CN105731964A - Municipal sludge treatment curing agent and preparation method thereof - Google Patents

Municipal sludge treatment curing agent and preparation method thereof Download PDF

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Publication number
CN105731964A
CN105731964A CN201610062883.8A CN201610062883A CN105731964A CN 105731964 A CN105731964 A CN 105731964A CN 201610062883 A CN201610062883 A CN 201610062883A CN 105731964 A CN105731964 A CN 105731964A
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China
Prior art keywords
parts
curing agent
raw material
municipal sludge
preparation
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Granted
Application number
CN201610062883.8A
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Chinese (zh)
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CN105731964B (en
Inventor
范洲卫
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New environment technology development Co., Ltd.
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范洲卫
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Priority to CN201610062883.8A priority Critical patent/CN105731964B/en
Priority to CN201710583371.0A priority patent/CN107235698A/en
Publication of CN105731964A publication Critical patent/CN105731964A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00767Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a municipal sludge treatment curing agent and a preparation method thereof. The curing agent is prepared from gypsum, a crude salt, bauxite, plant ash, carboxymethyl cellulose sodium, silicon dioxide, ferrous sulfate, sodium lignin sulfonate, sepiolite powder, triethanolamine and sodium carbonate, wherein the raw materials are taken in proportion, and then are mixed together at room temperature, then water is added for mixing, heating and stirring are performed, then the mixture is cooled to the room temperature, and then the mixture is dried and ground to obtain the curing agent. The curing agent disclosed by the invention has the advantages of strong penetrability, high speed, and less agent dosage, is good in curing effect, can ensure that the long-term strength cannot be reduced at the same time; the curing agent can remove sludge odor; and the curing agent can reduce the release of heavy metals to the environment.

Description

A kind of municipal sludge processes firming agent and preparation method thereof
Technical field
The present invention relates to field of sludge treatment, specifically a kind of municipal sludge processes firming agent and preparation method thereof.
Background technology
Municipal sludge complicated component, containing a large amount of microorganisms, pathogen, heavy metal and organic pollution etc..Along with the development of global economy and the movable increase of improving earth geographical environment, the workload of the dredging operation of city water channel is increasing.Due to reasons such as these mud or sludge granules is little, not easily dehydration, low bearing capacity, content of organics are high, mobility is big, it is impossible to the engineering being directly used as in reclamation, dyke building, road engineering is banketed.Mud is carried out, by solidification technology, a series of difficult problems that the utilization of resources becomes earth working material or the preprocessing means as landfill stabilization can solve the problem that in Treatment of Sludge.Exploitation highly effective sludge firming agent is the key of this processing procedure.
Domestic and international Normal practice is to add the inserts such as substantial amounts of sand in Sludge landfill process, but do so not only makes Sludge landfill cost be greatly increased, and also reduces the effective rate of utilization of landfill yard simultaneously.For the cured of mud, mud, current commonly used cement, Calx etc. are as firming agent.It is slow that ordinary cement, Calx condense hardening, and they will appear from the forward part sedimentation not condensed in high water-solid ratio situation, and mud organic substance content is high, can hinder the hydration reaction of cement, and solidification effect is poor, even cannot be carried out.
Summary of the invention
It is an object of the invention to provide a kind of municipal sludge and process firming agent and preparation method thereof, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of municipal sludge processes firming agent, it is prepared from by the raw material of following weight portion: 30~36 parts of Gypsum Fibrosum, crude salt 24~30 parts, bauxite 21~25 parts, plant ash 27~29 parts, sodium carboxymethyl cellulose 19~21 parts, silicon dioxide 9~13 parts, 8~10 parts of ferrous sulfate, sodium lignin sulfonate 7~9 parts, sepiolite powder 23~25 parts, triethanolamine 5~7 parts, soda 21~23 parts.
The preparation method that a kind of described municipal sludge processes firming agent, concrete preparation process is as follows:
(1) above-mentioned each raw material is taken by proportioning, standby;
(2) at ambient temperature, being mixed by above-mentioned each raw material, add the water of raw material 4~6 times, heating, to 110~120 DEG C, stirs 3~4h;
(3) it is cooled to room temperature, dry 6~7h at the temperature of 65~67 DEG C, and to be ground to particle diameter be 240~300 orders,.
Compared with prior art, the invention has the beneficial effects as follows: firming agent of the present invention has the advantage that penetration is strong, speed is fast, dosing is few, and solidification effect is good, ensure that later strength will not reduce simultaneously;Mud stink can be removed;Reduce heavy metal to the release in environment.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment 1
Municipal sludge processes firming agent, it is prepared from by the raw material of following weight portion: 30 parts of Gypsum Fibrosum, crude salt 30 parts, bauxite 21 parts, plant ash 29 parts, sodium carboxymethyl cellulose 19 parts, silica 13 parts, 8 parts of ferrous sulfate, sodium lignin sulfonate 9 parts, sepiolite powder 23 parts, triethanolamine 7 parts, soda 21 parts.
In above-described embodiment, the preparation process of municipal sludge process firming agent is as follows:
(1) above-mentioned each raw material is taken by proportioning, standby;
(2) at ambient temperature, being mixed by above-mentioned each raw material, add the water of raw material 4 times, heating, to 110 DEG C, stirs 4h;
(3) it is cooled to room temperature, dry 7h at the temperature of 65 DEG C, and to be ground to particle diameter be 300 orders,.
Mud is dug out from river course or lake, removes block therein and club class foreign material.The moisture content measuring mud is 47.4%.Being put into by 500g mud in agitator, add 30g firming agent, mechanical agitation so that it is Homogeneous phase mixing, after stirring 2min, mud is hardening gradually, stops stirring.After pelletize 2 days, its moisture content is reduced to 17.6%, and testting its intensity with an axle compression test is 586KN/m2, and mud odorless after solidifying, it is possible to meet landfill and building is banketed requirement, it is also possible to utilize grinding tool to make variously-shaped brick for building.
Embodiment 2
Municipal sludge processes firming agent, it is prepared from by the raw material of following weight portion: 33 parts of Gypsum Fibrosum, crude salt 27 parts, bauxite 24 parts, plant ash 28 parts, sodium carboxymethyl cellulose 20 parts, silica 11 part, 9 parts of ferrous sulfate, sodium lignin sulfonate 8 parts, sepiolite powder 24 parts, triethanolamine 6 parts, soda 22 parts.
In above-described embodiment, the preparation process of municipal sludge process firming agent is as follows:
(1) above-mentioned each raw material is taken by proportioning, standby;
(2) at ambient temperature, being mixed by above-mentioned each raw material, add the water of raw material 5 times, heating, to 115 DEG C, stirs 3~4h;
(3) it is cooled to room temperature, dry 6.5h at the temperature of 66 DEG C, and to be ground to particle diameter be 270 orders,.
Mud is dug out from river course or lake, removes block therein and club class foreign material.The moisture content measuring mud is 50.8%.Being put into by 500g mud in agitator, add 30g firming agent, mechanical agitation so that it is Homogeneous phase mixing, after stirring 1.5min, mud is hardening gradually, stops stirring.After pelletize 2 days, its moisture content is reduced to 12.8%, and testting its intensity with an axle compression test is 635KN/m2, and mud odorless after solidifying, it is possible to meet landfill and building is banketed requirement, it is also possible to utilize grinding tool to make variously-shaped brick for building.
Embodiment 3
Municipal sludge processes firming agent, it is prepared from by the raw material of following weight portion: 36 parts of Gypsum Fibrosum, crude salt 24 parts, bauxite 25 parts, plant ash 27 parts, sodium carboxymethyl cellulose 21 parts, silicon dioxide 9 parts, 10 parts of ferrous sulfate, sodium lignin sulfonate 7 parts, sepiolite powder 25 parts, triethanolamine 5 parts, soda 23 parts.
In above-described embodiment, the preparation process of municipal sludge process firming agent is as follows:
(1) above-mentioned each raw material is taken by proportioning, standby;
(2) at ambient temperature, being mixed by above-mentioned each raw material, add the water of raw material 6 times, heating, to 120 DEG C, stirs 3h;
(3) it is cooled to room temperature, dry 6h at the temperature of 67 DEG C, and to be ground to particle diameter be 240 orders,.
Mud is dug out from river course or lake, removes block therein and club class foreign material.The moisture content measuring mud is 48.3%.Being put into by 500g mud in agitator, add 30g firming agent, mechanical agitation so that it is Homogeneous phase mixing, after stirring 2min, mud is hardening gradually, stops stirring.After pelletize 2 days, its moisture content is reduced to 18.2%, and testting its intensity with an axle compression test is 510KN/m2, and mud odorless after solidifying, it is possible to meet landfill and building is banketed requirement, it is also possible to utilize grinding tool to make variously-shaped brick for building.
Solidification sludge after pulverizing contains the trace element such as the nutrient such as abundant Organic substance and nitrogen, phosphorus, potassium and calcium, magnesium, copper, ferrum, zinc, change Soil structure can be played, increase soil fertility, promote the effect of plant growing, can be used as the fertilizer of Garden Greenland, it is achieved the recycling of mud.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when without departing substantially from the spirit of the present invention or basic feature, it is possible to realize the present invention in other specific forms.Therefore, no matter from which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the invention rather than described above limits, it is intended that all changes in the implication of the equivalency dropping on claim and scope included in the present invention.

Claims (2)

1. a municipal sludge processes firming agent, it is characterised in that be prepared from by the raw material of following weight portion: 30~36 parts of Gypsum Fibrosum, crude salt 24~30 parts, bauxite 21~25 parts, plant ash 27~29 parts, sodium carboxymethyl cellulose 19~21 parts, silicon dioxide 9~13 parts, 8~10 parts of ferrous sulfate, sodium lignin sulfonate 7~9 parts, sepiolite powder 23~25 parts, triethanolamine 5~7 parts, soda 21~23 parts.
2. the preparation method that a municipal sludge as claimed in claim 1 processes firming agent, it is characterised in that concrete preparation process is as follows:
(1) above-mentioned each raw material is taken by proportioning, standby;
(2) at ambient temperature, being mixed by above-mentioned each raw material, add the water of raw material 4~6 times, heating, to 110~120 DEG C, stirs 3~4h;
(3) it is cooled to room temperature, dry 6~7h at the temperature of 65~67 DEG C, and to be ground to particle diameter be 240~300 orders,.
CN201610062883.8A 2016-01-30 2016-01-30 A kind of municipal sludge processing curing agent and preparation method thereof Expired - Fee Related CN105731964B (en)

Priority Applications (2)

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CN201610062883.8A CN105731964B (en) 2016-01-30 2016-01-30 A kind of municipal sludge processing curing agent and preparation method thereof
CN201710583371.0A CN107235698A (en) 2016-01-30 2016-01-30 A kind of municipal sludge processing curing agent and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108191181A (en) * 2018-01-12 2018-06-22 广州市水电建设工程有限公司 A kind of urban river sediment cleanser and its production method
CN111960624A (en) * 2020-07-09 2020-11-20 浙江海逸环科院有限公司 Curing agent formula and preparation method
CN117801826A (en) * 2024-02-28 2024-04-02 江苏省环境工程技术有限公司 Environment-friendly curing agent and method for repairing polluted soil by using same

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Publication number Priority date Publication date Assignee Title
CN109574435B (en) * 2018-12-26 2021-07-16 广西绿城水务股份有限公司 Method for using solidified sludge as landfill garbage

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108191181A (en) * 2018-01-12 2018-06-22 广州市水电建设工程有限公司 A kind of urban river sediment cleanser and its production method
CN108191181B (en) * 2018-01-12 2018-12-14 广州市水电建设工程有限公司 A kind of urban river sediment cleanser and its production method
CN111960624A (en) * 2020-07-09 2020-11-20 浙江海逸环科院有限公司 Curing agent formula and preparation method
CN117801826A (en) * 2024-02-28 2024-04-02 江苏省环境工程技术有限公司 Environment-friendly curing agent and method for repairing polluted soil by using same

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Publication number Publication date
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CN107235698A (en) 2017-10-10

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Effective date of registration: 20170717

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