CN110078154B - 从水性溶液除去氯和/或氯胺 - Google Patents
从水性溶液除去氯和/或氯胺 Download PDFInfo
- Publication number
- CN110078154B CN110078154B CN201910067312.7A CN201910067312A CN110078154B CN 110078154 B CN110078154 B CN 110078154B CN 201910067312 A CN201910067312 A CN 201910067312A CN 110078154 B CN110078154 B CN 110078154B
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- CN
- China
- Prior art keywords
- carbon
- sulfur
- chlorine
- chloramine
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000460 chlorine Substances 0.000 title claims abstract description 140
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 134
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 134
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical class ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 title claims abstract description 107
- 239000007864 aqueous solution Substances 0.000 title claims abstract description 54
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 299
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 258
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 127
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 119
- 239000011593 sulfur Substances 0.000 claims abstract description 116
- 239000011159 matrix material Substances 0.000 claims abstract description 97
- 238000000034 method Methods 0.000 claims abstract description 90
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 104
- 239000000758 substrate Substances 0.000 claims description 91
- 150000001875 compounds Chemical class 0.000 claims description 75
- 239000000376 reactant Substances 0.000 claims description 66
- 229910052757 nitrogen Inorganic materials 0.000 claims description 57
- 230000003647 oxidation Effects 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 16
- 238000005211 surface analysis Methods 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 43
- 229910052751 metal Inorganic materials 0.000 description 35
- 239000002184 metal Substances 0.000 description 35
- 239000000463 material Substances 0.000 description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 31
- 229910052760 oxygen Inorganic materials 0.000 description 31
- 239000001301 oxygen Substances 0.000 description 31
- 238000012360 testing method Methods 0.000 description 26
- 150000003839 salts Chemical class 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 21
- 239000000203 mixture Substances 0.000 description 21
- 238000010438 heat treatment Methods 0.000 description 20
- 239000001257 hydrogen Substances 0.000 description 20
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- 239000007788 liquid Substances 0.000 description 19
- 239000002245 particle Substances 0.000 description 19
- 239000012530 fluid Substances 0.000 description 17
- 239000011148 porous material Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 14
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 14
- 238000001914 filtration Methods 0.000 description 13
- 150000002431 hydrogen Chemical class 0.000 description 13
- -1 hypochlorite ions Chemical class 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 230000009467 reduction Effects 0.000 description 12
- 238000011282 treatment Methods 0.000 description 12
- 239000000356 contaminant Substances 0.000 description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
- 150000001450 anions Chemical class 0.000 description 10
- 238000007669 thermal treatment Methods 0.000 description 10
- 239000002023 wood Substances 0.000 description 10
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- 235000013162 Cocos nucifera Nutrition 0.000 description 7
- 244000060011 Cocos nucifera Species 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 7
- 238000009838 combustion analysis Methods 0.000 description 7
- 239000000645 desinfectant Substances 0.000 description 7
- 238000009792 diffusion process Methods 0.000 description 7
- 239000003651 drinking water Substances 0.000 description 7
- 235000020188 drinking water Nutrition 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 7
- 239000012085 test solution Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
- 229910052753 mercury Inorganic materials 0.000 description 6
- 229910052976 metal sulfide Inorganic materials 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229920010741 Ultra High Molecular Weight Polyethylene (UHMWPE) Polymers 0.000 description 5
- 239000003570 air Substances 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Substances C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000011550 stock solution Substances 0.000 description 5
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 5
- 229910019093 NaOCl Inorganic materials 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 229960002135 sulfadimidine Drugs 0.000 description 4
- ASWVTGNCAZCNNR-UHFFFAOYSA-N sulfamethazine Chemical compound CC1=CC(C)=NC(NS(=O)(=O)C=2C=CC(N)=CC=2)=N1 ASWVTGNCAZCNNR-UHFFFAOYSA-N 0.000 description 4
- 150000003462 sulfoxides Chemical class 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000009296 electrodeionization Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000012943 hotmelt Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 3
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000005180 public health Effects 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 125000004434 sulfur atom Chemical group 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- DXHPZXWIPWDXHJ-UHFFFAOYSA-N carbon monosulfide Chemical compound [S+]#[C-] DXHPZXWIPWDXHJ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
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- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000000502 dialysis Methods 0.000 description 2
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- 229920001903 high density polyethylene Polymers 0.000 description 2
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- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
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- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 2
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- BRNULMACUQOKMR-UHFFFAOYSA-N thiomorpholine Chemical compound C1CSCCN1 BRNULMACUQOKMR-UHFFFAOYSA-N 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
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- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 1
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
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- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
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- 235000007079 manganese sulphate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- CYRPECJLOQEQDX-UHFFFAOYSA-N oxo(sulfanylidene)molybdenum Chemical compound O=[Mo]=S CYRPECJLOQEQDX-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 229940116357 potassium thiocyanate Drugs 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- WHMDPDGBKYUEMW-UHFFFAOYSA-N pyridine-2-thiol Chemical compound SC1=CC=CC=N1 WHMDPDGBKYUEMW-UHFFFAOYSA-N 0.000 description 1
- 239000007845 reactive nitrogen species Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 description 1
- NYPFJVOIAWPAAV-UHFFFAOYSA-N sulfanylideneniobium Chemical compound [Nb]=S NYPFJVOIAWPAAV-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003553 thiiranes Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
- C02F1/4695—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis electrodeionisation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Removal Of Specific Substances (AREA)
- Carbon And Carbon Compounds (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361777010P | 2013-03-12 | 2013-03-12 | |
| US61/777,010 | 2013-03-12 | ||
| US201361875998P | 2013-09-10 | 2013-09-10 | |
| US61/875,998 | 2013-09-10 | ||
| CN201480014995.5A CN105073646A (zh) | 2013-03-12 | 2014-03-05 | 从水性溶液除去氯和/或氯胺 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480014995.5A Division CN105073646A (zh) | 2013-03-12 | 2014-03-05 | 从水性溶液除去氯和/或氯胺 |
Publications (2)
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|---|---|
| CN110078154A CN110078154A (zh) | 2019-08-02 |
| CN110078154B true CN110078154B (zh) | 2022-02-22 |
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| CN201910067312.7A Active CN110078154B (zh) | 2013-03-12 | 2014-03-05 | 从水性溶液除去氯和/或氯胺 |
| CN201480014995.5A Pending CN105073646A (zh) | 2013-03-12 | 2014-03-05 | 从水性溶液除去氯和/或氯胺 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480014995.5A Pending CN105073646A (zh) | 2013-03-12 | 2014-03-05 | 从水性溶液除去氯和/或氯胺 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20160023920A1 (enExample) |
| EP (1) | EP2969963A1 (enExample) |
| JP (1) | JP6611698B2 (enExample) |
| KR (1) | KR102239099B1 (enExample) |
| CN (2) | CN110078154B (enExample) |
| AU (1) | AU2014249631B2 (enExample) |
| BR (1) | BR112015022828A2 (enExample) |
| CA (1) | CA2905823A1 (enExample) |
| WO (1) | WO2014164120A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| BR112015005051B1 (pt) * | 2012-09-11 | 2020-04-07 | 3M Innovative Properties Co | método para remoção de cloramina de soluções aquosas |
| EP2969974B1 (en) * | 2013-03-12 | 2019-08-28 | 3M Innovative Properties Company | Removal of chloramine and mercury from aqueous solutions |
| BR112015022508A2 (pt) * | 2013-03-12 | 2017-07-18 | 3M Innovative Properties Co | remoção de compostos orgânicos e cloramina de soluções aquosas |
| US10640406B2 (en) | 2016-05-17 | 2020-05-05 | Texas Tech University System | Surface modification of zero valent iron material for enhanced reactivity for degrading chlorinated contaminants in water |
| JP7269695B2 (ja) * | 2017-02-13 | 2023-05-09 | カルゴン カーボン コーポレーション | クロラミンおよび塩素除去材料およびその製造方法 |
| US10289315B2 (en) * | 2017-03-27 | 2019-05-14 | Western Digital Technologies, Inc. | Managing I/O operations of large data objects in a cache memory device by dividing into chunks |
| WO2019133728A1 (en) | 2017-12-29 | 2019-07-04 | Marmon Water (Singapore) Pte. Ltd. | Filtration media for removing chloramine, chlorine, and ammonia, and method of making the same |
| WO2019160977A1 (en) | 2018-02-13 | 2019-08-22 | Calgon Carbon Corporation | Chemical sorbent oxidation method and sorbents made therefrom |
| CN110386654A (zh) * | 2018-04-23 | 2019-10-29 | 湖南能也科技发展有限公司 | 一种从污酸中脱除氯的方法 |
| WO2020206317A1 (en) | 2019-04-03 | 2020-10-08 | Calgon Carbon Corporation | Perfluoroalkyl and polyfluoroalkyl sorbent materials and methods of use |
| CN115943125B (zh) | 2020-07-14 | 2025-06-06 | 卡尔冈碳素公司 | 用于从流体中去除pfas的具有高体积碘值和高体积糖蜜值的吸附剂和其制备和使用方法 |
| CN116234626A (zh) | 2020-08-31 | 2023-06-06 | 卡尔冈碳素公司 | 铁和氮处理的吸附剂及其制备方法 |
| US12059668B2 (en) | 2020-08-31 | 2024-08-13 | Calgon Carbon Corporation | Copper, iron, and nitrogen treated sorbent and method for making same |
| KR20230060515A (ko) | 2020-08-31 | 2023-05-04 | 칼곤 카본 코포레이션 | 구리 및 질소로 처리된 흡착제 및 이를 제조하는 방법 |
| CN112239300A (zh) * | 2020-12-16 | 2021-01-19 | 科迈化工股份有限公司 | 硫代硫酸铵废水处理方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2688497A1 (fr) * | 1992-03-11 | 1993-09-17 | Atochem Elf Sa | Procede de diminution de la quantite d'acide cyanurique et de chloramines contenus dans l'eau d'une piscine. |
| WO2007008543A2 (en) * | 2005-07-08 | 2007-01-18 | Zentox Corporation | Method and apparatus for the production and delivery of monochloramine into water streams |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US2878195A (en) * | 1956-03-09 | 1959-03-17 | Gen Electric | Process of preparing an organopolysiloxane, the product thereof, mixtures of the product with rubbery polymers, and method of curing the mixtures |
| JPS5978915A (ja) * | 1982-10-25 | 1984-05-08 | Takeda Chem Ind Ltd | 硫黄担持活性炭の製造法 |
| US5338458A (en) | 1993-01-21 | 1994-08-16 | Calgon Carbon Corporation | Method for removing chloramine with catalytic carbon |
| JPH09248456A (ja) * | 1996-03-18 | 1997-09-22 | Isao Mochida | 選択的吸着能を持つ分子篩活性炭素繊維およびその製造方法 |
| US6270822B1 (en) * | 1997-10-27 | 2001-08-07 | Tekquest Industries | Methods for removal of chlorine from water |
| US6699393B2 (en) | 2002-05-08 | 2004-03-02 | Meadwestvaco Corporation | Method for removal of chloramines from drinking water |
| US20050274675A1 (en) * | 2004-06-10 | 2005-12-15 | Harusuke Naito | Portable purifier for potable liquids |
| CN102600808A (zh) * | 2006-01-30 | 2012-07-25 | 高级技术材料公司 | 纳米多孔碳材料，以及利用其的系统和方法 |
| US8205755B2 (en) | 2006-03-22 | 2012-06-26 | 3M Innovative Properties Company | Filter media |
| JP3122170U (ja) * | 2006-03-24 | 2006-06-01 | 日本プリコム有限会社 | 逆浸透膜浄水装置 |
| US7828969B2 (en) | 2007-08-07 | 2010-11-09 | 3M Innovative Properties Company | Liquid filtration systems |
| JP2010063629A (ja) * | 2008-09-10 | 2010-03-25 | Nippon Torimu:Kk | 透析装置 |
| TWI505987B (zh) * | 2010-03-31 | 2015-11-01 | Kuraray Chemical Kk | 活性碳及其用途 |
| US20120052502A1 (en) | 2010-08-30 | 2012-03-01 | Samsung Techwin Co., Ltd. | Real-time pcr detection using stabilized probes |
| FR2964941B1 (fr) | 2010-09-16 | 2013-03-08 | Eurocopter France | Pale a vulnerabilite minimisee |
| JP5367666B2 (ja) | 2010-09-21 | 2013-12-11 | 株式会社東芝 | 誘導ラマン断熱通過の操作方法及び位相ゲート操作の方法 |
| CN102000548A (zh) * | 2010-12-02 | 2011-04-06 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种低浓度有机废气的改性活性炭吸附剂的制备方法 |
| EP2794494B1 (en) * | 2011-12-22 | 2017-11-29 | 3M Innovative Properties Company | Use of a filtration device comprising a thermolysis product of a carbon oxychalcogenide and a metal salt and method of removing chloramine with this thermolysis product |
| BR112015005051B1 (pt) * | 2012-09-11 | 2020-04-07 | 3M Innovative Properties Co | método para remoção de cloramina de soluções aquosas |
-
2014
- 2014-03-05 JP JP2016500652A patent/JP6611698B2/ja active Active
- 2014-03-05 BR BR112015022828A patent/BR112015022828A2/pt not_active IP Right Cessation
- 2014-03-05 EP EP14717243.1A patent/EP2969963A1/en not_active Withdrawn
- 2014-03-05 CA CA2905823A patent/CA2905823A1/en not_active Abandoned
- 2014-03-05 WO PCT/US2014/020662 patent/WO2014164120A1/en not_active Ceased
- 2014-03-05 CN CN201910067312.7A patent/CN110078154B/zh active Active
- 2014-03-05 US US14/774,848 patent/US20160023920A1/en not_active Abandoned
- 2014-03-05 KR KR1020157027476A patent/KR102239099B1/ko not_active Expired - Fee Related
- 2014-03-05 AU AU2014249631A patent/AU2014249631B2/en not_active Ceased
- 2014-03-05 CN CN201480014995.5A patent/CN105073646A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2688497A1 (fr) * | 1992-03-11 | 1993-09-17 | Atochem Elf Sa | Procede de diminution de la quantite d'acide cyanurique et de chloramines contenus dans l'eau d'une piscine. |
| WO2007008543A2 (en) * | 2005-07-08 | 2007-01-18 | Zentox Corporation | Method and apparatus for the production and delivery of monochloramine into water streams |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2905823A1 (en) | 2014-10-09 |
| AU2014249631B2 (en) | 2016-11-24 |
| KR102239099B1 (ko) | 2021-04-12 |
| AU2014249631A1 (en) | 2015-10-01 |
| US20160023920A1 (en) | 2016-01-28 |
| KR20150127158A (ko) | 2015-11-16 |
| CN105073646A (zh) | 2015-11-18 |
| WO2014164120A1 (en) | 2014-10-09 |
| JP2016512163A (ja) | 2016-04-25 |
| EP2969963A1 (en) | 2016-01-20 |
| BR112015022828A2 (pt) | 2017-07-18 |
| CN110078154A (zh) | 2019-08-02 |
| JP6611698B2 (ja) | 2019-11-27 |
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