CN110106716B - Temperature-control knitted underwear fabric and manufacturing method thereof - Google Patents

Temperature-control knitted underwear fabric and manufacturing method thereof Download PDF

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Publication number
CN110106716B
CN110106716B CN201910350625.3A CN201910350625A CN110106716B CN 110106716 B CN110106716 B CN 110106716B CN 201910350625 A CN201910350625 A CN 201910350625A CN 110106716 B CN110106716 B CN 110106716B
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temperature
temperature control
fabric
dyeing
heating
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CN110106716A (en
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张鑫
陈慧
陈澄清
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Fujian Fynex Textile Science & Technology Co ltd
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Fujian Fynex Textile Science & Technology Co ltd
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/18Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • D06C7/02Setting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0032Determining dye recipes and dyeing parameters; Colour matching or monitoring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8219Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes

Abstract

The invention relates to a temperature-control knitted underwear fabric and a manufacturing method thereof, and belongs to the technical field of textile dyeing and finishing processes. The manufacturing method of the temperature control knitted underwear fabric comprises the steps of weaving → preliminary fixing → pretreatment → dyeing → soaping → drying → shaping and the like, and the shaping specifically comprises the following steps: and (3) shaping the dried colored cloth, and adding 48-52g/L of temperature control auxiliary agent and 18-22g/L of silicone oil T718 according to the water content during shaping. The internal qualities of the temperature control knitted underwear fabric obtained by the invention all meet the domestic textile detection requirements, and the temperature control effect of the temperature control knitted underwear fabric obviously exceeds that of the same type of temperature control materials. The production process of the fabric is simple and convenient, the cost is low, the temperature control treatment is only needed in the shaping process, the operation is simple and convenient, and the additional value is high.

Description

Temperature-control knitted underwear fabric and manufacturing method thereof
Technical Field
The invention belongs to the technical field of textile dyeing and finishing processes, and particularly relates to a temperature-control knitted underwear fabric and a manufacturing method thereof.
Background
The temperature control fabric is a novel fabric capable of reacting to environmental conditions, can effectively control the temperature of the fabric by absorbing or releasing heat, has a bidirectional temperature regulation effect, and provides a comfortable microclimate environment for a human body. In the current fabric market at home and abroad, the knitted high-grade temperature control fabric is very few, mainly adopts temperature control fiber as a raw material, is high in price and is almost not available at home. The knitted high-grade temperature control fabric is specially designed for clothing fabrics contacting with skin, and is mainly applied to close-fitting fabric clothing such as high-grade underwear, sportswear, vests and the like. The high-grade knitted temperature control fabric has the advantages of good thermal comfort, controllable dryness and cooling potential, thermal buffering performance, no toxicity, no harmful substances and the like. Therefore, the method has design and development performance and can fill the blank of domestic markets. In the market, the knitted underwear fabric is mainly made of cotton products, mainly because the cotton fibers have good hygroscopicity, under normal conditions, the pure cotton fibers can absorb moisture in the surrounding atmosphere, and the moisture content of the pure cotton fibers is 8-10%, so that people feel soft but not stiff when the pure cotton fibers contact the skin of people. The cotton fiber is poor conductor of heat and electricity, the heat conduction coefficient is extremely low, and because the cotton fiber has porosity, a large amount of air can be accumulated between the fibers, and the air is poor conductor of heat and electricity, the pure cotton fiber textile has good warmth retention property and wearing comfort. Because of good hygroscopicity and heat retention and moderate price, the cotton fiber is favored by consumers.
However, cotton fibers are poor in quick-drying property and slow in moisture release, and if the ambient humidity is high, the cotton fibers can easily absorb a large amount of moisture in air, so that people feel very moist and cool after wearing the cotton fabric for a long time. In summer with high temperature, the light and thin pure cotton fabric is easy to gather with sweat generated on the surface of skin, is not easy to volatilize, has a sticky body feeling and is poor in heat insulation. Nowadays, with the improvement of living standard and the enhancement of health consciousness and environmental consciousness of people, the requirements of people on underwear and clothes are continuously improved. The existing underwear has the characteristic of single comfort and can not meet the requirements of people. Besides the comfort of the underwear fabric, the functionality, the environmental protection and the health of the underwear fabric are more and more favored by people.
Therefore, in view of the disadvantages of cotton fibers, it is necessary to develop a controllable knitted underwear fabric that reacts to environmental conditions, and a relative dynamic thermal balance is established between human body and external environment, so as to achieve an active temperature regulation effect on human body, reduce the influence of external environment temperature on human body, prevent people from feeling cold or hot suddenly due to sudden changes in external weather, protect the health of people, and reduce the occurrence of common diseases.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the temperature control knitted underwear fabric and the manufacturing method thereof, and the obtained temperature control knitted underwear fabric has super-strong hygroscopicity and diffusivity, can establish relative dynamic heat balance between a human body and an external environment, and has a positive temperature regulation effect on the human body.
The manufacturing method of the temperature control knitted underwear fabric comprises the following steps:
step one, weaving: weaving gray fabric by adopting combed cotton 40S yarns and 20D spandex;
step two, initial determination: carrying out primary shaping on the grey cloth;
step three, pretreatment: pre-treating the preliminarily fixed grey cloth in a pre-treating liquid;
step four, dyeing: dyeing the pretreated grey cloth, specifically: adding water and dye for 18-22min, operating for 18-22min, sequentially adding anhydrous sodium sulfate, soda ash and fixation alkali XH-01, operating for 8-12min, heating to 40-80 deg.C at a heating rate of 0.5-2 deg.C/min, maintaining the temperature and operating for 20-60min, and discharging liquid;
step five, soaping: soaping the dyed grey cloth;
step six, drying: drying the grey cloth washed by the soap;
step seven, sizing: and (3) shaping the dried colored cloth, and adding 48-52g/L of temperature control auxiliary agent and 18-22g/L of silicone oil T718 according to the water content during shaping.
Further, the temperature during the primary shaping in the second step is 198 ℃, the vehicle speed is 26m/min, and the upper and lower overfeeding is 45%/6%.
Furthermore, the pretreatment liquid in the third step comprises the following components in terms of water: 0.8-1.2g/L low-foam refining oil removal agent SF-2, 2.8-3.2g/L caustic soda flakes, 7.8-8.2g/L hydrogen peroxide, 0.3-0.7g/L neutralizing acid 6004 and 0.13-0.17g/L oxygen removal enzyme DM-8618.
Further, the pretreatment in the third step is specifically: putting the blank cloth into a cylinder, adding warm water of 45-55 ℃, adding a low-foam refining degreasing agent SF-2, adding for 2-4min, operating for 4-6min, adding caustic soda flakes, adding for 8-12min, heating to 65-75 ℃ at the heating rate of 2.5-3.5 ℃/min, adding hydrogen peroxide, adding for 8-12min, heating to 105-115 ℃ at the heating rate of 2.5-3.5 ℃/min, operating for 25-35min under heat preservation, cooling to 75-85 ℃ at the cooling rate of 2.5-3.5 ℃/min, washing with overflow water for 8-12min, and discharging liquid; adding 45-55 deg.C warm water, keeping the temperature for 5-9min, and discharging liquid; adding 45-55 deg.C warm water, adding neutralizing acid 6004, measuring pH to 5.5-6.5, running for 5-9min, adding deoxyenzyme DM-8618, adding for 2-4min, running for 10-14min, and discharging.
Furthermore, 23-27g/L anhydrous sodium sulphate, 0.8-1.2g/L sodium carbonate and 2.2-2.6g/L fixation alkali XH-01 are added in the fourth step according to the water amount.
Furthermore, the step four of adding anhydrous sodium sulphate, soda ash and fixing alkali XH-01 is specifically as follows: adding 2/10-4/10 anhydrous sodium sulfate for 15-25min, and adding the rest anhydrous sodium sulfate for 15-25 min; then adding 2/10-4/10 of soda ash for 15-25min, and then adding the rest soda ash and the color fixing alkali XH-01 for 15-25 min.
Further, the soaping in the step five specifically comprises: adding 45-55 deg.C warm water, overflowing, washing for 10-14min, and discharging liquid; adding 45-55 deg.C warm water, adding 0.8-1.2g/L neutralization acid 6004 according to water amount, heating to 85-95 deg.C at a heating rate of 2.5-3.5 deg.C/min, adding 0.14-0.18g/L soaping agent during heating, keeping the temperature for 8-12min, cooling to 75-85 deg.C at a cooling rate of 1.5-2.5 deg.C/min, washing with overflow water for 8-10min, and draining; adding 45-55 deg.C warm water, washing with water for 5-9min, and draining.
Furthermore, the temperature during the drying in the sixth step is 135-140 ℃, and the speed is 15 m/min.
Furthermore, in the seventh step, the mangle rolling rate during the shaping is 60%, the temperature is 180 ℃, the vehicle speed is 16m/min, and the upper and lower overfeeding is 28%/6%.
The invention also provides the temperature control knitted underwear fabric prepared by the preparation method of the temperature control knitted underwear fabric.
Compared with the prior art, the invention has the following beneficial effects:
firstly, the method comprises the following steps: the invention adopts combed cotton 40S yarn and 20D spandex to weave full-lining stretch fabric as grey cloth, and then the temperature control knitted underwear fabric is prepared through the steps of preliminary setting → pretreatment → dyeing → soaping → drying → setting and the like, wherein the temperature control auxiliary agent AC-03 and silicone oil T718 are added in the setting process to process the fabric, so that the temperature control auxiliary agent forms a polymer film on the surface of the fabric yarn, and after moisture is contacted with the yarn, the moisture is diffused quickly and is evenly distributed to the surface of each fiber, and further, the moisture evaporation or cooling is promoted if necessary. When the external environment temperature rises, the temperature control film layer on the surface of the fiber can promote the water to be quickly evaporated, the water is converted into gas from liquid, and the heat is absorbed, so that the change of the external environment temperature to the environment temperature between the fabric and a human body is reduced. When the temperature of the external environment is reduced, the temperature control film layer on the surface of the fiber promotes the water to be converted from liquid to solid, the phase conversion process releases heat, a relative dynamic heat balance is established between a human body and the external environment, and the temperature regulation effect on the human body is achieved. The influence of the external environment temperature on the human body is reduced, so that the human body can not suddenly change in temperature or suddenly change in temperature due to the external weather, the human body can be protected, and the generation of common diseases is reduced;
secondly, the method comprises the following steps: the dyeing process is improved on the basis of the prior art, the dyeing process of the fabric is determined according to the relation between the dyeing temperature, the dyeing time, the heating rate and the K/S value, when the dyeing process adopts the heating rate of 1 ℃/min and is carried out for 40min at the temperature of 60 ℃, the uniformity of cloth cover dyeing can be ensured to the maximum extent, the dyeing process time is shortened, and the quality problems of dyeing defects, uneven coloring and the like are avoided;
thirdly, the method comprises the following steps: the internal qualities of the temperature control knitted underwear fabric meet the domestic textile detection requirements, and the temperature control effect of the temperature control knitted underwear fabric is obviously better than that of the temperature control materials of the same type by the detection of the temperature control technology of HeiQ company of Switzerland (namely the test on the temperature regulation performance in the specific implementation mode of the invention). In addition, the temperature control materials of the same type of temperature control fabrics in the existing market are high in price and poor in temperature control effect, are formed by blending multiple fibers, are not beneficial to dyeing and finishing post-processing, and are high in production risk and high in cost;
fourthly: the combed cotton 40S cotton yarn adopted by the invention has good hygroscopicity and softness, the 20D spandex is added, so that the fabric has elasticity and stretchability, and after the temperature control auxiliary agent is added for finishing, the defect of slow moisture release of the cotton fiber is overcome, the moisture absorption and quick drying performance of the cotton fiber is improved, and the wearing comfort and the temperature regulation function of the fabric are obviously improved. A relative dynamic balance is established between the human body and the external environment, and the positive temperature control and regulation effects are achieved on the human body. Therefore, the temperature-control knitted underwear fabric can be widely applied to next-to-skin underwear fabrics and sports garment fabrics, and has good application prospect and high cost performance;
fifth, the method comprises the following steps: the internal stress of the grey cloth can be eliminated through preliminary setting (presetting), the fabric width and the gram weight can reach the specified standards of customers, the fabric surface is smooth, the hand feeling is soft, and the defects of dyeing color splash, dead cross and the like are reduced. The technological requirements of selecting 20D spandex yarn for blank setting are strict, and the setting temperature, time (vehicle speed) and other technological parameters have great influence on the fabric surface effects of fabric such as width, gram weight, elasticity after dyeing, hand feeling, crease and the like. Therefore, the invention strictly sets the initial setting process, determines the initial setting parameter temperature of 198 ℃, the vehicle speed of 26m/min and the upper and lower overfeeding of 45%/6%, and lays a good foundation for the fabric quality; meanwhile, the pretreatment is the first process of the textile in dyeing and finishing processing. The pretreatment aims to remove natural impurities on the fiber and oil stains attached in the spinning and weaving process. The invention adopts the refining degreasing agent SF-2, caustic soda flakes, hydrogen peroxide, neutralization acid 6004 and deoxyenzyme DM-8618, and the cotton yarns are subjected to high-temperature oxygen bleaching in a Basoni low bath ratio dyeing machine, so that the cotton yarns have smooth surfaces, high whiteness, good capillary effect, soft hand feeling and better permeability, the excellent quality of the fibers is fully exerted, and qualified semi-finished products are provided for dyeing.
Drawings
FIG. 1 is a graph showing a pretreatment process in example 3 of the present invention;
FIG. 2 is a graph of a dyeing process according to example 3 of the present invention;
FIG. 3 is a graph of the soaping process of example 3 of the present invention;
FIG. 4 is a schematic diagram showing the effect of dyeing temperature on K/S value of cotton fiber according to the present invention;
FIG. 5 is a graph showing the effect of dyeing time on K/S value of cotton fiber according to the present invention;
FIG. 6 is a schematic view showing the yarn contact dynamics of a common fabric;
FIG. 7 is a schematic view showing the dynamic contact between fibers of the temperature-controlled knitted underwear fabric obtained in example 3 of the present invention and moisture.
Detailed Description
The present invention is described in further detail below by way of specific embodiments, but those skilled in the art will appreciate that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention.
The manufacturing method of the temperature control knitted underwear fabric comprises the following steps:
step one, weaving: weaving gray fabric by adopting combed cotton 40S yarns and 20D spandex;
step two, initial determination: carrying out primary setting on the grey cloth, wherein the temperature during the primary setting is 198 ℃, the speed is 26m/min, and the upper and lower overfeeding is 45%/6%;
step three, pretreatment: pretreating the preliminarily determined grey cloth in a pretreatment liquid, wherein the pretreatment liquid comprises the following components in percentage by weight: 0.8-1.2g/L low-foam refining oil removal agent SF-2, 2.8-3.2g/L caustic soda flakes, 7.8-8.2g/L hydrogen peroxide, 0.3-0.7g/L neutralization acid 6004 and 0.13-0.17g/L oxygen removal enzyme DM-8618; the pretreatment specifically comprises the following steps: putting the blank cloth into a cylinder, adding warm water of 45-55 ℃, adding a low-foam refining degreasing agent SF-2, adding for 2-4min, operating for 4-6min, adding caustic soda flakes, adding for 8-12min, heating to 65-75 ℃ at the heating rate of 2.5-3.5 ℃/min, adding hydrogen peroxide, adding for 8-12min, heating to 105-115 ℃ at the heating rate of 2.5-3.5 ℃/min, operating for 25-35min under heat preservation, cooling to 75-85 ℃ at the cooling rate of 2.5-3.5 ℃/min, washing with overflow water for 8-12min, and discharging liquid; adding 45-55 deg.C warm water, keeping the temperature for 5-9min, and discharging liquid; adding 45-55 deg.C warm water, adding neutralizing acid 6004, measuring pH to 5.5-6.5, running for 5-9min, adding deoxyenzyme DM-8618, adding for 2-4min, running for 10-14min, and discharging liquid;
step four, dyeing: dyeing the pretreated grey cloth, specifically: adding water and dye for 18-22min, operating for 18-22min, sequentially adding 23-27g/L anhydrous sodium sulphate, 0.8-1.2g/L soda ash and 2.2-2.6g/L fixation alkali XH-01 (firstly adding 2/10-4/10 anhydrous sodium sulphate, adding the rest anhydrous sodium sulphate and adding the rest anhydrous sodium sulphate for 15-25min, then adding 2/10-4/10 soda, adding the rest soda ash and fixation alkali XH-01, and adding the rest anhydrous sodium sulphate and fixation alkali 15-25 min.), operating for 8-12min, heating to 40-80 ℃ at a heating rate of 0.5-2 ℃/min, and operating for 20-60min with heat preservation, and discharging liquid;
step five, soaping: soaping the dyed grey cloth, which specifically comprises the following steps: adding 45-55 deg.C warm water, overflowing, washing for 10-14min, and discharging liquid; adding 45-55 deg.C warm water, adding 0.8-1.2g/L neutralization acid 6004 according to water amount, heating to 85-95 deg.C at a heating rate of 2.5-3.5 deg.C/min, adding 0.14-0.18g/L soaping agent during heating, keeping the temperature for 8-12min, cooling to 75-85 deg.C at a cooling rate of 1.5-2.5 deg.C/min, washing with overflow water for 8-10min, and draining; adding 45-55 deg.C warm water, washing with water for 5-9min, and discharging liquid;
step six, drying: drying the grey cloth washed by the soap at the temperature of 135-140 ℃ at the speed of 15 m/min;
step seven, sizing: and (3) shaping the dried colored cloth, wherein 48-52g/L of temperature control auxiliary agent and 18-22g/L of silicone oil T718 are added during shaping according to the water content, the mangle rolling rate is 60%, the temperature is 180 ℃, the vehicle speed is 16m/min, and the upper and lower overfeeding is 28%/6%.
The supplier of the combed cotton 40S yarn adopted in the invention is tin-free far spinning, the supplier of the 20D spandex is Xiaoxing spandex, and the supplier of the temperature control auxiliary agent AC-03 is Hainanhui chemical Co. The supplier of the dye used in the present invention is Shanghai Yayun textile chemical Co.
In the invention, a Meier single-side circular knitting machine is used for weaving gray fabric, and the stitch size is as follows: 34' -28G, number of paths: 108F, total number of needles: 2988N. Organization structure: a single-side weft-knitted plain stitch structure; the technological parameters are as follows: the length of the blank yarn is 28 cm/100G; the specification of gray fabric is as follows: 178cm × 150g/m2
For initial setting (also called pre-setting), a German BABCO-STAR10 box tentering setting machine is used, and the initial setting parameters are as follows: the temperature is 198 ℃, the vehicle speed is 26m/min, the upper and lower overfeeding is 45%/6%, and the specification after determination is as follows: 185cm × 156g/m2
Example 1
The manufacturing method of the temperature control knitted underwear fabric comprises the following steps:
step one, weaving: weaving gray fabric by adopting combed cotton 40S yarns and 20D spandex;
step two, initial determination: carrying out primary setting on the grey cloth, wherein the temperature during the primary setting is 198 ℃, the speed is 26m/min, and the upper and lower overfeeding is 45%/6%;
step three, pretreatment: pretreating the preliminarily determined grey cloth in a pretreatment liquid, wherein the pretreatment liquid comprises the following components in percentage by weight: 0.8g/L low-foam refining oil removal agent SF-2, 2.8g/L caustic soda flakes, 7.8g/L hydrogen peroxide, 0.3g/L neutralization acid 6004 and 0.13g/L oxygen removal enzyme DM-8618; the pretreatment specifically comprises the following steps: putting the fabric blank into a cylinder, adding warm water of 45 ℃, adding a low-foam refining degreasing agent SF-2, adding for 2min, operating for 4min, adding caustic soda flakes, adding for 8min, heating to 65 ℃ at the heating rate of 2.5 ℃/min, adding hydrogen peroxide, adding for 8min, heating to 105 ℃ at the heating rate of 2.5 ℃/min, operating for 25min while keeping the temperature, cooling to 75 ℃ at the cooling rate of 2.5 ℃/min, overflowing, washing for 8min, and discharging liquid; adding 45 deg.C warm water, keeping the temperature for 5min, and discharging liquid; adding 45 deg.C warm water, adding neutralizing acid 6004, measuring pH to 5.5-6.5, running for 5min, adding deoxyenzyme DM-8618, adding for 2min, running for 10min, and discharging liquid;
step four, dyeing: dyeing the pretreated grey cloth, specifically: adding water and dye (the added dye is specifically that 0.17% of elegance brilliant red BF-2B, 0.33% of elegance orange BF-DB and 0.01% of elegance blue BF-RS are added according to the weight of gray fabric), adding for 18min, operating for 18min, then sequentially adding 23g/L anhydrous sodium sulphate, 0.8g/L sodium carbonate and 2.2g/L fixation alkali XH-01 (firstly adding 2/10 anhydrous sodium sulphate, adding for 15min, then adding the rest anhydrous sodium sulphate, adding for 15min, then adding 2/10 sodium carbonate, adding for 15min, then adding the rest sodium carbonate and fixation alkali XH-01, adding for 15 min), operating for 8min, heating to 40 ℃ at the heating rate of 0.5 ℃/min, operating for 60min with heat preservation, and discharging liquid;
step five, soaping: soaping the dyed grey cloth, which specifically comprises the following steps: adding 45 deg.C warm water, overflowing, washing for 10min, and discharging liquid; adding 45 ℃ warm water, adding 0.8g/L of neutralizing acid 6004 according to the water content, heating to 85 ℃ at the heating rate of 2.5 ℃/min, adding 0.14g/L of soaping agent in the heating process, carrying out heat preservation operation for 8min, cooling to 75 ℃ at the cooling rate of 1.5 ℃/min, overflowing, washing with water for 8min, and discharging liquid; adding 45 deg.C warm water, washing with water for 5min, and discharging liquid;
step six, drying: drying the grey cloth washed by the soap at 135 ℃ at the speed of 15 m/min;
step seven, sizing: and (3) shaping the dried colored cloth, wherein 48g/L of temperature control auxiliary agent and 18g/L of silicone oil T718 are added according to the water content during shaping, the mangle rolling rate is 60%, the temperature is 180 ℃, the vehicle speed is 16m/min, and the upper and lower overfeeding is 28%/6%.
Example 2
The manufacturing method of the temperature control knitted underwear fabric comprises the following steps:
step one, weaving: weaving gray fabric by adopting combed cotton 40S yarns and 20D spandex;
step two, initial determination: carrying out primary setting on the grey cloth, wherein the temperature during the primary setting is 198 ℃, the speed is 26m/min, and the upper and lower overfeeding is 45%/6%;
step three, pretreatment: pretreating the preliminarily determined grey cloth in a pretreatment liquid, wherein the pretreatment liquid comprises the following components in percentage by weight: 1.2g/L low-foam refining oil removal agent SF-2, 3.2g/L caustic soda flakes, 8.2g/L hydrogen peroxide, 0.7g/L neutralization acid 6004 and 0.17g/L oxygen removal enzyme DM-8618; the pretreatment specifically comprises the following steps: putting the fabric blank into a cylinder, adding warm water of 55 ℃, adding a low-foam refining degreasing agent SF-2, adding for 4min, operating for 6min, adding caustic soda flakes, adding for 12min, heating to 75 ℃ at the heating rate of 3.5 ℃/min, adding hydrogen peroxide, adding for 12min, heating to 115 ℃ at the heating rate of 3.5 ℃/min, operating for 35min while keeping the temperature, cooling to 85 ℃ at the cooling rate of 3.5 ℃/min, overflowing, washing for 12min, and discharging liquid; adding warm water of 55 deg.C, keeping the temperature for 9min, and discharging liquid; adding 55 deg.C warm water, adding neutralizing acid 6004, measuring pH to 5.5-6.5, running for 9min, adding deoxyenzyme DM-8618, adding for 4min, running for 14min, and discharging liquid;
step four, dyeing: dyeing the pretreated grey cloth, specifically: adding water and dye (the added dye is specifically that 0.21% of elegance brilliant red BF-2B, 0.37% of elegance orange BF-DB and 0.014% of elegance blue BF-RS are added according to the weight of gray fabric), adding for 22min, operating for 22min, then sequentially adding 27g/L anhydrous sodium sulphate, 1.2g/L calcined soda and 2.6g/L fixation alkali XH-01 (firstly adding 4/10 anhydrous sodium sulphate, adding for 25min, then adding the rest anhydrous sodium sulphate, adding for 25min, then adding 4/10 anhydrous sodium sulphate, adding for 25min, then adding the rest calcined soda and fixation alkali XH-01, and adding for 25 min), operating for 12min, heating to 80 ℃ at the heating rate of 2 ℃/min, operating for 60min with heat preservation, and discharging liquid;
step five, soaping: soaping the dyed grey cloth, which specifically comprises the following steps: adding warm water of 55 deg.C, overflowing, washing for 14min, and discharging liquid; adding warm water of 55 ℃, adding 1.2g/L of neutralizing acid 6004 according to the water content, heating to 95 ℃ at the heating rate of 3.5 ℃/min, adding 0.18g/L of soaping agent in the heating process, carrying out heat preservation operation for 12min, cooling to 85 ℃ at the cooling rate of 2.5 ℃/min, carrying out overflow water washing for 10min, and discharging liquid; adding warm water of 55 deg.C, washing with water for 9min, and discharging liquid;
step six, drying: drying the grey cloth washed by the soap at the temperature of 135-140 ℃ at the speed of 15 m/min;
step seven, sizing: and (3) shaping the dried colored cloth, wherein 48-52g/L of temperature control auxiliary agent and 18-22g/L of silicone oil T718 are added during shaping according to the water content, the mangle rolling rate is 60%, the temperature is 180 ℃, the vehicle speed is 16m/min, and the upper and lower overfeeding is 28%/6%.
Example 3
The manufacturing method of the temperature control knitted underwear fabric comprises the following steps:
step one, weaving: weaving gray fabric by adopting combed cotton 40S yarns and 20D spandex;
step two, initial determination: carrying out primary setting on the grey cloth, wherein the temperature during the primary setting is 198 ℃, the speed is 26m/min, and the upper and lower overfeeding is 45%/6%;
step three, pretreatment: pretreating the preliminarily determined grey cloth in a pretreatment liquid, wherein the pretreatment liquid comprises the following components in percentage by weight: 1.0g/L low-foam refining oil removal agent SF-2, 3.0g/L caustic soda flakes, 8.0g/L hydrogen peroxide, 0.5g/L neutralization acid 6004 and 0.15g/L oxygen removal enzyme DM-8618; the pretreatment specifically comprises the following steps: putting the fabric blank into a cylinder, adding warm water at 50 ℃, adding a low-foam refining degreasing agent SF-2, adding for 3min, operating for 5min, adding caustic soda flakes, adding for 10min, heating to 70 ℃ at the heating rate of 3.0 ℃/min, adding hydrogen peroxide, adding for 10min, heating to 110 ℃ at the heating rate of 3.0 ℃/min, operating for 30min while keeping the temperature, cooling to 80 ℃ at the cooling rate of 3.0 ℃/min, overflowing, washing for 10min, and discharging liquid; adding 50 deg.C warm water, keeping the temperature for 7min, and discharging liquid; adding 50 deg.C warm water, adding neutralizing acid 6004, measuring pH to 5.5-6.5, running for 7min, adding deoxyenzyme DM-8618, adding for 3min, running for 12min, and discharging liquid. The pretreatment process graph is shown in figure 1.
Step four, dyeing: dyeing the pretreated grey cloth, specifically: adding water and dye (the added dye is specifically that 0.19 percent of ya Gegen bright red BF-2B, 0.35 percent of ya Gegen orange BF-DB and 0.012 percent of ya Gegen blue BF-RS are added according to the weight of the gray fabric), adding for 20min, operating for 20min, then sequentially adding 25g/L anhydrous sodium sulphate, 1.0g/L calcined soda and 2.4g/L fixation alkali XH-01 (firstly adding 3/10 anhydrous sodium sulphate, adding for 20min, then adding the rest anhydrous sodium sulphate, adding for 20min, then adding 3/10 calcined soda, adding for 20min, then adding the rest calcined soda and fixation alkali XH-01, adding for 20 min), operating for 10min, heating to 60 ℃ at the heating rate of 1 ℃/min, keeping the temperature and operating for 40min, and discharging liquid; the dyeing process is shown in figure 2.
Step five, soaping: soaping the dyed grey cloth, which specifically comprises the following steps: adding warm water of 50 deg.C, overflowing, washing for 12min, and discharging liquid; adding 50 ℃ warm water, adding 1.0g/L of neutralization acid 6004 according to the water content, heating to 90 ℃ at a heating rate of 3.0 ℃/min, adding 0.16g/L of soaping agent in the heating process, carrying out heat preservation operation for 10min, cooling to 80 ℃ at a cooling rate of 2.0 ℃/min, carrying out overflow water washing for 9min, and discharging liquid; adding 50 deg.C warm water, washing with water for 7min, and discharging liquid; the soaping process is shown in FIG. 3.
Step six, drying: drying the grey cloth washed by the soap at 135 ℃ at the speed of 15 m/min;
step seven, sizing: and (3) setting the dried colored cloth, adding 50g/L of temperature control auxiliary agent and 20g/L of silicone oil T718 according to a water content during setting, wherein the mangle rolling rate is 60%, the temperature is 180 ℃, the vehicle speed is 16m/min, and the upper and lower overfeeding is 28%/6%, so that the temperature control knitted underwear fabric is obtained.
The temperature control auxiliary agent can improve the thermal comfort of the fabric, prevent moisture from gathering between the fabric and the skin, has good moisture absorption and sweat releasing functions, can control the dryness of the fabric, has cooling potential, and is suitable for pad dyeing and dip dyeing processes. The adjuvant is non-toxic and complies with REACH regulations and with Bluesign certification. The temperature control auxiliary agent can be directly added into the mangle of the setting machine, and the liquid carrying rate of the temperature control auxiliary agent is measured, and if the temperature control auxiliary agent is added with other finishing products, the compatibility of the products needs to be measured.
TABLE 1 application formula of temperature control auxiliary agent pad dyeing
Figure BDA0002043821110000081
TABLE 2 temperature control adjuvant dip-dyeing application formula
Figure BDA0002043821110000091
In order to achieve the best performance of the temperature control assistant, the following matters are taken:
firstly, after the fabric is dyed, before the temperature control auxiliary agent is used, the surface of the fabric can not be stained with other softening agents and other finishing agents, and the softening agent or other finishing agents which must be used are added together with the temperature control auxiliary agent during shaping.
Secondly, before adding the temperature control auxiliary agent, the unfixed dye and the residual chemical substances on the fabric are thoroughly removed through reduction cleaning or soaping.
③ citric acid or acetic acid is used for adjusting the pH value to make it weak acidic (pH value is 4.5-6).
In the pad dyeing application formula, the actual dosage of the temperature control auxiliary agent is 3 percent per mangle liquor ratio is optimal.
When the ordinary fabric and the fabric of the temperature-controlled knitted underwear obtained in example 3 of the present invention are respectively contacted with moisture, the dynamic schematic diagrams of the fabric fibers contacting with moisture are shown in fig. 6 and 7, and can be known from the moisture dynamic schematic diagrams of fig. 6 and 7: after the yarns of the common fabric are contacted with water, the yarns are partially wetted and have low flowing speed; according to the fabric yarn subjected to temperature control treatment, the temperature control auxiliary agent forms a polymer film on the surface of the yarn, and when moisture is contacted with the yarn, the moisture is diffused quickly and is evenly distributed to the surface of each fiber, so that the moisture is promoted to evaporate (cool) if necessary.
Example 4
The cotton fibers were dyed according to the dyeing method described in step three of example 3, and the resulting cotton fibers were tested.
Example 5
This example differs from example 4 in that the dyeing temperature was 40 ℃ and the cotton fiber obtained was tested.
Example 6
This example differs from example 4 in that the dyeing temperature was 50 ℃ and the cotton fiber obtained was tested.
Example 7
This example differs from example 4 in that the dyeing temperature was 70 ℃ and the cotton fiber obtained was tested.
Example 8
This example differs from example 4 in that the dyeing temperature was 80 ℃ and the cotton fiber obtained was tested.
The cotton fibers obtained in examples 4 to 8 were subjected to leveling property and K/S test to obtain the effects of different dyeing temperatures on the color depth and leveling property of the cotton fibers, and the test methods are as follows:
K/S value test: accurately weighing 0.2g of dyed cotton fiber, smoothing with a brush, measuring the K/S value at the maximum absorption wavelength by using a Datacolor SF 600X color measurement formula instrument with an ultra-micro aperture, performing color calculation by using a CIE standard illuminant D65 and a 10-degree visual angle standard observer, measuring at different positions for 3 times, and taking an average value.
Leveling property: evaluation was by visual inspection under standard lighting box simulated daylight conditions.
The test results are shown in table 3 and fig. 4, respectively.
TABLE 3 Effect of dyeing temperature on leveling Properties of cotton fibers
Dyeing temperature/. degree.C 40 50 60 70 80
Levelling property In general In general Is preferably used Is preferably used Is preferably used
As can be seen from FIG. 4 and Table 3, the K/S values of the dyed cotton fibers showed a tendency to increase and decrease with increasing dyeing temperature. When the dyeing temperature is lower, the motion capability of the dye is lower, the dye is not easy to permeate into the fiber during dyeing and is gathered on the surface of the cotton fiber, and the dye is easy to wash and fall off in the later soaping process, so that the K/S value after dyeing is lower, when the dyeing temperature is increased to 60 ℃, the motion capability of the dye is enhanced, the K/S value of the cotton fiber after soaping is high, and the level-dyeing property is better. If the temperature is continuously increased, the K/S value and the level-dyeing property of the cotton fiber are not improved, but the color light of the dyed cotton fiber is changed. In general, the dyeing temperature is preferably 60 ℃.
Example 9
This example differs from example 4 in that the dyeing time was 20min and the cotton fibers obtained were tested.
Example 10
This example differs from example 4 in that the dyeing time was 30min and the cotton fibers obtained were tested.
Example 11
This example differs from example 4 in that the dyeing time was 50min and the cotton fibers obtained were tested.
Example 12
This example differs from example 4 in that the dyeing time was 60min and the cotton fibers obtained were tested.
The cotton fibers obtained in examples 4, 9 to 12 were subjected to leveling property and K/S test, and the effects of different dyeing times on the color depth and leveling property exhibited by the cotton fibers were obtained, and the results are shown in fig. 5 and table 4.
TABLE 4 Effect of dyeing time on levelness of dyed cotton/viscose/hemp fibers
Dyeing time/min 20 30 40 50 60
Levelling property Difference (D) In general Is preferably used Is preferably used Is preferably used
As can be seen from FIG. 5 and Table 4, the change in the K/S value of the dyed cotton fiber did not tend much as the dyeing time increased, and tended to be stable after 40 min. But has a great influence on the level-dyeing property of dyed cotton fibers. In the initial dyeing stage, the dye is rapidly adsorbed on the surface of the dyed cotton fiber and rapidly diffused on the surface of the cotton fiber to form accumulation, so that the color yield of the cotton fiber is high at the beginning, and the K/S value is high. With the increase of dyeing time, the dyes accumulated on the surface of the cotton fiber start to hydrolyze, and redundant dyes are diffused and permeated to the cotton fiber with less dyes, so that the leveling property of the cotton fiber is improved. Therefore, when the dyeing time is 40min, the K/S value and the level-dyeing property of the cotton fiber are good. In general, the dyeing time is preferably 40 min.
Example 13
This example is different from example 4 in that the temperature rising rate at the time of dyeing was 0.5 ℃/min, and the obtained cotton fiber was subjected to a test.
Example 14
This example is different from example 4 in that the temperature rising rate at the time of dyeing was 1.5 ℃/min, and the resulting cotton fiber was subjected to a test.
Example 15
This example is different from example 4 in that the temperature rising rate at the time of dyeing was 2 ℃/min, and the obtained cotton fiber was subjected to a test.
The cotton fibers obtained in examples 4, 13 to 15 were subjected to leveling property test, and the effects of different dyeing temperature-raising rates on the leveling property of the cotton fibers were obtained, and the results are shown in Table 5.
TABLE 5 Effect of temperature Rate of heating on leveling Properties of Cotton fiber fabrics
Heating rate/min 0.5 1 1.5 2
Levelling property Good taste Good taste In general Difference (D)
As can be seen from Table 5, when the dyeing temperature is 60 ℃ and the temperature is kept for 40min, and the temperature rise rate is controlled to be 0.5-1 ℃/min, the level dyeing effect of the cotton fiber is good, and the temperature rise rate is controlled to be 1 ℃/min on the premise of improving the production efficiency and ensuring the product quality.
The basic performance of the temperature control knitted underwear fabric obtained in the embodiment 3 is detected, and the fabric obtained is subjected to various evaluations such as intrinsic quality index of knitted finished fabric and the like by adopting an enterprise standard of Q/FZFZ015-2013 novel temperature control fabric knitwear and combining national standards of GB 18401 national safety technical Specification for textile products and GB/T22848 knitted finished fabric and the like. The results are shown in Table 6.
Table 6 basic performance test results of the temperature-controlled knitted underwear fabric obtained in example 3 of the present invention
Figure BDA0002043821110000121
As can be seen from the table above, all physical indexes of the temperature control knitted underwear fabric prepared by the invention all meet the standard requirements of Q/FZFZ015-2013 Enterprise Standard of novel temperature control fabric knitwear, GB 18401 basic safety technical Specification of national textile products, GB/T22848 knitted finished cloth and the like.
The dynamic evaporation rate performance of the temperature control knitted underwear fabric obtained in the example 3 is tested, the temperature regulation performance does not have a unified test method and standard at present, the test is usually carried out by a thermal analysis method, a temperature change method, a heat preservation instrument method, a microclimate instrument method and the like, and the temperature regulation performance of the temperature control fabric is discussed by the dynamic evaporation rate.
The dynamic moisture test results are shown in table 7 below:
table 7 dynamic moisture test results
Figure BDA0002043821110000122
Figure BDA0002043821110000131
Dynamic moisture control environment reference is made to table 8 below:
TABLE 8 dynamic moisture test Environment reference method
Figure BDA0002043821110000132
As can be seen from tables 7 and 8, the evaporation rate of the temperature-controlled knitted underwear fabric prepared by the invention after washing is far higher than that in a reference environment, and the temperature regulation and control capability is strong. Namely, the higher the evaporation rate, the slower the temperature change of the fabric, and the stronger the temperature control and regulation capacity. The temperature control auxiliary agent is a water functional polymer, and can absorb or release heat on the surface of the fiber to effectively control the temperature of the fabric. When the external environment temperature rises, the fiber surface temperature control film layer promotes the moisture to evaporate rapidly, the moisture is converted into gas from liquid, and the heat is absorbed, thereby reducing the change of the external environment temperature to the environment temperature between the fabric and the human body. When the temperature of the external environment is reduced, the temperature control film layer on the surface of the fiber promotes the water to be converted from liquid to solid, and the phase conversion process can release heat, so that a relative dynamic heat balance is established between a human body and the external environment, and a positive temperature regulation effect is achieved on the human body.
The drip diffusion time test and the fabric capillary test were performed on the temperature-controlled knitted underwear fabric obtained in example 3, and the results are shown in tables 9 and 10 below, respectively:
TABLE 9 drip diffusion time test results
Figure BDA0002043821110000133
TABLE 10 fabric capillary test results
Figure BDA0002043821110000134
Figure BDA0002043821110000141
The test results in tables 9 and 10 show that: the temperature-control knitted underwear fabric prepared by the invention has super-strong hygroscopicity and diffusivity, and has the effects of instant hygroscopicity and diffusivity.
The above-mentioned embodiments are merely preferred embodiments for fully illustrating the present invention, and the scope of protection is not limited thereto. The equivalents and modifications of the present invention which may occur to those skilled in the art are within the scope of the present invention as defined by the appended claims.

Claims (2)

1. The manufacturing method of the temperature control knitted underwear fabric is characterized by comprising the following steps:
step one, weaving: weaving gray fabric by adopting combed cotton 40S yarns and 20D spandex;
step two, initial determination: carrying out primary shaping on the grey cloth, wherein the temperature is 198 ℃, the vehicle speed is 26m/min, and the upper and lower overfeeding is 45%/6%;
step three, pretreatment: pretreating the preliminarily determined grey cloth in a pretreatment liquid, wherein the pretreatment liquid comprises the following components in percentage by weight: 0.8-1.2g/L low-foam refining oil removal agent SF-2, 2.8-3.2g/L caustic soda flakes, 7.8-8.2g/L hydrogen peroxide, 0.3-0.7g/L neutralization acid 6004 and 0.13-0.17g/L oxygen removal enzyme DM-8618;
the pretreatment process specifically comprises the following steps: putting the blank cloth into a cylinder, adding warm water of 45-55 ℃, adding a low-foam refining degreasing agent SF-2, adding for 2-4min, operating for 4-6min, adding caustic soda flakes, adding for 8-12min, heating to 65-75 ℃ at the heating rate of 2.5-3.5 ℃/min, adding hydrogen peroxide, adding for 8-12min, heating to 105-115 ℃ at the heating rate of 2.5-3.5 ℃/min, operating for 25-35min under heat preservation, cooling to 75-85 ℃ at the cooling rate of 2.5-3.5 ℃/min, washing with overflow water for 8-12min, and discharging liquid; adding 45-55 deg.C warm water, keeping the temperature for 5-9min, and discharging liquid; adding 45-55 deg.C warm water, adding neutralizing acid 6004, measuring pH to 5.5-6.5, running for 5-9min, adding deoxyenzyme DM-8618, adding for 2-4min, running for 10-14min, and discharging liquid;
step four, dyeing: dyeing the pretreated grey cloth, specifically: adding water and dye for 18-22min, operating for 18-22min, sequentially adding 23-27g/L anhydrous sodium sulphate, 0.8-1.2g/L sodium carbonate and 2.2-2.6g/L fixation alkali XH-01, operating for 8-12min, heating to 60 ℃ at a heating rate of 1 ℃/min, keeping the temperature and operating for 40min, and discharging liquid;
the addition of anhydrous sodium sulphate, soda ash and fixation alkali XH-01 is specifically as follows: adding 2/10-4/10 anhydrous sodium sulfate for 15-25min, and adding the rest anhydrous sodium sulfate for 15-25 min; adding 2/10-4/10 of soda ash for 15-25min, and adding the rest soda ash and the color fixing alkali XH-01 for 15-25 min;
step five, soaping: soaping the dyed grey cloth: adding 45-55 deg.C warm water, overflowing, washing for 10-14min, and discharging liquid; adding 45-55 deg.C warm water, adding 0.8-1.2g/L neutralization acid 6004 according to water amount, heating to 85-95 deg.C at a heating rate of 2.5-3.5 deg.C/min, adding 0.14-0.18g/L soaping agent during heating, keeping the temperature for 8-12min, cooling to 75-85 deg.C at a cooling rate of 1.5-2.5 deg.C/min, washing with overflow water for 8-10min, and draining; adding 45-55 deg.C warm water, washing with water for 5-9min, and discharging liquid;
step six, drying: drying the grey cloth washed by the soap at the temperature of 135-140 ℃ at the speed of 15 m/min;
step seven, sizing: and (3) shaping the dried colored cloth, adding 48-52g/L of temperature control auxiliary agent and 18-22g/L of silicone oil T718 according to the water content during shaping, and adjusting the pH value to 4.5-6 by using citric acid or acetic acid, wherein the mangle rolling rate during shaping is 60%, the temperature is 180 ℃, the vehicle speed is 16m/min, and the upper and lower overfeeding is 28%/6%.
2. The temperature-controlled knitted underwear fabric obtained by the method for producing a temperature-controlled knitted underwear fabric according to claim 1.
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