CN110126364A - The preparation method of honeycomb composite plate - Google Patents

The preparation method of honeycomb composite plate Download PDF

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Publication number
CN110126364A
CN110126364A CN201910267529.2A CN201910267529A CN110126364A CN 110126364 A CN110126364 A CN 110126364A CN 201910267529 A CN201910267529 A CN 201910267529A CN 110126364 A CN110126364 A CN 110126364A
Authority
CN
China
Prior art keywords
honeycomb
composite plate
honeycomb composite
core material
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910267529.2A
Other languages
Chinese (zh)
Inventor
丁友张
朱拥军
刘国华
张佳佳
邱红冰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Jilun Housing Technology Co Ltd
Original Assignee
Jiangsu Jilun Housing Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Jilun Housing Technology Co Ltd filed Critical Jiangsu Jilun Housing Technology Co Ltd
Priority to CN201910267529.2A priority Critical patent/CN110126364A/en
Publication of CN110126364A publication Critical patent/CN110126364A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/08Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles

Landscapes

  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of preparation method of honeycomb composite plate provided by the invention, by adjusting technique, environment temperature is controlled in 50 DEG C or so when will be foamed moulded, so that working environment is safer;And the Cooling Modes such as air-cooled, water cooling are combined, shorten the production time.The present invention also carries out uneven integralization by least one in the two contact ends by honeycomb core material and handles to obtain the contact end of surface irregularity, increases the contact area of honeycomb core material and other structures layer, to improve the bond strength of honeycomb core material Yu other structures layer.

Description

The preparation method of honeycomb composite plate
Technical field
The present invention relates to kitchen and bath's decorative materials technologies, particularly relate to a kind of preparation method of honeycomb composite plate.
Background technique
Background that this section is intended to provide an explanation of the embodiments of the present invention set forth in the claims or context.Herein Description recognizes it is the prior art not because not being included in this section.
The molding temperature that the foamed moulded process of existing honeycomb composite plate uses is high, generally 120 DEG C or so, adopts in this way Toxic, the stimulating component that foaming glue material contains can volatilize, and working environment is severe, not environmentally friendly enough;And subsequent cooling with The natural type of cooling, production efficiency are lower.In addition, the core material of cellular board (corrugated plating or corrugated sheet) due to adhesive layer contact surface The reason less and that core material self structure is thin of product results in planar stretch adhesion strength and shearing peel strength is relatively low.Cause This, is very easy to peel off by using the cellular board of the compound fixation of adhesive merely, biggish especially for area and weight For honeycomb composite plate (panel material is used such as ceramic tile, stone material etc.), especially when being applied to wall, by environmental condition ratio Such as exposing to the weather, the influence of steam etc., such honeycomb composite plate is more easily peelable, therefore the knot between honeycomb core material and adhesive Intensity is closed to need to be further increased.
Summary of the invention
In view of the foregoing, it is necessary to which a kind of preparation method of improved honeycomb composite plate is provided.
Technical solution provided by the invention are as follows: a kind of preparation method of honeycomb composite plate, the honeycomb composite plate include base The adhesive-layer of substrate described in material and honeycomb core material and adhesion or the honeycomb core material, which comprises
Adhesive is sprayed on substrate forms prefabricated adhesive-layer;Wherein, the adhesive is polyurethane adhesive, epoxy glue, urea One of urea formaldehyde etc. is a variety of;
The prefabricated adhesive-layer is directly attached to two contact ends of the honeycomb core material, obtains prefabricated honeycomb composite plate;
The prefabricated honeycomb composite plate progress is foamed moulded, wherein the ring of the foamed moulded prefabricated adhesive-layer in the process Temperature control in border is 45-55 DEG C, a length of 5-7min when foamed moulded;
Cooling obtains the honeycomb composite plate.
Further, the two contact ends that the prefabricated adhesive-layer is directly attached to the honeycomb core material, obtain pre- Before the step of honeycomb composite plate processed, which comprises
At least one in two contact ends of the honeycomb core material is carried out uneven integralization to handle to obtain surface irregularity Contact end.
Further, the uneven integralization of at least one progress handles to obtain in the two contact ends by the honeycomb core material The step of contact end of surface irregularity includes:
Pass through one of carding process, Cutting Process or chemical attack or the contact of a variety of molding surface irregularities End.
Further, described by one of carding process, Cutting Process or chemical attack or a variety of moldings table The step of contact end of face out-of-flatness includes:
The contact end of the surface irregularity of reciprocal combing molding burr structure is combed by using hard.
Further, described by one of carding process, Cutting Process or chemical attack or a variety of moldings table The step of contact end of face out-of-flatness includes:
Pass through the contact end of the surface irregularity of cutting forming broached-tooth design.
Further, the shape of the broached-tooth design is triangle, one of fan-shaped or abnormity or a variety of.
Further, described by described in one of carding process, Cutting Process or chemical attack or a variety of moldings After the step of contact end of surface irregularity, the method also includes:
The contact end of the surface irregularity is processed into bending.
Further, the substrate include brown paper, fibrous layer, plastic film, metal foil, ceramics, stone material, in plastic plate It is one or more.
Further, fibrous material includes glass fibre, carbon fiber, aramid fiber, one in asbestos in the fibrous layer Kind is a variety of.
Further, the cooling is realized by air-cooled or water cooling.
Further, the honeycomb core material is aluminum honeycomb or one of paper honeycomb or plastic honeycomb or a variety of.
Compared with prior art, the preparation method of a kind of honeycomb composite plate provided by the invention will be sent out by adjusting technique Environment temperature is controlled in 50 DEG C or so when bubble molding, so that working environment is safer;And combine the rapid coolings side such as air-cooled, water cooling Formula shortens the production time.The present invention is also carried out at uneven integralization by least one in the two contact ends by honeycomb core material Reason obtains the contact end of surface irregularity, increases the contact area of honeycomb core material and other structures layer, to improve honeycomb core The bond strength of material and other structures layer.
Detailed description of the invention
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Fig. 1 is the structural schematic diagram of honeycomb composite plate in a better embodiment of the invention.
Fig. 2 is the uneven integralization handling principle schematic diagram of honeycomb core material in a better embodiment of the invention.
Fig. 3 is the structural schematic diagram of honeycomb core material after uneven integralization processing in another better embodiment of the present invention.
Fig. 4 is the structural schematic diagram of honeycomb core material after uneven integralization processing in the another better embodiment of the present invention.
Description of symbols:
Honeycomb composite plate 100
Honeycomb core material 10
The contact end 11 of surface irregularity
Surface layer 30
Bottom 60
Fibrous layer 1
Adhesive-layer 2
Strip of paper used for sealing 3
Hard comb 500
Honeycomb composite panel 200
Shingle nail 220
Chassis 300
Top panel 330
The embodiment of the present invention that the following detailed description will be further explained with reference to the above drawings.
Specific embodiment
In order to be more clearly understood that the above objects, features, and advantages of the embodiment of the present invention, with reference to the accompanying drawing and The present invention will be described in detail for specific embodiment.It should be noted that in the absence of conflict, the embodiment party of the application Feature in formula can be combined with each other.
Embodiment in the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention, described reality Applying mode is only some embodiments of the invention, rather than whole embodiments.Based on the embodiment in the present invention, originally Field those of ordinary skill every other embodiment obtained without making creative work, belongs to this hair The range of bright embodiment protection.
Unless otherwise defined, all technical and scientific terms used herein and the technology for belonging to the embodiment of the present invention The normally understood meaning of the technical staff in field is identical.Term as used herein in the specification of the present invention is intended merely to The purpose of specific embodiment is described, it is not intended that in the limitation embodiment of the present invention.
Referring to Fig. 1, the present invention provides the preparation flow of the honeycomb composite plate 100 in a better embodiment, the honeycomb Composite plate 100 has the characteristics that light, sound insulation, can be used for the fields such as kitchen and bath, Automobile Products, space flight and aviation.
In the present embodiment, the preparation method includes:
Step S1: adhesive is sprayed on substrate and forms prefabricated adhesive-layer.
In present embodiment, the adhesive is one of polyurethane adhesive, epoxy glue, Lauxite etc. or a variety of.Institute Stating substrate includes one of brown paper, fibrous layer 1, plastic film, metal foil, ceramics, stone material, plastic plate.
Step S2: the prefabricated adhesive-layer is directly attached to two contact ends of the honeycomb core material 10, obtains prefabricated bee Honeycomb composite plate.
In present embodiment, the honeycomb core material 10 is aluminum honeycomb or one of paper honeycomb or plastic honeycomb or a variety of.
Step S3: the prefabricated honeycomb composite plate progress is foamed moulded, wherein described prefabricated viscous during foamed moulded The environment temperature control of glue-line 2 is 45-55 DEG C, a length of 5-7min when foamed moulded.
Step S4: cooling obtains the honeycomb composite plate.
In present embodiment, the cooling is realized by air-cooled or water cooling.
The method described in the present invention is reduced foamed moulded temperature by control, and is cooled down with Cooling Mode Processing, so that working environment is improved, production efficiency is effectively improved.
In other embodiments, before the step S2, the method also includes step S201: by the honeycomb core material At least one in 10 two contact ends carries out uneven integralization and handles to obtain the contact end 11 of surface irregularity.This step makes Honeycomb core material 10 and the contact area of other structures layer become larger, and bond strength is improved.In the present embodiment, step S201 In combed by using hard reciprocal combing molding burr structure the surface irregularity contact end 11, principle such as Fig. 2 institute Show, which includes the similar roughened surfaces such as thorn-like or hollow shape.In other embodiments, the step S201 In can also by the contact end 11 of the surface irregularity of cutting forming broached-tooth design, be illustrated in figure 3 triangle saw Toothing.In other embodiments, chemical attack or carding process, cutting can also be passed through in the step S201 The contact end 11 of a variety of moldings surface irregularity in technique or chemical attack, such as main structure body are triangular sawtooth Structure, surface are combed into burr structure and form micropore etc. through chemical attack.There is no absolutely between a variety for the treatment of process Ordinal relation, therefore not to repeat here.
It in other embodiments, include: step S202 after step S201: by the contact jaw of the surface irregularity Portion is processed into bending, and structure is as shown in Figure 4.The contact area of the processing not only honeycomb core material 10 that bends is big, solidifies simultaneously The rear tension between adhesive and honeycomb core material 10, resistance to compression and shear strength are more preferable, and the two combines stronger.
The above method is by feather plucking or serrating equal processing, and bends and handle so that in molding honeycomb composite plate 100 Honeycomb core material 10 and the bond strength of other structures layer are good, and adhesion strength is strong, and the service life is longer for the honeycomb composite plate 100.Under Mask body lists the structure of several honeycomb composite plates 100 and honeycomb composite panel or bottom using the honeycomb composite plate The structure of disk.
Honeycomb composite plate 100 as shown in Figure 1, including surface layer 30 and bottom 60 (being respectively one layer of substrate), the surface layer Honeycomb core material 10 is equipped between 30 and the bottom 60, the honeycomb core material 10 connects with the two of the surface layer 30 and the bottom 60 Contacting end portion is fixed with 2 adhesion of adhesive-layer, which is additionally provided with adhesive-layer 2 away from another surface of honeycomb core material 10 to coat envelope Skin 3 (such as brown paper, plastic packaging film), the surface layer 30 have adhesive-layer 2 similarly away from another surface of honeycomb core material 10 to be attached There are facing (such as ceramics, i.e., top panel 330) in honeycomb composite panel 200 in shingle nail 220 or chassis 300.This implementation In mode, the honeycomb core material 10 is hexagon aluminum honeycomb, and two contact ends are smooth, and surface layer 30 and bottom 60 are a fibrous layer 1. It is appreciated that different according to the scene of application, the honeycomb core material 10 can also be paper honeycomb or plastic honeycomb, wherein plastics bee Nest such as PP honeycomb etc..In other embodiments, the single section of the honeycomb core material 10 can be other polygons or more Kind combination of shapes, is not limited to hexagon.
In other embodiments, the structure of the honeycomb core material 10 can have surface as shown in Fig. 2, Fig. 3 or Fig. 4 The contact end 11 of out-of-flatness, wherein the shape of broached-tooth design can also be fan-shaped or abnormity, and therefore not to repeat here.
In other embodiments, the surface layer 30 may include multi-layer fiber layer 1, fibrous material in the fibrous layer 1 It can be one of reinforcing fibers such as glass fibre, carbon fiber, aramid fiber, asbestos or a variety of.In a specific embodiment In, the surface layer 30 is including, with the attachment of 2 phase of adhesive-layer, which can be modified poly- ammonia between 2 fibrous layer, 1,2 fibrous layer 1 Ester, epoxy viscose agent or other adhesives are constituted.
In other embodiments, the bottom 60, is generally housed in inside.In a specific embodiment, the bottom Layer 60 can only include an adhesive-layer 2.The adhesive-layer 2 and viscose glue agent material that the surface layer 30 uses can be identical or not Together.In other embodiments, it also may include several layers fibrous layer 1 to be attached with several layers adhesive layer, fiber in the fibrous layer 1 Material can be glass fibre, carbon fiber or aramid fiber etc., can be same or different with fiber in surface layer 30, specific structure It is not limited by above embodiment.
In other embodiments, using honeycomb composite panel or chassis made of the honeycomb composite plate 100, for stacking knot Structure, for honeycomb composite plate 100 with adhesive-layer 2 is attached one or both sides finishing material and obtains, finishing material can be ceramic tile, aluminium One of plate, steel plate, stone material, timber are a variety of.
In other embodiments, according to the demand of applying working condition, honeycomb is compound in the honeycomb composite panel or chassis Plate 100 can also be more honeycomb composite plates, for example is applied to exterior wall and makees heat-insulating and noise-insulating material.
To sum up, the preparation method of honeycomb composite plate provided by the invention is made by optimizing the moulding process of honeycomb composite plate Working environment it is more friendly, production efficiency is more efficient;And by handling the contact end out-of-flatnessization of honeycomb core material, so that bee The contact area of nest core material and other structures layer becomes larger, Adhesion enhancement, the bond strength both promoted, final honeycomb composite plate Service life extended, and application range is more extensive.
Embodiment of above is only to illustrate the technical solution of the embodiment of the present invention rather than limits, although referring to above preferable The embodiment of the present invention is described in detail in embodiment, those skilled in the art should understand that, it can be to this hair The technical solution of bright embodiment is modified or equivalent replacement should not all be detached from the embodiment of the present invention technical solution spirit and Range.

Claims (10)

1. a kind of preparation method of honeycomb composite plate, the honeycomb composite plate includes base described in substrate and honeycomb core material and adhesion The adhesive-layer of material or the honeycomb core material, which is characterized in that the described method includes:
Adhesive is sprayed on substrate forms prefabricated adhesive-layer;
The prefabricated adhesive-layer is directly attached to two contact ends of the honeycomb core material, obtains prefabricated honeycomb composite plate;
The prefabricated honeycomb composite plate progress is foamed moulded, wherein the environment temperature of the foamed moulded prefabricated adhesive-layer in the process Degree control is 45-55 DEG C, a length of 5-7min when foamed moulded;
Cooling obtains the honeycomb composite plate.
2. the preparation method of honeycomb composite plate as described in claim 1, which is characterized in that described that the prefabricated adhesive-layer is straight The two contact ends for connecing the honeycomb core material, before the step of obtaining prefabricated honeycomb composite plate, the method also includes:
At least one in two contact ends of the honeycomb core material is carried out uneven integralization to handle to obtain the contact of surface irregularity End.
3. the preparation method of honeycomb composite plate as claimed in claim 2, which is characterized in that described by the two of the honeycomb core material At least one in contact end carries out uneven integralization and handles the step of obtaining the contact end of surface irregularity
Pass through one of carding process, Cutting Process or chemical attack or the contact jaw of a variety of molding surface irregularities Portion.
4. the preparation method of honeycomb composite plate as claimed in claim 3, which is characterized in that described to pass through carding process, cutting The step of contact end of one of technique or chemical attack or a variety of moldings surface irregularity includes:
The contact end of the surface irregularity of reciprocal combing molding burr structure is combed by using hard.
5. the preparation method of honeycomb composite plate as claimed in claim 3, which is characterized in that described to pass through carding process, cutting The step of contact end of one of technique or chemical attack or a variety of moldings surface irregularity includes:
Pass through the contact end of the surface irregularity of cutting forming broached-tooth design.
6. the preparation method of honeycomb composite plate as claimed in claim 5, it is characterised in that: the shape of the broached-tooth design is three It is angular, one of fan-shaped or abnormity or a variety of.
7. the preparation method of honeycomb composite plate as claimed in claim 2, which is characterized in that it is described by carding process, cut After the step of cutting one of technique or chemical attack or a variety of contact ends for forming the surface irregularity, the method Further include:
The contact end of the surface irregularity is processed into bending.
8. the preparation method of honeycomb composite plate as described in claim 1, it is characterised in that: the substrate includes brown paper, fibre One of layer, plastic film, metal foil, ceramics, stone material, plastic plate or a variety of are tieed up, wherein fibrous material in the fibrous layer Including one of glass fibre, carbon fiber, aramid fiber, asbestos or a variety of.
9. the preparation method of honeycomb composite plate as described in claim 1, it is characterised in that: the cooling passes through air-cooled or water cooling To realize.
10. the preparation method of honeycomb composite plate as described in claim 1, it is characterised in that: the honeycomb core material is aluminum honeycomb Or one of paper honeycomb or plastic honeycomb or a variety of.
CN201910267529.2A 2019-04-03 2019-04-03 The preparation method of honeycomb composite plate Pending CN110126364A (en)

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Application Number Priority Date Filing Date Title
CN201910267529.2A CN110126364A (en) 2019-04-03 2019-04-03 The preparation method of honeycomb composite plate

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