CN109897506A - For the Environmental Protective Water-paint of structural metal template and its preparation, application method - Google Patents

For the Environmental Protective Water-paint of structural metal template and its preparation, application method Download PDF

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Publication number
CN109897506A
CN109897506A CN201910280427.4A CN201910280427A CN109897506A CN 109897506 A CN109897506 A CN 109897506A CN 201910280427 A CN201910280427 A CN 201910280427A CN 109897506 A CN109897506 A CN 109897506A
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CN
China
Prior art keywords
agent
paint
environmental protective
structural metal
metal template
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910280427.4A
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Chinese (zh)
Inventor
刘建忠
黄绍全
杨双成
黄河
魏林江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHONGQING HAILIAN WATERBORNE COATING Co Ltd
Original Assignee
CHONGQING HAILIAN WATERBORNE COATING Co Ltd
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Application filed by CHONGQING HAILIAN WATERBORNE COATING Co Ltd filed Critical CHONGQING HAILIAN WATERBORNE COATING Co Ltd
Priority to CN201910280427.4A priority Critical patent/CN109897506A/en
Publication of CN109897506A publication Critical patent/CN109897506A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of Environmental Protective Water-paints for structural metal template, raw material including following weight percent: deionized water 8%~15%, watersoluble modified epoxy emulsion 35%~45%, aqueous polyamine curing agent 10%~15%, coloring pigment 2%~18%, sericite 1%~2%, barium sulfate 10%~15%, talcum powder 5%~10%, polyphosphazene polymer mould assembly dispersing agent 0.2%~0.8%, containing silicon defoaming agent 0.2%~0.8%, PUA polyurethane thickener 0.2%~0.8%, low surface tension substrate wetting agent 0.2%~0.8%, siliceous levelling agent 0.5%~1%, anti-settling agent 0.2%~0.5%, cosolvent 8%~15%.The present invention realizes the demoulding functions of release agent and solves the problems, such as that plastics are used only once simultaneously, and template is protected to prevent from getting rusty;Have the characteristics that safe and environment-friendly, healthy.

Description

For the Environmental Protective Water-paint of structural metal template and its preparation, application method
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of Environmental Protective Water-paint for building iron template and its Preparation, application method.
Background technique
Existing market mainstream building template is divided into plank sheathing, superpower composite shuttering, bamboo glue pattern plate, aluminum alloy pattern plate and combined type Steel form.
Combined steel template is the new type formwork of a kind of " with steel Dai Mu ", using modern stencil manufacture technique, is had general Property it is strong, be convenient to mount and dismount, the number of turnover is more, fire-retardant, do not absorb water the advantages that indeformable, but has demoulding difficult, needs using taking off The defects of mould agent demoulding, increases working procedure, and plate easily gets rusty, is easily corroded, and service life is short, at high cost.
Although there is better aluminum alloy pattern plate in the market, aluminum alloy pattern plate is the New Type Architecture Mode of aluminium alloy production, and building trade is new The green construction template of rise, with easy to operate, construction is fast, return height, environmental protection and energy saving, access times are more, concreting is imitated The features such as fruit is good, recyclable, is used by each building constructor.With anti-flammability, do not absorb water indeformable, it is heavy in contrast to steel form Amount is light, easy to operate, can directly reach clear water effect, but because of its market price height, single use cost is high, in building trade Major part is still based on steel form.And the anti-corrosion of steel form just becomes an important problem, because the pH value of concrete exists Between 12-13, belong to strong basicity, and concrete is in the curing process, the reaction between concrete can generate heat, so right The used requirement painted of anti-corrosion is high, should anti-corrosion ability it is prominent, have excellent resisting basic energy again.In metal formwork stripping mistake It needs in journey using release agent, and when release agent needs to construct is coated, and is used only once, is cannot achieve repeatedly after coating Using and in coating procedure be easy release agent is coated on reinforcing bar to reinforcing bar and concrete binding during leading to concrete formation Power declines to a great extent.Based on above 3 points, it is intended that it is prominent to develop a kind of heat-resisting alkali ability, anti-corrosion capability, while can Substitute a kind of environment-friendly type coating of release agent.
Therefore those skilled in the art are dedicated to developing a kind of for structural metal template (combined steel formwork and aluminum alloy pattern plate Deng) Environmental Protective Water-paint and preparation method thereof, substitute existing release agent, realize the demoulding functions of release agent, solve remover Being used only once and be easily coated on rebar surface influences binding force problem, while heat-resisting alkali ability, anti-corrosion capability are prominent Out, protection is provided for the corrosion of steel form, improves the service life of steel form.
Summary of the invention
In view of the above drawbacks of the prior art, technical problem to be solved by the invention is to provide one kind for building gold The Environmental Protective Water-paint and preparation method thereof for belonging to template (combined steel formwork and aluminum alloy pattern plate etc.) substitutes existing release agent, realizes de- The demoulding functions of mould agent solve the problems, such as that remover is used only once and is easily coated on rebar surface and influences binding force, together Shi Naire alkali ability, anti-corrosion capability are prominent, provide protection for the corrosion of steel form, improve the service life of steel form.
To achieve the above object, the present invention provides a kind of Environmental Protective Water-paints for structural metal template, including such as The raw material of lower weight percent: deionized water 8%~15%, watersoluble modified epoxy emulsion 35%~45%, aqueous polyamine are solid Agent 10%~15%, coloring pigment 2%~18%, sericite 1%~2%, barium sulfate 10%~15%, talcum powder 5%~ 10%, polyphosphazene polymer mould assembly dispersing agent 0.2%~0.8% contains silicon defoaming agent 0.2%~0.8%, PUA polyurethane thickener 0.2%~0.8%, low surface tension substrate wetting agent 0.2%~0.8%, siliceous levelling agent 0.5%~1%, anti-settling agent 0.2%~0.5%, cosolvent 8%~15%.
Preferably, including the raw material of following weight percent: deionized water 8%, watersoluble modified epoxy emulsion 39% are aqueous Polyamine curing agent 12%, coloring pigment 10.5%, sericite 2%, barium sulfate 12%, talcum powder 6%, polyphosphazene polymer mould assembly point Powder 0.8%, containing silicon defoaming agent 0.2%, PUA polyurethane thickener 0.2%, low surface tension substrate wetting agent 0.3% is siliceous Levelling agent 0.7%, anti-settling agent 0.3%, cosolvent 8%.
Preferably, the cosolvent is propylene glycol monomethyl ether or dipropylene.
A kind of preparation method of the Environmental Protective Water-paint as described above for structural metal template, comprising the following steps:
1. deionized water is added in batching kettle, anti-settling agent, polyphosphazene polymer mould assembly dispersing agent, with the speed of 200-400r/min Degree stirring is gradually added coloring pigment, sericite, talcum powder, barium sulfate, containing silicon defoaming agent while stirring;
2. with the Rate Dispersion 8-15min of 2000-3000rpm;
3. being ground to fineness no more than 35 μm, stirred with the speed of 200-400r/mi n, aqueous change is added under stirring condition Property epoxy emulsion, low surface tension substrate wetting agent, siliceous levelling agent, cosolvent and PUA polyurethane thickener;
4. being stirred evenly using aqueous polyamine curing agent is added in first 10 minutes.
A kind of application method of the Environmental Protective Water-paint as described above for structural metal template, must complete 4 in preparation It is used in hour.
The beneficial effects of the present invention are: the present invention instead of existing release agent, realizes demoulding functions of release agent and same When solve the problems, such as that plastics are used only once, and template is protected to prevent from getting rusty;Have the characteristics that it is safe and environment-friendly, healthy, It uses water as retarder thinner and cleaning agent in production, work progress, greatly reduces and caused because using organic solvent Environmental pollution and injury to human body;For solvent based coating, VOC can be greatly reduced, to reduce photochemical dirt The haze weather for contaminating and therefore generating, achieves energy-saving and emission reduction purposes.
Specific embodiment
With embodiment, the invention will be further described below, embodiment described herein only to explain the present invention, Not to limit the present invention.
In following embodiment, unless otherwise stated, raw materials used is commercially available product.
Embodiment 1 is to embodiment 6
Embodiment 1 is prepared to embodiment 6 using raw material components as shown in Table 1.
Table 1: embodiment 1 to 6 list of ingredients of embodiment
In all of above embodiment, watersoluble modified epoxy emulsion is the production of Hexion enterprise management of chemical industry (Shanghai) Co., Ltd. EP3520WY55A;
In all of above embodiment, aqueous polyamine curing agent is the production of air chemical products (China) Investment Co., Ltd Anquamine-419;
In above embodiments, the coloring pigment in embodiment 1 is the titanium dioxide of 10.4kg and the carbon black of 0.1kg, embodiment 2 In all carbon blacks of coloring pigment, the coloring pigment in embodiment 3 is 2kg phthalocyanine blue pigment and 3.5 titanium dioxides, embodiment 4 In coloring pigment be 1.7kg ferric oxide red colorant and 0.3kg carbon black, all iron oxide reds of coloring pigment in embodiment 5 Pigment, all titanium dioxides of coloring pigment in embodiment 6.
In above embodiments, polyphosphazene polymer mould assembly dispersing agent is the BYK- of Bi Ke chemical company, Germany in embodiment 1 to 3 190;Polyphosphazene polymer mould assembly dispersing agent is to win wound Degussa Digao auxiliary agent Tego755W in embodiment 4 to 6;
It is to win wound Degussa Digao Tego 810 containing silicon defoaming agent in all of above embodiment;
In all of above embodiment, PUA polyurethane thickener is OMG Borchers GmbH company Gel 0620;
In all of above embodiment, low surface tension substrate wetting agent is to win wound Degussa Digao Tego 280;
In all of above embodiment, siliceous levelling agent is to win wound Degussa Digao Tego 425;
In above embodiments, anti-settling agent is this special chemical company of Britain's hamming LT in embodiment 1 to 3, and embodiment 4 is to 6 Middle anti-settling agent is the EW of this special chemical company of Britain's hamming;
In above embodiments, cosolvent is the propylene glycol monomethyl ether of Jinan star Chemical Co., Ltd. in embodiment 1 to 3;It is real Apply the dipropylene that cosolvent in example 4 to 6 is Jinan century sensible Chemical Co., Ltd..
Embodiment 1 to embodiment 6 is all made of following methods preparation, and being respectively coated on number is 6 pieces of 1 to 6 for building On steel form:
1. deionized water is added in batching kettle, anti-settling agent, polyphosphazene polymer mould assembly dispersing agent, with the speed of 200-400r/min Degree stirring is gradually added coloring pigment, sericite, talcum powder, barium sulfate, containing silicon defoaming agent while stirring;
2. with the Rate Dispersion 8-15min of 2000-3000rpm;
3. being ground to fineness no more than 35 μm, stirred with the speed of 200-400r/min, aqueous change is added under stirring condition Property epoxy emulsion, low surface tension substrate wetting agent, siliceous levelling agent, cosolvent and PUA polyurethane thickener;
4. being stirred evenly using aqueous polyamine curing agent is added in first 10 minutes.I.e. before being coated in steel form Aqueous polyamine curing agent is added in 100 minutes.
Specifically during the preparation process, step 1. in each embodiment of mixing speed be respectively: embodiment 1 be 300r/min, Embodiment 2 is 200r/min, embodiment 3 is 400r/min, embodiment 4 is 250r/min, embodiment 5 is 350r/min, implements Example 6 is 300r/min;Step 2. in each embodiment of rate of dispersion be respectively: embodiment 1 is 2500rpm, embodiment 2 is 2000rpm, embodiment 3 are 3000rpm, embodiment 4 is 2200rpm, embodiment 5 is 2800rpm, embodiment 6 is 2500rpm; Step 3. in each embodiment of mixing speed be respectively: embodiment 1 is 300r/min, embodiment 2 is 200r/min, embodiment 3 For 400r/min, embodiment 4 be 250r/min, embodiment 5 is 350r/min, embodiment 6 is 300r/min.
Step 4. in, the time of aqueous polyamine curing agent is added are as follows: embodiment 1 is to use first 2 minutes, implement 2 be Using first 4 minutes, implement 3 to use first 6 minutes, embodiment 4 is to use first 8 minutes, implements 5 to use first 10 minutes, implements 6 To use first 5 minutes.
Environmental Protective Water-paint prepared by embodiment 1 to embodiment 6 is coated on the 1st to No. 6 steel form, and embodiment 1 exists It is added in aqueous polyamine curing agent and half an hour after mixing evenly and completes coating;Aqueous polyamine is being added in embodiment 2 and 3 Coating is completed in curing agent and after mixing evenly 2 hours;Embodiment 4 and 5 is being added aqueous polyamine curing agent and is stirring equal Coating is completed in 3 hours after even;Embodiment 6 is being added aqueous polyamine curing agent and is completing to apply in stir evenly 4 hours It covers;For 1 to 6 coating time difference of embodiment within 5 minutes, main difference is that the initial time coated is different, coats postscript Water paint drying time and its performance for recording each embodiment, test, the result is shown in tables 2 in following manner.
The 1st to No. 6 steel form the performance test results table of table 2
Separately the steel form that No. 1 to No. 6 is coated with Environmental Protective Water-paint of the present invention is surrounded one week, is tested for pouring with mixed Solidifying earth pillar, this test use the concrete of C20, pour and complete after concrete strength reaches demoulding standard, successively demoulding is torn open When mould, No. 1 to No. 6 steel form does not use any release agent, and direct demoulding, experiment concrete column is not damaged after demoulding, and No. 1 extremely The case where there is not paint, are corroded in No. 6 steel forms.Using same method, used again using the concrete of C30, C40, C50 In test, in the case where not using any release agent, experiment concrete column is not damaged after demoulding, and No. 1 to No. 6 steel form is equal The case where there is not paint, being corroded.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea Technical solution, all should be within the scope of protection determined by the claims.

Claims (5)

1. a kind of Environmental Protective Water-paint for structural metal template, characterized in that the raw material including following weight percent: go Ionized water 8%~15%, watersoluble modified epoxy emulsion 35%~45%, aqueous polyamine curing agent 10%~15% colour face Material 2%~18%, sericite 1%~2%, barium sulfate 10%~15%, talcum powder 5%~10%, the dispersion of polyphosphazene polymer mould assembly Agent 0.2%~0.8% contains silicon defoaming agent 0.2%~0.8%, PUA polyurethane thickener 0.2%~0.8%, low surface tension Substrate wetting agents 0.2%~0.8%, siliceous levelling agent 0.5%~1%, anti-settling agent 0.2%~0.5%, cosolvent 8%~ 15%.
2. a kind of Environmental Protective Water-paint for structural metal template, characterized in that the raw material including following weight percent: go Ionized water 8%, watersoluble modified epoxy emulsion 39%, aqueous polyamine curing agent 12%, coloring pigment 10.5%, sericite 2%, Barium sulfate 12%, talcum powder 6%, polyphosphazene polymer mould assembly dispersing agent 0.8% contain silicon defoaming agent 0.2%, PUA polyurethane thickener 0.2%, low surface tension substrate wetting agent 0.3%, siliceous levelling agent 0.7%, anti-settling agent 0.3%, cosolvent 8%.
3. the Environmental Protective Water-paint of structural metal template is used for as claimed in claim 1 or 2, it is characterized in that: the cosolvent For propylene glycol monomethyl ether or dipropylene.
4. a kind of preparation method of the Environmental Protective Water-paint for structural metal template as described in claims 1 to 3 is any, It is characterized in, comprising the following steps:
1. deionized water is added in batching kettle, anti-settling agent, polyphosphazene polymer mould assembly dispersing agent is stirred with the speed of 200-400r/min It mixes, is gradually added coloring pigment, sericite, talcum powder, barium sulfate, containing silicon defoaming agent while stirring;
2. with the Rate Dispersion 8-15min of 2000-3000rpm;
3. being ground to fineness no more than 35 μm, stirred with the speed of 200-400r/min, watersoluble modified ring is added under stirring condition Oxygen lotion, low surface tension substrate wetting agent, siliceous levelling agent, cosolvent and PUA polyurethane thickener;
4. being stirred evenly using aqueous polyamine curing agent is added in first 10 minutes.
5. a kind of application method of the Environmental Protective Water-paint for structural metal template as described in claims 1 to 3 is any, It is characterized in: must completes to use in 4 hours in preparation.
CN201910280427.4A 2019-04-09 2019-04-09 For the Environmental Protective Water-paint of structural metal template and its preparation, application method Pending CN109897506A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111560206A (en) * 2020-03-10 2020-08-21 中建工程研究院有限公司 Concrete demolding paint primer capable of strongly protecting metal template and preparation method thereof
CN112812235A (en) * 2021-01-27 2021-05-18 重庆海联水性涂料有限公司 Water-based epoxy modified resin and preparation method thereof, and paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101104770A (en) * 2007-08-20 2008-01-16 维新环保涂料(深圳)有限公司 Water-based epoxy intermediate paint
CN103436136A (en) * 2013-07-24 2013-12-11 广州擎天材料科技有限公司 Room-temperature-curable aqueous anticorrosion primer used for coating external surface of construction crane and preparation method of primer
CN107083145A (en) * 2017-06-16 2017-08-22 江苏金陵特种涂料有限公司 Aqueous high molecular alloy heavy antisepsis priming paint
CN109517483A (en) * 2018-10-30 2019-03-26 河北晨阳工贸集团有限公司 A kind of aluminum profile is with exempting from high adhesion force epoxy-based lacquers and preparation method thereof of polishing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101104770A (en) * 2007-08-20 2008-01-16 维新环保涂料(深圳)有限公司 Water-based epoxy intermediate paint
CN103436136A (en) * 2013-07-24 2013-12-11 广州擎天材料科技有限公司 Room-temperature-curable aqueous anticorrosion primer used for coating external surface of construction crane and preparation method of primer
CN107083145A (en) * 2017-06-16 2017-08-22 江苏金陵特种涂料有限公司 Aqueous high molecular alloy heavy antisepsis priming paint
CN109517483A (en) * 2018-10-30 2019-03-26 河北晨阳工贸集团有限公司 A kind of aluminum profile is with exempting from high adhesion force epoxy-based lacquers and preparation method thereof of polishing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111560206A (en) * 2020-03-10 2020-08-21 中建工程研究院有限公司 Concrete demolding paint primer capable of strongly protecting metal template and preparation method thereof
CN112812235A (en) * 2021-01-27 2021-05-18 重庆海联水性涂料有限公司 Water-based epoxy modified resin and preparation method thereof, and paint and preparation method thereof

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Application publication date: 20190618