CN109912738B - 一种自修复型纳米复合乳液及其制备方法 - Google Patents
一种自修复型纳米复合乳液及其制备方法 Download PDFInfo
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- CN109912738B CN109912738B CN201910141776.8A CN201910141776A CN109912738B CN 109912738 B CN109912738 B CN 109912738B CN 201910141776 A CN201910141776 A CN 201910141776A CN 109912738 B CN109912738 B CN 109912738B
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- repairing
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- composite emulsion
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- 239000000839 emulsion Substances 0.000 title claims abstract description 69
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000004945 emulsification Methods 0.000 title claims description 24
- 238000000034 method Methods 0.000 claims abstract description 26
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002105 nanoparticle Substances 0.000 claims abstract description 12
- 229960003351 prussian blue Drugs 0.000 claims abstract description 12
- 239000013225 prussian blue Substances 0.000 claims abstract description 12
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920003192 poly(bis maleimide) Polymers 0.000 claims abstract description 10
- 238000001132 ultrasonic dispersion Methods 0.000 claims abstract description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 9
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 8
- GTUVXOOHBUUGBH-UHFFFAOYSA-N furan;methanol Chemical compound OC.C=1C=COC=1 GTUVXOOHBUUGBH-UHFFFAOYSA-N 0.000 claims abstract 2
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 238000010438 heat treatment Methods 0.000 claims description 23
- 229920000058 polyacrylate Polymers 0.000 claims description 19
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 18
- 238000009210 therapy by ultrasound Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 12
- 238000007599 discharging Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000005303 weighing Methods 0.000 claims description 11
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 6
- 238000003760 magnetic stirring Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 239000010985 leather Substances 0.000 abstract description 13
- 230000007246 mechanism Effects 0.000 abstract description 4
- 238000005698 Diels-Alder reaction Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 206010034960 Photophobia Diseases 0.000 abstract description 2
- 206010057040 Temperature intolerance Diseases 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000008543 heat sensitivity Effects 0.000 abstract description 2
- 208000013469 light sensitivity Diseases 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 230000001804 emulsifying effect Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000008439 repair process Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- -1 acrylic ester Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006352 cycloaddition reaction Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000002198 surface plasmon resonance spectroscopy Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Colloid Chemistry (AREA)
Abstract
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CN109912738B true CN109912738B (zh) | 2020-10-13 |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109265599A (zh) * | 2018-09-28 | 2019-01-25 | 陕西科技大学 | 一种自修复型聚丙烯酸酯乳液及其制备方法 |
CN109276537A (zh) * | 2018-09-12 | 2019-01-29 | 中南大学 | 一种共负载血管阻断剂与近红外光热响应纳米粒子的复合水凝胶及其制备和应用 |
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2019
- 2019-02-26 CN CN201910141776.8A patent/CN109912738B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109276537A (zh) * | 2018-09-12 | 2019-01-29 | 中南大学 | 一种共负载血管阻断剂与近红外光热响应纳米粒子的复合水凝胶及其制备和应用 |
CN109265599A (zh) * | 2018-09-28 | 2019-01-25 | 陕西科技大学 | 一种自修复型聚丙烯酸酯乳液及其制备方法 |
Non-Patent Citations (2)
Title |
---|
Synthesis and Characterization of a Furan-Based Self-Healing Polymer;Yeon Sung Ryu等;《Macromolecular Research》;20160919;第24卷(第10期);第874-880页 * |
基于Diels-Alder反应的自修复聚合物材料;李金辉等;《高分子通报》;20140331(第3期);第8-15页 * |
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Effective date of registration: 20210312 Address after: No.1902 jufuge, Yamei building, 39 Keji Road, Xi'an City, Shaanxi Province, 710075 Patentee after: XI'AN TONGRUI NEW MATERIAL DEVELOPMENT Co.,Ltd. Address before: 710021 Shaanxi city of Xi'an province Weiyang University City Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY |
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Denomination of invention: Self repairing nano composite emulsion and preparation method thereof Effective date of registration: 20220218 Granted publication date: 20201013 Pledgee: Xi'an innovation financing Company limited by guarantee Pledgor: XI'AN TONGRUI NEW MATERIAL DEVELOPMENT Co.,Ltd. Registration number: Y2022610000038 |
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Address after: 710005 No. 903, block a, Rongcheng Yungu, No. 57, Keji Third Road, Xi'an, Shaanxi Patentee after: XI'AN TONGRUI NEW MATERIAL DEVELOPMENT Co.,Ltd. Address before: No.1902 jufuge, Yamei building, 39 Keji Road, Xi'an City, Shaanxi Province, 710075 Patentee before: XI'AN TONGRUI NEW MATERIAL DEVELOPMENT Co.,Ltd. |
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Denomination of invention: Self repairing nano composite lotion and its preparation method Effective date of registration: 20230612 Granted publication date: 20201013 Pledgee: Xi'an innovation financing Company limited by guarantee Pledgor: XI'AN TONGRUI NEW MATERIAL DEVELOPMENT Co.,Ltd. Registration number: Y2023610000428 |