于阻燃液中,并经过压辊压合、晾干和整理;
c、于高温下,将表层织物和底衬织物通过复合机复合;
d、对复合后的壁布进行修剪和切边,得到阻燃壁布。
进一步优选为,所述表层织物与底衬织物之间的复合温度为120~130℃。
综上所述,与现有技术相比,本发明具有以下有益效果:
本发明采用表层织物和底衬织物组成,表层织物由不燃的玻璃纤维和金属丝制成,其可织成不同图案,美化墙壁和室内,易于擦拭,具有防霉防潮的效果,不易老化,其使用寿命更长。底衬织物由浸泡过阻燃剂的混纺织物或无纺布组成,其阻燃效果,阻燃性能可达到UL94V-0级,用作底衬织物时,易于粘贴在墙壁上。
具体实施方式
下面结合和实施例,对本发明进行详细描述。值得说明的是,其中未注明具体条件者,按照常规条件或制造商建议的条件下进行,所用试剂或仪器未注明生产厂商者,均为可以通过市售购买获得的常规产品。
实施例1:一种阻燃壁布,通过如下步骤制备获得:
a、采用专用的编织机对玻璃纤维进行经、纬线编织,并对其表面进行涂覆阻燃树脂,然后喷漆形成特定图案,得到表层织物;
b、将由无纺布组成的底衬织物反复浸泡于阻燃液中,并经过压辊压合、晾干和整理,得到底衬织物;
c、在125℃的温度下,将表层织物和底衬织物通过复合机进行复合;
d、最后对复合后的壁布进行修剪和切边,得到阻燃壁布;
其中阻燃树脂为聚氯乙烯树脂,阻燃液为磷酸三苯酯。
实施例2:一种阻燃壁布,与实施例1的不同之处在于,阻燃液采用甲基膦酸二甲酯。
实施例3:一种阻燃壁布,与实施例1的不同之处在于,阻燃液采用六溴环十二烷。
实施例4:一种阻燃壁布,与实施例1的不同之处在于,通过如下步骤制得:
a、采用专用的编织机对金属丝进行经、纬线编织,改变金属丝的走向以形成特定图案,得到表层织物;
b、将由无纺布组成的底衬织物反复浸泡于阻燃液中,并经过压辊压合、晾干和整理,得到底衬织物;
c、在125℃的温度下,将表层织物和底衬织物通过复合机进行复合;
d、最后对复合后的壁布进行修剪和切边,得到阻燃壁布;
其中金属丝采用金丝,金丝直径为0.1mm,阻燃液采用磷酸三苯酯。
实施例5:一种阻燃壁布,与实施例1的不同之处在于,金属丝采用银丝,银丝的直径为0.1mm。
实施例6:一种阻燃壁布,与实施例1的不同之处在于,金属丝采用不锈钢丝,不锈钢丝的直径为0.2mm。
性能测试
分别对实施例1-6中制得的底衬织物进行垂直燃烧性能和极限氧指数的测试;
垂直燃烧性能:采用垂直燃烧仪并按照UL94标准测试,样条尺寸为130*13*3;
极限氧指数:采用氧指数测试仪并按照GB/T2406-93标准测试,样条尺寸为80*10*4mm。
测试结果如下表,其中垂直燃烧性能的评价标准中,V-0为阻燃性能最好,通过测试的数据可知,本发明的阻燃壁布具有高阻燃性的优。
性能测试结果
垂直燃烧性能/UL94 极限氧指数(%)
实施例1 V-0 31.2
实施例2 V-0 30.7
实施例3 V-0 32.1
实施例4 V-0 31.2
实施例5 V-0 31.2
实施例6 V-0 31.3
以上所述仅是本发明的优选实施方式,本发明的保护范围并不仅局限于上述实施例,凡属于本发明思路下的技术方案均属于本发明的保护范围。应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理前提下的若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。

Claims (8)

1.一种阻燃壁布,其特征在于,所述阻燃壁布由表层织物和底衬织物组成,所述表层织物由经线和纬线上下交错编织而成,所述底衬织物由具有防火性能的混纺布料制成;
其中所述经线和纬线均采用不燃单丝制成,所述不燃单丝为玻璃纤维或金属丝;
所述混纺布料由浸泡过阻燃液的无纺布或纱线织布制成。
2.根据权利要求1所述的阻燃壁布,其特征在于,所述金属丝的直径为0.08~0.2mm。
3.根据权利要求1所述的阻燃壁布,其特征在于,所述金属丝采用金丝或银丝。
4.根据权利要求1所述的阻燃壁布,其特征在于,所述金属丝采用不锈钢丝。
5.根据权利要求1所述的阻燃壁布,其特征在于,所述玻璃纤维制成的表层织物表面涂覆有阻燃树脂,所述阻燃树脂为聚氯乙烯树脂。
6.根据权利要求1所述的阻燃壁布,其特征在于,所述阻燃液为磷酸三苯酯、甲基膦酸二甲酯和六溴环十二烷中的一种。
7.一种阻燃壁布的制备方法,其特征在于,包括以下步骤:
a、采用专用的编织机对玻璃纤维进行经、纬线编织,并对其表面进行涂覆阻燃树脂,然后喷漆形成特定图案,得到表层织物;
b、将底衬织物反复浸泡于阻燃液中,并经过压辊压合、晾干和整理;
c、于高温下,将表层织物和底衬织物通过复合机复合;
d、对复合后的壁布进行修剪和切边,得到阻燃壁布。
8.根据权利要求7所述的阻燃壁布的制备方法,其特征在于,所述表层织物与底衬织物之间的复合温度为120~130℃。
CN201910499695.5A 2019-06-11 2019-06-11 一种阻燃壁布及制备方法 Pending CN110126373A (zh)

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