CN110079015A - Toilet lid and preparation method thereof with hydrophobic function - Google Patents
Toilet lid and preparation method thereof with hydrophobic function Download PDFInfo
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- CN110079015A CN110079015A CN201910391078.3A CN201910391078A CN110079015A CN 110079015 A CN110079015 A CN 110079015A CN 201910391078 A CN201910391078 A CN 201910391078A CN 110079015 A CN110079015 A CN 110079015A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of toilet lid with hydrophobic function, it is related to a kind of toilet lid, the toilet lid is made of polypropylene A, polypropylene B, polypropylene C, fire retardant, new aqua, talcum powder, antioxidant, titanium dioxide, black powder, titan yellow and iron coffee, this toilet lid has certain hydrophobic effect, in the actual use process, spot or dirt can be effectively avoided to be infected with onto toilet lid, it can guarantee the cleaning of toilet lid, beautiful effect can also be brought simultaneously, bring many convenience to user.
Description
Technical field
The present invention relates to a kind of toilet lid, and in particular to a kind of toilet lid and preparation method thereof with hydrophobic function.
Background technique
In recent years, hydrophobic surface material causes the extensive concern of inside and outside every profession and trade scientific worker.Common hydrophobic material
Material refers to water droplet contact angle CA that greater than 150 °, roll angle, hydrophobic surface is typically characterised by less than 5 °: being molten by water or with water
The drop of agent is placed on hydrophobic surface, will form spherical water (liquid) pearl, as long as by the angle of surface inclination very little or in gentle breeze
Under the action of, water (liquid) pearl can quickly roll off from super hydrophobic surface, and the dirts such as the dust on surface are taken away while tumbling, and play certainly
Cleaning action, in addition, hydrophobic surface also has excellent anticorrosion, anti-ice jelly and waterproofness etc..Therefore can be used for steel bar anti-corrosion,
Timber is moisture-proof and the fields such as self-cleaning surface.
But existing toilet lid is essentially all to be made using common plastic material, during use,
It often will appear spot or dirt, and cleaning up is more troublesome, bring inconvenience to user, in order to solve above-mentioned skill
Art problem, spy propose a kind of new technical solution.
Summary of the invention
The toilet lid and preparation method thereof with hydrophobic function that the purpose of the present invention is to provide a kind of, to solve above-mentioned back
The problem of being proposed in scape technology.
To achieve the above object, the invention provides the following technical scheme: a kind of toilet lid with hydrophobic function, the closestool
Lid is by polypropylene A, polypropylene B, polypropylene C, fire retardant, new aqua, talcum powder, antioxidant, titanium dioxide, black powder, titan yellow and iron
Coffee composition, the parts by weight of the toilet lid each component are polypropylene A10-15 parts, B50-70 parts of polypropylene, C5-10 parts of polypropylene,
1-3 parts of fire retardant, aqua 1-3 parts new, 1-5 parts of talcum powder, 0.01-0.03 parts of antioxidant, 1-5 parts of titanium dioxide, black powder 0.1-1
Part, 0.1-1 parts of titan yellow and 0.1-2 parts of iron coffee compositions.
The parts by weight of the toilet lid each component be polypropylene A11-14 parts, B51-68 parts of polypropylene, C6-8 parts of polypropylene,
1.5-2.8 parts of fire retardant, aqua 1.1-2.9 parts new, 1.1-4.6 parts of talcum powder, 0.01-0.03 parts of antioxidant, titanium dioxide 1.1-3
Part, powder 0.1-0.8 parts black, 0.1-0.7 parts of titan yellow and 0.1-1.5 parts of iron coffee compositions.
The parts by weight of the toilet lid each component are polypropylene A13.98 parts, B66 parts of polypropylene, polypropylene C8.5
Part, 1.5 parts of fire retardant, 2 parts of new aqua, 3 parts of talcum powder, 0.02 part of antioxidant, 3.2 parts of titanium dioxide, 0.5 part of black powder, titan yellow 0.7
Part and 0.6 part of iron coffee composition.
The model PP150 powder of the polypropylene A；The model PPH1500 of the polypropylene B；Described poly- third
The model PP8025 of alkene C；The model HSF918 of fire retardant；The model RL105 of the new aqua；The antioxidant
Model 1010；The model R69 of the titanium dioxide；The model 660R of the black powder；The model of the titan yellow
For K2001；The model 130 of the iron coffee.
The fire retardant is made of urea, diammonium hydrogen phosphate and borax, and the parts by weight of the fire retardant each component are urine
1-5 parts plain, 2-3 parts of diammonium hydrogen phosphate and 1-5 parts of borax.
The antioxidant is tetrapentaerythritol ester, 2, and 2 '-methylene-bis-, triethylene-glycol be double or the double β-of triethylene glycol
(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester or bis- [3- (3, the 5- di-tert-butyl-hydroxy phenyl) propionic acid of hexylene glycol
Ester].
A kind of preparation method of the toilet lid with hydrophobic function, method includes the following steps:
Step 1: configuration material A: preparing a container A, polypropylene A, fire retardant, talcum powder and titanium are added in container A
Then white powder is stirred mixing to it by agitating device, the revolving speed of agitating device is 100 revolutions per seconds at this time, and mixing time is
3 minutes, then container A is placed on heating device, container A is heated by heating device, while to inside container A
Water is added, the heating temperature of heating device is 60 DEG C at this time, and heating time is 10 minutes；
Step 2: configuration material B: preparing a container B, polypropylene B, antioxidant and titan yellow are added in container B, then
It is stirred by agitating device, the revolving speed of agitating device is 10 revolutions per seconds at this time, and mixing time is 10 minutes；
Step 3: configuration material C: preparing a container C, the material A half that configuration is completed is poured into container C
Then portion, while new aqua and iron coffee being added in container C is stirred for uniformly, at the same place carry out under conditions of room temperature it is quiet
It sets, time of repose is 5 hours；
Step 4: toilet lid configures: preparing a container D, remaining half material A is poured into container D, is poured into simultaneously
Material B, then heats container, and the temperature heated at this time is 70 DEG C, while being stirred by agitating device, to be mixed
After uniformly, material C is added, then stops heating, agitating device does not stop working, is monitored at this time to temperature, drops to temperature
When as low as 30 DEG C, polypropylene C, black powder and iron coffee is added, is stirred simultaneously, the revolving speed of agitating device is 10 revolutions per seconds at this time, so
It is poured into the mold of production toilet lid afterwards, forms toilet lid.
Compared with prior art, the beneficial effects of the present invention are: this toilet lid has certain hydrophobic effect, actual
In use process, it can effectively avoid spot or dirt from being infected with onto toilet lid, can guarantee the cleaning of toilet lid, simultaneously
Beautiful effect can also be brought, brings many convenience to user.
Specific embodiment
Invention is further explained in conjunction with specific embodiments:
Embodiment one
A kind of toilet lid with hydrophobic function, the parts by weight of the toilet lid each component are polypropylene A10-15 parts, gather
It is B50 parts of propylene, C5 parts of polypropylene, 1 part of fire retardant, 1 part of new aqua, 1 part of talcum powder, 0.01 part of antioxidant, 1 part of titanium dioxide, black
0.1 part of powder, 0.1 part of titan yellow and 0.1 part of iron coffee composition；The model PP150 powder of the polypropylene A；The polypropylene B's
Model PPH1500；The model PP8025 of the polypropylene C；The model HSF918 of fire retardant；The new aqua
Model RL105；The model 1010 of the antioxidant；The model R69 of the titanium dioxide；The model of the black powder
For 660R；The model K2001 of the titan yellow；The model 130 of the iron coffee.The parts by weight of the fire retardant each component
For 1 part of urea, 2 parts of diammonium hydrogen phosphate and 1 part of borax.The antioxidant is tetrapentaerythritol ester, 2,2 '-methylene-bis-, two
Contracting triethylene glycol pair or double β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic esters of triethylene glycol or the bis- [3- (3,5- of hexylene glycol
Di-tert-butyl-hydroxy phenyl) propionic ester].
Embodiment two
A kind of toilet lid with hydrophobic function, the parts by weight of the toilet lid each component are polypropylene A13.98
Part, B66 parts of polypropylene, C8.5 parts of polypropylene, 1.5 parts of fire retardant, 2 parts of new aqua, 3 parts of talcum powder, 0.02 part of antioxidant, titanium white
3.2 parts of powder, 0.5 part of black powder, 0.7 part of titan yellow and 0.6 part of iron coffee composition；The model PP150 powder of the polypropylene A；It is described
Polypropylene B model PPH1500；The model PP8025 of the polypropylene C；The model HSF918 of fire retardant；Institute
The model RL105 for the new aqua stated；The model 1010 of the antioxidant；The model R69 of the titanium dioxide；It is described
Black powder model 660R；The model K2001 of the titan yellow；The parts by weight of the fire retardant each component be 1 part of urea,
2 parts of diammonium hydrogen phosphate and 1 part of borax.The antioxidant is tetrapentaerythritol ester, 2,2 '-methylene-bis-, triethylene-glycol
Double β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic esters of double or triethylene glycol or bis- [3- (3, the 5- di-t-butyl -4- of hexylene glycol
Hydroxy phenyl) propionic ester].
Embodiment three
A kind of toilet lid with hydrophobic function, the parts by weight of the toilet lid each component are polypropylene A15 parts, polypropylene
B70 parts, C10 parts of polypropylene, 3 parts of fire retardant, 3 parts of new aqua, 5 parts of talcum powder, 0.03 part of antioxidant, 5 parts of titanium dioxide, black powder 1
Part, 1 part of titan yellow and 2 parts of iron coffee compositions；The model PP150 powder of the polypropylene A；The model of the polypropylene B
PPH1500；The model PP8025 of the polypropylene C；The model HSF918 of fire retardant；The model of the new aqua
RL105；The model 1010 of the antioxidant；The model R69 of the titanium dioxide；The model of the black powder
660R；The model K2001 of the titan yellow；The model 130 of the iron coffee.The parts by weight of the fire retardant each component are
5 parts of urea, 3 parts of diammonium hydrogen phosphate and 5 parts of borax.The antioxidant is tetrapentaerythritol ester, 2,2 '-methylene-bis-, two contractings
Triethylene glycol pair or double β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic esters of triethylene glycol or the bis- [3- (3,5- bis- of hexylene glycol
Tert-butyl-hydroxy phenyl) propionic ester].
Three above embodiment is all made of following methods and is prepared:
A kind of preparation method of the toilet lid with hydrophobic function, method includes the following steps:
Step 1: configuration material A: preparing a container A, polypropylene A, fire retardant, talcum powder and titanium are added in container A
Then white powder is stirred mixing to it by agitating device, the revolving speed of agitating device is 100 revolutions per seconds at this time, and mixing time is
3 minutes, then container A is placed on heating device, container A is heated by heating device, while to inside container A
Water is added, the heating temperature of heating device is 60 DEG C at this time, and heating time is 10 minutes；
Step 2: configuration material B: preparing a container B, polypropylene B, antioxidant and titan yellow are added in container B, then
It is stirred by agitating device, the revolving speed of agitating device is 10 revolutions per seconds at this time, and mixing time is 10 minutes；
Step 3: configuration material C: preparing a container C, the material A half that configuration is completed is poured into container C
Then portion, while new aqua and iron coffee being added in container C is stirred for uniformly, at the same place carry out under conditions of room temperature it is quiet
It sets, time of repose is 5 hours；
Step 4: toilet lid configures: preparing a container D, remaining half material A is poured into container D, is poured into simultaneously
Material B, then heats container, and the temperature heated at this time is 70 DEG C, while being stirred by agitating device, to be mixed
After uniformly, material C is added, then stops heating, agitating device does not stop working, is monitored at this time to temperature, drops to temperature
When as low as 30 DEG C, polypropylene C, black powder and iron coffee is added, is stirred simultaneously, the revolving speed of agitating device is 10 revolutions per seconds at this time, so
It is poured into the mold of production toilet lid afterwards, forms toilet lid.
Using effect experiment:
This research is continuously tried out one month by 100 people, investigates the effect of the hydrophobic toilet lid various aspects.Test item
Standards of grading are as follows: very satisfied 5 points, be satisfied with 4 points, general 3 points, be unsatisfied with 2 points, very dissatisfied 1 point.Wherein common group is general
Logical toilet lid；
Can explicitly it be found out by the above effect, the hydrophobic toilet lid of the present invention has good hydrophobicity, has simultaneously
Easy effect is cleaned, while peculiar smell not yet, environment is polluted not yet after long-time use, using effect is all good, can
It is satisfied with the demand of user.
For those skilled in the art, it is various corresponding that other can be made according to above technical scheme and design
Change and deformation, and all these change and modification all should belong within the scope of protection of the claims of the present invention.
Claims (7)
1. a kind of toilet lid with hydrophobic function, it is characterised in that: the toilet lid by polypropylene A, polypropylene B, polypropylene C,
Fire retardant, new aqua, talcum powder, antioxidant, titanium dioxide, black powder, titan yellow and iron coffee composition, the parts by weight of the toilet lid each component
Number is polypropylene A10-15 parts, B50-70 parts of polypropylene, C5-10 parts of polypropylene, 1-3 parts of fire retardant, aqua 1-3 parts new, talcum
0.1-2 parts of 1-5 parts of powder, 0.01-0.03 parts of antioxidant, 1-5 parts of titanium dioxide, powder 0.1-1 parts black, 0.1-1 parts of titan yellow and iron coffee groups
At.
2. the toilet lid according to claim 1 with hydrophobic function, it is characterised in that: the weight of the toilet lid each component
Number is polypropylene A11-14 parts, B51-68 parts of polypropylene, C6-8 parts of polypropylene, 1.5-2.8 parts of fire retardant, new aqua 1.1-
2.9 parts, 1.1-4.6 parts of talcum powder, 0.01-0.03 parts of antioxidant, 1.1-3 parts of titanium dioxide, powder 0.1-0.8 parts black, titan yellow 0.1-
0.7 part and 0.1-1.5 parts of iron coffee composition.
3. the toilet lid according to claim 1 or 2 with hydrophobic function, it is characterised in that: described toilet lid is each
The parts by weight of component are polypropylene A13.98 parts, B66 parts of polypropylene, C8.5 parts of polypropylene, 1.5 parts of fire retardant, new aqua 2
Part, 3 parts of talcum powder, 0.02 part of antioxidant, 3.2 parts of titanium dioxide, 0.5 part of black powder, 0.7 part of titan yellow and 0.6 part of iron coffee composition.
4. the toilet lid according to claim 1 or 2 with hydrophobic function, it is characterised in that: the type of the polypropylene A
Number be PP150 powder；The model PPH1500 of the polypropylene B；The model PP8025 of the polypropylene C；Fire retardant
Model HSF918；The model RL105 of the new aqua；The model 1010 of the antioxidant；The titanium dioxide
Model R69；The model 660R of the black powder；The model K2001 of the titan yellow；The model of the iron coffee
130。
5. the toilet lid according to claim 1 or 2 with hydrophobic function, it is characterised in that: the fire retardant is by urinating
Element, diammonium hydrogen phosphate and borax composition, the parts by weight of the fire retardant each component are urea 1-5 parts, 2-3 parts of diammonium hydrogen phosphate and
1-5 parts of borax.
6. the toilet lid according to claim 1 or 2 with hydrophobic function, it is characterised in that: the antioxidant is four
Pentaerythritol ester, 2,2 '-methylene-bis-, triethylene-glycol be double or the double β-(3- tertiary butyl-4-hydroxy -5- methylbenzenes of triethylene glycol
Base) propionic ester or hexylene glycol it is bis- [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic ester].
7. a kind of preparation method of the toilet lid with hydrophobic function, it is characterised in that: method includes the following steps:
Step 1: configuration material A: preparing a container A, polypropylene A, fire retardant, talcum powder and titanium white are added in container A
Then powder is stirred mixing to it by agitating device, the revolving speed of agitating device is 100 revolutions per seconds at this time, mixing time 3
Minute, then container A is placed on heating device, container A is heated by heating device, while to inside container A
Water is added, the heating temperature of heating device is 60 DEG C at this time, and heating time is 10 minutes；
Step 2: configuration material B: preparing a container B, polypropylene B, antioxidant and titan yellow are added in container B, then passes through
Agitating device is stirred it, and the revolving speed of agitating device is 10 revolutions per seconds at this time, and mixing time is 10 minutes；
Step 3: configuration material C: prepare a container C, the material A half that configuration is completed is poured into inside container C,
New aqua and iron coffee are added in container C simultaneously, is then stirred for uniformly, while placing and being stood under conditions of room temperature,
Time of repose is 5 hours；
Step 4: toilet lid configures: preparing a container D, remaining half material A is poured into container D, while pouring into material
Then B heats container, the temperature heated at this time is 70 DEG C, while being stirred by agitating device, to be mixed uniform
Afterwards, material C is added, then stops heating, agitating device does not stop working, is monitored at this time to temperature, is reduced to temperature
At 30 DEG C, polypropylene C, black powder and iron coffee is added, is stirred simultaneously, the revolving speed of agitating device is 10 revolutions per seconds at this time, then will
In its mold for being poured into production toilet lid, form toilet lid.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910391078.3A CN110079015A (en) | 2019-05-11 | 2019-05-11 | Toilet lid and preparation method thereof with hydrophobic function |
| CN201911391257.3A CN111995814A (en) | 2019-05-11 | 2019-12-30 | Easy-to-clean polypropylene material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910391078.3A CN110079015A (en) | 2019-05-11 | 2019-05-11 | Toilet lid and preparation method thereof with hydrophobic function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110079015A true CN110079015A (en) | 2019-08-02 |
Family
ID=67419731
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910391078.3A Pending CN110079015A (en) | 2019-05-11 | 2019-05-11 | Toilet lid and preparation method thereof with hydrophobic function |
| CN201911391257.3A Pending CN111995814A (en) | 2019-05-11 | 2019-12-30 | Easy-to-clean polypropylene material and preparation method thereof |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201911391257.3A Pending CN111995814A (en) | 2019-05-11 | 2019-12-30 | Easy-to-clean polypropylene material and preparation method thereof |
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| CN (2) | CN110079015A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718541A (en) * | 2020-07-03 | 2020-09-29 | 东莞市亿家卫浴科技有限公司 | Toilet lid and processing method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106674753A (en) * | 2016-12-26 | 2017-05-17 | 上海普利特复合材料股份有限公司 | Surface-hydrophobic polypropylene aesthetic resin composite and preparation method thereof |
-
2019
- 2019-05-11 CN CN201910391078.3A patent/CN110079015A/en active Pending
- 2019-12-30 CN CN201911391257.3A patent/CN111995814A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718541A (en) * | 2020-07-03 | 2020-09-29 | 东莞市亿家卫浴科技有限公司 | Toilet lid and processing method thereof |
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| Publication number | Publication date |
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| CN111995814A (en) | 2020-11-27 |
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