CN109971425A - A kind of environment protection snow-dissolved agent and preparation method - Google Patents

A kind of environment protection snow-dissolved agent and preparation method Download PDF

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Publication number
CN109971425A
CN109971425A CN201711464969.4A CN201711464969A CN109971425A CN 109971425 A CN109971425 A CN 109971425A CN 201711464969 A CN201711464969 A CN 201711464969A CN 109971425 A CN109971425 A CN 109971425A
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CN
China
Prior art keywords
parts
humic acid
peat
ammonium acetate
product
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Pending
Application number
CN201711464969.4A
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Chinese (zh)
Inventor
陈红
洪岩
纪聪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yingkou Rich Peat Technology Co Ltd
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Yingkou Rich Peat Technology Co Ltd
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Priority to CN201711464969.4A priority Critical patent/CN109971425A/en
Publication of CN109971425A publication Critical patent/CN109971425A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C09K3/185Thawing materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

A kind of preparation method of snow melt product agent described in one of claim 1-2, it is characterized in that: this method comprises the following steps: (1) collecting product liquid therein after first reacting corn stover at 70-80 DEG C with homemade catalyst, solid product, which stays, to use it for anything else;(2) it after again being mixed peat and self-control oxidant, is reacted under microwave condition, microwave power 200-300W, reaction time 10-30min, after reaction isolated Peat Humic Acid.(3) 25 parts of stalk reactant and the mixing of 15 parts of Peat Humic Acid are measured, start agitating device, control revolving speed is that 1000 ~ 1500 turns/min is advisable, then the ammonium acetate for calculating weighing is added slowly in mixer to be stirred well to and is thoroughly uniformly dispersed, excess water is added after mentioned component stirs into mixer, continue to be dispersed with stirring to solution to pack after finished product is dry, dehydration in uniform liquid.

Description

A kind of environment protection snow-dissolved agent and preparation method
Technical field
The present invention relates to a kind of environment protection snow-dissolved agent and preparation methods.
Belong to the deicing salt product of a kind of urban road, highway, such deicing salt is substitution highway deicing A kind of novel environment-friendly product of agent (sodium chloride) and exploitation, to the concrete and corrosivity in highway infrastructures It is small, substantially soil and water source are not polluted, while there is good water solubility, fusing point is low, it is biodegradable the advantages that.
Background technique: deicing salt also known as changes cryosel, road antifreezing agent, is mainly used for winter airport, highway, square, parking Field, railway, avenue etc. play snow removing and antifreeze effect, and the deicing salt type of China's exploitation at present is more, are divided by states of matter Solid and liquid;It is divided into the mixing of inorganic matter and inorganic matter and organic matter, by composition with the mixture of inorganic matter and organic matter It is most;Can also be by different purpose classifications, the quality for being generally used for urban road is lower, and the quality for bridge airport and other places is wanted Ask higher, but its quality all has to comply with standard.Country's deicing salt volume of production and marketing data are counted roughly by the yield of calcium chloride at present It calculates.Domestic deicing salt annual output is at 1,000,000 tons or so, and export volume is 1/3.Organic deicing salt does not corrode work to infrastructure With, due to selling at exorbitant prices, now only applied on a small quantity in places such as airport, golf courses;Snow melt is answered in city, highway With wider still chloride salt deicing salt.Villaumite Snow Agent ingredient will lead to greening and planted based on the salts such as sodium chloride, calcium chloride It by mortality, causes highway, bridge concrete road surface heavy corrosion to destroy, can also pollute rivers, underground water, destroy ecological ring Border.Aiming at the problem that current deicing salt, need to develop that cheap and easy to get, snow melt effect is good, low-corrosiveness, pollution-free, non-corrosive New Kind of Solvent of Snow-melted.
Summary of the invention:
The object of the present invention is to provide a kind of New Kind of Solvent of Snow-melted and preparation method thereof of environmental protection.
Above-mentioned purpose is realized by following technical scheme: environment protection snow-dissolved agent, and composition includes: by following raw materials by weight Measure number composition: 20~30 parts of Corn Stalk Decomposition object, 15~25 parts of Peat Humic Acid, 10-20 parts of ammonium acetate, remaining Amount is water.The present invention is equipped with ammonium acetate etc. using Corn Stalk Decomposition object, Peat Humic Acid as main component.
The New Kind of Solvent of Snow-melted of road, the expressway etc. is made of in parts by weight following raw materials: 20 parts of corn Straw decomposing object, 15 parts of Peat Humic Acid, 20 parts of ammonium acetate, surplus are water.
The New Kind of Solvent of Snow-melted of the road, expressway, is made of in parts by weight following raw materials: 25 parts of corn stalk Stalk decomposition product, 20 parts of Peat Humic Acid, 15 parts of ammonium acetate, surplus are water.
The New Kind of Solvent of Snow-melted of the road, expressway, is made of in parts by weight following raw materials: 30 parts of corn stalk Stalk decomposition product, 15 parts of Peat Humic Acid, 10 parts of ammonium acetate, surplus are water.
The road deicing salt preparation method of the road, high speed, this method comprises the following steps: (1) first by corn stalk Stalk collects product liquid therein after reacting at 70-80 DEG C with homemade catalyst, solid product, which stays, to use it for anything else;(2) again will After peat and self-control oxidant are mixed, reacted under microwave condition, microwave power 200-300W, reaction time 10- 30min, after reaction isolated Peat Humic Acid.(3) 25 parts of stalk reactant and 15 parts of Peat Humic Acid are measured Agitating device is started in mixing, and control revolving speed is that 1000 ~ 1500 turns/min is advisable, and then will calculate the ammonium acetate weighed and slowly adds Enter to be stirred well into mixer and thoroughly be uniformly dispersed, excess water is added after mentioned component stirs to mixing In device, continue to be dispersed with stirring to solution to pack after finished product is dry, dehydration in uniform liquid.
Beneficial effects of the present invention:
This work uses Straw decomposing object and Peat Humic Acid, reduces theoretical, anti-corrosion of metal theory as foundation using freezing point, obtains one Efficient, pollution-free, the moderate environment protection snow-dissolved agent of kind, makes stalk turn waste into wealth, has not only reached the utilization of biomass resource, but also Reduce the pollution to environment.
The present invention is to use Straw decomposing object and Peat Humic Acid for primary raw material, and a kind of snow melt of environment-friendly high-efficiency has been made Product has excellent snow melt and environment-friendly type.By spray pattern operation, good snow melt effect can reach.
The raw material composition of deicing salt of the present invention is safe and reliable, has many advantages, such as that environmentally friendly, degradable, dosage is small.
Specific embodiment:
Embodiment 1: a kind of highway, expressway snow melt product, composition includes: to be made of in parts by weight following raw materials: 20 The Corn Stalk Decomposition object of part, 15 parts of Peat Humic Acid, 20 parts of ammonium acetate, surplus are water.
Embodiment 2: according to the novel environment friendly deicing salt of road described in embodiment 1, in parts by weight by following raw materials Composition: 25 parts of Corn Stalk Decomposition object, 20 parts of Peat Humic Acid, 15 parts of ammonium acetate, surplus are water.
Embodiment 3: according to the novel environment friendly deicing salt of road product described in embodiment 1, by weight by following raw materials Number composition: 30 parts of Corn Stalk Decomposition object, 15 parts of Peat Humic Acid, 10 parts of ammonium acetate, surplus are water.
Production method is according to the following steps: (1) receiving after first reacting corn stover at 70-80 DEG C with homemade catalyst Collect product liquid therein, solid product, which stays, to use it for anything else;(2) after again being mixed peat and self-control oxidant, in micro-strip It is reacted under part, microwave power 200-300W, reaction time 10-30min, after reaction isolated Peat Humic Acid. (3) 25 parts of stalk reactant and the mixing of 15 parts of Peat Humic Acid are measured, starts agitating device, control revolving speed is 1000 ~ 1500 turns/min is advisable, and then will calculate the ammonium acetate weighed and be added slowly in mixer to be stirred well to and thoroughly disperse It is even, excess water is added after mentioned component stirs into mixer, continues to be dispersed with stirring to solution in uniform liquid Body is packed after finished product is dry, dehydration.

Claims (5)

1. a kind of environment protection snow-dissolved agent, composition includes: to be made of in parts by weight following raw materials: 20~30 parts of corn stover point Solving object object, 15~25 parts of Peat Humic Acid, 10-20 parts of ammonium acetate, surplus is water.
2. the present invention is equipped with ammonium acetate etc. using Corn Stalk Decomposition object, Peat Humic Acid as main component.
3. environment protection snow-dissolved agent product according to claim 1, it is characterized in that: being made of in parts by weight following raw materials: 25 Corn Stalk Decomposition object, 15 parts of the Peat Humic Acid, 10 parts of ammonium acetate of part, surplus is water.
4. the preparation method of snow melt product agent described in a kind of one of claim 1-2, it is characterized in that: this method includes as follows Step: (1) collecting product liquid therein after first reacting corn stover at 70-80 DEG C with homemade catalyst, solid produces Object, which stays, to use it for anything else;(2) it after again being mixed peat and self-control oxidant, is reacted under microwave condition, microwave power 200-300W, reaction time 10-30min, after reaction isolated Peat Humic Acid.
25 parts of stalk reactant and the mixing of 15 parts of Peat Humic Acid 5.(3) are measured, agitating device is started, control revolving speed is 1000 ~ 1500 turns/min is advisable, and then will calculate the ammonium acetate weighed and be added slowly in mixer to be stirred well to and thoroughly divide It dissipates uniformly, excess water is added after mentioned component stirs into mixer, continue to be dispersed with stirring to solution in equal Even liquid is packed after finished product is dry, dehydration.
CN201711464969.4A 2017-12-28 2017-12-28 A kind of environment protection snow-dissolved agent and preparation method Pending CN109971425A (en)

Priority Applications (1)

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CN201711464969.4A CN109971425A (en) 2017-12-28 2017-12-28 A kind of environment protection snow-dissolved agent and preparation method

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Application Number Priority Date Filing Date Title
CN201711464969.4A CN109971425A (en) 2017-12-28 2017-12-28 A kind of environment protection snow-dissolved agent and preparation method

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110951461A (en) * 2019-12-10 2020-04-03 辽宁大学 Environment-friendly snow-melting agent taking acetic acid waste liquid and straw ash as raw materials and preparation method and application thereof
CN113201310A (en) * 2021-05-12 2021-08-03 北华大学 Method for preparing environment-friendly organic calcium-magnesium salt snow melting agent by using corn straws
KR102467509B1 (en) * 2021-09-17 2022-11-16 주식회사 제일트레이딩 Eco-friendly deicer composition using humus substances

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101294086A (en) * 2007-04-26 2008-10-29 王栋 Catalysis gasification technique for leaves, haulm of plants
CN101792495A (en) * 2010-02-11 2010-08-04 浙江理工大学 Method for ultrasonically catalyzing and extracting hemicellulose, cellulose and lignin from plant straws
CN102320921A (en) * 2011-05-12 2012-01-18 中科院广州化学有限公司 Method for preparing biomass polylol by using ultrasonic waves and application thereof
CN104843700A (en) * 2015-03-26 2015-08-19 中国科学院生态环境研究中心 Powered activated carbon prepared by using peat compounding corn stalks as raw materials and preparation method
CN105838326A (en) * 2016-04-28 2016-08-10 北京联合大学 Ecological rehabilitation promoting snow-melting agent and preparation method thereof
CN106590532A (en) * 2016-12-15 2017-04-26 陕西易阳科技有限公司 Preparation method of snow melting agent
CN107216855A (en) * 2017-06-07 2017-09-29 常州杰轩纺织科技有限公司 A kind of environment-friendly type fulvic acid composite snow-melting agent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101294086A (en) * 2007-04-26 2008-10-29 王栋 Catalysis gasification technique for leaves, haulm of plants
CN101792495A (en) * 2010-02-11 2010-08-04 浙江理工大学 Method for ultrasonically catalyzing and extracting hemicellulose, cellulose and lignin from plant straws
CN102320921A (en) * 2011-05-12 2012-01-18 中科院广州化学有限公司 Method for preparing biomass polylol by using ultrasonic waves and application thereof
CN104843700A (en) * 2015-03-26 2015-08-19 中国科学院生态环境研究中心 Powered activated carbon prepared by using peat compounding corn stalks as raw materials and preparation method
CN105838326A (en) * 2016-04-28 2016-08-10 北京联合大学 Ecological rehabilitation promoting snow-melting agent and preparation method thereof
CN106590532A (en) * 2016-12-15 2017-04-26 陕西易阳科技有限公司 Preparation method of snow melting agent
CN107216855A (en) * 2017-06-07 2017-09-29 常州杰轩纺织科技有限公司 A kind of environment-friendly type fulvic acid composite snow-melting agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110951461A (en) * 2019-12-10 2020-04-03 辽宁大学 Environment-friendly snow-melting agent taking acetic acid waste liquid and straw ash as raw materials and preparation method and application thereof
CN113201310A (en) * 2021-05-12 2021-08-03 北华大学 Method for preparing environment-friendly organic calcium-magnesium salt snow melting agent by using corn straws
KR102467509B1 (en) * 2021-09-17 2022-11-16 주식회사 제일트레이딩 Eco-friendly deicer composition using humus substances

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