CN108192443A - A kind of power equipment antirust paint - Google Patents

A kind of power equipment antirust paint Download PDF

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Publication number
CN108192443A
CN108192443A CN201810066184.XA CN201810066184A CN108192443A CN 108192443 A CN108192443 A CN 108192443A CN 201810066184 A CN201810066184 A CN 201810066184A CN 108192443 A CN108192443 A CN 108192443A
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CN
China
Prior art keywords
parts
antirust paint
power equipment
water
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810066184.XA
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Chinese (zh)
Inventor
程劲松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Still Strong Electric Technology Co Ltd
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Hefei Still Strong Electric Technology Co Ltd
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Filing date
Publication date
Application filed by Hefei Still Strong Electric Technology Co Ltd filed Critical Hefei Still Strong Electric Technology Co Ltd
Priority to CN201810066184.XA priority Critical patent/CN108192443A/en
Publication of CN108192443A publication Critical patent/CN108192443A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention belongs to material of paint technical fields, and in particular to a kind of power equipment antirust paint.The antirust paint includes following component:Water-base resin, modified soluble Ludox, zinc oxide, talcum powder, sericite part, trbasic zinc phosphate, barium sulfate, thickener, levelling agent, pigment, antifoaming agent, deionized water.Wherein water-base resin is aqueous anionic acrylic resin lotion;Water silica sol is modified by adding nano-carbon powder and iron oxide by the way of Hybrid Heating.It after antirust paint each group lease making mixing dispersion, also needs to be ground refinement so that paint vehicle more uniform and smooth, generation protective layer is more stable and fine and close after spraying, improves the barrier propterty of paint vehicle.The antirust paint has the advantages of anti-oxidant, corrosion resistance is outstanding, nontoxic, and production cost is relatively low.

Description

A kind of power equipment antirust paint
Technical field
The invention belongs to material of paint technical fields, and in particular to a kind of power equipment antirust paint.
Background technology
Antirust paint is a kind of painting for the chemistry or electrochemical corrosion for protecting metal surfaces from air, seawater, salt fog etc. Material;Main component is rust resisting pigment and film forming matter.Antirust paint currently on the market is broadly divided into two kinds of oil paint and water paint, Wherein, oil paint has the advantages that cheap, easy to use, but the greasy easy attachment dirt in oil paint surface, cleans It is next cumbersome, and the body of paint spraying operating personnel is good for containing noxious materials such as nitrite, chromate in ingredient Health harm is larger, has been rarely employed at present.
Water paint has the advantages that Environmental Safety is healthy, and with the progress of material science and technology, the film forming of aqueous antirust paint Effect, anticorrosion, anti-aging property are very outstanding, but the adhesive force of aqueous antirust paint, membranous layer stability etc. are comprehensive Can be still to be improved, and the production cost of aqueous antirust paint is generally higher.
Invention content
In view of the above problems, the purpose of the present invention is to provide a kind of power equipment antirust paint, the antirust paint film layer is attached Put forth effort that strong, stability is high, it is corrosion-resistant, anti-aging property is good, and production cost is relatively low.
A kind of power equipment antirust paint, it is characterised in that:According to mass fraction, the antirust paint contains following component: 30-45 parts of water-base resin, 7-12 parts of modified soluble Ludox, 10-15 parts of zinc oxide, 10-16 parts of talcum powder, sericite part 8- 10 parts, 5-8 parts of trbasic zinc phosphate, 5-7 parts of barium sulfate, 3-6 parts of thickener, 2-3 parts of levelling agent, 15-25 parts of pigment;Antifoaming agent 0.3- 0.5 part, 15-20 parts of deionized water.
Preferably, according to mass fraction, the antirust paint contains following component:35-40 parts of water-base resin, modified soluble 8-10 parts of Ludox, 12-13 parts of zinc oxide, 12-15 parts of talcum powder, 8-9 parts of sericite part, 6-7 parts of trbasic zinc phosphate, barium sulfate 5-6 Part, 4-5 parts of thickener, 2.5-3 parts of levelling agent, 20-22 parts of pigment;0.4-0.5 parts of antifoaming agent, 17-18 parts of deionized water.
Wherein, the preparation method of the modified soluble Ludox is:It is 6- that mass fraction is added in hydrotropism's Ludox 8% nano-carbon powder and the iron oxide of 4-6%, then heat the mixture to 45-50 DEG C, stir evenly postcooling to room temperature i.e. It can.
Preferably, the water-base resin is aqueous anionic acrylic resin lotion;Using the resin emulsion as bonding The progress of pigment, filler and various auxiliary agents can effectively be bonded, improves the compatibility of each paint components by agent.
Preferably, the thickener is polyacrylic acid and the mixture of silica;Antifoaming agent is polyether-modified poly- silica Alkane;Thickener and antifoaming agent are used to improve the property of antirust paint, by the gas dissolution rate in its paint vehicle, improve the stability of enamelled coating And compactness extent.
Wherein, the pigment selects one kind in titanium dioxide, aluminium triphosphate, carbon black, iron oxide red, the mesh number of pigment Higher than 800 mesh;The zinc oxide, talcum powder, sericite part, trbasic zinc phosphate and barium sulfate mesh number be 300-500 mesh;It is thin using this The filler of degree grade can allow paint vehicle evenly, also allow for the later stage to paint vehicle progress further grinding and refinement.
Antirust paint provided by the invention, preparation method are:By water-base resin, modified silicasol, zinc oxide, talcum powder, Sericite part, trbasic zinc phosphate, barium sulfate and antifoaming agent are uniformly mixed in batching kettle, then feed the mixture into high-speed dispersing kettle In be stirred and disperse, thickener, levelling agent, pigment are put into before dispersion, and disperseed will gradually to go simultaneously from Sub- water is added in high-speed dispersing kettle;The rotating speed of Scattered Kettle is 2800-3000r/min, and jitter time 40-50min has disperseed Slurry is sent to progress wet type sand milling in sand mill, the fineness of slurry is ground to 15-20 μm, you can needed for obtaining by Cheng Hou Antirust paint.
A kind of power equipment antirust paint provided by the invention, compared with prior art, has the following advantages:
The antirust paint is water paint, and by organic binder, filler, the components such as auxiliary agent and pigment are formed, and each component is pair The nontoxic green material of human body;Therefore the antirust paint product also has the characteristics that green, safe, to antirust paint spraying application The health of personnel will not damage, and the administrative staff of the equipment using the antirust paint will not be damaged.
The antirust paint degree of protection is high, and coating property is uniform, adhesive force is good, and film layer is fine and smooth and fine and close;With good anti- Rust, corrosion-resistant, antioxygenic property, and the ageing-resistant performance of paint vehicle is also preferable, it is ensured that and coating is anti-in longer life Protect effect.
In addition, the filler and other components of the antirust paint while ensureing paint vehicle performance, are produced into after preferably This more conventional aqueous antirust paint is also reduced.
Specific embodiment
The specific embodiment of the present invention is described in detail below.It should be understood that specific implementation described herein Mode is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
Embodiment 1
The nano-carbon powder and 4% iron oxide that mass fraction is 6% are added in hydrotropism's Ludox, then heats the mixture to 45 DEG C, it stirs evenly postcooling to room temperature and obtains modified soluble Ludox.
According to mass fraction, prepare following raw material:30 parts of water-base resin, 7 parts of modified soluble Ludox, zinc oxide 10 Part, 10 parts of talcum powder, 8 parts of sericite part, 5 parts of trbasic zinc phosphate, 5 parts of barium sulfate, 3 parts of thickener, 2 parts of levelling agent, 15 parts of pigment;Disappear 0.3 part of infusion, 15 parts of deionized water.
Wherein, water-base resin is aqueous anionic acrylic resin lotion;Thickener is polyacrylic acid and silica Mixture;Antifoaming agent is Siloxane-Oxyalkylene Copolymers;Pigment selects titanium dioxide, and the mesh number of pigment is 850 mesh;The oxidation Zinc, talcum powder, sericite part, trbasic zinc phosphate and barium sulfate mesh number be 300 mesh.
Water-base resin, modified silicasol, zinc oxide, talcum powder, sericite part, trbasic zinc phosphate, barium sulfate and antifoaming agent are existed In batching kettle be uniformly mixed, then feed the mixture into high-speed dispersing kettle and be stirred and disperse, dispersion before by thickener, Levelling agent, pigment input, and disperseed gradually deionized water is added in high-speed dispersing kettle simultaneously;Scattered Kettle turns Speed is 2800r/min, jitter time 40min, and after the completion of dispersion, slurry is sent to progress wet type sand milling in sand mill, will The fineness of slurry is ground to 15 μm, you can obtains required antirust paint.
Embodiment 2
The nano-carbon powder and 6% iron oxide that mass fraction is 8% are added in hydrotropism's Ludox, then heats the mixture to 50 DEG C, it stirs evenly postcooling to room temperature and obtains modified soluble Ludox.
According to mass fraction, prepare following raw material:45 parts of water-base resin, 12 parts of modified soluble Ludox, zinc oxide 15 Part, 16 parts of talcum powder, 10 parts of sericite part, 8 parts of trbasic zinc phosphate, 7 parts of barium sulfate, 6 parts of thickener, 3 parts of levelling agent, 25 parts of pigment; 0.5 part of antifoaming agent, 20 parts of deionized water.
Wherein, water-base resin is aqueous anionic acrylic resin lotion;Thickener is polyacrylic acid and silica Mixture;Antifoaming agent is Siloxane-Oxyalkylene Copolymers;Pigment selects aluminium triphosphate, and the mesh number of pigment is 900 mesh;The oxidation Zinc, talcum powder, sericite part, trbasic zinc phosphate and barium sulfate mesh number be 500 mesh.
Water-base resin, modified silicasol, zinc oxide, talcum powder, sericite part, trbasic zinc phosphate, barium sulfate and antifoaming agent are existed In batching kettle be uniformly mixed, then feed the mixture into high-speed dispersing kettle and be stirred and disperse, dispersion before by thickener, Levelling agent, pigment input, and disperseed gradually deionized water is added in high-speed dispersing kettle simultaneously;Scattered Kettle turns Speed is 3000r/min, jitter time 50min, and after the completion of dispersion, slurry is sent to progress wet type sand milling in sand mill, will The fineness of slurry is ground to 20 μm, you can obtains required antirust paint.
Embodiment 3
The nano-carbon powder and 5% iron oxide that mass fraction is 7% are added in hydrotropism's Ludox, then heats the mixture to 48 DEG C, it stirs evenly postcooling to room temperature and obtains modified soluble Ludox.
According to mass fraction, prepare following raw material:40 parts of water-base resin, 10 parts of modified soluble Ludox, zinc oxide 13 Part, 14 parts of talcum powder, 9 parts of sericite part, 7 parts of trbasic zinc phosphate, 6 parts of barium sulfate, 5 parts of thickener, 2.5 parts of levelling agent, 20 parts of pigment; 0.4 part of antifoaming agent, 17 parts of deionized water.
Wherein, water-base resin is aqueous anionic acrylic resin lotion;Thickener is polyacrylic acid and silica Mixture;Antifoaming agent is Siloxane-Oxyalkylene Copolymers;Pigment selects carbon black, and the mesh number of pigment is 850 mesh;The zinc oxide, cunning Mountain flour, sericite part, trbasic zinc phosphate and barium sulfate mesh number be 400 mesh.
Water-base resin, modified silicasol, zinc oxide, talcum powder, sericite part, trbasic zinc phosphate, barium sulfate and antifoaming agent are existed In batching kettle be uniformly mixed, then feed the mixture into high-speed dispersing kettle and be stirred and disperse, dispersion before by thickener, Levelling agent, pigment input, and disperseed gradually deionized water is added in high-speed dispersing kettle simultaneously;Scattered Kettle turns Speed is 2900r/min, jitter time 45min, and after the completion of dispersion, slurry is sent to progress wet type sand milling in sand mill, will The fineness of slurry is ground to 18 μm, you can obtains required antirust paint.
Embodiment 4
The nano-carbon powder and 4% iron oxide that mass fraction is 8% are added in hydrotropism's Ludox, then heats the mixture to 45 DEG C, it stirs evenly postcooling to room temperature and obtains modified soluble Ludox.
According to mass fraction, prepare following raw material:45 parts of water-base resin, 7 parts of modified soluble Ludox, zinc oxide 15 Part, 16 parts of talcum powder, 8 parts of sericite part, 8 parts of trbasic zinc phosphate, 5 parts of barium sulfate, 6 parts of thickener, 2 parts of levelling agent, 20 parts of pigment;Disappear 0.3 part of infusion, 20 parts of deionized water.
Wherein, water-base resin is aqueous anionic acrylic resin lotion;Thickener is polyacrylic acid and silica Mixture;Antifoaming agent is Siloxane-Oxyalkylene Copolymers;Pigment selects iron oxide red, and the mesh number of pigment is 900 mesh;The oxidation Zinc, talcum powder, sericite part, trbasic zinc phosphate and barium sulfate mesh number be 500 mesh.
Water-base resin, modified silicasol, zinc oxide, talcum powder, sericite part, trbasic zinc phosphate, barium sulfate and antifoaming agent are existed In batching kettle be uniformly mixed, then feed the mixture into high-speed dispersing kettle and be stirred and disperse, dispersion before by thickener, Levelling agent, pigment input, and disperseed gradually deionized water is added in high-speed dispersing kettle simultaneously;Scattered Kettle turns Speed is 3000r/min, jitter time 40min, and after the completion of dispersion, slurry is sent to progress wet type sand milling in sand mill, will The fineness of slurry is ground to 15 μm, you can obtains required antirust paint.
Performance test
According to GB/T1731-1993《Paint film flexibility measuring method》, GB/T 1732-1993《Paint film impact resistance mensuration》, GB/T 1771-2007《The resistance to neutral salt spray performance measurement of paint and varnish》Etc. technical standards, it is flexibility to the present embodiment, resistance to Impact, salt spray resistance and artificial weathering ageing resistance can wait and be tested, and obtain following test result:
Table 1:The performance test results of this implementation antirust paint
Project Index Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Flexibility Without reticulate pattern, crackle, peeling It is qualified It is qualified It is qualified It is qualified
Impact resistance Flawless, wrinkle, peeling It is qualified It is qualified It is qualified It is qualified
Salt spray resistance ≥200h 320 310 320 300
Artificial weathering ageing resistance's energy ≥1000h It is qualified It is qualified It is qualified It is qualified
Adhesive force grade \ 1 grade 1 grade 1 grade 1 grade
Data above surface, the present invention provide a kind of power equipment antirust paint, and properties are all very outstanding;In addition, this hair For the antirust paint of bright offer by statistics, production cost declines 4-6% compared with common product also has higher economic value.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (8)

1. a kind of power equipment antirust paint, it is characterised in that:According to mass fraction, the antirust paint contains following component:Water 30-45 parts of resin of property, 7-12 parts of modified soluble Ludox, 10-15 parts of zinc oxide, 10-16 parts of talcum powder, sericite part 8-10 Part, 5-8 parts of trbasic zinc phosphate, 5-7 parts of barium sulfate, 3-6 parts of thickener, 2-3 parts of levelling agent, 15-25 parts of pigment;Antifoaming agent 0.3-0.5 Part, 15-20 parts of deionized water.
2. a kind of power equipment antirust paint according to claim 1, it is characterised in that:According to mass fraction, the antirust Paint contains following component:35-40 parts of water-base resin, 8-10 parts of modified soluble Ludox, 12-13 parts of zinc oxide, talcum powder 12- 15 parts, 8-9 parts of sericite part, 6-7 parts of trbasic zinc phosphate, 5-6 parts of barium sulfate, 4-5 parts of thickener, 2.5-3 parts of levelling agent, pigment 20- 22 parts;0.4-0.5 parts of antifoaming agent, 17-18 parts of deionized water.
3. a kind of power equipment antirust paint according to claim 1, it is characterised in that:The modified soluble Ludox Preparation method is:Mass fraction is added in hydrotropism's Ludox as the nano-carbon powder of 6-8% and the iron oxide of 4-6%, it then will be mixed Close object be heated to 45-50 DEG C, stir evenly postcooling to room temperature is sufficient.
4. a kind of power equipment antirust paint according to claim 1, it is characterised in that:The water-base resin for it is aqueous it is cloudy from Sub- emulsion acrylic resin.
5. a kind of power equipment antirust paint according to claim 1, it is characterised in that:The thickener for polyacrylic acid and The mixture of silica;Antifoaming agent is Siloxane-Oxyalkylene Copolymers.
6. a kind of power equipment antirust paint according to claim 1, it is characterised in that:The pigment selection titanium dioxide, One kind in aluminium triphosphate, carbon black, iron oxide red, the mesh number of pigment are higher than 800 mesh.
7. a kind of power equipment antirust paint according to claim 1, it is characterised in that:The zinc oxide, talcum powder, thin,tough silk cloud The mesh number of female part, trbasic zinc phosphate and barium sulfate is 300-500 mesh.
8. a kind of power equipment antirust paint according to claim 1, it is characterised in that:The preparation method of the antirust paint For:By water-base resin, modified silicasol, zinc oxide, talcum powder, sericite part, trbasic zinc phosphate, barium sulfate and antifoaming agent in batching kettle In be uniformly mixed, then feed the mixture into high-speed dispersing kettle and be stirred and disperse, by thickener, levelling before dispersion Agent, pigment input, and disperseed gradually deionized water is added in high-speed dispersing kettle simultaneously;The rotating speed of Scattered Kettle is Slurry after the completion of dispersion, is sent to progress wet type sand in sand mill by 2800-3000r/min, jitter time 40-50min Mill, is ground to 15-20 μm, you can obtain required antirust paint by the fineness of slurry.
CN201810066184.XA 2018-01-24 2018-01-24 A kind of power equipment antirust paint Withdrawn CN108192443A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022165375A1 (en) * 2021-01-29 2022-08-04 Nitto Denko Corporation Corrosion resistant high voltage electrochemically de-bondable adhesive composition
CN115710444A (en) * 2022-11-28 2023-02-24 永记造漆工业(昆山)有限公司 Water-based acrylic acid antirust paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181231A (en) * 2011-04-20 2011-09-14 杭州灯塔涂料玻璃有限公司 Preparation method of water-based environmentally-friendly anticorrosion paint
CN102993796A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 Metal anti-rust paint and preparation method thereof
CN103555109A (en) * 2013-11-11 2014-02-05 山东乐化漆业股份有限公司 Water-based antirust paint and preparation method thereof
CN106634324A (en) * 2016-09-27 2017-05-10 李昌柱 High-efficient water-based antirust paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181231A (en) * 2011-04-20 2011-09-14 杭州灯塔涂料玻璃有限公司 Preparation method of water-based environmentally-friendly anticorrosion paint
CN102993796A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 Metal anti-rust paint and preparation method thereof
CN103555109A (en) * 2013-11-11 2014-02-05 山东乐化漆业股份有限公司 Water-based antirust paint and preparation method thereof
CN106634324A (en) * 2016-09-27 2017-05-10 李昌柱 High-efficient water-based antirust paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022165375A1 (en) * 2021-01-29 2022-08-04 Nitto Denko Corporation Corrosion resistant high voltage electrochemically de-bondable adhesive composition
CN115710444A (en) * 2022-11-28 2023-02-24 永记造漆工业(昆山)有限公司 Water-based acrylic acid antirust paint and preparation method thereof

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Application publication date: 20180622