CN109963546A - 抛光的滑石微珠 - Google Patents
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Abstract
本发明涉及抛光的滑石微珠(即平均最大直径小于500μm的抛光的滑石颗粒)及其制备方法。本发明的抛光的滑石微珠特别适合用作在化妆品和个人卫生用品中使用的塑料微珠的替代品。因此,本发明还涉及包含本发明的抛光的滑石微珠的身体磨砂膏、牙膏和皂类。特别是,本发明涉及滑石含量大于70%(w/w)且最大直径小于500μm的抛光的滑石微珠作为化妆品和个人卫生用品中的塑料微珠的替代品的用途。
Description
本发明涉及抛光的滑石微珠(即平均最大直径小于500μm的抛光的滑石颗粒)及其制备方法。本发明的抛光的滑石微珠特别适合用作在化妆品和个人卫生用品中使用的塑料微珠(如聚乙烯微珠)的替代品。因此,本发明还涉及包含本发明的抛光的滑石微珠的身体磨砂膏、牙膏和皂类。
目前,微珠是它们的最大尺寸小于0.5毫米的固体塑料颗粒。它们通常由聚乙烯制成,但也可以由其它塑料(如聚丙烯和聚苯乙烯)制成。已经将微珠用于个人护理产品、化妆品和牙膏以及用于生物医学和健康科学研究。球形度和粒度均匀性在乳膏和洗液中产生滚珠效果,从而产生柔滑的质地和铺展性。光滑度和圆度提供润滑。
微珠在使用后,通常被冲洗至下水道,并且可以未经过滤而由污水处理厂排出,最终进入河流和运河,导致塑料颗粒水污染。微珠可以吸收和浓缩污染物(如农药和多环烃)。已经发现微珠以高浓度污染了五大湖,尤其是伊利湖(Lake Erie)。纽约州立大学的一项研究发现,五大湖表面每平方英里有1500至100万个微珠。
由于许多国家(如美国和欧洲)对微珠的禁令增加,因而许多化妆品公司正逐步从其去角质剂、清洁剂和沐浴露生产线中淘汰微珠。
考虑到上述情况,本领域对易于应用于化妆品和个人卫生用品并且环境友好的塑料微珠替代品明显存在需求。
除其它目的之外,本发明的目的是满足本领域中的上述需求。
如所附权利要求所概述的,满足了除其它目的之外的本发明目的。
具体地,根据第一方面,通过采用滑石含量大于70%(w/w)如80%、90%、91%、92%、93%、94%、95%如96%、97%、98%、99%和基本上100%且最大直径小于500μm的抛光滑石微珠作为化妆品和个人卫生用品的塑料微珠的替代品,满足了除其它目的之外的本发明目的。
本发明人惊奇地发现,具有足够纯度(即>75%(w/w))的相对小的滑石颗粒(即小于500μm)可以为塑料微珠提供合适的替代品。然而,这类滑石颗粒只有具有足够球形度和光滑度,或被不同地配制,充分抛光才可以提供替代品。根据本发明,可以通过将筛分过的小于500μm的滑石颗粒添加到转筒中并且允许滑石颗粒翻滚(即翻转)来容易地获得这种抛光。虽然具体的时间范围取决于工艺条件,但是所考虑的合适时间范围是5分钟至2小时。
考虑到上述情况,根据第二方面,本发明涉及用于提供抛光的滑石微珠的方法,该方法包括以下步骤:
a)提供滑石含量为至少70%、优选至少95%且平均最大直径为1cm至10cm之间的粗滑石;
b)压碎该粗滑石颗粒;
c)使压碎的滑石颗粒通过筛子来进行筛分,从而获得平均最大直径小于500μm的滑石颗粒;
d)对筛分出的滑石颗粒进行翻滚,从而获得抛光的滑石微珠。
根据本发明,可以将最大直径在500μm和250μm之间的抛光的滑石微珠用于身体磨砂膏中;可以将最大直径在250μm和125μm之间的抛光的滑石微珠用于面部磨砂膏中;以及可以将最大直径在125μm和0.5μm之间(如90μm)的抛光的滑石微珠用于牙膏、乳膏和皂类中。
根据本发明,还可以将抛光的滑石颗粒以1%至5%(w/w)的量与量为1%至15%(w/w)的一种或多种表面活性剂组合用于液体(即水基)皂中。
根据本发明,还可以将本发明的抛光的滑石颗粒用于干皂中,该干皂包含与一种或多种表面活性剂组合的大于50%(w/w/)的本发明的抛光的滑石微珠。
在本发明优选实施方式的以下实施例中将进一步详述本发明。这些实施例参考了图1,其中:
图1:示出放大30倍的在翻滚之后(右)和翻滚之前(左)的本发明的抛光的滑石微珠。
实施例
实施例1:抛光的滑石微珠的大体制备
对直径小于10cm的粗滑石(水合硅酸镁)进行压碎,然后过筛,从而得到1)平均最大直径为500-250μm的级分;2)平均最大直径为250至125μm的级分;3)平均最大直径为125至90μm的级分和4)平均最大直径小于90μm的级分。随后,将这些级分加入到转筒中,并且允许以60rpm翻滚20分钟以抛光这些滑石颗粒。图1示出了500至250μm的级分在翻滚之前(左)和翻滚之后(右)的代表性实例。如图1可见,翻滚为滑石颗粒提供了光滑度和圆度,此外还提供了更好的球形度。
实施例2:粉状皂(干皂)
通过以任何给定顺序将组成性成分混合来制备三种配方的粉状(干)皂:
配方1
化合物 | 以百分数计的量(w/w) | 功能 |
月桂醇磺基乙酸钠 | 26 | 表面活性剂 |
抛光的滑石 | 添加至100 | 小于250μm的级分 |
山梨糖醇 | 5 | 湿润剂 |
柠檬酸一水合物 | 0.3 | 缓冲剂 |
配方2
化合物 | 以百分数计的量(w/w) | 功能 |
月桂醇肌氨酸钠 | 24.7 | 表面活性剂 |
抛光的滑石 | 添加至100 | 小于250μm的级分 |
柠檬酸 | 0.3 | 缓冲剂 |
甲基椰油酰基牛磺酸钠 | 5.2 | 表面活性剂 |
配方3
化合物 | 以百分数计的量(w/w) | 功能 |
月桂醇磺基乙酸钠 | 23.0 | 表面活性剂 |
抛光的滑石 | 添加至100 | 小于250μm的级分 |
柠檬酸 | 0.3 | 缓冲剂 |
甲基椰油酰基牛磺酸钠 | 5.7 | 表面活性剂 |
山梨糖醇 | 5.0 | 湿润剂 |
尿囊素 | 0.2 | 皮肤舒缓和保护 |
尿素 | 0.3 | 皮肤调理 |
实施例3:液体皂
液体皂的配方
制备步骤:
将水相A加热至40℃。在搅拌下,加入丙烯酸酯/丙烯酸C10-30烷基酯交联聚合物,并且均质化1至2分钟以确保完全水合。将剩余成分混合,并且用三乙醇胺将pH调节至6.8。以中等速度搅拌直至获得均匀的凝胶。
Claims (15)
1.滑石含量大于70%(w/w)且最大直径小于500μm的抛光的滑石微珠作为化妆品和个人卫生用品中的塑料微珠的代替品的用途。
2.根据权利要求1所述的用途,其中所述最大直径在500μm和250μm之间并且所述个人卫生用品是身体磨砂膏。
3.根据权利要求1所述的用途,其中所述最大直径在250μm和125μm之间并且所述个人卫生用品是面部磨砂膏。
4.根据权利要求1所述的用途,其中所述最大直径在125μm和0.5μm之间并且所述个人卫生用品是牙膏、乳膏或皂类。
5.根据权利要求1所述的用途,其中所述个人卫生用品是包含1%至5%(w/w)的所述抛光的滑石微珠、1%至15%(w/w)的一种或多种表面活性剂和补齐至100%(w/w)的水的液体皂。
6.根据权利要求1所述的用途,其中所述个人卫生用品是包含至少50%(w/w)的所述抛光的滑石微珠和至少15%(w/w)的一种或多种表面活性剂的干皂。
7.一种身体磨砂膏,包含滑石含量大于70%(w/w)且最大直径在500μm和250μm之间的抛光的滑石微珠。
8.一种面部磨砂膏,包含滑石含量大于75%(w/w)且最大直径在250μm和125μm之间的抛光的滑石微珠。
9.牙膏、乳膏或皂类,包含滑石含量大于75%(w/w)且最大直径在125μm和0.5μm之间的抛光的滑石微珠。
10.一种液体皂,包含1%至5%(w/w)的抛光的滑石微珠、1%至15%(w/w)的一种或多种表面活性剂和补齐至100%(w/w)的水。
11.一种干皂,包含至少50%(w/w)的抛光的滑石微珠和至少15%(w/w)的一种或多种表面活性剂。
12.一种用于提供抛光的滑石微珠的方法,所述方法包括以下步骤:
a)提供滑石含量为至少70%且平均最大直径为1cm至10cm之间的粗滑石;
b)压碎所述粗滑石颗粒;
c)使压碎的滑石颗粒通过筛子来进行筛分,从而获得平均最大直径小于500μm的滑石颗粒;
d)在滚筒中对筛分出的滑石颗粒进行翻滚,从而获得所述抛光的滑石微珠。
13.根据权利要求12所述的方法,其中步骤(a)中的所述粗滑石具有至少80%、90%、95%、96%、97%或98%、优选至少99%、更优选基本上100%的滑石含量。
14.根据权利要求12或权利要求13所述的方法,其中步骤c)中获得的所述滑石颗粒具有小于250μm或小于125μm的平均最大直径。
15.根据权利要求12至14中任一项所述的方法能够获得的抛光的滑石微珠。
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PCT/EP2016/074729 WO2018068865A1 (en) | 2016-10-14 | 2016-10-14 | Polished talc microbeads |
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CN112076137A (zh) * | 2020-08-22 | 2020-12-15 | 荣鼎(广东)生物科技有限公司 | 一种含印加果的精油身体磨砂膏及其制备方法 |
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CN112076137A (zh) * | 2020-08-22 | 2020-12-15 | 荣鼎(广东)生物科技有限公司 | 一种含印加果的精油身体磨砂膏及其制备方法 |
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KR20190075963A (ko) | 2019-07-01 |
RS64199B1 (sr) | 2023-06-30 |
RU2751195C2 (ru) | 2021-07-12 |
AU2016425949B2 (en) | 2023-01-19 |
DK3525749T3 (da) | 2023-04-24 |
SI3525749T1 (sl) | 2023-07-31 |
FI3525749T3 (fi) | 2023-05-05 |
CA3039946C (en) | 2023-09-26 |
LT3525749T (lt) | 2023-06-12 |
AU2016425949A1 (en) | 2019-05-02 |
RU2019114192A (ru) | 2020-11-16 |
BR112019007495B1 (pt) | 2022-01-18 |
US20190307660A1 (en) | 2019-10-10 |
HRP20230407T1 (hr) | 2023-07-07 |
PT3525749T (pt) | 2023-06-05 |
HUE062038T2 (hu) | 2023-09-28 |
EP3525749A1 (en) | 2019-08-21 |
EP3525749B1 (en) | 2023-03-22 |
BR112019007495A2 (pt) | 2019-07-02 |
CA3039946A1 (en) | 2018-04-19 |
US11304883B2 (en) | 2022-04-19 |
PL3525749T3 (pl) | 2023-07-24 |
WO2018068865A1 (en) | 2018-04-19 |
ES2945900T3 (es) | 2023-07-10 |
BR112019007495B8 (pt) | 2022-08-02 |
RU2019114192A3 (zh) | 2020-11-16 |
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