CN110054922A - A kind of UV resistant PVC floor surface treating agent - Google Patents
A kind of UV resistant PVC floor surface treating agent Download PDFInfo
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- CN110054922A CN110054922A CN201910421129.2A CN201910421129A CN110054922A CN 110054922 A CN110054922 A CN 110054922A CN 201910421129 A CN201910421129 A CN 201910421129A CN 110054922 A CN110054922 A CN 110054922A
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- pvc floor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of UV resistant PVC floor surface treating agents, raw material components including following parts by weight: 1,6- 10-20 parts of glycol diacrylate, 20-40 parts of ethoxylated trimethylolpropane triacrylate, 15-30 parts of siloxane oligomer, 25-45 parts of polysiloxanes, 3-7 parts of photoinitiator, 0.1-1 parts of dispersing agent, 0.1-2 parts of levelling agent, 0.2-1 parts of defoaming agent, 5-15 parts of flatting silica, 5-15 parts of abrasion-resistant powder, 0.2-1 parts of anti-settling agent, 0.1-1 parts of feel auxiliary agent.By the present invention, treated that PVC floor product curing rate is fast, and adhesive force is good, and lustrous surface is soft, and hardness is high, and wearability is good, and resistant effect is good.
Description
Technical field
The present invention relates to PVC floor UV processing technology field, specifically a kind of UV resistant PVC floor surface treating agent.
Background technique
PVC floor is popular a kind of novel light body floor decorative material in the world today, also referred to as " light body
Material ".It is a kind of product very popular in American-European and Asia Japan and Korea S, fashionable foreign countries initially enter Chinese city from the beginning of the eighties
, big and medium-sized cities at home have obtained universal approval so far, using very extensive, for example family, hospital, school, do
Public building, factory, public place, supermarket, business, etc. various places." PVC floor " just refers to using pvc material production
Floor.Particularly as being that filler, plasticizer, stabilizer, colorant etc. is added using polyvinyl chloride and its copolymer resins as primary raw material
Auxiliary material coated technique or produces on sheet continuous base material through calendering, extrusion or extrusion process.
During PVC floor is manufactured, it usually needs carry out UV processing, in UV treatment process, UV to PVC floor
The selection of surface treating agent directly affects subsequent UV treatment effect.Using existing surface treating agent treated product solidification speed
Degree is slower, reduces the efficiency of manufacturing of PVC floor, adhesive force is slightly worse, and wearability is not also high, leads to the use in floor later period
Service life is relatively short.
Summary of the invention
The purpose of the present invention is to provide a kind of UV resistant PVC floor surface treating agents, to solve in above-mentioned background technique
The problem of proposition.
To achieve the above object, the invention provides the following technical scheme:
A kind of UV resistant PVC floor surface treating agent, the raw material components including following parts by weight: 1,6- glycol diacrylate
10-20 parts, 20-40 parts of ethoxylated trimethylolpropane triacrylate, 15-30 parts of siloxane oligomer, polysiloxanes 25-
45 parts, it is 3-7 parts of photoinitiator, 0.1-1 parts of dispersing agent, 0.1-2 parts of levelling agent, 0.2-1 parts of defoaming agent, 5-15 parts of flatting silica, resistance to
Be milled 5-15 parts, 0.2-1 parts of anti-settling agent, 0.1-1 parts of feel auxiliary agent.
As a further solution of the present invention: the photoinitiator uses benzoin and derivative, benzil class, alkylbenzene
At least two mixtures in ketone, benzophenone.
As a further solution of the present invention: the levelling agent is using the mixed of esters of acrylic acid levelling agent and fluorine class levelling agent
Close object, wherein the mass fraction of esters of acrylic acid levelling agent is 90-95%, remaining is fluorine class levelling agent.
As a further solution of the present invention: the anti-settling agent uses organobentonite, castor oil derivative, gas phase dioxy
The mixture of SiClx and polyolefin-wax particle, wherein bentonite mass fraction is 30-35%, castor oil derivative
Mass fraction is 25-30%, and the mass fraction of fumed silica is 15-19%, remaining is polyolefin-wax particle.
As a further solution of the present invention: the feel auxiliary agent uses the modified organic silicon class feel of smooth, resistance to scratch-type
Auxiliary agent.
As a further solution of the present invention: the raw material components including following parts by weight: 1,6- glycol diacrylate
10 parts, it is 20 parts of ethoxylated trimethylolpropane triacrylate, 15 parts of siloxane oligomer, 25 parts of polysiloxanes, light-initiated
3 parts of agent, 0.1 part of dispersing agent, 0.1 part of levelling agent, 0.2 part of defoaming agent, 5 parts of flatting silica, 5 parts of abrasion-resistant powder, 0.2 part of anti-settling agent, hand
0.1 part of auxiliary agent of sense.
As a further solution of the present invention: the raw material components including following parts by weight: 1,6- glycol diacrylate
20 parts, it is 40 parts of ethoxylated trimethylolpropane triacrylate, 30 parts of siloxane oligomer, 45 parts of polysiloxanes, light-initiated
7 parts of agent, 1 part of dispersing agent, 2 parts of levelling agent, 1 part of defoaming agent, 15 parts of flatting silica, 15 parts of abrasion-resistant powder, 1 part of anti-settling agent, feel auxiliary agent 1
Part.
As a further solution of the present invention: the raw material components including following parts by weight: 1,6- glycol diacrylate
15 parts, it is 30 parts of ethoxylated trimethylolpropane triacrylate, 25 parts of siloxane oligomer, 33 parts of polysiloxanes, light-initiated
5 parts of agent, 0.7 part of dispersing agent, 1.2 parts of levelling agent, 0.7 part of defoaming agent, 13 parts of flatting silica, 12 parts of abrasion-resistant powder, 0.7 part of anti-settling agent,
0.9 part of feel auxiliary agent.
Compared with prior art, the beneficial effects of the present invention are: UV resistant PVC floor surface treating agent of the invention, packet
Include the raw material components of following parts by weight: 1,6- glycol diacrylate, ethoxylated trimethylolpropane triacrylate, silicon
Oxygen alkane oligomer, polysiloxanes, photoinitiator, dispersing agent, levelling agent, defoaming agent, flatting silica, abrasion-resistant powder, anti-settling agent and hand
Feel auxiliary agent, treated that product curing rate is fast by the present invention, and adhesive force is good, and lustrous surface is soft, and hardness is high, wearability
Good, resistant effect is good.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1:
A kind of UV resistant PVC floor surface treating agent, the raw material components including following parts by weight: the raw material including following parts by weight
Component: 10 parts of 1,6- glycol diacrylate, 20 parts of ethoxylated trimethylolpropane triacrylate, siloxane oligomer
15 parts, 25 parts of polysiloxanes, 3 parts of photoinitiator, 0.1 part of dispersing agent, 0.1 part of levelling agent, 0.2 part of defoaming agent, 5 parts of flatting silica,
5 parts of abrasion-resistant powder, 0.2 part of anti-settling agent, 0.1 part of feel auxiliary agent.
Wherein, the photoinitiator is using in benzoin and derivative, benzil class, alkylbenzene ketone, benzophenone
At least two mixtures.
The levelling agent uses the mixture of esters of acrylic acid levelling agent and fluorine class levelling agent, wherein esters of acrylic acid stream
The mass fraction of flat agent is 90-95%, remaining is fluorine class levelling agent.
The anti-settling agent is using organobentonite, castor oil derivative, fumed silica and polyolefin-wax particle
Mixture, wherein bentonite mass fraction is 30%, and the mass fraction of castor oil derivative is 25%, gas phase titanium dioxide
The mass fraction of silicon is 15%, remaining is polyolefin-wax particle.The feel auxiliary agent uses the modified organic silicon of smooth, resistance to scratch-type
Class feel auxiliary agent.
Embodiment 2:
A kind of UV resistant PVC floor surface treating agent, the raw material components including following parts by weight: 1,6- glycol diacrylate
20 parts, it is 40 parts of ethoxylated trimethylolpropane triacrylate, 30 parts of siloxane oligomer, 45 parts of polysiloxanes, light-initiated
7 parts of agent, 1 part of dispersing agent, 2 parts of levelling agent, 1 part of defoaming agent, 15 parts of flatting silica, 15 parts of abrasion-resistant powder, 1 part of anti-settling agent, feel auxiliary agent 1
Part.
Wherein, the photoinitiator is using in benzoin and derivative, benzil class, alkylbenzene ketone, benzophenone
At least two mixtures.
The levelling agent uses the mixture of esters of acrylic acid levelling agent and fluorine class levelling agent, wherein esters of acrylic acid stream
The mass fraction of flat agent is 90-95%, remaining is fluorine class levelling agent.
The anti-settling agent is using organobentonite, castor oil derivative, fumed silica and polyolefin-wax particle
Mixture, wherein bentonite mass fraction is 35%, and the mass fraction of castor oil derivative is 30%, gas phase titanium dioxide
The mass fraction of silicon is 19%, remaining is polyolefin-wax particle.The feel auxiliary agent uses the modified organic silicon of smooth, resistance to scratch-type
Class feel auxiliary agent.
Embodiment 3:
A kind of UV resistant PVC floor surface treating agent, the raw material components including following parts by weight: 1,6- glycol diacrylate
15 parts, it is 30 parts of ethoxylated trimethylolpropane triacrylate, 25 parts of siloxane oligomer, 33 parts of polysiloxanes, light-initiated
5 parts of agent, 0.7 part of dispersing agent, 1.2 parts of levelling agent, 0.7 part of defoaming agent, 13 parts of flatting silica, 12 parts of abrasion-resistant powder, 0.7 part of anti-settling agent,
0.9 part of feel auxiliary agent.
Wherein, the photoinitiator is using in benzoin and derivative, benzil class, alkylbenzene ketone, benzophenone
At least two mixtures.
The levelling agent uses the mixture of esters of acrylic acid levelling agent and fluorine class levelling agent, wherein esters of acrylic acid stream
The mass fraction of flat agent is 90-95%, remaining is fluorine class levelling agent.
The anti-settling agent is using organobentonite, castor oil derivative, fumed silica and polyolefin-wax particle
Mixture, wherein bentonite mass fraction is 33%, and the mass fraction of castor oil derivative is 28%, gas phase titanium dioxide
The mass fraction of silicon is 17%, remaining is polyolefin-wax particle.The feel auxiliary agent uses the modified organic silicon of smooth, resistance to scratch-type
Class feel auxiliary agent.
It will be write on the product of unusual pen after treatment, the person's handwriting of writing can care for light wiping, illustrate by this hair
Bright treated PVC floor has good resistant effect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
Claims (8)
1. a kind of UV resistant PVC floor surface treating agent, which is characterized in that the raw material components including following parts by weight: 1,6- second
10-20 parts of omega-diol diacrylate, 20-40 parts of ethoxylated trimethylolpropane triacrylate, siloxane oligomer 15-30
Part, 0.2-1 parts of defoaming agent, disappears at 25-45 parts of polysiloxanes, 3-7 parts of photoinitiator, 0.1-1 parts of dispersing agent, 0.1-2 parts of levelling agent
5-15 parts of light powder, 5-15 parts of abrasion-resistant powder, 0.2-1 parts of anti-settling agent, 0.1-1 parts of feel auxiliary agent.
2. a kind of UV resistant PVC floor surface treating agent according to claim 1, which is characterized in that the photoinitiator
Using at least two mixtures in benzoin and derivative, benzil class, alkylbenzene ketone, benzophenone.
3. a kind of UV resistant PVC floor surface treating agent according to claim 1, which is characterized in that the levelling agent is adopted
With the mixture of esters of acrylic acid levelling agent and fluorine class levelling agent, wherein the mass fraction of esters of acrylic acid levelling agent is 90-
95%, remaining is fluorine class levelling agent.
4. a kind of UV resistant PVC floor surface treating agent according to claim 1, which is characterized in that the anti-settling agent is adopted
With the mixture of organobentonite, castor oil derivative, fumed silica and polyolefin-wax particle, wherein organic swelling
The mass fraction of soil is 30-35%, and the mass fraction of castor oil derivative is 25-30%, and the mass fraction of fumed silica is
15-19%, remaining is polyolefin-wax particle.
5. a kind of UV resistant PVC floor surface treating agent according to claim 1, which is characterized in that the feel auxiliary agent
Using the modified organic silicon class feel auxiliary agent of smooth, resistance to scratch-type.
6. a kind of UV resistant PVC floor surface treating agent according to claim 1, which is characterized in that including following weight
The raw material components of part: 10 parts of 1,6- glycol diacrylate, 20 parts of ethoxylated trimethylolpropane triacrylate, silicon oxygen
15 parts of alkane oligomer, 3 parts of photoinitiator, 0.1 part of dispersing agent, 0.1 part of levelling agent, 0.2 part of defoaming agent, disappears at 25 parts of polysiloxanes
5 parts of light powder, 5 parts of abrasion-resistant powder, 0.2 part of anti-settling agent, 0.1 part of feel auxiliary agent.
7. a kind of UV resistant PVC floor surface treating agent according to claim 1, which is characterized in that including following weight
The raw material components of part: 20 parts of 1,6- glycol diacrylate, 40 parts of ethoxylated trimethylolpropane triacrylate, silicon oxygen
30 parts of alkane oligomer, 45 parts of polysiloxanes, 7 parts of photoinitiator, 1 part of dispersing agent, 2 parts of levelling agent, 1 part of defoaming agent, flatting silica 15
Part, 15 parts of abrasion-resistant powder, 1 part of anti-settling agent, 1 part of feel auxiliary agent.
8. a kind of UV resistant PVC floor surface treating agent according to claim 1, which is characterized in that including following weight
The raw material components of part: 15 parts of 1,6- glycol diacrylate, 30 parts of ethoxylated trimethylolpropane triacrylate, silicon oxygen
25 parts of alkane oligomer, 5 parts of photoinitiator, 0.7 part of dispersing agent, 1.2 parts of levelling agent, 0.7 part of defoaming agent, disappears at 33 parts of polysiloxanes
13 parts of light powder, 12 parts of abrasion-resistant powder, 0.7 part of anti-settling agent, 0.9 part of feel auxiliary agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910421129.2A CN110054922A (en) | 2019-05-21 | 2019-05-21 | A kind of UV resistant PVC floor surface treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910421129.2A CN110054922A (en) | 2019-05-21 | 2019-05-21 | A kind of UV resistant PVC floor surface treating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110054922A true CN110054922A (en) | 2019-07-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910421129.2A Withdrawn CN110054922A (en) | 2019-05-21 | 2019-05-21 | A kind of UV resistant PVC floor surface treating agent |
Country Status (1)
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140272424A1 (en) * | 2013-03-14 | 2014-09-18 | Bayer Materialscience Llc | Fast cure aspartate polysiloxane hybrid coating |
| CN106280978A (en) * | 2016-08-05 | 2017-01-04 | 成都纳硕科技有限公司 | A kind of high temperature resistant photocureable coating |
| CN106752737A (en) * | 2016-11-14 | 2017-05-31 | 上海普力通新材料科技有限公司 | A kind of PVC floor ultraviolet-curing paint and preparation method thereof |
| CN108864635A (en) * | 2018-07-03 | 2018-11-23 | 合肥华盖光伏科技有限公司 | A kind of preparation method on PVC roll material floor |
| CN108913012A (en) * | 2018-07-18 | 2018-11-30 | 上海海隆赛能新材料有限公司 | Ultraviolet light solidifies high resistant matt floor paint and preparation method thereof |
| CN109468016A (en) * | 2018-10-15 | 2019-03-15 | 唐山市丰润区米乐感光新材料有限公司 | Agent UV coating is scalded in PVC floor anti-pollution Smoke prevention |
-
2019
- 2019-05-21 CN CN201910421129.2A patent/CN110054922A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140272424A1 (en) * | 2013-03-14 | 2014-09-18 | Bayer Materialscience Llc | Fast cure aspartate polysiloxane hybrid coating |
| CN106280978A (en) * | 2016-08-05 | 2017-01-04 | 成都纳硕科技有限公司 | A kind of high temperature resistant photocureable coating |
| CN106752737A (en) * | 2016-11-14 | 2017-05-31 | 上海普力通新材料科技有限公司 | A kind of PVC floor ultraviolet-curing paint and preparation method thereof |
| CN108864635A (en) * | 2018-07-03 | 2018-11-23 | 合肥华盖光伏科技有限公司 | A kind of preparation method on PVC roll material floor |
| CN108913012A (en) * | 2018-07-18 | 2018-11-30 | 上海海隆赛能新材料有限公司 | Ultraviolet light solidifies high resistant matt floor paint and preparation method thereof |
| CN109468016A (en) * | 2018-10-15 | 2019-03-15 | 唐山市丰润区米乐感光新材料有限公司 | Agent UV coating is scalded in PVC floor anti-pollution Smoke prevention |
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Application publication date: 20190726 |
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