CN110048199A - A kind of integrated VO in part2Terahertz active modulator of material and preparation method thereof - Google Patents

A kind of integrated VO in part2Terahertz active modulator of material and preparation method thereof Download PDF

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Publication number
CN110048199A
CN110048199A CN201910337443.2A CN201910337443A CN110048199A CN 110048199 A CN110048199 A CN 110048199A CN 201910337443 A CN201910337443 A CN 201910337443A CN 110048199 A CN110048199 A CN 110048199A
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terahertz
photoresist
substrate
time
active modulator
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张彩虹
李花
吴敬波
金飚兵
陈健
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Nanjing University
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Nanjing University
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/16Coating processes; Apparatus therefor
    • G03F7/162Coating on a rotating support, e.g. using a whirler or a spinner
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2002Exposure; Apparatus therefor with visible light or UV light, through an original having an opaque pattern on a transparent support, e.g. film printing, projection printing; by reflection of visible or UV light from an original such as a printed image
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/30Imagewise removal using liquid means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01PWAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
    • H01P1/00Auxiliary devices
    • H01P1/20Frequency-selective devices, e.g. filters
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01PWAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
    • H01P11/00Apparatus or processes specially adapted for manufacturing waveguides or resonators, lines, or other devices of the waveguide type
    • H01P11/008Manufacturing resonators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01PWAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
    • H01P7/00Resonators of the waveguide type

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)

Abstract

The invention discloses a kind of parts to integrate VO2The Terahertz active modulator of material, including Al2O3Substrate is grown in the Al2O3Part on substrate integrates VO2The metallic resonator structure of structure, the metallic resonator structure include the cellular construction of multiple periodic arrangements.The invention also discloses prepare above-mentioned part to integrate VO2The method and modulator approach of the Terahertz active modulator of material.The configuration of the present invention is simple uses transition metal oxide vanadium dioxide (VO2), the integrated VO in part2The resonator structure of material and metal, device are prepared and are modulated simple and fast.

Description

A kind of integrated VO in part2Terahertz active modulator of material and preparation method thereof
Technical field
The invention belongs to THz wave transmission technique field, in particular to a kind of part integrates vanadium dioxide (VO2) material Terahertz active modulator and preparation method thereof.
Background technique
Terahertz Technology was developed rapidly at the past more than 20 years, in high-speed radiocommunication, terahertz imaging and spectroscopy The application of aspect needs development function complete full of prospect in order to realize the actually active application to Terahertz Technology, meets The various efficient THz devices of actual demand.Nearest more than ten years, Terahertz active control Meta Materials rapidly develop, a series of super The Terahertz Meta Materials for leading metal or oxide production, by alternating temperature, magnetic field or optical pumping adjust the tune realized to THz wave System, but regulation requires high or mode cumbersome mostly, is not easy to be widely applied.
Summary of the invention
In order to solve the above problems existing in the present technology, the present invention provides a kind of parts to integrate VO2The terahertz of material Hereby active modulator and preparation method thereof, design Terahertz active modulator structure reduce modulation demand, realize and believe Terahertz Number transmission freely regulate and control.
For achieving the above object, the first technical solution provided by the invention are as follows:
A kind of integrated VO in part2The Terahertz active modulator of material, including Al2O3Substrate is grown in the Al2O3Substrate On part integrate VO2The metallic resonator structure of structure, the metallic resonator structure include the unit of multiple periodic arrangements Structure.
Second of technical solution provided by the invention are as follows:
A kind of part integrates VO as described above2The preparation method of the Terahertz active modulator of material, includes the following steps: (1) in Al2O3VO is grown on substrate2Film;(2) spin coating photoresist AZ1500: VO is being grown2The Al of film2O3Substrate On, spin coating photoresist AZ1500;(3) Al for coating photoresist AZ1500 uv-exposure and development: is placed on litho machine2O3Base Piece and mask plate are simultaneously aligned, and the structure of the mask plate is periodic structure, have been exposed followed by be shown with developer for positive photoresist Shadow dries after then carrying out;(4) VO is etched using reactive ion etching (RIE) technique2Structure, acetone clean photoresist AZ1500 is dried after the cleaning of alcohol deionized water;(5) two layer photoresist LOR10b and AZ1500 of spin coating;It repeats step (3), this When mask plate patterns be golden structure graph;(6) magnetron sputtering apparatus, the Al after step (5) sputtering metal membrane: are used2O3Substrate One layer of metal of upper sputtering, will sputter the Al of one layer of metal2O3Substrate removing removes on remaining photoresist and the photoresist Then one layer of metal removes remaining photoresist and obtains the resonator structure of periodic arrangement.
The third technical solution provided by the invention are as follows:
VO is integrated using a kind of part as described above2The modulator approach of the Terahertz active modulator of material, including Following 3 kinds of modulation means:
1) temperature regulates and controls: the part is integrated VO2The Terahertz active modulator of material is fixed on controllable temperature specimen holder, It is placed in test terahertz time-domain spectroscopy system, modulation Terahertz transmission spectrum is heated by thermal station;
2) part strong THz electric field regulation: is integrated into VO2The Terahertz active modulator of material is fixed on high field terahertz Hereby at the Terahertz hot spot convergence in time-domain spectroscopy system, the Terahertz active modulator is got to using the change of Terahertz wiregrating Terahertz electric field level modulation Terahertz transmission spectrum;
3) laser pump (ing) regulates and controls: the part is integrated VO2The Terahertz active modulator of material is fixed on test with too In hertz time-domain spectroscopy system, modulation Terahertz transmission on the Terahertz active modulator is got to using femtosecond laser Spectrum.
The invention has the benefit that
The configuration of the present invention is simple uses transition metal oxide vanadium dioxide (VO2), the integrated VO in part2Material and metal Resonator structure, device are prepared and are modulated simple and fast.
Detailed description of the invention
Fig. 1 is the integrated VO in part2The cellular construction schematic diagram of the Terahertz active modulator of material;
Fig. 2 is the integrated VO in part2The section structural schematic diagram of the Terahertz active modulator of material;
Fig. 3 is the biography of the test sample temperature modulation for the Terahertz active modulator that part of the invention integrates VO2 material Defeated spectrogram.
Specific embodiment
In the following with reference to the drawings and specific embodiments, the present invention is furture elucidated, it should be understood that these embodiments are merely to illustrate Use scope of the invention rather than that limitation is of the invention, after the present invention has been read, those skilled in the art are to the present invention The modifications of various equivalent forms fall within the application range as defined in the appended claims.
One, the integrated VO in design part2The Terahertz active modulator of material
For the integrated VO in design part2The structure of the Terahertz active modulator of material, has studied various Meta Materials Structure.Most Terahertz Meta Materials modulation requires high, VO2Material can undergo phase transition near room temperature and generate precipitous weigh Multiple insulated metal phase transformation is to realize the good functional material of active control Meta Materials device.While in order to obtain more tune Freely, we devise a kind of integrated VO in part for control2The Terahertz active modulator structure of material, schematic diagram was as shown in Figure 1, should The overall structure of modulator is Al2O3+VO2+ Au, in VO2When material electric conductivity is low, resonance is given in 0.704THz in resonance peak position Device heating leads to VO2Structural material phase transformation, conductivity increase considerably, and resonance peak is offset to 0.476THz.
For the design parameter for determining the structure, a large amount of moulds first are carried out with the electromagnetism farm software CST based on time-domain integration algorithm Quasi- emulation, finally determines best design parameter according to transmission characteristic, as depicted in figs. 1 and 2.
Two, based on the integrated VO in part2The Terahertz active modulator processing and fabricating of material
Actual fabrication is carried out according to the Terahertz modulator structure parameter that such as Fig. 1 and Fig. 2 is simulated, uses L-edit software first The structure of Fig. 1 is drawn into mask plate file, then is made into mask plate.Then the specific steps process of sample making is as follows:
(1) in Al2O3VO is grown on substrate2Film
(2) spin coating photoresist AZ1500
(the Al on substrate2O3+VO2), spin coating 1 layer photoresist Z1500, pre- revolving speed 600rpm, stabilized (steady-state) speed 4000rpm, in advance The time of revolving speed and stabilized (steady-state) speed is respectively 6 seconds and 40 seconds, and baking temperature is 90 DEG C, and the time is 5 minutes.
(3) uv-exposure and development
The substrate for coating photoresist and mask plate (MASK) are placed on litho machine and are aligned, mask plate structure VO2Week Phase structure.Time for exposure is 18 seconds, has been exposed followed by be developed with developer for positive photoresist, and developing time is 17 seconds, then It is dried after progress, baking temperature is 90 DEG C, and the time is 10 minutes.
(4) VO is etched2
The part VO for needing to leave after development2Material is photo-etched glue AZ1500 covering, uses reactive ion etching (RIE) work Skill carves VO2Structure, etching condition are as follows: etching gas CF4, flow 40sccm, and etching process pressure is 3Pa, radio frequency source function Rate is 100W, etch period 3min.It is cleaned after the completion of etching, acetone removes photoresist, is cleaned afterwards using alcohol deionized water, 90 Degree drying.
(5) two layer photoresist LOR10b and AZ1500 of spin coating
In step (4) afterwards sample, first spin coating one layer photoresist LOR10B, pre- revolving speed 600rpm, stabilized (steady-state) speed The time of 4000rpm, pre- revolving speed and stabilized (steady-state) speed is respectively 6 seconds and 40 seconds, and baking temperature is 150 DEG C, and the time is 5 minutes, then The time of the second layer photoresist of spin coating AZ1500, pre- revolving speed 600rpm, stabilized (steady-state) speed 4000rpm, pre- revolving speed and stabilized (steady-state) speed point Wei not be 6 seconds and 40 seconds, baking temperature is 90 DEG C, and the time is 5 minutes.
(6) uv-exposure and the development of step (3) are repeated, mask plate structure at this moment is metal periodic structure, and is needed VO before alignment2Structure carries out alignment, and the time for exposure 18 seconds, developing time was 14 seconds.
(7) on the photoresist AZ1500 and substrate one layer of 200nm thickness of magnetron sputtering golden film, then one layer will have been sputtered The substrate of golden film is immersed in one on the remaining photoresist AZ1500 and photoresist AZ1500 of removing removal in acetone soln Layer golden film, then removes remaining photoresist LOR10b with developer solution.
By procedure above, so that it may obtain the integrated VO in part as depicted in figs. 1 and 22The Terahertz of material is actively modulated Device.
Three, the integrated VO in part2The Terahertz active modulators modulate method of material
(1) temperature regulates and controls: the part is integrated VO2The Terahertz active modulator of material is fixed on controllable temperature sample Frame is placed in test terahertz time-domain spectroscopy system, heats modulation Terahertz transmission spectrum by thermal station;
(2) part strong THz electric field regulation: is integrated into VO2The Terahertz active modulator of material is fixed on high field too At Terahertz hot spot convergence in hertz time-domain spectroscopy system, change the Terahertz electricity for getting to the modulator using Terahertz wiregrating Field size modulations Terahertz transmission spectrum;
(3) laser pump (ing) regulates and controls: the part is integrated VO2The Terahertz active modulator of material is fixed on test with too In hertz time-domain spectroscopy system, is got on the modulator using femtosecond laser and modulate Terahertz transmission spectrum.
Four, the integrated VO in part2The Terahertz active modulator experimental result of material and discussion
The part that the present invention designs integrates VO2The most important application aspect of Terahertz active modulator of material is that signal passes Defeated modulation.As can be seen from Figure 3, when temperature is 60 degree, in 0.704THz, temperature increases the centre frequency of transmission peaks modulator transmission peaks When to 68 degree, the centre frequency of transmission peaks is in 0.595THz, and when temperature continues to increase to 72 degree, the centre frequency of transmission peaks is 0.476THz, frequency modulation(PFM) reach 228GHz.
In addition, part of the invention integrates VO2The Terahertz active modulator of material also can be used Terahertz electric field with And the method for laser regulation modulates transmission spectrum.Other active Terahertz modulators relatively reported in the literature, can be with smaller Additional temperature, Terahertz electric field, laser change to obtain bigger modulation range, while the integrated VO in part2The Terahertz master of material Dynamic modulator uses minimal amount of VO2Material regulates and controls freer and more economical practical.
In short, the part that we design and produce integrates VO2The Terahertz active modulator of material, it is new to be mainly reflected in structure The advantages that grain husk, the selection of material is superior, and modulator approach is simple and convenient, and modulation is free, and modulation rate is high.According to actual needs, by right The optimization design of structure can also obtain the better device of other tuning performances.Therefore, it is widely used in Terahertz modulator side Face.

Claims (9)

1. a kind of part integrates VO2The Terahertz active modulator of material, which is characterized in that including Al2O3Substrate is grown in institute State Al2O3Part on substrate integrates VO2The metallic resonator structure of structure, the metallic resonator structure include multiple periods The cellular construction of arrangement.
2. a kind of part integrates VO according to claim 12The Terahertz active modulator of material, which is characterized in that the list Metal structure in meta structure is opening resonance Fang Huan, the VO2Structure is integrated in the opening of opening resonance Fang Huan.
3. a kind of part integrates VO according to claim 12The Terahertz active modulator of material, which is characterized in that described Al2O3Substrate with a thickness of 0.5mm.
4. a kind of part integrates VO as described in claim 12The preparation method of the Terahertz active modulator of material, feature exist In including the following steps: (1) in Al2O3VO is grown on substrate2Film;(2) spin coating photoresist AZ1500: VO is being grown2It is thin The Al of film2O3On substrate, spin coating photoresist AZ1500;(3) it uv-exposure and development: is placed on litho machine and coats photoetching The Al of glue AZ15002O3Substrate and mask plate are simultaneously aligned, and the structure of the mask plate is periodic structure, have been exposed followed by use Developer for positive photoresist develops, and dries after then carrying out;(4) VO is etched using reactive ion etching process2Structure, acetone cleaning Photoresist AZ1500 is dried after the cleaning of alcohol deionized water;(5) two layer photoresist LOR10b and AZ1500 of spin coating;Repeat step (3), mask plate patterns are golden structure graph at this time;(6) sputtering metal membrane: magnetron sputtering apparatus is used, after step (5) Al2O3One layer of metal is sputtered on substrate, will sputter the Al of one layer of metal2O3Substrate removing remove remaining photoresist with it is described One layer of metal on photoresist, then removes remaining photoresist and obtains the resonator structure of periodic arrangement.
5. the integrated VO in part according to claim 42The preparation method of the Terahertz active modulator of material, which is characterized in that In the step (2) and step (3), in the Al2O3One layer photoresist AZ1500, pre- revolving speed 600rpm of spin coating on substrate stablize The time of revolving speed 4000rpm, pre- revolving speed and stabilized (steady-state) speed is respectively 6 seconds and 40 seconds, and baking temperature is 90 DEG C, and the time is 5 minutes, The photoresist AZ1500 is exposed using litho machine, the time is 18 seconds, is shown after having exposed with developer for positive photoresist Shadow, time are 17 seconds, are dried after then carrying out, and baking temperature is 90 DEG C, and the time is 10 minutes.
6. the integrated VO in part according to claim 42The preparation method of the Terahertz active modulator of material, which is characterized in that Reactive ion etching process is used in the step (4), by gas CF4, controls throughput 40sccm, etch period 3min, In the Al2O3Substrate surface processes periodic VO2Structure.
7. the integrated VO in part according to claim 42The preparation method of the Terahertz active modulator of material, which is characterized in that In the step (5), in the Al2O3On substrate, first spin coating one layer photoresist LOR10b, pre- revolving speed 600rpm, stabilized (steady-state) speed The time of 4000rpm, pre- revolving speed and stabilized (steady-state) speed is respectively 6 seconds and 40 seconds, and baking temperature is 150 DEG C, and the time is 5 minutes, then The time of the second layer photoresist of spin coating AZ1500, pre- revolving speed 600rpm, stabilized (steady-state) speed 4000rpm, pre- revolving speed and stabilized (steady-state) speed point Wei not be 6 seconds and 40 seconds, baking temperature is 90 DEG C, and the time is 5 minutes;Using litho machine to the photoresist LOR10b and AZ1500 It is exposed, the time is 18 seconds, is developed after having exposed with developer for positive photoresist, and the time is 14 seconds, is dried after then carrying out, and is dried Roasting temperature is 90 DEG C, and the time is 10 minutes.
8. the integrated VO in part according to claim 42The preparation method of the Terahertz active modulator of material, which is characterized in that In the step (6), in the Al of the photoresist AZ1500 and exposing2O3One layer of metal is grown on substrate, will grown one layer of gold The Al of category2O3Substrate is immersed in removing in acetone soln and removes on the remaining photoresist AZ1500 and photoresist AZ1500 Then one layer of metal removes remaining photoresist LOR10b with developer solution and obtains the resonator structure of periodic arrangement.
9. integrating VO using a kind of part as described in claim 12The modulator approach of the Terahertz active modulator of material, it is special Sign is, including following 3 kinds of modulation means:
1) temperature regulates and controls: the part is integrated VO2The Terahertz active modulator of material is fixed on controllable temperature specimen holder, is placed in In test terahertz time-domain spectroscopy system, modulation Terahertz transmission spectrum is heated by thermal station;
2) part strong THz electric field regulation: is integrated into VO2When the Terahertz active modulator of material is fixed on high field Terahertz At Terahertz hot spot convergence in the spectroscopic system of domain, the Terahertz active modulator is got to too using the change of Terahertz wiregrating Hertz electric field level modulation Terahertz transmission spectrum;
3) laser pump (ing) regulates and controls: the part is integrated VO2When the Terahertz active modulator of material is fixed on test Terahertz In the spectroscopic system of domain, is got on the Terahertz active modulator using femtosecond laser and modulate Terahertz transmission spectrum.
CN201910337443.2A 2019-04-25 2019-04-25 A kind of integrated VO in part2Terahertz active modulator of material and preparation method thereof Pending CN110048199A (en)

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CN110426867A (en) * 2019-07-31 2019-11-08 电子科技大学 A kind of broadband Terahertz modulator based on gradual change opening
CN111123422A (en) * 2020-01-07 2020-05-08 南京大学 Novel terahertz dynamic adjustable grating and preparation method thereof
CN111641010A (en) * 2020-06-15 2020-09-08 桂林电子科技大学 Terahertz waveband temperature control switch device
CN116053735A (en) * 2023-03-20 2023-05-02 电子科技大学 Adjustable terahertz SSPPs transmission line

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN110426867A (en) * 2019-07-31 2019-11-08 电子科技大学 A kind of broadband Terahertz modulator based on gradual change opening
CN110426867B (en) * 2019-07-31 2020-09-25 电子科技大学 Broadband terahertz modulator based on gradual change opening
CN111123422A (en) * 2020-01-07 2020-05-08 南京大学 Novel terahertz dynamic adjustable grating and preparation method thereof
CN111641010A (en) * 2020-06-15 2020-09-08 桂林电子科技大学 Terahertz waveband temperature control switch device
CN116053735A (en) * 2023-03-20 2023-05-02 电子科技大学 Adjustable terahertz SSPPs transmission line
CN116053735B (en) * 2023-03-20 2024-03-08 电子科技大学 Adjustable terahertz SSPPs transmission line

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Application publication date: 20190723