CN110122406A - A kind of molecular level oxygen-increasing device based on electrolysis and hydrogen fuel cell energy regenerating - Google Patents
A kind of molecular level oxygen-increasing device based on electrolysis and hydrogen fuel cell energy regenerating Download PDFInfo
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- CN110122406A CN110122406A CN201910430911.0A CN201910430911A CN110122406A CN 110122406 A CN110122406 A CN 110122406A CN 201910430911 A CN201910430911 A CN 201910430911A CN 110122406 A CN110122406 A CN 110122406A
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- electrolysis
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 95
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 95
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 92
- 239000000446 fuel Substances 0.000 title claims abstract description 63
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 46
- 230000001172 regenerating effect Effects 0.000 title claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 92
- 238000007667 floating Methods 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 238000004146 energy storage Methods 0.000 claims description 12
- 238000002955 isolation Methods 0.000 claims description 12
- 230000005540 biological transmission Effects 0.000 claims description 8
- 238000013461 design Methods 0.000 claims description 8
- 238000011084 recovery Methods 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 13
- 239000001301 oxygen Substances 0.000 abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 abstract description 13
- 238000000354 decomposition reaction Methods 0.000 abstract description 4
- 239000005416 organic matter Substances 0.000 abstract description 4
- 241001148470 aerobic bacillus Species 0.000 abstract description 3
- 238000003911 water pollution Methods 0.000 abstract 1
- 230000006872 improvement Effects 0.000 description 18
- 238000006213 oxygenation reaction Methods 0.000 description 17
- 239000007789 gas Substances 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000035699 permeability Effects 0.000 description 7
- 230000004888 barrier function Effects 0.000 description 6
- 241000251468 Actinopterygii Species 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 241000238557 Decapoda Species 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000009360 aquaculture Methods 0.000 description 2
- 244000144974 aquaculture Species 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000036647 reaction Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
- A01K63/042—Introducing gases into the water, e.g. aerators, air pumps
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2203/00—Apparatus and plants for the biological treatment of water, waste water or sewage
- C02F2203/006—Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Sustainable Development (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Hydrology & Water Resources (AREA)
- Sustainable Energy (AREA)
- Water Supply & Treatment (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Microbiology (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
Abstract
The present invention relates to a kind of based on the molecular level oxygen-increasing device being electrolysed with hydrogen fuel cell energy regenerating, including shell, driving device, hydrogen fuel cell, electrolysis unit, power supply unit and floating platform, the shell include connected housing upper section and housing lower section；The electrolysis unit includes electrolysis anode, electrolytic cathode；It is axially arranged with several ducts in housing upper section side wall, electrolytic cathode is installed in duct；Electrolysis just extremely ring structure, is fixed on shell a section inner cavity；Each duct is equipped with through hole, is connected to housing upper section inner cavity, and the through hole level height is lower than the level height of electrolytic cathode bottom.Apparatus of the present invention not only can effectively improve the oxygen content inside water body, promote the work of aerobic bacteria rapidly and efficiently inside water body, accelerates the decomposition to water body inside organic matter, prevent water pollution, zero consumption to the energy can be realized based on energy circulation simultaneously, substantially reduces operating cost.
Description
Technical field
The present invention relates to environmental protection technologies and aquaculture field, and in particular to one kind is based on electrolysis and hydrogen fuel cell energy
The molecular level oxygen-increasing device of recycling.
Background technique
As Urbanization in China develops, urban population is intensive, and original urban sewage engineering is not perfect, causes a large amount of
Sanitary sewage, industrial wastewater are directly discharged to urban river, and river is caused seriously to pollute, and a large amount of black smelly rivers occur, seriously affect
The health of city dweller, does great damage to city Ecology.Black smelly river is administered to have become and curb environmental pollution
The most important thing.
Culture fishery is the important component of modern agriculture, not with socio-economic development and living standards of the people
It is disconnected to improve, it is increasingly vigorous to the aquatic products demand such as various fishes, shrimp, the development of culture fishery is greatly facilitated.Simultaneously because through
Ji development, inevitably causes the waters such as river and lake reservoir by different degrees of pollution, and water eutrophication is got worse, and
It is cultivated due to concentrating, it is also very big to oxygen consumption in water body.In the breeding process, animal wastes and extra bait also can
Further pollution is formed to water body, so that water quality deteriorates, seriously affects the normal life of aquatile, leads to the fish of cultivation
There is Large Scale Death in shrimp, brings huge economic loss to raiser.Since animal excrements and extra bait can not be complete
It totally disappeared solution, these organic matters will sink to fish pond bottom, form the pond sludge of high content of organics, and raiser is forced to need periodically to carry out
The pool is turned over, aquaculture cost is increased.
River appearance is black smelly, most important the reason is that a large amount of pollutant emission, seriously has exceeded urban river water system
Pollutant carrying capacity, the mobility of urban river, water coke slurry ability are poor in addition, and the self-purification capacity of itself is greatly inhibited, into one
Step exacerbates the pollution level of urban river.Sufficient dissolved oxygen is the root for ensureing water body vigor, in black smelly river improvement and water quality
It is promoted in engineering, oxygenation is essential engineering means.Current oxygen increasing equipment mostly uses and stirs ability of swimming, water jet, waterwheel
The oxygenation methods such as formula, jetting type, that there are oxygenation ways is simple, low efficiency, operating cost are high, weak to water bottom oxygen transfer rate etc.
Problem.
The efficiency of oxygenation, the space convection current for establishing water body, the dissolved oxygen layering for breaking water body how are improved, is filled in guarantee water body
While dividing oxygenation, energy consumption is reduced, is the key problem in technology for needing to overcome at present.Based on this, the present invention provides one kind based on electricity
The molecular level oxygen increasing equipment of solution and hydrogen fuel cell energy regenerating, the equipment is by the way of electrolysis water, in combination with hydrogen fuel
Battery realize energy regenerating, and assist it is solar powered, realize can energy circulation molecular level oxygenation.It can in equipment running process
It realizes the convection current up and down of water body, realizes efficient three-dimensional oxygenation.
Summary of the invention
The object of the present invention is to provide a kind of efficiently molecular level oxygenation based on electrolysis and hydrogen fuel cell energy regenerating
Device realizes efficient, the three-dimensional oxygenation to water body using energy circulation.
To realize the above-mentioned technical purpose, the present invention adopts the following technical scheme:
A kind of molecular level oxygen-increasing device based on electrolysis and hydrogen fuel cell energy regenerating, including shell, driving device, hydrogen fuel
Battery, electrolysis unit, power supply unit and floating platform, the shell include connected housing upper section and housing lower section；
The driving device is set to above housing upper section, and driving device transmission shaft protrudes into inside housing upper section, connects water dumping wheel,
Drive the rotation of water dumping wheel；
The housing upper section lateral wall is equipped at least one water jet, and the water jet connects sparge pipe；
The electrolysis unit includes electrolysis anode, electrolytic cathode；It is axially arranged with several ducts in housing upper section side wall, pacifies in duct
Fill electrolytic cathode；Electrolysis anode is fixed on shell a section inner cavity；Each duct is equipped with through hole, connects with housing upper section inner cavity
It is logical；
The hydrogen fuel cell connects the electrolytic cathode of electrolysis unit by hydrogen recovery pipe, collects electrolysis unit reaction and generates
Hydrogen, and the power storage that reaction is generated is to energy storage device；
The floating platform is fixed at the top of housing upper section, is integrally located at shell under water；Floating platform is fixed by fixed anchoring；
The power supply unit is used to power to power device.
Apparatus of the present invention drive the rotation of water dumping wheel by driving device, and lower part water body is drawn up, and are formed from bottom to top
Flowing, while the oxygen molecule that electrolysis generates quickly being brought into water, is injected to extraneous waters by water jet, electrolysis generates
Hydrogen collected by hydrogen recovery pipe, the obtained hydrogen of electrolysis is sent into inside hydrogen fuel cell, hydrogen fuel cell is passed through
Reaction, produces electricl energy, is transported to energy storage device.Power supply unit can make up the energy lost in the conversion of hydrogen fuel cell energy, lead to
Cross the matched design of each plant capacity, realize can energy circulation molecular level oxygenation, considerably increase the efficiency of oxygenation, if
Oxygen in air has indirectly been transported in water by standby operation in the form of molecule, and using sunlight as energy supplement,
Realize high-efficient solid oxygenation.
As a further improvement of the present invention, the housing upper section is top closed, and cross section is rounded, and vertical section is in square
Shape；Housing lower section bottom is open, and cross section is rounded, and vertical section is in isosceles trapezoid.Housing lower section can according to practical Larger water depths,
Length and bottom opening diameter are adjusted, to adapt to engineering demand, water body enters oxygen increasing equipment from housing lower section bottom.Shell uses
This design method, so that water inlet flow velocity is very low, can prevent from preventing sundries suction-operated while guaranteeing enough inflows
Only sundries enters equipment blocking pipeline, while avoiding the muddiness for making the sludge stirring of bottom water body to become, and influences culturing fish and shrimp
Normal life.
As a further improvement of the present invention, the sparge pipe and the tangent arrangement of housing upper section, sparge pipe horizontal extension side
To consistent with driving device rotation direction.Further, the sparge pipe angle with horizontal plane is -30 ° ~ 0 °；Water spray pipe diameter
For gradual design, water outlet diameter > water inlet diameter.
As a further improvement of the present invention, the through hole is radially opened up along housing upper section, and through hole level height is low
Level height in electrolytic cathode bottom.The bottom of electrolytic cathode slightly above penetrates through hole site, and through hole radially opens up, i.e.,
Perpendicular to housing upper section side wall, the operation because of equipment inner high speed water flow is avoided to generate negative pressure, inside hydrogen inhalation device, from
And it realizes hydrogen, oxygen and efficiently separates.
As a further improvement of the present invention, the electrolysis just extremely ring structure, is fixed below water dumping wheel.
As a further improvement of the present invention, the hydrogen fuel cell vertical section designs for gear shape, increase hydrogen and
The contact area of oxygen and catalyst in air, improves the reaction efficiency of hydrogen fuel cell.
As a further improvement of the present invention, the hydrogen fuel cell is made of several battery units, forms fuel cell
Storehouse, battery unit can be arranged using the forms such as in parallel, series connection, series-parallel according to actual needs.
As a further improvement of the present invention, the hydrogen fuel cell air inlet be arranged air filter, into
The air for entering hydrogen fuel cell is filtered, and is prevented adsorbing powder dust to hydrogen fuel cell catalyst surface, is influenced catalyst work
Efficiency.
As a further improvement of the present invention, air inlet, bottom setting is arranged in the hydrogen chamber top of the hydrogen fuel cell
Exhaust outlet, exhaust outlet are controlled using inlet non return check valve, only gas are allowed to be vented outwards from hydrogen chamber, are not allowed outside air to pass through
Lower exhaust port enters hydrogen chamber.Hydrogen chamber top setting air inlet is passed through hydrogen, and exhaust outlet is arranged in lower part, and hydrogen density is small,
The condensation vapor that effectively air original in hydrogen chamber and hydrogen can be carried at water by exhaust outlet discharge, be convenient for
After later period maintenance, fast evacuation gas guarantees the purity of hydrogen in hydrogen chamber, improves reaction efficiency.
The air chamber of the hydrogen fuel cell is divided into the air on air mistress and both sides by two aperture isolation boards
Room；The aperture isolation board aperture obliquely；The air mistress connects air filter, and air mistress and air filter connect
It meets place and is equipped with inlet non return check valve；Air interior room bottom is equipped with several exhaust outlets, and exhaust outlet is controlled using inlet non return check valve.
As a further improvement of the present invention, the air chamber of the hydrogen fuel cell is divided by two aperture isolation boards
The air interior room of air mistress and both sides；The aperture isolation board aperture obliquely, when air being forced to enter interior room from mistress, gas
Stream directly blows to hydrogen fuel cell side of the positive electrode, improves reaction efficiency.The air mistress connects air filter, air mistress and
Air filter junction is equipped with inlet non return check valve, only allows air to enter mistress from extraneous, gas is not allowed to drive in the wrong direction；The sky
Gas interior room bottom is equipped with several exhaust outlets, and exhaust outlet is controlled using inlet non return check valve, only air is allowed to be discharged from air interior room, no
Air is allowed to drive in the wrong direction.This design scheme can guarantee fuel cell in a non-operative state, and interior room is in closed state, guarantee battery
Internal certain humidity, reaction efficiency decline and proton permeability film dehydration caused by preventing proton permeability film moisture content too low
Proton permeability film caused by after-contraction is damaged.The radiator fan of the exhaust outlet connection driving device of air interior room bottom, utilizes drive
The radiator fan of dynamic device, draws air into the side of the positive electrode of hydrogen fuel cell, increases the soakage of air, is ensureing hydrogen fuel electricity
While the rapidly and efficiently reaction in pond, radiate to fuel cell.
As a further improvement of the present invention, the electrolysis anode is set to the water dumping wheel lower part position 5-10cm, by solid
Fixed pole connected with outer casing upper section side wall inner surfaces, the fixed link are isolation material or and the positive same material of electrolysis；Electrolysis anode and
The control of electrolytic cathode spacing is 2cm or so, and decomposition voltage uses the low-voltage of 12V-24V.
As a further improvement of the present invention, the floating body selects the light material of plastics or foam etc.
As a further improvement of the present invention, the housing upper section is isolation material.
As a further improvement of the present invention, the outer casing bottom is equipped with garbage barrier net；Opened up on the garbage barrier net it is rectangular or
Round hole, aperture are not more than 0.5cm.Block can prevent sundries in small fish or water from entering inside equipment, influence equipment operation.
As a further improvement of the present invention, the bearing portion that the transmission shaft is connected with water dumping wheel is equipped with waterproof oil seal,
Prevent the water of lower part from entering driving device.
As a further improvement of the present invention, the driving device is the direct current reduction of speed motor of waterproof.
As a further improvement of the present invention, the power supply unit is solar power supply apparatus；The hydrogen fuel cell produces
Raw power storage is in the energy storage device of solar power supply apparatus.
The device of the invention drives the rotation of water dumping wheel by driving device, so that water body forms three-dimensional convection current, electric motor starting
Meanwhile electrolysis unit is powered by energy storage device, is electrolysed to the water entered inside equipment, is electrolysed the oxygen molecule quilt of generation
External waters is taken away rapidly and be ejected into high-velocity flow inside equipment, realizes molecular level oxygenation, in electrolysis unit of the invention,
Electrolysis anode is placed in shell inner cavity, and when device is run, inside can generate high-velocity flow, and the oxygen that electrolysis anode is generated is fast
Speed belt is walked, and the hydrogen density that electrolytic cathode generates is small, the quickly aggregation upwards in duct, into recovery pipe；In addition, electrolysis is negative
The bottom of pole slightly above penetrates through hole site, and through hole perpendicular outer wall, avoids the operation because of equipment inner high speed water flow from generating negative
Pressure, inside the hydrogen inhalation device, to realize that hydrogen, oxygen efficiently separate.The hydrogen generated is electrolysed to recycle by hydrogen
Pipeline enters hydrogen fuel cell, produces electricl energy through hydrogen fuel cell reaction, is fed to energy storage device；Solar power supply apparatus is in sun
It is produced electricl energy under light action, is fed to energy storage device further to make up the energy loss in reaction process, is put down with reaching energy
Weighing apparatus realizes molecular level oxygenation.The operation of equipment may make control waters to form convection current from bottom to top, make polluted-water bottom
Sludge rich in organic matter accelerates resolution under the action of aerobic bacteria, realizes the promotion of whole water quality.The longtime running of equipment, can
The self-purification capacity of water body is activated, while realizing oxygenation, the vigor of microorganism, promotes aerobic bacteria inside water body inside activation water body
Work rapidly and efficiently accelerates the decomposition to water body inside organic matter, under water body solid convection action, by bottom eutrophic water
Body takes water body top to, under the collective effect of microorganism and sunlight, realizes the rapid-digestion to organic matter, reaches water quality promotion
Purpose.
Detailed description of the invention
Fig. 1 is the device of the invention structural schematic diagram；
Wherein, 1. driving device, 2. waterproof oil seals, 3. transmission shafts, 4. water dumping wheels, 5. hydrogen fuel cells, 6. sparge pipes,
7. electrolysis anode, 8. electrolytic cathodes, 9. housing upper sections, 10. flanges, 11. housing lower sections, 12. garbage barrier nets, 13. hydrogen
Recovery pipe, 14. air filters, 15. hydrogen fuel cell units, 16. solar panels, 17. energy storage devices, 18. is floating
Platform, 19. fixed anchors.
Fig. 2 is water dumping wheel cross-section diagram.
Fig. 3 is hydrogen fuel cell skiagraph；
Wherein, 20. inlet non return check valve, 21. aperture isolation boards, 22. bleeding points, 23. hydrogen inlets, 24. air exhausts
Mouthful, 25. hydrogen chamber, 26. air interior rooms, 27. air mistress.
Fig. 4 is hydrogen fuel cell top view；
Wherein, 28. hydrogen fuel cell shell.
Fig. 5 is hydrogen fuel cell unit sectional view；
Wherein, 29. gas diffusion layers, 30. catalyst layers, 31. proton permeability films.
Fig. 6 is electrolysis unit the schematic diagram of the section structure；
Wherein, 32. duct；33. fixed link；34. through hole.
Specific embodiment
Below with reference to embodiment and attached drawing explanation, technical scheme is described further.
Embodiment 1
The device as shown in Fig. 1 ~ 6, including shell, driving device 1, hydrogen fuel cell 5, electrolysis unit, power supply unit and floating platform
18, shell includes the housing upper section 9 and housing lower section 11 being connected by flange 10；Housing upper section 9 is top closed, and cross section is in circle
Shape, vertical section are in rectangle；11 bottom of housing lower section is open, and cross section is rounded, and vertical section is in isosceles trapezoid.
Driving device 1 is the direct current reduction of speed motor of waterproof, is set to 9 top of housing upper section, and 1 transmission shaft 3 of driving device is stretched
Enter inside housing upper section 9, connect water dumping wheel 4, driving water dumping wheel 4 rotates.The bearing portion that transmission shaft 3 and water dumping wheel 4 connect is set
The sealing of waterproof oil seal 2 is set, spray is prevented to be splashed into transmission shaft 3.Water dumping wheel 4 be 3 leaves or 4 leaf water dumping wheels, as shown in Figure 2.
9 lateral wall of housing upper section is equipped at least one water jet, the centre-height and 4 centre-height one of water dumping wheel of water jet
It causes；Water jet connects sparge pipe 6；Sparge pipe 6 and the tangent arrangement of housing upper section 9,6 horizontal extension direction of sparge pipe and driving device
1 rotation direction is consistent.6 angle with horizontal plane of sparge pipe is -30 ° ~ 0 °；6 diameter of sparge pipe is gradual design, water outlet diameter >
Water inlet diameter.Water outlet diameter is 50-80mm in the present embodiment, and water inlet diameter is 40-50mm.
Electrolysis unit structure is as shown in fig. 6, include being electrolysed positive 7, electrolytic cathode 8；It is axially arranged in 9 side wall of housing upper section
Several ducts 32, the design of duct 32 should avoid water jet aperture position；Electrolytic cathode 8 is installed in duct 32；Electrolysis anode 7 is ring
Shape structure, electrolysis anode 7 are set to the 4 lower part position 5-10cm of water dumping wheel, pass through table in 33 connected with outer casing upper section of fixed link, 9 side wall
Face, the fixed link 33 are isolation material or and the positive same material of electrolysis；Each duct 32 is equipped with through hole 34, through hole 34
It perpendicular to side wall of outer shell, is connected to 9 inner cavity of housing upper section, so that electrolysis anode 7, electrolytic cathode 8 are connected to, through hole 34 is horizontal high
Degree is lower than the level height of 8 bottom of electrolytic cathode.Electrolysis anode and the control of electrolytic cathode spacing are 2cm or so, and decomposition voltage is adopted
With the low-voltage of 12V-24V.
Hydrogen fuel cell 5 connects the electrolytic cathode 8 of electrolysis unit by hydrogen recovery pipe 13, collects electrolysis unit reaction
The hydrogen of generation.For 5 structure of hydrogen fuel cell as shown in Fig. 3 ~ 5, vertical section is gear shape.Hydrogen fuel cell 5 can be used existing
Hydrogen fuel cell structure, including hydrogen fuel cell shell 28, the hydrogen chamber being set in shell 25 and air chamber, hydrogen chamber and sky
Hydrogen fuel cell unit 15 of the setting for reaction between gas chamber, structure includes gas diffusion layers 29, catalyst layer 30 and proton
Permeable membrane 31.In the present embodiment, the air chamber of hydrogen fuel cell is divided into 27 He of air mistress by two aperture isolation boards 21
The air interior room 26 on both sides；The aperture obliquely of aperture isolation board 21；Air mistress 27 connects air filter 14, air mistress 27
Inlet non return check valve 20 is equipped with 14 junction of air filter；26 bottom of air interior room is equipped with several air exhaust ports 24, air
The air exhaust port 24 of interior room bottom is connected to the radiator fan of driving device 1, draws air into hydrogen fuel by bleeding point 22
The side of the positive electrode of battery.Air exhaust port 24 is controlled using inlet non return check valve 20.25 top of hydrogen chamber of hydrogen fuel cell 5 be arranged into
Exhaust outlet is arranged in port 23, bottom, and exhaust outlet is controlled using inlet non return check valve 20.
In the present embodiment, hydrogen fuel cell 5 is made of several battery units, formation fuel cell stack, between battery unit
Using in parallel, series connection or series-parallel form arrangement.
Floating platform 18 selects the light material of plastics or foam etc, is fixed on 9 top of housing upper section, shell is made to be integrally located at water
Under；It is fixed that floating platform 18 passes through fixed anchor 19.
Power supply unit is solar power supply apparatus, including solar panels 16, energy storage device 17；What hydrogen fuel cell 5 generated
Power storage is in energy storage device 17.
In the present embodiment, 11 bottom of housing lower section is equipped with garbage barrier net 12；Rectangular or round hole, aperture are opened up on garbage barrier net 12
No more than 0.5cm, water body enters oxygen increasing equipment from 11 bottom of housing lower section.
Above-mentioned apparatus is put into water body, device floats on water surface, power under the effect of floating platform 18, straight in waterproof
Under galvanic electricity machine 1 acts on, transmission shaft 3 and water dumping wheel 4 is driven to rotate, so that lower part water body is entered in equipment by garbage barrier net 12
Portion, while electrolysis unit starts, and is electrolysed to the water entered inside equipment, generates oxygen molecule and is taken away by high-velocity flow, and
It is ejected into outside body of water, realizes the molecular level oxygenation to water body.Be electrolysed simultaneously the hydrogen of generation by hydrogen recovery pipe 13 into
Enter hydrogen fuel cell 5, hydrogen enters hydrogen chamber 25 by hydrogen inlet 23, and hydrogen passes through gas diffusion layers 29 and catalyst layer
30 contacts so that hydrogen molecule loses two electronics, become two protons, electronics can not pass through proton permeability film by catalysis
31, can only be by entering the side of the positive electrode of fuel cell by circuit cycles, proton can pass through proton permeability film 31 and directly reach
To the side of the positive electrode of fuel cell, and under the action of catalyst, makes the oxygen molecule in air, anode is reached by proton permeability film 31
The electronics that the proton and external circuit of side cycle to reach side of the positive electrode reacts, and generates water.It will be chemical by fuel cell reaction
It can be converted into electric energy, realize the partially recycled of electrolytic energy, and power storage is cooperated into solar powered dress in energy storage device 17
Set electric energy supplement, realize can energy circulation molecular level oxygenation.
The above is preferred embodiment example of the invention, is not limited to not invent, for those skilled in the art,
It is referred to the detailed description of the invention, is modified to the technical solution of aforementioned each functional component, or to part of technology
Feature is equivalently replaced, all within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on, and
It should be included within protection scope of the present invention.
Claims (10)
1. a kind of molecular level oxygen-increasing device based on electrolysis and hydrogen fuel cell energy regenerating, which is characterized in that including shell, drive
Dynamic device (1), hydrogen fuel cell (5), electrolysis unit, power supply unit, energy storage device (17) and floating platform (18), the shell include
Connected housing upper section (9) and housing lower section (11)；
The driving device (1) is set to above housing upper section (9), and driving device (1) transmission shaft (3) protrudes into housing upper section (9)
Inside connects water dumping wheel (4), driving water dumping wheel (4) rotation；
Housing upper section (9) lateral wall is equipped at least one water jet, and the water jet connects sparge pipe (6)；
The electrolysis unit includes being electrolysed positive (7), electrolytic cathode (8)；Several ducts are axially arranged in housing upper section (9) side wall
(32), electrolytic cathode (8) are installed in duct (32)；It is electrolysed positive (7) and is fixed on shell section (9) inner cavity；Each duct (32)
It is equipped with through hole (34), is connected to housing upper section (9) inner cavity；
The hydrogen fuel cell (5) connects the electrolytic cathode (8) of electrolysis unit by hydrogen recovery pipe (13), collects electrolysis dress
The hydrogen that reaction generates is set, and the power storage that reaction is generated is to energy storage device (17)；
The floating platform (18) is fixed at the top of housing upper section (9), is integrally located at shell under water；Floating platform (18) passes through fixed anchor
(19) fixed；
The power supply unit is used to power to power device.
2. the apparatus according to claim 1, which is characterized in that the housing upper section (9) is top closed, and cross section is in circle
Shape, vertical section are in rectangle；Housing lower section (11) bottom is open, and cross section is rounded, and vertical section is in isosceles trapezoid.
3. the apparatus according to claim 1, which is characterized in that the sparge pipe (6) and housing upper section (9) tangent arrangement,
Sparge pipe (6) horizontal extension direction is consistent with driving device (1) rotation direction.
4. the apparatus according to claim 1, which is characterized in that sparge pipe (6) angle with horizontal plane is -30 ° ~ 0 °；
Sparge pipe (6) diameter is gradual design, water outlet diameter > water inlet diameter.
5. the apparatus according to claim 1, which is characterized in that the through hole (34) radially opens up along housing upper section (9),
Through hole (34) level height is lower than the level height of electrolytic cathode (8) bottom.
6. the apparatus according to claim 1, which is characterized in that the electrolysis positive (7) is ring structure, is fixed on water dumping
It takes turns below (4).
7. the apparatus according to claim 1, which is characterized in that hydrogen fuel cell (5) vertical section is gear shape.
8. device according to claim 1 or claim 7, which is characterized in that the hydrogen fuel cell (5) is by several stacks of cells
At fuel cell stack being formed, using in parallel, series connection or series-parallel form arrangement between battery unit.
9. the apparatus according to claim 1, which is characterized in that hydrogen chamber (25) top of the hydrogen fuel cell (5) is set
It sets air inlet (23), exhaust outlet is arranged in bottom, and exhaust outlet is controlled using inlet non return check valve (20).
10. the apparatus according to claim 1, which is characterized in that the air chamber of the hydrogen fuel cell passes through two apertures
Isolation board (21) is divided into the air interior room (26) on air mistress (27) and both sides；The aperture isolation board (21) is opened obliquely
Hole；The air mistress (27) connects air filter (14), and air mistress (27) and air filter (14) junction are equipped with
Inlet non return check valve (20)；Air interior room (26) bottom is equipped with several exhaust outlets (24), the exhaust outlet of air interior room bottom
(24) it is connected to the radiator fan of driving device (1), exhaust outlet (24) is controlled using inlet non return check valve (20).
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910430911.0A CN110122406B (en) | 2019-05-22 | 2019-05-22 | Molecular-level oxygenation device based on electrolysis and hydrogen fuel cell energy recovery |
| PCT/CN2019/090600 WO2020232766A1 (en) | 2019-05-22 | 2019-06-10 | Molecular-scale oxygenation device based on electrolysis and hydrogen fuel cell energy recovery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910430911.0A CN110122406B (en) | 2019-05-22 | 2019-05-22 | Molecular-level oxygenation device based on electrolysis and hydrogen fuel cell energy recovery |
Publications (2)
| Publication Number | Publication Date |
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| CN110122406A true CN110122406A (en) | 2019-08-16 |
| CN110122406B CN110122406B (en) | 2021-09-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910430911.0A Active CN110122406B (en) | 2019-05-22 | 2019-05-22 | Molecular-level oxygenation device based on electrolysis and hydrogen fuel cell energy recovery |
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| Country | Link |
|---|---|
| CN (1) | CN110122406B (en) |
| WO (1) | WO2020232766A1 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108293947A (en) * | 2018-03-20 | 2018-07-20 | 南京森淼环保科技有限公司 | A kind of aquaculture aeration equipment |
| CN108411328A (en) * | 2018-06-13 | 2018-08-17 | 四川大爱科技有限公司 | A kind of device of Electrowinning oxygen |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070062820A1 (en) * | 2005-09-06 | 2007-03-22 | Smotkin Eugene S | Fuel cell cogeneration system |
| CN203087296U (en) * | 2012-09-19 | 2013-07-31 | 李华贤 | Solar water body oxygenating ark |
| CN105347521A (en) * | 2015-12-07 | 2016-02-24 | 张彬 | Low-energy-consumption water oxygen increasing device |
| CN108178288B (en) * | 2018-01-09 | 2020-04-28 | 宁波大红鹰学院 | River pollutant biological treatment device |
-
2019
- 2019-05-22 CN CN201910430911.0A patent/CN110122406B/en active Active
- 2019-06-10 WO PCT/CN2019/090600 patent/WO2020232766A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108293947A (en) * | 2018-03-20 | 2018-07-20 | 南京森淼环保科技有限公司 | A kind of aquaculture aeration equipment |
| CN108411328A (en) * | 2018-06-13 | 2018-08-17 | 四川大爱科技有限公司 | A kind of device of Electrowinning oxygen |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020232766A1 (en) | 2020-11-26 |
| CN110122406B (en) | 2021-09-21 |
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