CN110092531A - A kind of multifunctional assembled Tailwater Depth denitrogenation dephosphorizing artificial wet land system - Google Patents
A kind of multifunctional assembled Tailwater Depth denitrogenation dephosphorizing artificial wet land system Download PDFInfo
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 38
- 239000011574 phosphorus Substances 0.000 claims abstract description 38
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002028 Biomass Substances 0.000 claims abstract description 26
- 230000020477 pH reduction Effects 0.000 claims abstract description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 16
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- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 7
- 244000005700 microbiome Species 0.000 claims abstract description 7
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- 238000005192 partition Methods 0.000 claims description 7
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- -1 polypropylene Polymers 0.000 claims description 6
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- 230000001546 nitrifying effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
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- 229910052791 calcium Inorganic materials 0.000 abstract description 3
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- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 2
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
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- Environmental & Geological Engineering (AREA)
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Abstract
本发明公开了一种组合式多功能尾水深度脱氮除磷人工湿地系统,该系统包括水解酸化区(1)、生物质填料放置区(2)、反硝化湿地区(3)、硝化湿地区(4)、反硝化湿地区(5)、强化除磷区(6)。尾水进入水解酸化区(1)与生物挂膜组合填料接触,有效利用尾水氮磷元素,尾水通过导流槽进入生物质填料放置区(2),该填料可释放有机物,为后续反硝化提供有利条件。反硝化湿地区(3)、(5)采用封闭式顶盖,可为微生物提供缺氧环境。强化除磷区(6)内高钙粉煤灰陶粒和硫铁复合填料可有效去除磷。该系统能有效解决尾水除磷和脱氮对碳源需求的矛盾,不易堵塞,出水水质好,投资少,配合种植水生植物,还可达到美化景观的效果。
The invention discloses a combined multi-functional artificial wetland system for deep denitrification and phosphorus removal of tail water. The system includes a hydrolysis acidification area (1), a biomass filler placement area (2), a denitrification wet area (3), a nitrification wet area (4), denitrification wet area (5), enhanced phosphorus removal area (6). The tail water enters the hydrolysis acidification area (1) and contacts with the bio-film composite filler to effectively utilize the nitrogen and phosphorus elements of the tail water. The tail water enters the biomass filler placement area (2) through the diversion tank. Nitrification provides favorable conditions. The denitrification wet areas (3) and (5) adopt closed top covers, which can provide anoxic environment for microorganisms. The high-calcium fly ash ceramsite and sulfur-iron composite filler in the enhanced phosphorus removal zone (6) can effectively remove phosphorus. This system can effectively solve the contradiction between tail water dephosphorization and denitrification on the demand for carbon source. It is not easy to block, the effluent quality is good, and the investment is small. With the planting of aquatic plants, it can also achieve the effect of beautifying the landscape.
Description
技术领域technical field
本发明涉及污水处理技术领域,具体涉及一种组合式多功能尾水深度脱氮除磷人工湿地系统。The invention relates to the technical field of sewage treatment, in particular to a combined multifunctional artificial wetland system for deep denitrification and dephosphorization of tail water.
背景技术Background technique
目前我国污水处理厂出水水质普遍执行《城镇污水处理厂污染物排放标准》(GB18918-2002)中的一级A或B标准。但是很多城镇污水厂因为污水处理工艺和处理设备的不合理,使得污水处理效率低下,处理能耗大,大量的污水厂尾水直接排放至受纳水体。污水处理厂尾水尽管大部分能达到排放标准,但是仍然具有较多的污染物,以地表III类水为例,污水厂出水浓度为《地表水环境质量标准》(GB3838-2002)的3~15倍(COD为3倍;总氮为15倍),两者之间存在较大差距,直接排放会带来一系列问题。城市污水处理厂尾水水量大,有机物浓度较低且成分复杂,氮磷含量较高,对其进行深度处理具有一定的难度。At present, the effluent water quality of my country's sewage treatment plants generally implements the first-class A or B standard in the "Pollutant Discharge Standards for Urban Sewage Treatment Plants" (GB18918-2002). However, due to the unreasonable sewage treatment process and treatment equipment in many urban sewage plants, the efficiency of sewage treatment is low, the energy consumption is high, and a large amount of tail water from sewage plants is directly discharged to receiving water bodies. Although most of the tail water of the sewage treatment plant can meet the discharge standard, it still has a lot of pollutants. Taking the third class water on the surface as an example, the concentration of the effluent from the sewage treatment plant is 3-3% of the "Environmental Quality Standard for Surface Water" (GB3838-2002). 15 times (COD is 3 times; total nitrogen is 15 times), there is a big gap between the two, and direct discharge will bring a series of problems. The tail water of urban sewage treatment plants has a large amount of water, low concentration of organic matter and complex components, and high content of nitrogen and phosphorus, so it is difficult to carry out advanced treatment.
人工湿地技术是由人工建造和控制运行的生态系统,将污水、污泥有控制地投配到经人工建造的湿地上,污水与污泥在沿一定方向流动的过程中,利用土壤、人工介质、植物、微生物的物理、化学、生物三重协同作用吸收污水中的有机物、氮、磷等污染物质。人工湿地技术处理尾水具有投资维护费用较低,二次污染小等特点,符合现代水处理发展的需求。但是单一的人工湿地处理效率不高,处理效果不稳定,受温度影响较大。尾水中污染物有机物含量较少,而微生物生长活动需要利用碳源,因此人工湿地作为尾水处理单元往往无法将其处理能力完全发挥出来。Constructed wetland technology is an ecological system that is artificially constructed and controlled to operate. Sewage and sludge are distributed to the artificially constructed wetland in a controlled manner. In the process of flowing sewage and sludge in a certain direction, soil and artificial media are used to The physical, chemical and biological triple synergy of plants, microorganisms absorb organic matter, nitrogen, phosphorus and other pollutants in sewage. The treatment of tail water by constructed wetland technology has the characteristics of low investment and maintenance costs and small secondary pollution, which meets the needs of modern water treatment development. However, the treatment efficiency of a single constructed wetland is not high, the treatment effect is unstable, and is greatly affected by temperature. The organic content of pollutants in the tail water is relatively small, and the growth of microorganisms requires the use of carbon sources, so the constructed wetland as a tail water treatment unit often cannot fully exert its treatment capacity.
申请号为201510680367.7的中国发明专利公开了一种人工湿地复合砾石床,该发明复合砾石床由生长基质层和填料层组成,对COD去除率高于50%,总氮总磷的去除率也均在 60%以上,但当进水水力负荷、冲击负荷较大时,单一的复合砾石床就无法满足出水水质要求。The Chinese invention patent with the application number 201510680367.7 discloses a composite gravel bed for constructed wetlands. The composite gravel bed of the invention is composed of a growth matrix layer and a filler layer. The removal rate of COD is higher than 50%, and the removal rate of total nitrogen and phosphorus is also average. It is more than 60%, but when the hydraulic load and impact load of the influent are large, a single composite gravel bed cannot meet the water quality requirements of the effluent.
申请号为201610419636.9的中国发明专利公开了一种强化脱氮除磷组合式人工潜流湿地处理系统,该发明通过筛网去除污水中的悬浮污染物,利用微生物、植物、基质吸附作用脱氮除磷,但当污水进水的有机物不足时,难以进行反硝化脱氮,导致出水水质恶化。The Chinese invention patent with the application number 201610419636.9 discloses a combined artificial subsurface flow wetland treatment system for enhanced nitrogen and phosphorus removal. This invention removes suspended pollutants in sewage through screens, and uses microorganisms, plants, and matrix adsorption to remove nitrogen and phosphorus. , but when the organic matter in the sewage influent is insufficient, it is difficult to carry out denitrification and denitrification, resulting in the deterioration of the effluent water quality.
因此,针对现有技术的不足,开发出一种集尾水预处理、组合湿地脱氮除磷系统为一体、节能降耗、与景观相结合,既能达到当前尾水处理要求、又能满足未来尾水处理需求的湿地处理系统。Therefore, aiming at the deficiencies of existing technologies, a system integrating tail water pretreatment and combined wetland denitrification and phosphorus removal is developed, which can save energy and reduce consumption, and combine with landscape, which can not only meet the current tail water treatment requirements, but also meet the Wetland treatment system for future tail water treatment needs.
发明内容Contents of the invention
技术问题:本发明的目的是提供一种组合式多功能尾水深度脱氮除磷人工湿地系统,通过区域之间的相互组合来处理尾水,使其进一步达到《地表水环境质量标准》(GB3838-2002)的相关要求,满足未来水处理的趋势。Technical problem: The purpose of this invention is to provide a combined multifunctional tail water deep denitrification and phosphorus removal artificial wetland system, through the mutual combination between areas to treat the tail water, so that it can further meet the "Environmental Quality Standards for Surface Water" ( GB3838-2002) to meet the relevant requirements of future water treatment trends.
为实现上述目的,本发明提供如下技术方案:To achieve the above object, the present invention provides the following technical solutions:
一种组合式多功能尾水深度脱氮除磷人工湿地系统,尾水通过相互独立的预处理功能区和深度脱氮除磷处理功能区。在所述各功能区之间组合处理尾水,各功能区间尾水通过隔板溢流进入下一个功能区。A combined multifunctional tail water deep nitrogen and phosphorus removal artificial wetland system, the tail water passes through independent pretreatment functional areas and deep nitrogen and phosphorus removal treatment functional areas. The tail water is treated in combination between the functional areas, and the tail water in each functional area overflows through the partition and enters the next functional area.
根据以上方案,尾水依次通过所述预处理功能区水解酸化区(1)、生物质填料放置区(2)。According to the above scheme, the tail water sequentially passes through the pretreatment functional zone hydrolysis acidification zone (1) and the biomass filler placement zone (2).
根据以上方案,所述水解酸化区(1)内竖向设置单元直径为150mm,长度为0.9m的双圈聚丙烯生物挂膜组合填料,尾水通过水解酸化区(1)底部导流槽进入生物质填料放置区(2),生物质填料放置区(2)内横向设置尺寸为25cm*25cm的带孔隔板,隔板上每隔 3cm开直径为3cm圆孔,隔板上放置由聚酰胺纤维包裹的生物质填料,释放有机碳源为微生物所利用,有利于尾水反硝化的进行。According to the above scheme, in the hydrolytic acidification zone (1), the unit diameter is 150mm and the length is 0.9m, and the double-circle polypropylene biofilm composite filler is vertically arranged, and the tail water enters through the diversion groove at the bottom of the hydrolysis acidification zone (1). The biomass filler placement area (2), the biomass filler placement area (2) is horizontally provided with a partition with a size of 25cm*25cm, the partition is opened with a diameter of 3cm round holes every 3cm, and the partition is placed on the partition. The biomass filler wrapped by amide fiber releases organic carbon source for the use of microorganisms, which is conducive to the denitrification of tail water.
根据以上方案,该系统采用多点进水,尾水进水管分别通过水解酸化区进水管(7),生物质填料放置区进水管(8),反硝化湿地区进水管(9),反硝化湿地区进水管(10)依次连接水解酸化区(1)、生物质填料放置区(2)、反硝化湿地区(3)、反硝化湿地区(5),每个进水口都与不锈钢丝扣闸阀连接,用来调节进水流量,使每个进水口流量为Q/4。其中在反硝化湿地区(3)、硝化湿地区(4)、反硝化湿地区(5)设置阻流板,使尾水能够溢流进入下一区,尾水通过溢流管进入反硝化湿地区(3)、硝化湿地区(4)、反硝化湿地区(5)、强化除磷区(6),最后尾水通过强化除磷区(6)底部设置的出水管(11)出水。According to the above plan, the system adopts multi-point water intake, and the tail water inlet pipe respectively passes through the water inlet pipe (7) of the hydrolysis acidification area, the water inlet pipe (8) of the biomass filler placement area, the water inlet pipe (9) of the denitrification wet area, and the water inlet pipe of the denitrification area. The water inlet pipe (10) in the wet area is sequentially connected to the hydrolytic acidification area (1), the biomass filler placement area (2), the denitrification wet area (3), and the denitrification wet area (5). Each water inlet is connected with a stainless steel thread The gate valve is connected to adjust the water flow so that the flow of each water inlet is Q/4. Among them, baffle plates are set in the denitrification wet area (3), nitrification wet area (4), and denitrification wet area (5), so that the tail water can overflow into the next area, and the tail water enters the denitrification wet area through the overflow pipe. area (3), nitrification wet area (4), denitrification wet area (5), enhanced phosphorus removal area (6), and finally the tail water is discharged through the outlet pipe (11) provided at the bottom of the enhanced phosphorus removal area (6).
根据以上方案,尾水通过所述反硝化湿地区(3)、反硝化湿地区(5)时均在该区域顶部嵌置可移动的尺寸为25cm*25cm的PVC材质顶盖(12)、(13)。According to the above scheme, when the tail water passes through the denitrification wet area (3) and the denitrification wet area (5), a removable PVC material top cover (12) with a size of 25cm*25cm is embedded on the top of the area, ( 13).
根据以上方案,尾水通过所述反硝化湿地区(3)时,在区域内设置高度为70cm、粒径为25mm聚丙烯材质的塑料球组合填料。According to the above scheme, when the tail water passes through the wet denitrification area (3), plastic ball composite fillers with a height of 70 cm and a particle size of 25 mm made of polypropylene are set in the area.
根据以上方案,尾水通过所述硝化湿地区(4)、强化除磷区(6)时,区域内部均通过自然沉降自下而上依次形成第一填料区、第二填料区、第三填料区,所述硝化湿地区(4) 分别填充厚度为30cm粒径为2-5mm的砾石填料层、厚度为20cm粒径为1-3mm的改性沸石填料层和厚度为20cm粒径为1-2mm的细沙填料层,强化除磷区(6)分别填充厚度为30cm 粒径为2-5mm的砾石填料层、厚度为20cm粒径为1-3mm的高钙粉煤灰陶粒和硫铁复合填料和厚度为20cm粒径为1-2mm的细沙填料层。According to the above plan, when the tail water passes through the nitrification wet area (4) and the enhanced phosphorus removal area (6), the first packing area, the second packing area, and the third packing area are sequentially formed from bottom to top inside the area through natural settlement. District, the nitrification wet area (4) is respectively filled with a thickness of 30cm with a particle diameter of 2-5mm gravel filler layer, a thickness of 20cm with a particle diameter of 1-3mm modified zeolite filler layer and a thickness of 20cm with a particle diameter of 1-3mm 2mm fine sand packing layer, the enhanced phosphorus removal zone (6) is filled with a gravel packing layer with a thickness of 30cm and a particle size of 2-5mm, and a 20cm-thick high-calcium fly ash ceramsite and sulfur iron with a particle size of 1-3mm Composite filler and fine sand filler layer with a thickness of 20cm and a particle size of 1-2mm.
根据以上方案,尾水通过所述反硝化湿地区(5)时,在区域内设置高度为70cm粒径为2cm的聚丙烯移动床生物流化床填料。According to the above scheme, when the tail water passes through the denitrification wet area (5), a polypropylene moving bed biological fluidized bed filler with a height of 70 cm and a particle size of 2 cm is set in the area.
根据以上方案,尾水通过所述硝化湿地区(4)、强化除磷区(6)时,均在区域内种植对氮磷等污染物有较高去除效果、易于收割,且收割后可作为生物质碳源能释放较高COD、较低总氮的湿地植物。According to the above scheme, when the tail water passes through the nitrification wet area (4) and the enhanced phosphorus removal area (6), planting in the area has a high removal effect on pollutants such as nitrogen and phosphorus, is easy to harvest, and can be used as Biomass carbon source can release wetland plants with higher COD and lower total nitrogen.
根据以上方案,尾水通过所述生物质填料放置区(2)时,区域内聚酰胺纤维包裹的生物质填料,可由所述硝化湿地区(4)、强化除磷区(6)种植的湿地植物收割得到。According to the above scheme, when the tail water passes through the biomass filler placement area (2), the biomass filler wrapped by polyamide fiber in the area can be planted by the nitrification wet area (4) and the enhanced phosphorus removal area (6). Plants are harvested.
有益效果:本发明具有下述特点:Beneficial effect: the present invention has following characteristics:
(1)该系统能保证有效的进一步去除尾水中的氮、磷等污染物。(1) The system can ensure the effective further removal of nitrogen, phosphorus and other pollutants in the tail water.
(2)该系统能够使尾水经过生物质填料放置区(2),提高尾水碳氮比,为微生物反硝化提供碳源。(2) The system can make the tail water pass through the biomass filler placement area (2), increase the carbon-nitrogen ratio of the tail water, and provide carbon source for microbial denitrification.
(3)该系统在水解酸化区(1)的生物挂膜组合填料,利用填料既能有效切割气泡,提高氧的转移速率和利用率,增强尾水脱氮除磷能力。(3) In the hydrolytic acidification zone (1), the bio-film composite filler of the system can effectively cut air bubbles, improve the transfer rate and utilization rate of oxygen, and enhance the nitrogen and phosphorus removal capacity of tail water.
(4)该系统在强化除磷区(6)内填料对磷元素有较强的去除效果,进一步提高了出水水质。(4) In the enhanced phosphorus removal zone (6) of the system, the filler has a strong removal effect on phosphorus, which further improves the quality of the effluent.
附图说明Description of drawings
下面结合附图对本发明进行进一步说明。The present invention will be further described below in conjunction with the accompanying drawings.
该图为一种组合式多功能尾水深度脱氮除磷人工湿地系统示意图。This figure is a schematic diagram of a combined multi-functional tail water deep nitrogen and phosphorus removal constructed wetland system.
其中有:水解酸化区(1),生物质填料放置区(2),反硝化湿地区(3),硝化湿地区(4),反硝化湿地区(5),强化除磷区(6),水解酸化区进水管(7),生物质填料放置区进水管(8),反硝化湿地区进水管(9),反硝化湿地区进水管(10),出水管(11),反硝化湿地区顶盖(12),反硝化湿地区顶盖(13)。Among them are: hydrolytic acidification area (1), biomass filler placement area (2), denitrification wet area (3), nitrification wet area (4), denitrification wet area (5), enhanced phosphorus removal area (6), Water inlet pipe for hydrolysis acidification area (7), water inlet pipe for biomass filler placement area (8), water inlet pipe for denitrification wet area (9), water inlet pipe for denitrification wet area (10), water outlet pipe (11), denitrification wet area The top cover (12), the top cover (13) of the denitrification wet area.
具体实施方式Detailed ways
本发明是一种组合式多功能尾水深度脱氮除磷人工湿地系统,尾水依次通过水解酸化区 (1)、生物质填料放置区(2)、反硝化湿地区(3)、硝化湿地区(4)、反硝化湿地区(5)、强化除磷区(6)进行深度处理。尾水进水管分别通过水解酸化区进水管(7),生物质填料放置区进水管(8),反硝化湿地区进水管(9),反硝化湿地区进水管(10)依次进入水解酸化区(1)、生物质填料放置区(2)、反硝化湿地区(3)、反硝化湿地区(5),进水流量均为 Q/4。尾水通过水解酸化区(1)底部导流槽进入生物质填料放置区(2),在反硝化湿地区(3)、硝化湿地区(4)、反硝化湿地区(5)设置阻流板,使尾水能够溢流进入下一区,尾水通过溢流管进入反硝化湿地区(3)、硝化湿地区(4)、反硝化湿地区(5)、强化除磷区(6),最后尾水通过强化除磷区(6)底部设置的出水管(11)出水。The invention is a combined multifunctional tail water deep denitrification and phosphorus removal artificial wetland system. The tail water passes through the hydrolysis and acidification area (1), the biomass filler placement area (2), the denitrification wet area (3), and the nitrification wet area in sequence. Area (4), denitrification wet area (5), enhanced phosphorus removal area (6) for advanced treatment. The tail water inlet pipe respectively passes through the water inlet pipe (7) of the hydrolysis acidification area, the water inlet pipe (8) of the biomass filler placement area, the water inlet pipe (9) of the denitrification wet area, and the water inlet pipe (10) of the denitrification wet area respectively enters the hydrolysis acidification area (1), biomass filler placement area (2), denitrification wet area (3), denitrification wet area (5), the influent flow rate is Q/4. The tail water enters the biomass filler placement area (2) through the diversion groove at the bottom of the hydrolysis acidification area (1), and baffles are installed in the denitrification wet area (3), nitrification wet area (4), and denitrification wet area (5) , so that the tail water can overflow into the next area, and the tail water enters the denitrification wet area (3), the nitrification wet area (4), the denitrification wet area (5), and the enhanced phosphorus removal area (6) through the overflow pipe. Finally, the tail water is discharged through the outlet pipe (11) provided at the bottom of the enhanced phosphorus removal zone (6).
尾水进入水解酸化区(1)与直径为150mm,长度为0.9m的生物挂膜组合填料充分接触,该组合填料既能挂膜,又能有效切割气泡,提高氧的转移速率和利用率,使水气生物膜得到充分交换,使水中的有机物得到高效处理,同时挂膜微生物可有效利用尾水氮磷元素作为自身营养物质。尾水通过底部导流槽进入生物质填料放置区(2),生物质填料可以大量释放有机物增加尾水的碳氮比,改善尾水的可生化性,为后续反硝化脱氮提供有利条件。尾水通过反硝化湿地区(3)高度为70cm、直径为25mm聚丙烯材质的塑料球组合填料,在厌氧条件下进行生物脱氮。尾水以溢流方式进入硝化湿地区(4),通过填充高度为30cm的砾石填料层、高度为20cm的改性沸石填料层和高度为20cm的细沙填料层,期间进行硝化反应。尾水以溢流方式进入反硝化湿地区(5),通过高度为70cm的,直径为2cm的聚丙烯移动床生物流化床填料,在缺氧好氧交替条件下进行硝化反硝化反应。尾水以溢流方式进入强化除磷区(6),在好氧条件下去除水中有机物,同时通过强化除磷区(6)内除磷填料高钙粉煤灰陶粒和硫铁复合填料,去除含磷污染物,使尾水水质进一步提升。最后经过净化后的尾水从出水管11排出。The tail water enters the hydrolysis and acidification zone (1) and fully contacts with the biofilm-hanging composite filler with a diameter of 150mm and a length of 0.9m. The composite filler can not only hang a membrane, but also effectively cut air bubbles, improve the transfer rate and utilization rate of oxygen, The water-air biofilm can be fully exchanged, and the organic matter in the water can be efficiently treated. At the same time, the membrane-hanging microorganisms can effectively use the nitrogen and phosphorus elements of the tail water as their own nutrients. The tail water enters the biomass filler placement area (2) through the bottom diversion tank. The biomass filler can release a large amount of organic matter to increase the carbon-nitrogen ratio of the tail water, improve the biodegradability of the tail water, and provide favorable conditions for subsequent denitrification and denitrification. The tail water passes through the denitrification wet area (3) with a height of 70cm and a diameter of 25mm made of polypropylene plastic balls to perform biological denitrification under anaerobic conditions. The tail water enters the nitrification wet area (4) by way of overflow, and is filled with a gravel packing layer with a height of 30 cm, a modified zeolite packing layer with a height of 20 cm, and a fine sand packing layer with a height of 20 cm, during which nitrification takes place. The tail water enters the denitrification wet area (5) by way of overflow, passes through the polypropylene moving bed biofluidized bed filler with a height of 70 cm and a diameter of 2 cm, and performs nitrification and denitrification reaction under alternating conditions of anoxic and aerobic. The tail water enters the enhanced dephosphorization zone (6) through overflow, and removes organic matter in the water under aerobic conditions. At the same time, through the enhanced dephosphorization zone (6) filled with high-calcium fly ash ceramsite and sulfur-iron composite filler, Phosphorus-containing pollutants are removed to further improve the quality of tail water. Finally, the purified tail water is discharged from the outlet pipe 11.
在硝化湿地区(4)、强化除磷区(6)可以种植菖蒲、风车草、水葫芦、灯芯草、水葱等湿地植物。生物质填料放置区2区域内由聚酰胺纤维包裹的生物质填料,可由硝化湿地区4、强化除磷区6种植的湿地植物收割得到。Wetland plants such as calamus, windmill grass, water hyacinth, rush grass, water onion and the like can be planted in the nitrification wet area (4) and the enhanced phosphorus removal area (6). The biomass filler wrapped by polyamide fibers in the biomass filler placement area 2 can be harvested from the wetland plants planted in the nitrification wet area 4 and the enhanced phosphorus removal area 6 .
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