CN110093092A - A kind of anti-corrosion waterproof material and preparation method - Google Patents

A kind of anti-corrosion waterproof material and preparation method Download PDF

Info

Publication number
CN110093092A
CN110093092A CN201910458977.0A CN201910458977A CN110093092A CN 110093092 A CN110093092 A CN 110093092A CN 201910458977 A CN201910458977 A CN 201910458977A CN 110093092 A CN110093092 A CN 110093092A
Authority
CN
China
Prior art keywords
mass ratio
resin
corrosion
tung oil
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910458977.0A
Other languages
Chinese (zh)
Inventor
张帆
张卫
张钧博
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN STAR WATERPROOF MATERIAL Co Ltd
Original Assignee
WUHAN STAR WATERPROOF MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHAN STAR WATERPROOF MATERIAL Co Ltd filed Critical WUHAN STAR WATERPROOF MATERIAL Co Ltd
Priority to CN201910458977.0A priority Critical patent/CN110093092A/en
Publication of CN110093092A publication Critical patent/CN110093092A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5046Amines heterocyclic
    • C08G59/5053Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/5073Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/56Amines together with other curing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62Alcohols or phenols
    • C08G59/64Amino alcohols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/327Aluminium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/328Phosphates of heavy metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The embodiment of the present invention provides a kind of anti-corrosion waterproof material and preparation method, with TO resin anticorrosive paint based on the vegetable oil such as tung oil raw material, polar rubber makees intrinsic toughening agent, copolymer compound using cis-butenedioic anhydride etc. containing unsaturated double-bond is modified, cold high-molecular compound of the spelling with epoxy group, several functions auxiliary agent and mixed type solidifying agent etc. is added to be formulated, to solve the disadvantage that water-repellent paint is that cohesive force is low in the prior art, poor corrosion resistance, resistance to low temperature is poor, and has the problem of waterproof and breathable.

Description

A kind of anti-corrosion waterproof material and preparation method
Technical field
The present embodiments relate to construction material technical field more particularly to a kind of anti-corrosion waterproof material and preparation sides Method.
Background technique
Coatings industry belongs to the modern industry, but coating itself has long history.China is in the world using natural Coating of the resin as film forming matter --- the earliest country of lacquer.Really understand using solvent, with solvent come dissolved solid Natural resin, it is inchoate in the middle of the 19th century that the coating of quick-drying, which is made,.Simplest water paint is lime slurry, is about existed Emulsification linseed oil was added thereto with regard to once someone plan before 100 years to improve, it is exactly earliest emulsion paint that this, which I'm afraid,.70- Representative of the eighties as contemporary water paint --- emulsion paint has obtained certain development, but promote and apply enter it is low Paddy.Emulsion paint wants and is in fashion the interior wall coating in the whole nation to carry out price competition, as a result, losing all standing and reputation, or even substantial portion of Builder and adnornment industry are negated, while boffo ceramic tile has seized the market of exterior wall latex paint most again.
Water-repellent paint is not suitable for the occasion containing corrosive media most without anti-corrosion function at present.It is widely used at present Be polymer cement waterproof paint in national standard GB-23445-2009 " polymer cement waterproof paint ", wherein polymer emulsion For acrylate, ethane-acetic acid ethyenyl ester etc..The shortcomings that such polymer cement waterproof paint is that cohesive force is low, corrosion resistance Can be poor, resistance to low temperature is poor, and has waterproof and breathable (hydrone does not pass through, and gas molecule can pass through, and it is non-moistureproof to be commonly called as waterproof) Characteristic.
Summary of the invention
The embodiment of the present invention provides a kind of anti-corrosion waterproof material and preparation method, to solve water-repellent paint in the prior art The shortcomings that be that cohesive force is low, poor corrosion resistance, resistance to low temperature is poor, and has the problem of waterproof and breathable.
In a first aspect, the embodiment of the present invention provides a kind of anti-corrosion waterproof material, including tung oil acid anhydride, epoxy resin, iron oxide red Powder, talcum powder, trbasic zinc phosphate, organobentonite, aluminium triphosphate, rutile type titanium white, carbon black, barium sulfate, defoaming agent, levelling Agent, preservative, plasticizer, filler, portland cement;Wherein, tung oil acid anhydride, epoxy resin 1:1 in mass ratio are prepared into TO tree Rouge;Portland cement, filler, preservative are that 1-2:1:0.2-0.5 is prepared by mixing into powder according to weight ratio.
Further, TO resin, iron oxide red, talcum powder, trbasic zinc phosphate, aluminium triphosphate, organobentonite in mass ratio 35: 15:15:14:5:0.5 being prepared into anti-decaying paint bottom;TO resin, carbon black, barium sulfate, organobentonite, disappears at rutile type titanium white Infusion, levelling agent, filler, powder 50:22:1:10:0.5:0.3:0.3:10:10 in mass ratio are prepared into anti-corrosion lacquer painting.
Further, the filler be one or more of quartz sand, silica flour, calcium carbonate, talcum powder, titanium dioxide with Arbitrary proportion mixing;The preservative is the mixture that one or both of trbasic zinc phosphate or aluminum phosphate are mixed with arbitrary proportion.
Second aspect, the embodiment of the present invention provide a kind of anti-corrosion waterproof material preparation method, comprising:
Tung oil pours into the four-hole boiling flask equipped with high speed agitator and heating device, is passed through nitrogen, is warming up to 120 DEG C, takes off 0.5~1h of water is cooled to 60 DEG C, and cis-butenedioic anhydride is slowly added into while stirring, automatic heating to 170 DEG C, maintain reaction 0.5~ 1h obtains tung oil acid anhydride;
Tung oil acid anhydride obtained is mixed with toluene in mass ratio 1: 1, the transparent clarification of acquired solution;
Tung oil acid anhydride and epoxy resin 6101 in mass ratio 1: 1 are mixed at 80 DEG C, stirs evenly, is rapidly decreased to room Temperature obtains TO resin;
By TO resin, iron oxide red, talcum powder, trbasic zinc phosphate, aluminium triphosphate, organobentonite 35:15:15 in mass ratio: 14:5:0.5 is prepared into anti-decaying paint bottom;By TO resin, rutile type titanium white, carbon black, barium sulfate, organobentonite, defoaming agent, Levelling agent, filler, powder 50:22:1:10:0.5:0.3:0.3:10:10 in mass ratio are prepared into anti-corrosion lacquer painting.
Further, further includes:
The mixture of triethanolamine and methylimidazole is curing agent, curing agent and anti-corrosion lacquer painting or anti-decaying paint bottom mass ratio For 1:20.
A kind of anti-corrosion waterproof material provided in an embodiment of the present invention and preparation method, with TO resin anticorrosive paint with tung oil Raw material based on equal vegetable oil, polar rubber make intrinsic toughening agent, and the copolymer compound using cis-butenedioic anhydride etc. containing unsaturated double-bond is modified, Cold high-molecular compound of the spelling with epoxy group, adds several functions auxiliary agent and mixed type solidifying agent etc. and is formulated, to Solve the disadvantage that water-repellent paint is that cohesive force is low in the prior art, poor corrosion resistance, resistance to low temperature is poor, and has waterproof and breathable The problem of.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making Every other embodiment obtained, shall fall within the protection scope of the present invention under the premise of creative work.
In a first aspect, the embodiment of the present invention provides a kind of anti-corrosion waterproof material, including tung oil acid anhydride, epoxy resin, iron oxide red Powder, talcum powder, trbasic zinc phosphate, organobentonite, aluminium triphosphate, rutile type titanium white, carbon black, barium sulfate, defoaming agent, levelling Agent, preservative, plasticizer, filler, portland cement;Wherein, tung oil acid anhydride, epoxy resin 1:1 in mass ratio are prepared into TO tree Rouge;Portland cement, filler, preservative are that 1-2:1:0.2-0.5 is prepared by mixing into powder according to weight ratio.
Further, TO resin, iron oxide red, talcum powder, trbasic zinc phosphate, aluminium triphosphate, organobentonite in mass ratio 35: 15:15:14:5:0.5 being prepared into anti-decaying paint bottom;TO resin, carbon black, barium sulfate, organobentonite, disappears at rutile type titanium white Infusion, levelling agent, filler, powder 50:22:1:10:0.5:0.3:0.3:10:10 in mass ratio are prepared into anti-corrosion lacquer painting.
Further, the filler be one or more of quartz sand, silica flour, calcium carbonate, talcum powder, titanium dioxide with Arbitrary proportion mixing;The preservative is the mixture that one or both of trbasic zinc phosphate or aluminum phosphate are mixed with arbitrary proportion.
Second aspect, the embodiment of the present invention provide a kind of anti-corrosion waterproof material preparation method, comprising:
Tung oil pours into the four-hole boiling flask equipped with high speed agitator and heating device, is passed through nitrogen, is warming up to 120 DEG C, takes off 0.5~1h of water is cooled to 60 DEG C, and cis-butenedioic anhydride is slowly added into while stirring, automatic heating to 170 DEG C, maintain reaction 0.5~ 1h obtains tung oil acid anhydride;
Tung oil acid anhydride obtained is mixed with toluene in mass ratio 1: 1, the transparent clarification of acquired solution;
Tung oil acid anhydride and epoxy resin 6101 in mass ratio 1: 1 are mixed at 80 DEG C, stirs evenly, is rapidly decreased to room Temperature obtains TO resin;
By TO resin, iron oxide red, talcum powder, trbasic zinc phosphate, aluminium triphosphate, organobentonite 35:15:15 in mass ratio: 14:5:0.5 is prepared into anti-decaying paint bottom;By TO resin, rutile type titanium white, carbon black, barium sulfate, organobentonite, defoaming agent, Levelling agent, filler, powder 50:22:1:10:0.5:0.3:0.3:10:10 in mass ratio are prepared into anti-corrosion lacquer painting.
Further, further includes:
The mixture of triethanolamine and methylimidazole is curing agent, curing agent and anti-corrosion lacquer painting or anti-decaying paint bottom mass ratio For 1:20.
A kind of anti-corrosion waterproof material provided in an embodiment of the present invention and preparation method, with TO resin anticorrosive paint with tung oil Raw material based on equal vegetable oil, polar rubber make intrinsic toughening agent, and the copolymer compound using cis-butenedioic anhydride etc. containing unsaturated double-bond is modified, Cold high-molecular compound of the spelling with epoxy group, adds several functions auxiliary agent and mixed type solidifying agent etc. and is formulated, to Solve the disadvantage that water-repellent paint is that cohesive force is low in the prior art, poor corrosion resistance, resistance to low temperature is poor, and has waterproof and breathable The problem of.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although Present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: it still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features; And these are modified or replaceed, technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution spirit and Range.

Claims (5)

1. a kind of anti-corrosion waterproof material, which is characterized in that including tung oil acid anhydride, epoxy resin, iron oxide red, talcum powder, trbasic zinc phosphate, Organobentonite, aluminium triphosphate, rutile type titanium white, carbon black, barium sulfate, defoaming agent, levelling agent, preservative, plasticizer, Filler, portland cement;Wherein, tung oil acid anhydride, epoxy resin 1:1 in mass ratio are prepared into TO resin;Portland cement is filled out Material, preservative are that 1-2:1:0.2-0.5 is prepared by mixing into powder according to weight ratio.
2. anti-corrosion waterproof material according to claim 1, which is characterized in that TO resin, iron oxide red, talcum powder, trbasic zinc phosphate, Aluminium triphosphate, organobentonite 35:15:15:14:5:0.5 in mass ratio are prepared into anti-decaying paint bottom;TO resin, rutile-type Titanium dioxide, carbon black, barium sulfate, organobentonite, defoaming agent, levelling agent, filler, powder 50:22:1:10:0.5 in mass ratio: 0.3:0.3:10:10 is prepared into anti-corrosion lacquer painting.
3. anti-corrosion waterproof material according to claim 1, which is characterized in that the filler is quartz sand, silica flour, carbonic acid One or more of calcium, talcum powder, titanium dioxide are mixed with arbitrary proportion;The preservative is one in trbasic zinc phosphate or aluminum phosphate Kind or two kinds of mixtures mixed with arbitrary proportion.
4. a kind of anti-corrosion waterproof material preparation method characterized by comprising
Tung oil pours into the four-hole boiling flask equipped with high speed agitator and heating device, is passed through nitrogen, is warming up to 120 DEG C, dehydration 0.5 ~1h is cooled to 60 DEG C, and cis-butenedioic anhydride is slowly added into while stirring, and automatic heating maintains 0.5~1h of reaction, obtain to 170 DEG C Tung oil acid anhydride;
Tung oil acid anhydride obtained is mixed with toluene in mass ratio 1: 1, the transparent clarification of acquired solution;
Tung oil acid anhydride and epoxy resin 6101 in mass ratio 1: 1 are mixed at 80 DEG C, stirs evenly, is rapidly decreased to room temperature, obtain To TO resin;
By TO resin, iron oxide red, talcum powder, trbasic zinc phosphate, aluminium triphosphate, organobentonite 35:15:15:14:5 in mass ratio: 0.5 is prepared into anti-decaying paint bottom;By TO resin, rutile type titanium white, carbon black, barium sulfate, organobentonite, defoaming agent, levelling Agent, filler, powder 50:22:1:10:0.5:0.3:0.3:10:10 in mass ratio are prepared into anti-corrosion lacquer painting.
5. anti-corrosion waterproof material preparation method according to claim 4, which is characterized in that further include:
The mixture of triethanolamine and methylimidazole is curing agent, curing agent and anti-corrosion lacquer painting or anti-decaying paint bottom mass ratio is 1: 20。
CN201910458977.0A 2019-05-29 2019-05-29 A kind of anti-corrosion waterproof material and preparation method Pending CN110093092A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910458977.0A CN110093092A (en) 2019-05-29 2019-05-29 A kind of anti-corrosion waterproof material and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910458977.0A CN110093092A (en) 2019-05-29 2019-05-29 A kind of anti-corrosion waterproof material and preparation method

Publications (1)

Publication Number Publication Date
CN110093092A true CN110093092A (en) 2019-08-06

Family

ID=67449619

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910458977.0A Pending CN110093092A (en) 2019-05-29 2019-05-29 A kind of anti-corrosion waterproof material and preparation method

Country Status (1)

Country Link
CN (1) CN110093092A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101007921A (en) * 2006-01-24 2007-08-01 中国科学院过程工程研究所 Anticorrosion paint for chimney of electric plant and its uses
CN101671515A (en) * 2009-09-01 2010-03-17 中国人民解放军海军后勤技术装备研究所 Anticorrosive coating for concrete structure reinforcing bars and preparation method thereof
CN104231863A (en) * 2014-09-26 2014-12-24 水利部交通运输部国家能源局南京水利科学研究院 Solvent-free anticorrosive paint composition capable of being solidified in seawater
CN108250936A (en) * 2018-01-29 2018-07-06 山西聚脲防护材料有限公司 Resin cement waterproof anticorrosive paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101007921A (en) * 2006-01-24 2007-08-01 中国科学院过程工程研究所 Anticorrosion paint for chimney of electric plant and its uses
CN101671515A (en) * 2009-09-01 2010-03-17 中国人民解放军海军后勤技术装备研究所 Anticorrosive coating for concrete structure reinforcing bars and preparation method thereof
CN104231863A (en) * 2014-09-26 2014-12-24 水利部交通运输部国家能源局南京水利科学研究院 Solvent-free anticorrosive paint composition capable of being solidified in seawater
CN108250936A (en) * 2018-01-29 2018-07-06 山西聚脲防护材料有限公司 Resin cement waterproof anticorrosive paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
魏向阳等: "TO树脂重防腐涂料的研制", 《上海涂料》 *

Similar Documents

Publication Publication Date Title
CN103725051B (en) A kind of body material of inorganic paint and application thereof
CN109942258A (en) A kind of polymer cement waterproof paint and preparation method thereof of the anti-accumulation of salt in the surface soil
CN104789057A (en) Colored organic fluorine-modified styrene-acrylic waterproof paint and preparation method thereof
CN106280789A (en) A kind of double-component silicon third anticracking waterproof coating and preparation method thereof
CN110386788A (en) A kind of JS cement base anti-counterfeit paint, Preparation method and use
CN112321765B (en) Waterproof coating based on self-crosslinking modified styrene-acrylic emulsion and preparation method and application thereof
CN110093092A (en) A kind of anti-corrosion waterproof material and preparation method
CN113088147A (en) Bi-component primer-free exterior wall paint and preparation and application methods thereof
CN104987669A (en) Filling agent used for filling plate and preparation method
CN112300647A (en) Black single-component polymer inorganic mineral waterproof coating for concrete base surface
CN110093093A (en) A kind of resistance to limit low temperature waterproof material and preparation method
CN104974643A (en) Water-based coating for protecting stony cultural relics and preparation method of coating
CN104497655A (en) High-water-permeability weather-resistant exterior wall coating and preparation method thereof
CN103897592A (en) Method for preparing polymer material by taking raw lacquer as biomass base and polymer material prepared by using method
CN108659634A (en) A kind of corrosion-resistant emulsion paint of anti-crack
CN106866047A (en) A kind of antistatic inorganic dry powder construction paint and its application
CN109095848B (en) Attapulgite facing mortar and preparation method thereof
CN110423500A (en) A kind of dip-coating type syncretic zinc cold spray coating and preparation method thereof
JPS63310782A (en) Method for strengthening surface of inorganic ceramic building material
CN106833146A (en) A kind of coating and preparation method thereof
CN105647248B (en) A kind of basis material and its preparation method and application
JPS6113506B2 (en)
CN109734397A (en) A kind of environmental protection type wall body building material and preparation method thereof
CN105565748B (en) A kind of building marine glue and preparation method thereof
CN115611596B (en) Special cement-based road marking paint and preparation method and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190806