CN110055433B - 一种液态金属铋萃取回收钕铁硼废料中稀土元素的方法 - Google Patents
一种液态金属铋萃取回收钕铁硼废料中稀土元素的方法 Download PDFInfo
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- CN110055433B CN110055433B CN201910052446.1A CN201910052446A CN110055433B CN 110055433 B CN110055433 B CN 110055433B CN 201910052446 A CN201910052446 A CN 201910052446A CN 110055433 B CN110055433 B CN 110055433B
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- rare earth
- iron boron
- neodymium iron
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- metal
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- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 178
- 229910001172 neodymium magnet Inorganic materials 0.000 title claims abstract description 158
- QJVKUMXDEUEQLH-UHFFFAOYSA-N [B].[Fe].[Nd] Chemical compound [B].[Fe].[Nd] QJVKUMXDEUEQLH-UHFFFAOYSA-N 0.000 title claims abstract description 145
- 239000002699 waste material Substances 0.000 title claims abstract description 131
- 238000000034 method Methods 0.000 title claims abstract description 73
- 229910052797 bismuth Inorganic materials 0.000 title claims abstract description 61
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 229910001338 liquidmetal Inorganic materials 0.000 title claims abstract description 37
- 238000004064 recycling Methods 0.000 title abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 109
- 229910052751 metal Inorganic materials 0.000 claims abstract description 108
- 239000002184 metal Substances 0.000 claims abstract description 106
- 239000000956 alloy Substances 0.000 claims abstract description 49
- 239000007791 liquid phase Substances 0.000 claims abstract description 49
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 48
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 37
- 229910052742 iron Inorganic materials 0.000 claims abstract description 35
- 239000000463 material Substances 0.000 claims abstract description 35
- 239000000155 melt Substances 0.000 claims abstract description 23
- -1 bismuth rare earth Chemical class 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 17
- 238000005191 phase separation Methods 0.000 claims abstract description 13
- 229910052796 boron Inorganic materials 0.000 claims abstract description 10
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002844 melting Methods 0.000 claims abstract description 8
- 230000008018 melting Effects 0.000 claims abstract description 8
- 150000002910 rare earth metals Chemical class 0.000 claims description 54
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 33
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 28
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- 229910052771 Terbium Inorganic materials 0.000 claims description 13
- 229910000691 Re alloy Inorganic materials 0.000 claims description 12
- 238000005516 engineering process Methods 0.000 claims description 11
- 229910052723 transition metal Inorganic materials 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 238000005292 vacuum distillation Methods 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 3
- 229910001152 Bi alloy Inorganic materials 0.000 claims description 2
- 230000006698 induction Effects 0.000 abstract description 14
- ZDVYABSQRRRIOJ-UHFFFAOYSA-N boron;iron Chemical compound [Fe]#B ZDVYABSQRRRIOJ-UHFFFAOYSA-N 0.000 abstract description 6
- 150000002739 metals Chemical class 0.000 abstract description 6
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 abstract description 6
- 229910000521 B alloy Inorganic materials 0.000 abstract description 4
- 238000007738 vacuum evaporation Methods 0.000 abstract description 3
- 239000012071 phase Substances 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 description 18
- 230000008569 process Effects 0.000 description 17
- 238000011084 recovery Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 238000000605 extraction Methods 0.000 description 10
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000005265 energy consumption Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 230000005291 magnetic effect Effects 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 238000004321 preservation Methods 0.000 description 4
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910000583 Nd alloy Inorganic materials 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 238000010248 power generation Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000002910 solid waste Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- PEFIIJCLFMFTEP-UHFFFAOYSA-N [Nd].[Mg] Chemical compound [Nd].[Mg] PEFIIJCLFMFTEP-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- KPLQYGBQNPPQGA-UHFFFAOYSA-N cobalt samarium Chemical compound [Co].[Sm] KPLQYGBQNPPQGA-UHFFFAOYSA-N 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000011978 dissolution method Methods 0.000 description 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910000938 samarium–cobalt magnet Inorganic materials 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012320 chlorinating reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000000462 isostatic pressing Methods 0.000 description 1
- 238000010902 jet-milling Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- CRLLGLJOPXYTLX-UHFFFAOYSA-N neodymium silver Chemical compound [Ag].[Nd] CRLLGLJOPXYTLX-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
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- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
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- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B15/00—Other processes for the manufacture of iron from iron compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mechanical Engineering (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Priority Applications (2)
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CN201910052446.1A CN110055433B (zh) | 2019-01-21 | 2019-01-21 | 一种液态金属铋萃取回收钕铁硼废料中稀土元素的方法 |
PCT/CN2020/070215 WO2020151478A1 (fr) | 2019-01-21 | 2020-01-03 | Procédé de récupération d'un élément des terres rares à partir de déchets de néodyme-fer-bore par extraction à l'aide de bismuth métallique liquide |
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CN201910052446.1A CN110055433B (zh) | 2019-01-21 | 2019-01-21 | 一种液态金属铋萃取回收钕铁硼废料中稀土元素的方法 |
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CN110055433A CN110055433A (zh) | 2019-07-26 |
CN110055433B true CN110055433B (zh) | 2021-05-18 |
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CN (1) | CN110055433B (fr) |
WO (1) | WO2020151478A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110055433B (zh) * | 2019-01-21 | 2021-05-18 | 中国科学院金属研究所 | 一种液态金属铋萃取回收钕铁硼废料中稀土元素的方法 |
CN111778399B (zh) * | 2020-01-06 | 2022-05-27 | 中南大学 | 一种熔体萃取分离回收废旧钴基高温合金中镍钴的方法 |
CN111876795B (zh) * | 2020-07-28 | 2022-12-06 | 江苏金石稀土有限公司 | 一种回收稀土熔盐渣中电解质的方法 |
CN114427042B (zh) * | 2022-01-28 | 2023-02-03 | 江苏南方永磁科技有限公司 | 一种从钕铁硼废料中提取高纯稀土氧化物的分离装置 |
CN115821075B (zh) * | 2022-11-23 | 2024-09-17 | 昆明理工大学 | 一种回收钐钴永磁废料中稀土金属的方法 |
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CN106086418A (zh) * | 2016-06-30 | 2016-11-09 | 江西省钨与稀土产品质量监督检验中心(江西省钨与稀土研究院) | 一种烧结钕铁硼废旧器件性能恢复的方法 |
CN106319249A (zh) * | 2016-08-23 | 2017-01-11 | 赣州市恒源科技股份有限公司 | 一种从钕铁硼废料中回收稀土的方法 |
CN108426928A (zh) * | 2018-03-14 | 2018-08-21 | 哈尔滨工程大学 | 在线监测熔盐与液态金属还原萃取稀土离子浓度的方法 |
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CN102011020B (zh) * | 2009-12-14 | 2012-09-05 | 包头市玺骏稀土有限责任公司 | 从钕铁硼废料中回收稀土元素的方法 |
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CN104016399B (zh) * | 2014-06-10 | 2016-01-20 | 上海大学 | 从钕铁硼永磁材料中回收制备纳米稀土氢氧化物的方法 |
CN104087755B (zh) * | 2014-07-23 | 2016-01-13 | 安徽工业大学 | 一种钕铁硼废料中稀土元素的回收方法 |
CN108359798A (zh) * | 2017-06-03 | 2018-08-03 | 江西离子型稀土工程技术研究有限公司 | 一种快速高效回收利用钕铁硼废料的方法 |
CN110055433B (zh) * | 2019-01-21 | 2021-05-18 | 中国科学院金属研究所 | 一种液态金属铋萃取回收钕铁硼废料中稀土元素的方法 |
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2019
- 2019-01-21 CN CN201910052446.1A patent/CN110055433B/zh active Active
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2020
- 2020-01-03 WO PCT/CN2020/070215 patent/WO2020151478A1/fr active Application Filing
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JP2004361417A (ja) * | 2004-08-20 | 2004-12-24 | Toshiba Corp | 使用済み燃料の溶融塩電解再処理方法 |
CN103667751A (zh) * | 2013-11-18 | 2014-03-26 | 上海交通大学 | 采用钕铁硼磁铁废料制备镁钕中间合金的方法 |
CN105018733A (zh) * | 2015-07-09 | 2015-11-04 | 中国科学院金属研究所 | 废弃电路板多金属混合资源中铋元素的富集与分离方法 |
CN106086418A (zh) * | 2016-06-30 | 2016-11-09 | 江西省钨与稀土产品质量监督检验中心(江西省钨与稀土研究院) | 一种烧结钕铁硼废旧器件性能恢复的方法 |
CN106319249A (zh) * | 2016-08-23 | 2017-01-11 | 赣州市恒源科技股份有限公司 | 一种从钕铁硼废料中回收稀土的方法 |
CN108426928A (zh) * | 2018-03-14 | 2018-08-21 | 哈尔滨工程大学 | 在线监测熔盐与液态金属还原萃取稀土离子浓度的方法 |
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