CN110002814A - Modified high elasticity waterproof coating and preparation method thereof - Google Patents
Modified high elasticity waterproof coating and preparation method thereof Download PDFInfo
- Publication number
- CN110002814A CN110002814A CN201910134210.2A CN201910134210A CN110002814A CN 110002814 A CN110002814 A CN 110002814A CN 201910134210 A CN201910134210 A CN 201910134210A CN 110002814 A CN110002814 A CN 110002814A
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- Prior art keywords
- waterproof coating
- high elasticity
- liquid material
- modified high
- elasticity waterproof
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/10—Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of modified high elasticity waterproof coating and preparation method thereof, and the coating includes liquid material part and powder part;It is in terms of 100% by the weight of liquid material part, the liquid material part includes each component of following weight content: acrylic acid modified macromolecule emulsion 85%~95%;Coalescing agent 0~10%;Defoaming agent 1%~5%;Water 1%~10%;It is in terms of 100% by the weight of powder part, the powder part includes each component of following weight content: portland cement 30%~40%;Calcium carbonate 29.5%~50%;Resin sand 10%~30%;Water-reducing agent 0.1%~0.5%.Liquid material and powder are prepared by the mass ratio of 1:1.1~1.5.Coating of the present invention has the advantages of preferable extensibility, tensile strength, water resistance and weatherability, good water-proof effect, aqueous, environmentally protective, pollution-free painting construction easy for construction, cold is easy to special-shaped part construction, seamless good integrity.
Description
Technical field
The present invention relates to water-repellent paint technical fields, and in particular, to a kind of modified high elasticity waterproof coating and its system
Preparation Method.
Background technique
Middle nineteen nineties in last century, China discloses the GB5020794 national standard of " Technical code for roof engineering ", right
The quality requirement and construction method of different classes of water-repellent paint, the acceptance of work are all made that clearly stipulate that this is to water-repellent paint
Development play positive effect.Currently, waterproof material in the market has two major classes: one kind is polyurethanes water-repellent paint.This
Class material is usually to be made of polyurethane and pitch prill as raw material, but when using this coating, generally using it is containing toluene,
The organic solvents such as dimethylbenzene dilute, thus containing toxic, so also being used by limitation.Another kind of is polymer cement-based waterproof
Coating.The lotion that it is synthesized by a variety of waterborne polymerics is formed with the high grade cement mixed with various additives, the flexibility of polymer
It is became one with the rigidity of cement, so that it is excellent in terms of impermeability is with stability.Its advantages are easy for construction, comprehensive
Close low cost, short time limit, and asepsis environment-protecting.Therefore, polyalcohol cement basis has become the leading role in water-repellent paint market, but it draws
It stretches that adhesion strength is lower, flexibility is general, has limitation to the use of moisture substrate.
The application for a patent for invention of Publication No. CN106699066A discloses a kind of two-component polyacrylate water-repellent paint,
Including component A and B component, wherein component A includes styrene-acrylic emulsion, N-N methylene-bisacrylamide, dispersing agent, defoaming agent, B group
Divide includes 425 portland cements, silica flour, powdered whiting, carboxylate water-reducing agent;A, B component passes through rational proportion, compound system
At a kind of double-component aqueous building water-proof paint, so that elastic waterproof layer obtained tensile strength with higher, water-fast, weather-proof
Property is good.But the water-repellent paint of the patent is due to having selected styrene-acrylic emulsion, since styrene-acrylic emulsion is mainly gathered by styrene and acrylic acid
It closes, object point is that adhesive force is good, and paint film is transparent, and water-fast, water resistance, alkaline resistance properties are good, and weaker in terms of weatherability
And it is poor in the adhesion strength of moisture substrate.
Summary of the invention
For the defects in the prior art, the object of the present invention is to provide a kind of modified high elasticity waterproof coating and its systems
Preparation Method.
The purpose of the present invention is achieved through the following technical solutions:
The present invention provides a kind of modified high elasticity waterproof coating, and the waterproof coating includes liquid material part and powder portion
Point;
It is in terms of 100% by the weight of liquid material part, the liquid material part includes each component of following weight percent content:
It is in terms of 100% by the weight of powder part, the powder part includes each component of following weight percent content:
Preferably, the mass ratio of the liquid material part and powder part is 1:1.3.
Preferably, the acrylic acid modified macromolecule emulsion is self-cross linking type pure acrylic latex.The lotion is free from first
The high-performance elastic lotion of aldehyde and its derivative.Since self-crosslinking technology is to introduce a small amount of bridging property list in emulsion polymerization process
Body makes acrylate linear macromolecular chain is lightly crosslinked to reticulate.This lightly crosslinked movement for making macromolecular chain is by appropriate
Limitation, improve water resistance and ageing resistance.
It is highly preferred that the acrylic acid modified macromolecule emulsion is selected from the RS-9689A of Ahmedabad enrichment group.Due to RS-
9689A has used lotion self-crosslinking technology and ultraviolet curing oligomer technology, hands over acrylate linear macromolecular chain slightly
It is unified into netted.This lightly crosslinked movement for making macromolecular chain by limitation appropriate, improve water resistance and ageing resistance and
And excellent elasticity is still able to maintain under low temperature makes product of the present invention have the property such as better waterproofness, extensibility and ageing resistance
Energy.According to the self-cross linking type pure acrylic latex of other models, production of the present invention is not achieved in terms of uvioresistant and extension property
The performance of product.
Preferably, the mass ratio of the acrylic acid modified macromolecule emulsion, portland cement and resin sand is 1:0.41:
0.14。
Preferably, the coalescing agent is selected from Guangzhou Ang Di Chemical Co., Ltd., model AD-82.
Preferably, the defoaming agent is GPE type defoaming agent.
Preferably, the portland cement is No. 32.5 or No. 42.5 portland cements.
Preferably, the mesh number of the calcium carbonate is 200 mesh~300 mesh, and the calcium carbonate is powdered whiting.
Preferably, the resin sand is casting sand, and fineness is 50 mesh~100 mesh.Due to being added to resin in the present invention
Sand improves adhesion strength of this product on moisture substrate, overcomes other waterproof materials and is difficult answering on moisture substrate
Use problem;And the roughness of waterproof membrane coated surface is also improved, increase the adhesion strength and shearing force of subsequent stickup.
Preferably, the water-reducing agent is the water-reducing agent of German BASF.
The present invention also provides a kind of preparation methods of modified high elasticity waterproof membrane, include the following steps:
S1, acrylic acid modified macromolecule emulsion, coalescing agent defoaming agent and water are uniformly mixed, liquid material part is made;
S2, cement, calcium carbonate, resin sand and water-reducing agent are sequentially added in mixing machine, is stirred evenly, powder portion is made
Point;
S3, the powder part is added in the liquid material part, then stirs evenly pulp, that is, can be used.
Compared with prior art, the invention has the following beneficial effects:
1, due to being pressed using the acrylic acid modified macromolecule emulsion of super-weathering resistance and inorganic ordinary portland cement and resin sand
The modified high elasticity waterproof membrane of certain proportion preparation, stronger with mortar affinity, more alkali resistance, tensile bond strength height prolong
It is good to stretch performance, and can also play its effect on moisture substrate.
2, modified high elasticity waterproof membrane of the invention uses the acrylic acid modified macromolecule emulsion of super-weathering resistance, with super strength
Anti-uv-ray, not easy to aging, cracking, low temperature flexibility is good.
3, modified high elasticity waterproof coating of the invention, construction is simple, brushing roller coating, spray, scrape and smear construction.
4, adhesion strength of this product on moisture substrate is improved, is overcome due to being added to resin sand in the present invention
Other waterproof materials are difficult the application problem on moisture substrate;And the roughness of waterproof membrane coated surface is also improved, increase
The adhesion strength and shearing force of subsequent stickup.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field
For personnel, without departing from the inventive concept of the premise, several changes and improvements can also be made.These belong to the present invention
Protection scope.
The present invention provides a kind of modified high elasticity waterproof coating, and the waterproof coating includes liquid material part and powder portion
Point;
It is in terms of 100% by the weight of liquid material part, the liquid material part includes each component of following weight percent content:
It is in terms of 100% by the weight of powder part, the powder part includes each component of following weight percent content:
The mass ratio of the liquid material part and powder part is 1:1.3.
The acrylic acid modified macromolecule emulsion is self-cross linking type pure acrylic latex, the RS- selected from Ahmedabad enrichment group
The mass ratio of acrylic acid modified macromolecule emulsion, portland cement and resin sand described in 9689A is 1:0.41:0.14.
The coalescing agent is selected from Guangzhou Ang Di Chemical Co., Ltd., model AD-82.
The defoaming agent is GPE type defoaming agent.
The portland cement is No. 32.5 or No. 42.5 portland cements.
The mesh number of the calcium carbonate is 200 mesh~300 mesh, and the calcium carbonate is powdered whiting.
The resin sand is casting sand, and fineness is 50 mesh~100 mesh.
Preferably, the water-reducing agent is the water-reducing agent of German BASF.
Examples 1 to 7
Examples 1 to 7 is related to a kind of modified high elasticity waterproof coating and preparation method thereof, the group of the waterproof coating
Divide and its content is shown in Table 1.
Preparation method following steps:
The preparation of S1, liquid material part: it adds water in the acrylic acid modified macromolecule emulsion of super-weathering resistance, stirs evenly again
Coalescing agent is added, defoaming agent continues to stir evenly;
The preparation of S2, powder part: by ordinary portland cement, powdered whiting, resin sand, water-reducing agent sequentially adds mixed
In conjunction machine, it is thoroughly mixed uniformly;
Powder part is added to liquid material part and is stirred by S3, last (liquid material and powder quality ratio) to scale
Pulpous state can be used.
Table 1
Comparative example 1
This comparative example is related to a kind of modified high elasticity waterproof coating and preparation method thereof, the component of the waterproof coating
It is almost the same with embodiment 2, it the difference is that only: resin sand being replaced using silica flour in the coating of this comparative example.Preparation side
The step of method, is same as Example 2.
Comparative example 2
This comparative example is related to a kind of modified high elasticity waterproof coating and preparation method thereof, the component of the waterproof coating
It is almost the same with embodiment 2, it the difference is that only: self-cross linking type pure C alkene being replaced using conventional pure-acrylic emulsion in this comparative example
Yogurt liquid.The step of preparation method, is same as Example 2.
Performance detection
It is mixed in each embodiment and comparative example by liquid material with powder quality ratio for 1:1.3, performance detection is carried out, respectively to each
Solid content, tensile strength, the elongation at break of the waterproof membrane of embodiment and comparative example preparation, adhesion strength, impermeability etc. carry out
Detection, as a result such as table 2.
Table 2
By embodiment 2 in table 2 it is found that the constant increase lotion dosage of powder component of the present invention, can mention compared with embodiment 3
High elongation at tear and adhesion strength;It, can also by embodiment 3 it is found that the constant reduction cement dosage of liquid material compared with embodiment 4
Elongation at break is improved, and adhesion strength and tensile strength decrease, but tree refers to that the increase of sand can be improved in moisture substrate
Adhesion strength and tensile strength;By embodiment 1 it is found that lotion dosage reduces and the increase of cement dosage is disconnected compared with embodiment 5
Elongation reduction is split, lotion dosage increases cement dosage and reduces elongation at break raising.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned
Particular implementation, those skilled in the art can make a variety of changes or modify within the scope of the claims, this not shadow
Ring substantive content of the invention.In the absence of conflict, the feature in embodiments herein and embodiment can any phase
Mutually combination.
Claims (10)
1. a kind of modified high elasticity waterproof coating, which is characterized in that the waterproof coating includes liquid material part and powder portion
Point;
It is in terms of 100% by the weight of liquid material part, the liquid material part includes each component of following weight percent content:
It is in terms of 100% by the weight of powder part, the powder part includes each component of following weight percent content:
2. modified high elasticity waterproof coating according to claim 1, which is characterized in that the liquid material part and powder portion
The mass ratio divided is 1:1.3.
3. modified high elasticity waterproof coating according to claim 1, which is characterized in that the acrylic acid modified macromolecule
Lotion is self-cross linking type pure acrylic latex.
4. modified high elasticity waterproof coating according to claim 1, which is characterized in that the acrylic acid modified macromolecule
The mass ratio of lotion, portland cement and resin sand is 1:0.41:0.14.
5. modified high elasticity waterproof coating according to claim 1, which is characterized in that the coalescing agent is selected from Guangzhou
Ang Di Chemical Co., Ltd., model AD-82.
6. modified high elasticity waterproof coating according to claim 1, which is characterized in that the defoaming agent is that GPE type disappears
Infusion.
7. modified high elasticity waterproof coating according to claim 1, which is characterized in that the portland cement is 32.5
Number or No. 42.5 portland cements.
8. modified high elasticity waterproof coating according to claim 1, which is characterized in that the mesh number of the calcium carbonate is
200 mesh~300 mesh, the calcium carbonate are powdered whiting.
9. modified high elasticity waterproof coating according to claim 1, which is characterized in that the resin sand is cast moulding
Sand, fineness are 50 mesh~100 mesh.
10. a kind of preparation method of modified high elasticity waterproof coating according to claim 1, which is characterized in that including
Following steps:
S1, acrylic acid modified macromolecule emulsion, coalescing agent defoaming agent and water are uniformly mixed, liquid material part is made;
S2, cement, calcium carbonate, resin sand and water-reducing agent are sequentially added in mixing machine, is stirred evenly, powder part is made;
S3, the powder part is added in the liquid material part, then stirs evenly pulp, that is, can be used.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111576207A (en) * | 2020-05-26 | 2020-08-25 | 河南省交通规划设计研究院股份有限公司 | Bridge drip structure |
CN114644868A (en) * | 2022-04-28 | 2022-06-21 | 重庆市盛百利防水建材有限公司 | Quick-drying polymer cement waterproof coating |
CN115403965A (en) * | 2022-08-23 | 2022-11-29 | 河北艾科赛林新材料科技有限公司 | Preparation method of water-based acrylic epoxy resin high-elasticity particle glue |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111576207A (en) * | 2020-05-26 | 2020-08-25 | 河南省交通规划设计研究院股份有限公司 | Bridge drip structure |
CN114644868A (en) * | 2022-04-28 | 2022-06-21 | 重庆市盛百利防水建材有限公司 | Quick-drying polymer cement waterproof coating |
CN115403965A (en) * | 2022-08-23 | 2022-11-29 | 河北艾科赛林新材料科技有限公司 | Preparation method of water-based acrylic epoxy resin high-elasticity particle glue |
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