CN109987921A - Anion ceramic sanitary appliance and preparation method thereof - Google Patents
Anion ceramic sanitary appliance and preparation method thereof Download PDFInfo
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- CN109987921A CN109987921A CN201711490809.7A CN201711490809A CN109987921A CN 109987921 A CN109987921 A CN 109987921A CN 201711490809 A CN201711490809 A CN 201711490809A CN 109987921 A CN109987921 A CN 109987921A
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- C04B33/13—Compounding ingredients
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/6261—Milling
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
- C04B35/62665—Flame, plasma or melting treatment
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
- C04B2235/445—Fluoride containing anions, e.g. fluosilicate
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate, hypophosphite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5454—Particle size related information expressed by the size of the particles or aggregates thereof nanometer sized, i.e. below 100 nm
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The present invention relates to a kind of anion ceramic sanitary appliances, are grouped as by each group of following parts by weight: 23~35 parts of negative ion powder, 5~12 parts of limonite, 2~4 parts of Cha Luoshi, 10~15 parts of china clay, 9~13 parts of kaolin, 6~9 parts of clay, 3~7 parts of plant ash, 4~8 parts of green bean rock, 1~3 part of magnesia;The negative ion powder is grouped as by each group of following parts by weight: 6~12 parts of tourmaline, 2~5 parts of monazite, 6~12 parts of apatite, 3~7 parts of fluorite, 1~3 part of bastnaesite, 9~15 parts of granite.The present invention is suitable for the production of the sanitary wares such as hand basin, bathtub, toilet, squatting pan, can stablize release anion, and haze particle institute is positively charged in neutralization air, makes it easier to floc sedimentation sedimentation, plays the effect of purification air;The volatile organic gas such as energy decomposing formaldehyde, keep domestic environment safer;Anion also has the function of antibacterial, anti-mildew, protection whole family's health.
Description
Technical field
The present invention relates to ceramic sanitary appliances, more particularly, to a kind of anion ceramic sanitary appliance and preparation method thereof.
Background technique
Toilet be urinate and defecate for occupant, the place of bathing, a large amount of bacterium, germ can distribute with excreta
In air, moisture is also easily gathered, is the breeding ground of bacterial growth breeding, is also easy to cause phenomena such as mouldy, sanitary condition is straight
Connect the health for being related to user.And it usually will be installed a large amount of ceramics such as hand basin, bathtub, closestool, squatting pan in toilet
Sanitary ware, ceramic sanitary appliance on the market only has itself bathing and excretory function at present, if can develop environment purification, resist
Bacterium mould proof ceramic sanitary appliance escorts for the health of user, will have huge Social benefit and economic benefit.
Summary of the invention
It is capable of releasing negative ion the object of the present invention is to provide a kind of anion ceramic sanitary appliance and preparation method thereof, more ring
Health care health.
The object of the invention is achieved by the following technical programs:
A kind of anion ceramic sanitary appliance is provided, is grouped as by each group of following parts by weight: 23~35 parts of negative ion powder, limonite
5~12 parts, 2~4 parts of Cha Luoshi, 10~15 parts of china clay, 9~13 parts of kaolin, 6~9 parts of clay, 3~7 parts of plant ash, mung bean
4~8 parts of rock, 1~3 part of magnesia.
Further, the negative ion powder is grouped as by each group of following parts by weight: 6~12 parts of tourmaline, monazite 2
~5 parts, 6~12 parts of apatite, 3~7 parts of fluorite, 1~3 part of bastnaesite, 9~15 parts of granite.
Further, the preparation step of the negative ion powder is as follows: take negative ion powder raw material ball mill mixing 6~
9h is heated to 1280~1450 DEG C of meltings, then keeps the temperature 2~4h, and frit is made in quenching, be ground to particle diameter distribution 50~
80nm, drying of being sieved, obtains negative ion powder.
The preparation method of the anion ceramic sanitary appliance, preparation step are as follows:
S1 takes raw material to expect: ball: water=1:2:0.6~0.8 enters ball milling, and fineness control tails over 0.2 in 300 meshes~
0.3%, slurry iron-removing sieving is aging 1~2 day, spare;
In the mud obtained by step S1 0.1~0.3% CMC is added, 0.2~0.4% potassium sorbate stirs evenly, spare in S2;
Mud obtained by step S2 is injected into the mold of ceramic sanitary appliance by S3 with the pressure of 0.02~0.04MPa, and compression moulding takes
Then green body out enters kiln oxidizing flame after water on drying, repaired biscuit and forces firing.
Further, the firing temperature in the step S3 is 1050~1280 DEG C.
Further, the firing time in the step S3 is 20~25h.
Compared with prior art, the invention has the following advantages:
The present invention provides a kind of anion ceramic sanitary appliances and preparation method thereof, are suitable for hand basin, bathtub, toilet, squat toilet
The production of the sanitary wares such as device, obtained sanitary ware, which is placed in toilet, can stablize release anion, neutralize haze particle in air
(PM2.5) institute is positively charged, makes it easier to floc sedimentation sedimentation, plays the effect of purification air;The oxidisability of anion can play
The effect of the volatile organic gas such as decomposing formaldehyde keeps domestic environment safer;Anion also has the function of antibacterial, anti-mildew,
Protect whole family's health.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below.
Embodiment 1
Present embodiment discloses a kind of anion ceramic sanitary appliances, are grouped as by each group of following parts by weight: 23 parts of negative ion powder,
12 parts of limonite, 2 parts of Cha Luoshi, 15 parts of china clay, 9 parts of kaolin, 9 parts of clay, 3 parts of plant ash, 8 parts of green bean rock, magnesia 1
Part.
The preparation step of the negative ion powder is as follows: take 12 parts of tourmaline, 2 parts of monazite, and 12 parts of apatite, 3 parts of fluorite,
3 parts of bastnaesite, 9 parts of granite ball mill mixing 9h is heated to 1280 DEG C of meltings, then keeps the temperature 4h, and frit is made in quenching,
Particle diameter distribution is ground in 50nm, drying of being sieved obtains negative ion powder.
Embodiment 2
Present embodiment discloses a kind of anion ceramic sanitary appliances, are grouped as by each group of following parts by weight: 35 parts of negative ion powder,
5 parts of limonite, 4 parts of Cha Luoshi, 10 parts of china clay, 13 parts of kaolin, 6 parts of clay, 7 parts of plant ash, 4 parts of green bean rock, magnesia 3
Part.
The preparation step of the negative ion powder is as follows: take 6 parts of tourmaline, 5 parts of monazite, and 6 parts of apatite, 7 parts of fluorite, fluorine
1 part of carbon cerium mine, 15 parts of granite ball mill mixing 6h are heated to 1450 DEG C of meltings, then keep the temperature 2h, and frit is made in quenching,
Particle diameter distribution is ground in 80nm, drying of being sieved obtains negative ion powder.
Embodiment 3
Present embodiment discloses a kind of anion ceramic sanitary appliances, are grouped as by each group of following parts by weight: 28 parts of negative ion powder,
7 parts of limonite, 3 parts of Cha Luoshi, 12 parts of china clay, 12 parts of kaolin, 8 parts of clay, 6 parts of plant ash, 7 parts of green bean rock, magnesia 2
Part.
The preparation step of the negative ion powder is as follows: take 10 parts of tourmaline, 4 parts of monazite, and 8 parts of apatite, 4 parts of fluorite,
2 parts of bastnaesite, 10 parts of granite ball mill mixing 7h is heated to 1300 DEG C of meltings, then keeps the temperature 3h, quenching is made molten
Block is ground to particle diameter distribution in 60nm, and drying of being sieved obtains negative ion powder.
Embodiment 4
Present embodiment discloses a kind of anion ceramic sanitary appliances, are grouped as by each group of following parts by weight: 32 parts of negative ion powder,
10 parts of limonite, 2 parts of Cha Luoshi, 14 parts of china clay, 10 parts of kaolin, 7 parts of clay, 4 parts of plant ash, 5 parts of green bean rock, magnesia 1
Part.
The preparation step of the negative ion powder is as follows: take 8 parts of tourmaline, 3 parts of monazite, and 10 parts of apatite, 6 parts of fluorite,
1 part of bastnaesite, 12 parts of granite ball mill mixing 8h is heated to 1400 DEG C of meltings, then keeps the temperature 4h, quenching is made molten
Block is ground to particle diameter distribution in 70nm, and drying of being sieved obtains negative ion powder.
Embodiment 5
Present embodiment discloses a kind of preparation methods of anion ceramic sanitary appliance, comprising the following steps:
The raw material of 1~4 any embodiment of S1 Example are to expect: ball: water=1:2:0.6 enters ball milling, and fineness control exists
300 meshes tail over 0.3%, and slurry iron-removing sieving is aging 1 day, spare;
In the mud obtained by step S1 0.3% CMC is added, 0.2% potassium sorbate stirs evenly, spare in S2;
Mud obtained by step S2 is injected into the mold of ceramic sanitary appliance by S3 with the pressure of 0.04MPa, and base is taken out in compression moulding
Then body enters kiln oxidizing flame after water on drying, repaired biscuit and forces firing, firing temperature is 1050 DEG C, firing time 25h.
Embodiment 6
Present embodiment discloses a kind of preparation methods of anion ceramic sanitary appliance, comprising the following steps:
The raw material of 1~4 any embodiment of S1 Example are to expect: ball: water=1:2:0.8 enters ball milling, and fineness control exists
300 meshes tail over 0.2%, and slurry iron-removing sieving is aging 2 days, spare;
In the mud obtained by step S1 0.1% CMC is added, 0.4% potassium sorbate stirs evenly, spare in S2;
Mud obtained by step S2 is injected into the mold of ceramic sanitary appliance by S3 with the pressure of 0.02MPa, and base is taken out in compression moulding
Then body enters kiln oxidizing flame after water on drying, repaired biscuit and forces firing, firing temperature is 1280 DEG C, firing time 20h.
Embodiment 7
Present embodiment discloses a kind of preparation methods of anion ceramic sanitary appliance, comprising the following steps:
The raw material of S1 Example 1~4 are to expect: ball: water=1:2:0.7 enters ball milling, and fineness control is tailed in 300 meshes
0.2%, slurry iron-removing sieving is aging 2 days, spare;
In the mud obtained by step S1 0.2% CMC is added, 0.3% potassium sorbate stirs evenly, spare in S2;
Mud obtained by step S2 is injected into the mold of ceramic sanitary appliance by S3 with the pressure of 0.03MPa, and base is taken out in compression moulding
Then body enters kiln oxidizing flame after water on drying, repaired biscuit and forces firing, firing temperature is 1100 DEG C, firing time 22h.
Claims (6)
1. a kind of anion ceramic sanitary appliance, which is characterized in that be grouped as by each group of following weight fraction: negative ion powder 23~35
Part, 5~12 parts of limonite, 2~4 parts of Cha Luoshi, 10~15 parts of china clay, 9~13 parts of kaolin, 6~9 parts of clay, plant ash 3~
7 parts, 4~8 parts of green bean rock, 1~3 part of magnesia.
2. anion ceramic sanitary appliance according to claim 1, which is characterized in that the negative ion powder is by following parts by weight
Each group be grouped as: 6~12 parts of tourmaline, 2~5 parts of monazite, 6~12 parts of apatite, 3~7 parts of fluorite, bastnaesite 1~3
Part, 9~15 parts of granite.
3. anion ceramic sanitary appliance according to claim 1 or 2, which is characterized in that the preparation step of the negative ion powder
It is as follows: it takes negative ion powder raw material ball mill to mix 6~9h, is heated to 1280~1450 DEG C of meltings, then keeps the temperature 2~4h,
Frit is made in quenching, is ground to particle diameter distribution in 50~80nm, drying of being sieved obtains negative ion powder.
4. the preparation method of anion ceramic sanitary appliance according to claim 1, which is characterized in that preparation step is as follows:
S1 takes raw material to expect: ball: water=1:2:0.6~0.8 enters ball milling, and fineness control tails over 0.2 in 300 meshes~
0.3%, slurry iron-removing sieving is aging 1~2 day, spare;
In the mud obtained by step S1 0.1~0.3% CMC is added, 0.2~0.4% potassium sorbate stirs evenly, spare in S2;
Mud obtained by step S2 is injected into the mold of ceramic sanitary appliance by S3 with the pressure of 0.02~0.04MPa, and compression moulding takes
Then green body out enters kiln oxidizing flame after water on drying, repaired biscuit and forces firing.
5. the preparation method of anion ceramic sanitary appliance according to claim 1, which is characterized in that the burning in the step S3
Temperature processed is 1050~1280 DEG C.
6. the preparation method of anion ceramic sanitary appliance according to claim 4, which is characterized in that the burning in the step S3
Time processed is 20~25h.
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CN201711490809.7A CN109987921A (en) | 2017-12-30 | 2017-12-30 | Anion ceramic sanitary appliance and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110919834A (en) * | 2019-12-10 | 2020-03-27 | 重庆国之四维卫浴有限公司 | Process for improving flatness of installation plane of basin under sanitary ceramic table and improving installation quality of product |
CN113880593A (en) * | 2021-10-25 | 2022-01-04 | 中国地质大学(武汉) | High-temperature sintered tourmaline type negative ion unglazed ceramic and preparation method thereof |
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CN106699147A (en) * | 2016-12-29 | 2017-05-24 | 广东顺祥陶瓷有限公司 | Easy-to-clean domestic ceramic and preparation method thereof |
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JP2003321269A (en) * | 2002-02-28 | 2003-11-11 | Sanyu:Kk | Negative ion generating ceramic material and producing method therefor |
KR20020064265A (en) * | 2002-07-18 | 2002-08-07 | 김기태 | Ceramic composition emitting anion |
CN1587186A (en) * | 2004-09-03 | 2005-03-02 | 佛山欧神诺陶瓷有限公司 | Method for producing health ceramic brick capable of releasing negative ion |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110919834A (en) * | 2019-12-10 | 2020-03-27 | 重庆国之四维卫浴有限公司 | Process for improving flatness of installation plane of basin under sanitary ceramic table and improving installation quality of product |
CN113880593A (en) * | 2021-10-25 | 2022-01-04 | 中国地质大学(武汉) | High-temperature sintered tourmaline type negative ion unglazed ceramic and preparation method thereof |
CN113880593B (en) * | 2021-10-25 | 2023-01-13 | 中国地质大学(武汉) | High-temperature sintered tourmaline type negative ion unglazed ceramic and preparation method thereof |
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