CN110104951A - The preparation method of crackle enamel glaze slip, preparation method and crackle enamel glaze panel - Google Patents
The preparation method of crackle enamel glaze slip, preparation method and crackle enamel glaze panel Download PDFInfo
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- CN110104951A CN110104951A CN201910493386.7A CN201910493386A CN110104951A CN 110104951 A CN110104951 A CN 110104951A CN 201910493386 A CN201910493386 A CN 201910493386A CN 110104951 A CN110104951 A CN 110104951A
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- crackle
- enamel glaze
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D5/00—Coating with enamels or vitreous layers
- C23D5/02—Coating with enamels or vitreous layers by wet methods
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D7/00—Treating the coatings, e.g. drying before burning
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2207/00—Compositions specially applicable for the manufacture of vitreous enamels
- C03C2207/04—Compositions specially applicable for the manufacture of vitreous enamels for steel
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses crackle enamel glaze slip, the preparation method of preparation method and crackle enamel glaze panel, crackle enamel glaze slip is prepared by clear frit, suspending agent and the water that mass ratio is 100:6~8:40~50, is ground after being mixed, and is sieved, and standing obtains；By its soak ward off or wet spray by way of impose on done bottoming processing plate embryo on, firing after drying can be obtained crackle enamel glaze panel, the appearance of enamel glaze panel using crackle enamel glaze slip of the present invention for crack effect can be directly obtained on panel, not only the quality appearance and advantage of original base enamel plate had effectively been kept, but also has assigned a kind of charming visual effect of aging crack of enamel product surface.
Description
Technical field
The present invention relates to crackle enamel glaze slips, the preparation method of preparation method and crackle enamel glaze panel, belong to enamel plate
Preparation process field.
Background technique
With the continuous development of enamel industry, nowadays building decoration enamel plate can be in many public arenas as
Its figure is seen on the decoration of exterior wall such as iron, tunnel, bus shelter, communal facility.
However, as people are to the increasingly higher demands such as ornament materials appearance, design, more peculiar moulding, design
More and more receive the pursuit of people.
In traditional Ceramics Ceramic industry, crack ceramic glaze has been a kind of more mature technical field, still,
The industrial crackle enamel glaze of enamel is but because various limitations are constantly in a kind of space state.Therefore, in order to break through this line
Industry limitation, invents a kind of crackle enamel glaze, so that enamel ornament materials is more beautiful in appearance, more abundant more in moulding
It is color, using it is upper be urgent problem to be solved in the art more extensively.
Summary of the invention
In view of this, traditional industries limitation is broken through present invention aims at a kind of crackle glazing effect of enamel glaze is assigned,
Make enamel ornament materials is more beautiful in appearance, in moulding it is more rich and varied, using it is upper more extensively, provide one kind and split
Line enamel glaze slip and preparation method thereof and the method for preparing crackle enamel glaze panel using it.
To achieve the goals above, the present invention adopts the following technical scheme:
Crackle enamel glaze slip is prepared by clear frit, suspending agent and water that mass ratio is 100:6~8:40~50, excellent
Choosing, the mass ratio of clear frit, suspending agent and water is that the mass ratio of 100:6~7:40~50 or clear frit, suspending agent and water is
100:7~8:40~50.
The beneficial effect of crackle enamel glaze slip of the present invention is, is mixed by the glaze and suspending agent of above-mentioned formula
Glaze slurry can assign enamel glaze a kind of crackle glazing effect, make enamel ornament materials is more beautiful in appearance, in moulding
It is more rich and varied, using it is upper more extensively.
Further, suspending agent is clay.
Be using above-mentioned further beneficial effect, using clay as suspending agent, can effectively facilitate glaze slip suspend and
Increase the enamel film strength of blank surface.
Further, the clear frit is prepared by the raw material of following weight percent: silica 65~75%, oxidation
Boron 2~5%, aluminium oxide 15~20%, zirconium oxide 1~10%, titanium oxide 1~6%, lithia 1~4%, sodium oxide molybdena 1~5%.
The present invention also provides the preparation methods of above-mentioned crackle enamel glaze slip, and steps are as follows:
(1) clear frit, suspending agent and water are weighed in mass ratio, are uniformly mixed and are obtained mixture；
(2) mixture is ground, is sieved, up to crackle enamel glaze slip after 10~20min of standing.
Further, it is ground to be ground with ball mill, grinding revolving speed is 1200-1600r/min, preferably 1400r/
Min, milling time are 10~30min, and being ground to fineness degree is 0.15 ± 0.05g, 1.62~1.76g/ml of bulk density.Sieving was
80-140 mesh, preferably 140 mesh standard sieves；
The fineness degree is the quality of the screen over-size after drying after 100ml glaze slip crosses 150 mesh standard sieves.
The present invention also provides the methods for preparing crackle enamel glaze panel with above-mentioned crackle enamel glaze slip, and steps are as follows:
(1) by above-mentioned crackle enamel glaze slip soak ward off or wet spray by way of impose on done bottoming processing steel
On plate embryo, enamel plate is obtained；
(2) after enamel plate being dried 1~2min at 300~500 DEG C, then at 780~800 DEG C fire 3.5~
4.5min obtains crackle enamel glaze panel.
Crackle enamel glaze panel preparation manipulation of the present invention is simple, at low cost, saves the time, and operability is high, prepared
The appearance that crackle enamel glaze panel has enamel product glaze special, both effectively outside the quality of holding original base enamel plate
Sight and advantage, and assign a kind of charming visual effect of aging crack of enamel product surface.
Further, spray in step (1) with a thickness of 200~500 μm, spray gun between plate embryo at a distance from be 15~20cm,
The movement speed of spray gun is 3~6cm/s, and the angle between rifle mouth and plate embryo is 80 °~100 °
It is using above-mentioned further beneficial effect, keeps spraying thickness moderate and each position is substantially uniform consistent；Most
Soleplate block coating quality is good, is not in orange peel line.
Detailed description of the invention
Fig. 1 is crackle enamel glaze panel in the embodiment of the present invention 1；
Fig. 2 is crackle enamel glaze panel in the embodiment of the present invention 1；
Fig. 3 is crackle enamel glaze panel in the embodiment of the present invention 2；
Fig. 4 is crackle enamel glaze panel in the embodiment of the present invention 2；
Fig. 5 is crackle enamel glaze panel in comparative example 1 of the present invention；
Fig. 6 is crackle enamel glaze panel in comparative example 2 of the present invention.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
In the examples below, clear frit be pearly-lustre glaze 403 (buying from Xing Liaowuna Chemical Co., Ltd., Foshan City) or
Clear frit 6108 (buying is from Caro than sub- (China) new high-tech material Co., Ltd), the raw material of pearly-lustre glaze 403 and clear frit 6108
The following raw material component is all made of to be made: silica 65~75%, boron oxide 2~5%, aluminium oxide 15~20%, zirconium oxide 1~
10%, titanium oxide 1~6%, lithia 1~4%, sodium oxide molybdena 1~5%.
Other raw materials for not doing specified otherwise are conventional raw material in the art.
Embodiment 1
The preparation method of crackle enamel glaze slip, steps are as follows:
It (1) is that 0.01g electronic balance carries out standard with precision by clear frit 200g (pearly-lustre glaze 403), clay 13g, water 80g
It is fitted into after really weighing in the De Lixi board KM-2 type Quick ball grinder standard configuration ball grinder that capacity is 1L；
(2) ball grinder is placed on ball mill stationary fixture and fixes intact, the then ball milling 15 under the revolving speed of 1400r/min
Minute, until fineness degree crosses 140 mesh standard sieves in 0.15 ± 0.05g, bulk density stands 10~20 minutes in 1.62~1.76g/ml.
In the method that above-mentioned crackle enamel glaze slip prepares crackle enamel glaze panel, steps are as follows:
(1) crackle enamel glaze slip is imposed in a manner of wet spray on the steel plate embryo for having done bottoming processing, spraying
Thickness at 200~500 μm；Rifle mouth be 15~20cm at a distance between spray object；The movement speed of spray gun is 3~6cm/ seconds；
Rifle mouth and by the angle between spray object be 90 ° ± 10 °, obtain enamel plate；
(2) enamel plate obtained above is placed in the high temperature drying case that temperature is 300 DEG C~500 DEG C and dries 1~2 point
Clock is placed in the firing furnace that temperature is 780~800 DEG C, is burnt into 3.5~4.5 minutes, obtains crackle enamel glaze panel.
Prepared enamel plate not only has the texture of the porcelain jade of enamel, while assigning that enamel glaze is a kind of special to be split
Line glazing effect, as depicted in figs. 1 and 2.
Embodiment 2
The preparation method of crackle enamel glaze slip, steps are as follows:
It (1) is that 0.01g electronic balance carries out with precision by clear frit 200g (clear frit 6108), clay 14g, water 100g
It is fitted into after precise in the De Lixi board KM-2 type Quick ball grinder standard configuration ball grinder that capacity is 1L；
(2) ball grinder is placed on ball mill stationary fixture and fixes intact, the then ball milling 15 under the revolving speed of 1400r/min
Minute, until fineness degree crosses 140 mesh standard sieves in 0.15 ± 0.05g, bulk density stands 10~20 minutes in 1.62~1.76g/ml.
In the method that above-mentioned crackle enamel glaze slip prepares crackle enamel glaze panel, steps are as follows:
(1) crackle enamel glaze slip is imposed in a manner of wet spray on the steel plate embryo for having done bottoming processing, spraying
Thickness at 200~500 μm；Rifle mouth be 15~20cm at a distance between spray object；The movement speed of spray gun is 3~6cm/ seconds；
Rifle mouth and by the angle between spray object be 90 ° ± 10 °, obtain enamel plate；
(2) enamel plate obtained above is placed in the high temperature drying case that temperature is 300 DEG C -500 DEG C and is dried 1~2 minute,
It is placed in the firing furnace that temperature is 780~800 DEG C, is burnt into 3.5~4.5 minutes, obtains crackle enamel glaze panel.
Prepared enamel plate not only has the texture of the porcelain jade of enamel, while assigning that enamel glaze is a kind of special to be split
Line glazing effect, as shown in Figure 3 and Figure 4.
Comparative example 1
The preparation method of crackle enamel glaze slip, steps are as follows:
(1) by base glaze 200g (the base glaze be titanium white base glaze), clay 13g, water 80g, with precision be 0.01g electronic balance into
It is fitted into after row precise in the De Lixi board KM-2 type Quick ball grinder standard configuration ball grinder that capacity is 1L；
(2) ball grinder is placed on ball mill stationary fixture and fixes intact, the then ball milling 15 under the revolving speed of 1400r/min
Minute, until fineness degree crosses 140 mesh standard sieves in 0.15 ± 0.05g, bulk density stands 10~20 minutes in 1.62~1.76g/ml.
In the method that above-mentioned crackle enamel glaze slip prepares crackle enamel glaze panel, steps are as follows:
(1) crackle enamel glaze slip is imposed in a manner of wet spray on the steel plate embryo for having done bottoming processing, spraying
Thickness at 200~500 μm；Rifle mouth be 15~20cm at a distance between spray object；The movement speed of spray gun is 3~6cm/ seconds；
Rifle mouth and by the angle between spray object be 90 ° ± 10 °, obtain enamel plate；
(2) enamel plate obtained above is placed in the high temperature drying case that temperature is 300 DEG C~500 DEG C and dries 1~2 point
Clock is placed in the firing furnace that temperature is 780~800 DEG C, is burnt into 3.5~4.5 minutes, obtains crackle enamel glaze panel.
Prepared enamel plate is since base glaze uses titanium white base glaze, so crackle can not be formed, as shown in Figure 5.
Comparative example 2
The preparation method of crackle enamel glaze slip, steps are as follows:
It (1) is that 0.01g electronic balance carries out standard with precision by clear frit 200g (pearly-lustre glaze 403), clay 13g, water 80g
It is fitted into after really weighing in the De Lixi board KM-2 type Quick ball grinder standard configuration ball grinder that capacity is 1L；
(2) ball grinder is placed on ball mill stationary fixture and fixes intact, the then ball milling 15 under the revolving speed of 1400r/min
Minute, until fineness degree crosses 140 mesh standard sieves in 0.15 ± 0.05g, bulk density stands 10~20 minutes in 1.62~1.76g/ml.
In the method that above-mentioned crackle enamel glaze slip prepares crackle enamel glaze panel, steps are as follows:
(1) crackle enamel glaze slip is imposed in a manner of wet spray on the steel plate embryo for having done bottoming processing, spraying
Thickness at 200~500 μm；Rifle mouth be 15~20cm at a distance between spray object；The movement speed of spray gun is 3~6cm/ seconds；
Rifle mouth and by the angle between spray object be 90 ° ± 10 °, obtain enamel plate；
(2) enamel plate obtained above is placed in the high temperature drying case that temperature is 100 DEG C~200 DEG C and dries 4~5 points
Clock is placed in the firing furnace that temperature is 780~800 DEG C, is burnt into 3.5~4.5 minutes, obtains crackle enamel glaze panel.
Prepared enamel plate since stoving process is unreasonable, so can not formation rule crackle, as shown in Figure 6.
Claims (10)
1. crackle enamel glaze slip, which is characterized in that the crackle enamel glaze slip is the transparent of 100:6~8:40~50 by mass ratio
Glaze, suspending agent and water are prepared.
2. crackle enamel glaze slip according to claim 1, which is characterized in that the quality of the clear frit, suspending agent and water
Than for 100:6~7:40~50.
3. crackle enamel glaze slip according to claim 1, which is characterized in that the quality of the clear frit, suspending agent and water
Than for 100:7~8:40~50.
4. described in any item crackle enamel glaze slips according to claim 1~3, which is characterized in that the clear frit is by following heavy
The raw material of amount percentage is prepared: silica 65~75%, boron oxide 2~5%, aluminium oxide 15~20%, and zirconium oxide 1~
10%, titanium oxide 1~6%, lithia 1~4%, sodium oxide molybdena 1~5%.
5. described in any item crackle enamel glaze slips according to claim 1~3, which is characterized in that the suspending agent is clay.
6. the preparation method of crackle enamel glaze slip, which is characterized in that steps are as follows:
(1) clear frit, suspending agent and water are weighed by the described in any item mass ratioes of Claims 1 to 5, is mixed
Material；
(2) mixture is ground, is sieved, up to the crackle enamel glaze slip after 10~20min of standing.
7. the preparation method of crackle enamel glaze slip according to claim 6, which is characterized in that ground described in step (2)
Revolving speed be 1200-1600r/min, milling time be 10~30min；
The sieving was 80-140 mesh standard sieve.
8. the preparation method of crackle enamel glaze panel, which is characterized in that steps are as follows:
(1) by the described in any item crackle enamel glaze slips of Claims 1 to 5 leaching ward off or wet spray by way of impose on
On the steel plate embryo for doing bottoming processing, enamel plate is obtained；
(2) it will be fired after enamel plate drying and obtain the crackle enamel glaze panel.
9. the preparation method of crackle enamel glaze panel according to claim 8, which is characterized in that spray in the step (1)
Apply with a thickness of 200~500 μm；
Spray gun between plate embryo at a distance from be 15~20cm；
The movement speed of spray gun is 3~6cm/s；
Angle between rifle mouth and plate embryo is 80 °~100 °.
10. the preparation method of crackle enamel glaze panel according to claim 8, which is characterized in that dried described in step (2)
Dry temperature is 300~500 DEG C, and drying time is 1~2min；
The temperature of the firing is 780~800 DEG C, and the firing time is 3.5~4.5min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910493386.7A CN110104951B (en) | 2019-06-06 | 2019-06-06 | Crack enamel glaze slip, preparation method and preparation method of crack enamel glaze panel |
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| CN201910493386.7A CN110104951B (en) | 2019-06-06 | 2019-06-06 | Crack enamel glaze slip, preparation method and preparation method of crack enamel glaze panel |
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| CN110104951A true CN110104951A (en) | 2019-08-09 |
| CN110104951B CN110104951B (en) | 2021-09-21 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105313570A (en) * | 2014-07-21 | 2016-02-10 | 毛琼 | Matrix cracking method |
| CN106430960A (en) * | 2016-08-31 | 2017-02-22 | 浙江开尔新材料股份有限公司 | Preparation method of pearl enamel |
-
2019
- 2019-06-06 CN CN201910493386.7A patent/CN110104951B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105313570A (en) * | 2014-07-21 | 2016-02-10 | 毛琼 | Matrix cracking method |
| CN106430960A (en) * | 2016-08-31 | 2017-02-22 | 浙江开尔新材料股份有限公司 | Preparation method of pearl enamel |
Non-Patent Citations (8)
| Title |
|---|
| 吴玉敏等: "炻器开片釉的研制 ", 《河南科技》 * |
| 周玉所等: "一种高翘曲性裂纹釉的试制 ", 《山东陶瓷》 * |
| 周玉所等: "裂纹釉的试制 ", 《河北陶瓷》 * |
| 武同青等: "中温炻瓷冰裂纹釉的研制 ", 《佛山陶瓷》 * |
| 董伟霞等: "低成本无光高白裂纹釉的研制 ", 《江苏陶瓷》 * |
| 郑庆海等: "《瓷釉制造与搪瓷工艺》", 31 May 1963, 中国财政经济出版社 * |
| 陈坤怀: "浅谈开片釉形成的机理 ", 《江苏陶瓷》 * |
| 陶勇霞: "建陶制品裂纹釉的研制 ", 《佛山陶瓷》 * |
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