CN110002910A - A kind of organic fertilizer flowerpot and preparation method thereof based on foamed polymer carrier - Google Patents

A kind of organic fertilizer flowerpot and preparation method thereof based on foamed polymer carrier Download PDF

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Publication number
CN110002910A
CN110002910A CN201811379505.8A CN201811379505A CN110002910A CN 110002910 A CN110002910 A CN 110002910A CN 201811379505 A CN201811379505 A CN 201811379505A CN 110002910 A CN110002910 A CN 110002910A
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CN
China
Prior art keywords
parts
flowerpot
fertilizer
chicken manure
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811379505.8A
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Chinese (zh)
Inventor
陈辉
刘萌
董占锁
刘双
张岩
徐静
黄晨轩
常丽云
白康
周荣艳
王德贺
武圣儒
王飞
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Hebei Agricultural University
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Hebei Agricultural University
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Publication date
Application filed by Hebei Agricultural University filed Critical Hebei Agricultural University
Priority to CN201811379505.8A priority Critical patent/CN110002910A/en
Publication of CN110002910A publication Critical patent/CN110002910A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/02Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
    • A01G9/021Pots formed in one piece; Materials used therefor
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/45Form not covered by groups C05G5/10 - C05G5/18, C05G5/20 - C05G5/27, C05G5/30 - C05G5/38 or C05G5/40, e.g. soluble or permeable packaging

Abstract

The invention discloses a kind of organic fertilizer flowerpots based on foamed polymer carrier, it is made up by weight ratio of the following raw material: 200 ~ 300 parts of chicken manure, 50 ~ 70 parts of humic acid, 30 ~ 50 parts of kaolin, 120 ~ 150 parts of PVC paste resin, 10 ~ 20 parts of chlorinated polyvinyl chloride resin, 5 ~ 10 parts of crosslinking agent, 20 ~ 40 parts of isocyanates, 8 ~ 15 parts of acid anhydrides, 10 ~ 20 parts of azo foaming agent, crosslinking agent is Triallyl isocyanurate, and isocyanates is poly methylene poly phenyl poly isocyanate, acid anhydrides is cis- hexamethylene -1,2- dicarboxylic anhydride.Using fertilizer such as chicken manure, humic acid as Main Nutrients, fertilizer is dispersed the flowerpot by the structural support of foam-like, has the advantages that sustained release, tasteless, easy to use, can persistently play fertilizer efficiency, utilization rate of fertilizer height.

Description

A kind of organic fertilizer flowerpot and preparation method thereof based on foamed polymer carrier
Technical field
The present invention relates to chicken manures to handle application field, has organic fertilizer using chicken manure production in particular to a kind of The flowerpot of function.
Background technique
Chicken manure is a kind of more good organic fertilizer, contains purity nitrogen, phosphorus (P2O5), potassium (K2O) be about 1.63%, 1.54%, 0.85%.Chicken manure before administration must by adequately it is decomposed, the helminth in chicken manure and its ovum and communicable one will be present A little germs in the process of decomposed retting by being inactivated.Chicken manure through sufficiently it is decomposed after become long-term cropping high-quality base manure, and And greatly reduce niff.
Currently, the Land use systems mainly directly fertilising use to chicken manure, although the usage mode of this simple coarse exists Farmland, fruit tree etc. are also difficult to go deep into excavating chicken manure as excellent fertilizer compared with there is the advantages of operation readiness under overall situation Deeply value, cannot generate higher added value.Such as raise flowers in the equal more activity of elegance in individual, be limited to operation, smell, The reason of perception etc., less someone use chicken manure as fertilizer.Promotion is transformed to the usage mode of chicken manure, for more The manurial value for playing chicken manure well, promoting added value of product has greater significance.Application for a patent for invention CN107691021 is disclosed A kind of nutrient flower-pot, by bagasse, sugarcane skin, chicken manure etc. fermentation after animal wastes and loose poroid waste material using bonding agent into Row is bonded and is fabricated to flowerpot, and bonding agent is using substances such as starch, flour, dextrin, sodium carboxymethylcelluloses.Used in the flowerpot Slow release coating agent is one of sulfur-bearing thermosetting polymer and resin, and is the inner surface for being sprayed on forming flowerpot, without It is difference Wrapped fertilizer particle, in this way after release membranes rupture, the fertilizer in flowerpot will discharge together, however, it is difficult to play The effect of sustained release, when doing raw material using chicken manure, the chicken manure of high fertility concentrates release, is easy burn flowers and plants.Although the flowerpot is adopted Certain hole is produced with poroid waste material, but hole exists only in inside poroid waste material, since the bonding agent of use is bonded consolidation, It is difficult to generate hole between fertilizer and fertilizer, is unfavorable for fertilizer and transports and permeate outward, internal fertilizer is actually made to be difficult to play Fertilizer efficiency.
Summary of the invention
The object of the present invention is to provide a kind of organic fertilizer flowerpot based on foamed polymer carrier, the flowerpot with chicken manure, The fertilizer such as humic acid are Main Nutrients, and fertilizer is dispersed by the structural support of foam-like, have and are sustained, are tasteless, easy to use excellent Point, can persistently play fertilizer efficiency, and utilization rate of fertilizer is high.
To achieve the above object, the present invention takes following technical scheme:
A kind of organic fertilizer flowerpot based on foamed polymer carrier, is made up by weight ratio of the following raw material: chicken manure 200 ~ 300 parts, 50 ~ 70 parts of humic acid, 30 ~ 50 parts of kaolin, 120 ~ 150 parts of PVC paste resin, chlorinated polyvinyl chloride resin 10 ~ 20 parts, 5 ~ 10 parts of crosslinking agent, 20 ~ 40 parts of isocyanates, 8 ~ 15 parts of acid anhydrides, 10 ~ 20 parts of azo foaming agent, the crosslinking agent is Triallyl isocyanurate, the isocyanates are poly methylene poly phenyl poly isocyanate, and the acid anhydrides is cis- hexamethylene Alkane -1,2- dicarboxylic anhydride.
Preferably, the chicken manure is by decomposed chicken manure, and the K value of the PVC paste resin is 70 ~ 80, and chlorination is poly- Vinyl chloride resin chlorinty is not less than 64%, and the foaming agent is the mixture of azodicarbonamide and azodiisobutyronitrile, the two Weight ratio is 1:1 ~ 1:5.
It is a further object to provide the preparation methods of the organic flowerpot of above-mentioned chicken manure, adopt the following technical scheme that:
The preparation method of the above-mentioned organic fertilizer flowerpot based on foamed polymer carrier, includes the following steps:
(a) chicken manure, humic acid, kaolin are crushed to 200 mesh or more and are uniformly mixed, obtain solid powder;
(b) at 0.09MPa, by the PVC paste resin, chlorinated polyvinyl chloride resin, crosslinking agent, isocyanates, acid Acid anhydride, azo foaming agent are uniformly mixed, and the solid powder is then added, and obtain pasty mixture within stirring 15 ~ 20 minutes;
(b) Mould for flower pot that pasty mixture is poured into good seal, in temperature be 120 ~ 130 DEG C and pressure is 10 ~ 30MPa's Under the conditions of be pressed and molded, cooling mold is opened to obtain flowerpot idiosome;
(c) the flowerpot idiosome is placed in 90 ~ 98 DEG C of vaporium and is foamed, then carried out in 60 DEG C of vaporium Curing process obtains A chicken-manure organic fertilizer flowerpot.
The beneficial effects of the present invention are crush decomposed chicken manure, these biological nutriment of humic acid and kaolin and mix Close, kaolin has the advantages that easy bonding forming, mixed integrally with fertilizer, can play the role of release membranes, i.e., with It is kaolinic to be slowly dissolved precipitation, the fertility of fertilizer also corresponding slow release.Humic acid can be used for improving the soil in flowerpot, It prevents hardened.By said components and PVC paste resin, chlorinated polyvinyl chloride resin, crosslinking agent, isocyanates, acid anhydrides, idol The raw material that nitrogen class foaming agent etc. prepares foam mixes, and forming is reacted under specific temperature and pressure, then foaming and setting again, this Fertilizer components and kaolin are supported mould that is immobilized, and utilizing flowerpot shape in the structure that space is stretched using crosslinked resin by sample Tool forms flowerpot shape, is evenly distributed with bubble in the flowerpot, these bubbles can not only make flowerpot ventilative, but also have and keep moisture The moisture of function, bubble absorption can be slowly dissolved kaolin and fertilizer nutrient, make fertility slow release.
Specific embodiment
The present invention will be further described below:
Every part of following formulas are 50 grams.
Embodiment 1
Be formulated as follows: 200 parts of chicken manure, 50 parts of humic acid, 30 parts of kaolin, K value is 120 parts of PVC paste resin of 70, is contained 20 parts of 64% chlorinated polyvinyl chloride resin of chlorine dose, 10 parts of crosslinking agent, 20 parts of isocyanates, 15 parts of acid anhydrides, azo foaming agent 10 Part, crosslinking agent is Triallyl isocyanurate, and isocyanates is poly methylene poly phenyl poly isocyanate, and acid anhydrides is cis- ring Hexane -1,2- dicarboxylic anhydride, foaming agent are the mixture of azodicarbonamide and azodiisobutyronitrile, and the two weight ratio is 1: 1。
According to formula ingredient, chicken manure, humic acid, kaolin are crushed to 200 mesh or more and are uniformly mixed, solid powder is obtained Material.In the case where vacuum degree is 0.09MPa, by PVC paste resin, chlorinated polyvinyl chloride resin, crosslinking agent, isocyanates, acid Acid anhydride, azo foaming agent are uniformly mixed, and solid powder is then added, and obtain pasty mixture within stirring 20 minutes;By the thickener of preparation 20mm thickness steel Mould for flower pot is filled, mold is put into 120 DEG C of platen-press after molding, pressure is to keep under 10MPa Cooling mold, is opened when mold temperature is lower than 60 DEG C after 10min;By the flowerpot idiosome of taking-up be placed in 90 DEG C of vaporium into Row foaming, is made foam;Foam is post-processed 2 days in 60 DEG C of vaporium, is obtained based on the organic of foamed polymer carrier Fertilizer flowerpot.
Embodiment 2
Be formulated as follows: 300 parts of chicken manure, 70 parts of humic acid, 50 parts of kaolin, K value is 150 parts of PVC paste resin of 75, is contained 10 parts of 68% chlorinated polyvinyl chloride resin of chlorine dose, 5 parts of crosslinking agent, 40 parts of isocyanates, 8 parts of acid anhydrides, 20 parts of azo foaming agent, Crosslinking agent is Triallyl isocyanurate, and isocyanates is poly methylene poly phenyl poly isocyanate, and acid anhydrides is cis- hexamethylene Alkane -1,2- dicarboxylic anhydride, foaming agent are the mixture of azodicarbonamide and azodiisobutyronitrile, and the two weight ratio is 1:5.
According to formula ingredient, chicken manure, humic acid, kaolin are crushed to 200 mesh or more and are uniformly mixed, solid powder is obtained Material.In the case where vacuum degree is 0.09MPa, by PVC paste resin, chlorinated polyvinyl chloride resin, crosslinking agent, isocyanates, acid Acid anhydride, azo foaming agent are uniformly mixed, and solid powder is then added, and obtain pasty mixture within stirring 20 minutes;By the thickener of preparation 20mm thickness steel Mould for flower pot is filled, mold is put into 130 DEG C of platen-press after molding, pressure is to keep under 30MPa Cooling mold, is opened when mold temperature is lower than 60 DEG C after 10min;By the flowerpot idiosome of taking-up be placed in 98 DEG C of vaporium into Row foaming, is made foam;Foam is post-processed 2 days in 60 DEG C of vaporium, is obtained based on the organic of foamed polymer carrier Fertilizer flowerpot.
Embodiment 3
Be formulated as follows: 260 parts of chicken manure, 60 parts of humic acid, 40 parts of kaolin, K value is 130 parts of PVC paste resin of 80, is contained 15 parts of 64% chlorinated polyvinyl chloride resin of chlorine dose, 8 parts of crosslinking agent, 30 parts of isocyanates, 10 parts of acid anhydrides, 15 parts of azo foaming agent, Crosslinking agent is Triallyl isocyanurate, and isocyanates is poly methylene poly phenyl poly isocyanate, and acid anhydrides is cis- hexamethylene Alkane -1,2- dicarboxylic anhydride, foaming agent are the mixture of azodicarbonamide and azodiisobutyronitrile, and the two weight ratio is 1:3.
According to formula ingredient, chicken manure, humic acid, kaolin are crushed to 200 mesh or more and are uniformly mixed, solid powder is obtained Material.In the case where vacuum degree is 0.09MPa, by PVC paste resin, chlorinated polyvinyl chloride resin, crosslinking agent, isocyanates, acid Acid anhydride, azo foaming agent are uniformly mixed, and solid powder is then added, and obtain pasty mixture within stirring 20 minutes;By the thickener of preparation 20mm thickness steel Mould for flower pot is filled, mold is put into 125 DEG C of platen-press after molding, pressure is to keep under 20MPa Cooling mold, is opened when mold temperature is lower than 60 DEG C after 10min;By the flowerpot idiosome of taking-up be placed in 90 DEG C of vaporium into Row foaming, is made foam;Foam is post-processed 2 days in 60 DEG C of vaporium, obtains A chicken-manure organic fertilizer flowerpot.
The using effect of the flowerpot of the present invention of embodiment 4
Using embodiment 3 make flowerpot 1, comparison flowerpot 2, comparison flowerpot 3 plant respectively the identical Chinese rose of initial situation, Each 30 plants of rose, tree peony, the duration 1 year, as a result as shown in following each table:
Table 1 is to Chinese rose, rose and tree peony planting effect
The flowerpot 2 of comparison is common mud earthen basin, and the flowerpot 3 of comparison is to make by embodiment 4 in application for a patent for invention CN107691021 The flowerpot of work.
In above-mentioned 1 year breeding process, do not apply fertilizer using 1 overall process of flowerpot of the invention, and without going out Existing chicken manure peculiar smell, 1 liang of week of comparison flowerpot mend a fertilizer, and comparison 2 first trimester of flowerpot does not apply fertilizer, and burn seedlings feelings occurs in centre Condition affects growing way.It is comprehensively compared, flowerpot of the invention will be due to two flowers of comparison to above-mentioned three kinds of colored culture efficiencies Basin.
Above-described embodiment is the explanation to present inventive concept and realization, is not intended to limit it, in present inventive concept Under, without the technical solution that substantially converts still in protection scope.

Claims (3)

1. a kind of organic fertilizer flowerpot based on foamed polymer carrier, it is characterised in that made by weight ratio by the following raw material At: 200 ~ 300 parts of chicken manure, 50 ~ 70 parts of humic acid, 30 ~ 50 parts of kaolin, 120 ~ 150 parts of PVC paste resin, chlorinated polyvinyl chloride 10 ~ 20 parts of vinyl, 5 ~ 10 parts of crosslinking agent, 20 ~ 40 parts of isocyanates, 8 ~ 15 parts of acid anhydrides, 10 ~ 20 parts of azo foaming agent, The crosslinking agent is Triallyl isocyanurate, and the isocyanates is poly methylene poly phenyl poly isocyanate, the acid Acid anhydride is cis- hexamethylene -1,2- dicarboxylic anhydride.
2. as described in claim 1 based on the organic fertilizer flowerpot of foamed polymer carrier, it is characterised in that the chicken manure is By decomposed chicken manure, the K value of the PVC paste resin is 70 ~ 80, and chlorinated polyvinyl chloride resin chlorinty is not less than 64%, the foaming agent is the mixture of azodicarbonamide and azodiisobutyronitrile, and the two weight ratio is 1:1 ~ 1:5.
3. the preparation method of the organic fertilizer flowerpot based on foamed polymer carrier, feature exist as claimed in claim 1 or 2 In including the following steps:
(a) chicken manure, humic acid, kaolin are crushed to 200 mesh or more and are uniformly mixed, obtain solid powder;
(b) at 0.09MPa, by the PVC paste resin, chlorinated polyvinyl chloride resin, crosslinking agent, isocyanates, acid Acid anhydride, azo foaming agent are uniformly mixed, and the solid powder is then added, and obtain pasty mixture within stirring 15 ~ 20 minutes;
(c) Mould for flower pot that pasty mixture is poured into good seal, in temperature be 120 ~ 130 DEG C and pressure is 10 ~ 30MPa's Under the conditions of be pressed and molded, cooling mold is opened to obtain flowerpot idiosome;
(d) the flowerpot idiosome is placed in 90 ~ 98 DEG C of vaporium and is foamed, then carried out in 60 DEG C of vaporium Curing process obtains A chicken-manure organic fertilizer flowerpot.
CN201811379505.8A 2018-11-20 2018-11-20 A kind of organic fertilizer flowerpot and preparation method thereof based on foamed polymer carrier Pending CN110002910A (en)

Priority Applications (1)

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CN201811379505.8A CN110002910A (en) 2018-11-20 2018-11-20 A kind of organic fertilizer flowerpot and preparation method thereof based on foamed polymer carrier

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Application Number Priority Date Filing Date Title
CN201811379505.8A CN110002910A (en) 2018-11-20 2018-11-20 A kind of organic fertilizer flowerpot and preparation method thereof based on foamed polymer carrier

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4193909A (en) * 1977-03-16 1980-03-18 Ashland Oil, Inc. Flower pot and method for making
CN101580573A (en) * 2009-06-08 2009-11-18 常州天晟新材料股份有限公司 Improved crosslinked polyvinyl chloride structural foam and preparation method thereof
WO2015056987A1 (en) * 2013-10-18 2015-04-23 한국산업기술대학교산학협력단 Artificial soil composition and method for manufacturing artificial flowerpot by using artificial soil composition
CN106069310A (en) * 2016-08-16 2016-11-09 梁文涛 A kind of degradative flower bowl and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4193909A (en) * 1977-03-16 1980-03-18 Ashland Oil, Inc. Flower pot and method for making
CN101580573A (en) * 2009-06-08 2009-11-18 常州天晟新材料股份有限公司 Improved crosslinked polyvinyl chloride structural foam and preparation method thereof
WO2015056987A1 (en) * 2013-10-18 2015-04-23 한국산업기술대학교산학협력단 Artificial soil composition and method for manufacturing artificial flowerpot by using artificial soil composition
CN106069310A (en) * 2016-08-16 2016-11-09 梁文涛 A kind of degradative flower bowl and preparation method thereof

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