CN109888325B - Multi-stage uniform flow field fuel cell and working method thereof - Google Patents

Multi-stage uniform flow field fuel cell and working method thereof Download PDF

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CN109888325B
CN109888325B CN201910054353.2A CN201910054353A CN109888325B CN 109888325 B CN109888325 B CN 109888325B CN 201910054353 A CN201910054353 A CN 201910054353A CN 109888325 B CN109888325 B CN 109888325B
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flow field
fuel
anode
shaped
tree
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CN109888325A (en
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李印实
王睿
何雅玲
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Xian Jiaotong University
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Xian Jiaotong University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The invention discloses a multi-stage uniform flow field fuel cell and a working method thereof.A tree-shaped fuel supply branch is unfolded by a fuel distribution flow path through a step-by-step dispersed tree-shaped flow field, and a tree-shaped step-by-step dispersed longitudinal inflow flow field is adopted, so that electrolyte can uniformly enter the surface of an electrode, the reaction degree of the electrolyte is improved, and the cell efficiency is further improved; meanwhile, the array-shaped product discharge branches are uniformly distributed and connected to the product recovery flow path, and the array-distributed longitudinal outflow flow field combined with the inflow flow field is adopted, so that the electrolyte can flow out of the electrode downstream after the reaction is finished, the uniform high concentration of the fuel at the electrode side is ensured all the time, and the mixing of the fuel and the product is avoided.

Description

Multi-stage uniform flow field fuel cell and working method thereof
Technical Field
The invention relates to the technical field of fuel cells, in particular to a multi-stage uniform flow field fuel cell.
Background
Energy is an important material basis on which human beings live and develop, and all activities of the human society cannot leave the energy. With the rapid development of economy and the continuous progress of society, the consumption of energy by human beings is continuously increased. The energy demand continues to increase worldwide and the consumption of traditional fossil energy remains dominant. However, traditional fossil energy reserves are limited and some of the energy will be depleted in the coming decades. In addition, in the process of utilizing traditional fossil energy, the problem of environmental pollution is also increasing, and the problems of greenhouse effect, acid rain, ozone layer damage and the like caused by the problem seriously threaten the survival and development of human beings. In the face of serious challenges of energy crisis and environmental protection, finding clean sustainable energy capable of replacing traditional fossil energy is certainly the focus of human research.
At present, solar energy, wind energy, tidal energy, geothermal energy and the like have the advantages of sufficient energy, clean and pollution-free utilization process and the like. However, the energy sources have the problems of intermittency, instability, low efficiency and the like in the utilization process. Fuel cells are receiving much attention because of their advantages such as high energy conversion efficiency, low pollution, and no noise. As a new generation of energy technology, the fuel cell provides a new idea for solving the problems of energy crisis and environmental pollution, and has strategic significance. The fuel cell technology is a novel power generation technology, can directly convert chemical energy existing in fuel and oxidant into electric energy, has the remarkable advantages of high efficiency, no pollution, no noise, high reliability, modularization, quick response to load change and the like, and is considered as an ultimate solution for solving the energy crisis.
The fuel cell mainly comprises an ion exchange membrane, a positive electrode, a negative electrode and a bipolar plate. The Membrane Electrode Assembly (MEA) composed of a cathode electrode, an ion exchange membrane and an anode electrode is a place where electrochemical reaction of the fuel cell occurs. Fuel and oxidant are introduced into the anode and cathode of the cell, respectively. Fuel (e.g. H) passed to the anode2、CH3OH、CH3CH2OH、CO(NH2)2、NaBH4HCOONa, etc.) to release electrons, which flow to the cathode through an external circuit and react with the cathode's oxidant (e.g., O)2、H2O2Etc.) the reduction reaction occurs in combination. While ions migrate through the electrolyte membrane to the cathode (or anode) to form a circuit.
Among the various types of fuel cells, Direct Liquid Fuel Cells (DLFC) have received much attention in recent years due to advantages such as high fuel energy density, convenience in storage and transportation, and the like. The direct liquid fuel cell is a fuel cell using liquid such as methanol, ethanol, urea, sodium borohydride, formate and the like as fuel. Direct liquid fuel cells can be classified into acid direct liquid fuel cells and alkaline direct liquid fuel cells according to the kind of the solid electrolyte membrane.
As a key part of a direct liquid fuel cell, the anode flow field has the functions of conveying fuel, distributing fuel and recovering products, and plays a very key role in the whole operation process of the fuel cell. The current anode flow field of the fuel cell mainly comprises a serpentine flow field, a parallel flow field, a discontinuous flow field, an interdigital flow field and the like, and the anode flow field mainly enters an electrode for reaction through the diffusion effect of fuel flowing on one side of the electrode. In the process, along with the flowing of the fuel in the flow channel and the diffusion reaction in the electrode, the fuel continuously consumes products and continuously enters the flow channel, the concentration of the fuel is gradually reduced, the concentration distribution of the fuel in the electrode is uneven, the electrode reaction efficiency is reduced, and the working efficiency of the direct liquid fuel cell is further reduced.
Therefore, in order to solve the problems of fuel product mixing and uneven fuel concentration distribution in the flow reaction process of fuel cell fuel, a high-efficiency fuel cell with fuel product phase separation and concurrent flow transmission and uniform fuel concentration distribution is in urgent need.
Disclosure of Invention
In view of the problems in the prior art, an object of the present invention is to provide a multi-stage uniform flow field fuel cell and a working method thereof, which enable fuel to directly and uniformly reach the surface of an electrode, ensure the downstream transport of the fuel and a product, and avoid the mixing of the fuel product.
In order to achieve the purpose, the invention adopts the following technical scheme to realize the purpose:
a multi-stage uniform flow field fuel cell comprises an anode flow field plate, an anode collector plate, an anode electrode, an exchange membrane, a cathode electrode, a cathode collector plate and a cathode flow field plate which are arranged on a fuel cell body;
the anode current collecting plate is connected with the anode flow field plate and the anode electrode, the anode electrode and the cathode electrode are separated by an exchange membrane, and the cathode current collecting plate is connected with the cathode electrode and the cathode flow field plate;
the anode flow field plate is provided with a fuel inlet, a fuel distribution flow path, a tree-shaped fuel supply branch, an array-shaped product discharge branch, a product recovery flow path and a product outlet, wherein the tree-shaped fuel supply branch is unfolded by the fuel distribution flow path through the tree-shaped flow field which is dispersed step by step, and the array-shaped product discharge branch is uniformly distributed and connected on the product recovery flow path;
the fuel inlet is an inlet of a fuel distribution flow path connected with the outer side of the fuel cell, the inlet of a tree-shaped fuel supply branch path is connected with the fuel distribution flow path, the outlet of the tree-shaped fuel supply branch path is connected with an anode electrode through an anode collector plate, the inlet of an array-shaped product discharge branch path is connected with the anode electrode through the anode collector plate, the outlet of the array-shaped product discharge branch path is connected with a product recovery flow path, the tree-shaped fuel supply branch path and the array-shaped product discharge branch path are pipelines which are positioned in an anode flow field plate and are not mutually staggered and communicated, and the product outlet is an outlet of the product recovery flow path connected with the outer side of the fuel cell;
the anode current collecting plate is a flat plate with array distribution holes, a pore passage in the anode current collecting plate is communicated with the outlet of the tree-shaped fuel supply branch and the inlet of the array-shaped product discharge branch, the cathode current collecting plate is a flat plate with a pore passage corresponding to a flow passage of the cathode flow field plate, and the cathode flow field plate is a flat plate with a flow passage.
Furthermore, the product recovery flow path is longitudinally arranged in the anode flow field plate, the product outlet is positioned at the top of the anode flow field plate, and the fuel inlet is positioned on the side wall of the anode flow field plate.
Furthermore, the outlets of the tree-shaped fuel supply branches and the inlets of the array-shaped product discharge branches are arranged at equal intervals.
Furthermore, the tree-shaped fuel supply branch is a binary tree-shaped stepwise dispersion flow field, that is, the tree-shaped fuel supply branch is divided into 4 branches by 1 electrolyte supply flow path in a 90-degree rotation array, the 4 branches are further divided into 16 branches, and the branches are distributed in a stepwise dispersion manner of 1-4-16.
Further, the array-like product discharge branches are distributed outside the electrodes in a "3 × 3" array.
Furthermore, the anode flow field plate and the cathode flow field plate are made of inorganic non-metallic materials, metal composite materials or organic polymer materials.
Furthermore, the anode current collecting plate and the cathode current collecting plate are made of inorganic nonmetal or metal conductive materials.
Further, the anode electrode and the cathode electrode are made of a conductive metal material or a carbon material coated with a corresponding catalyst having a porous structure.
Further, the exchange membrane is a cation exchange membrane, an anion exchange membrane or a neutral exchange membrane;
a working method of a multi-stage uniform flow field fuel cell comprises the following steps:
step S100: uniform distribution of fuel into the electrodes:
unreacted fuel of the fuel cell enters the anode side of the fuel cell through a fuel inlet, is uniformly distributed to the tree-shaped fuel supply branches through a fuel distribution flow path under the action of pumping work, and enters an anode electrode; meanwhile, the oxidant enters the cathode electrode through a cathode flow field plate and a cathode current collecting plate;
step S200: and (3) battery discharge reaction:
the fuel carries out discharge reaction on the surface of the anode electrode;
step S300: the product flowed out of the cell:
after the fuel reaction is finished, the fuel flowing in from the outlet of each tree-shaped fuel supply branch passes through the anode electrode, flows out from the inlet of the array-shaped product discharge branch in a downstream manner, converges to the product recovery flow path, and is discharged from the product outlet.
Compared with the prior art, the invention has the following advantages and effects:
the invention relates to a multi-stage uniform flow field fuel cell, which comprises an anode flow field plate, an anode collector plate, an anode electrode, an exchange membrane, a cathode electrode, a cathode collector plate and a cathode flow field plate, wherein the anode flow field plate, the anode collector plate, the anode electrode, the exchange membrane, the cathode electrode, the cathode collector plate and the cathode flow field plate are arranged on a fuel cell body; the anode current collecting plate is connected with the anode flow field plate and the anode electrode, the anode electrode and the cathode electrode are separated by the exchange membrane, and the cathode current collecting plate is connected with the cathode electrode and the cathode flow field plate; the tree-shaped fuel supply branch is unfolded by the fuel distribution flow path through the tree-shaped flow field which is dispersed step by step, and the tree-shaped longitudinal inflow flow field which is dispersed step by step is adopted, so that the electrolyte can uniformly enter the surface of the electrode, the reaction degree of the electrolyte is improved, and the efficiency of the battery is further improved;
meanwhile, the array-shaped product discharge branches are uniformly distributed and connected to the product recovery flow path, and the array-distributed longitudinal outflow flow field combined with the inflow flow field is adopted, so that the electrolyte can flow out of the electrode downstream after the reaction is finished, the uniform high concentration of the fuel at the electrode side is ensured all the time, and the mixing of the fuel and the product is avoided.
Furthermore, the outlets of the tree-shaped fuel supply branches and the inlets of the array-shaped product discharge branches are arranged at equal intervals, after the fuel reaction is finished, the fuel flowing into the outlets of the tree-shaped fuel supply branches flows out from the inlets of the array-shaped product discharge branches close to each other, and converges to the product recovery flow path for discharge, so that the pressure difference between the inlet and the outlet is further reduced, the extra pumping power of the battery is reduced, and the battery efficiency is improved.
Drawings
FIG. 1 is a schematic view of a fuel cell according to the present invention;
figure 2 is a side view of a collector plate for a fuel cell of the present invention;
in the figure, 1-anode flow field plate, 2-anode current collecting plate, 3-anode electrode, 4-exchange membrane, 5-cathode electrode, 6-cathode current collecting plate, 7-cathode flow field plate, 8-fuel inlet, 9-fuel distribution flow path, 10-tree-shaped fuel supply branch, 11-array-shaped product discharge branch, 12-product recovery flow path and 13-product outlet.
Detailed Description
The invention is described in further detail below with reference to the figures and the examples, but without limiting the invention.
Referring to fig. 1-2, the multi-stage uniform flow field fuel cell of the present invention includes an anode flow field plate 1, an anode flow collecting plate 2, an anode electrode 3, an exchange membrane 4, a cathode electrode 5, a cathode flow collecting plate 6 and a cathode flow field plate 7 disposed on a fuel cell body; the anode current collecting plate 2 is connected with the anode current flow field plate 1 and the anode electrode 3, the anode electrode 3 and the cathode electrode 5 are separated by an exchange membrane 4, and the cathode current collecting plate 6 is connected with the cathode electrode 5 and the cathode current flow field plate 7.
The anode flow field plate 1 is a flow field plate provided with a fuel inlet 8, a fuel distribution flow path 9, a tree-shaped fuel supply branch path 10, an array-shaped product discharge branch path 11, a product recovery flow path 12 and a product outlet 13, wherein the tree-shaped fuel supply branch path 10 is spread by the fuel distribution flow path 9 through a tree-shaped flow field which is dispersed step by step, and the array-shaped product discharge branch path 11 is uniformly distributed and connected on the product recovery flow path 12.
The fuel inlet 8 is an inlet of the fuel distribution flow path 9 connected with the outer side of the fuel cell, the inlet of the tree-shaped fuel supply branch 10 is connected with the fuel distribution flow path 9, the outlet of the tree-shaped fuel supply branch 10 is connected with the anode electrode 3 through the anode current collecting plate 2, the inlet of the array-shaped product discharge branch 11 is connected with the anode electrode 3 through the anode current collecting plate 2, the outlet of the array-shaped product discharge branch 11 is connected with the product recovery flow path 12, the tree-shaped fuel supply branch 10 and the array-shaped product discharge branch 11 are pipelines which are positioned in the anode current field plate 1 and are not mutually staggered and communicated, and the product outlet 13 is an outlet of the product recovery flow path 12 connected with the outer side of the fuel cell.
The product recovery flow path 12 is longitudinally arranged in the anode flow field plate 1, the product outlet 13 is positioned at the top of the anode flow field plate 1, and the fuel inlet 8 is positioned on the side wall of the anode flow field plate 1.
The outlets of the plurality of tree-shaped fuel supply branches 10 and the inlets of the plurality of array-shaped product discharge branches 11 are arranged at equal intervals.
The anode current collecting plate 2 is a flat plate with array distribution holes, the pore channel in the anode current collecting plate 2 is communicated with the outlet of the tree-shaped fuel supply branch 10 and the inlet of the array-shaped product discharge branch 11, and the cathode current collecting plate 6 is a flat plate with pore channels corresponding to the flow channel of the cathode flow field plate 7. The cathode flow field plate 7 is a flat plate having a serpentine flow channel, a parallel flow channel, a discontinuous flow channel, an interdigitated flow channel, and the like.
Wherein the fuel is a liquid solution having chemical energy and capable of being converted into electric energy, and comprises CH3OH、CH3CH2OH、CO(NH2)2、NaBH4And HCOONa.
The materials used for the anode flow field plate 1 and the cathode flow field plate 7 have mechanical strength required for a fuel cell and corrosion resistance to the electrolyte used, and include inorganic nonmetallic materials such as graphite, metal composite materials such as stainless steel, and organic polymer materials such as polymethyl methacrylate.
The anode current collecting plate 2 and the cathode current collecting plate 6 are made of inorganic nonmetal such as graphite or conductive material of metal such as stainless steel.
The anode electrode 3 and the cathode electrode 5 are conductive metal materials or carbon materials coated with corresponding catalysts and having porous structures; the exchange membrane 4 is a cation exchange membrane, an anion exchange membrane or a middle exchange membrane;
the tree-shaped fuel supply branch 10 is a binary tree-shaped step-by-step dispersive flow field, namely the tree-shaped fuel supply branch can be divided into 4 branches by 1 electrolyte supply flow path in a 90-degree rotary array, the 4 branches are further divided into 16 branches, and the electrolyte can enter the electrode more uniformly in a step-by-step dispersive mode of 1-4-16; the arrayed product discharge branches 11 are distributed in a "3 × 3" array outside the electrodes.
The working method of the multi-stage uniform flow field fuel cell comprises the following steps:
step S100: uniform distribution of fuel into the electrodes:
unreacted fuel of the fuel cell enters the anode side of the fuel cell through a fuel inlet 8, is uniformly distributed to tree-shaped fuel supply branches 10 through a fuel distribution flow path 9 under the action of pumping work, and enters the anode electrode 3; meanwhile, the oxidant enters the cathode electrode 5 through the cathode flow field plate 7 and the cathode current collecting plate 6 in an active or passive mode;
step S200: and (3) battery discharge reaction:
taking an acid fuel cell as an example, fuel is subjected to oxidation reaction on the surface of an anode electrode 3 to generate protons, electrons are lost and the valence is raised, the lost electrons enter the anode side through the anode electrode 3 and an anode collector plate 2 through an external circuit, and the protons enter the cathode side through an exchange membrane 4 under the action of an electric field; the electrons reach the surface of the cathode electrode 3 through an external circuit and the cathode collector plate 6, and the oxidant and the protons undergo a reduction reaction on the surface of the anode to obtain electrons, so that the valence is reduced, and the primary discharge reaction of the battery is realized;
step S300: the product flowed out of the cell:
after the fuel reaction is finished, the fuel flowing in from the outlet of each tree-shaped fuel supply branch 10 flows out from the inlet of the array-shaped product discharge branch 11 through the anode electrode 3, and further the electrolyte is converged by the array-shaped product discharge branch 11 to the product recovery flow path 12 to be discharged through the product outlet 13.
Compared with the prior art, the invention adopts a novel binary tree-shaped longitudinal inflow flow field which is dispersed step by step, so that the electrolyte can uniformly enter the surface of the electrode, the reaction degree of the electrolyte is improved, and the efficiency of the battery is further improved; meanwhile, the invention adopts the array distribution longitudinal outflow flow field combined with the inflow flow field to ensure that the electrolyte can flow out of the electrode downstream after the reaction is finished, thereby ensuring that the fuel at the electrode side is uniform and high in concentration all the time and avoiding the mixing of fuel products.
Finally, it should be noted that: although the present invention has been described in detail with reference to the above embodiments, it should be understood by those skilled in the art that: modifications and equivalents may be made to the embodiments of the invention without departing from the spirit and scope of the invention, which is to be covered by the claims.

Claims (10)

1. A multi-stage uniform flow field fuel cell, comprising: comprises an anode flow field plate (1), an anode flow collecting plate (2), an anode electrode (3), an exchange membrane (4), a cathode electrode (5), a cathode flow collecting plate (6) and a cathode flow field plate (7) which are arranged on a fuel cell body;
the anode current collecting plate (2) is connected with the anode flow field plate (1) and the anode electrode (3), the anode electrode (3) and the cathode electrode (5) are separated by an exchange membrane (4), and the cathode current collecting plate (6) is connected with the cathode electrode (5) and the cathode flow field plate (7);
the anode flow field plate (1) is provided with a fuel inlet (8), a fuel distribution flow path (9), a tree-shaped fuel supply branch (10), an array-shaped product discharge branch (11), a product recovery flow path (12) and a product outlet (13), wherein the tree-shaped fuel supply branch (10) is unfolded from the fuel distribution flow path (9) through a tree-shaped flow field which is dispersed step by step, and the array-shaped product discharge branch (11) is uniformly distributed and connected on the product recovery flow path (12);
the fuel inlet (8) is an inlet of a fuel distribution flow path (9) connected with the outer side of a fuel cell, the inlet of a tree-shaped fuel supply branch (10) is connected with the fuel distribution flow path (9), the outlet of the tree-shaped fuel supply branch (10) is connected with an anode electrode (3) through an anode collector plate (2), the inlet of an array-shaped product discharge branch (11) is connected with the anode electrode (3) through the anode collector plate (2), the outlet of the array-shaped product discharge branch (11) is connected with a product recovery flow path (12), the tree-shaped fuel supply branch (10) and the array-shaped product discharge branch (11) are pipelines which are positioned in the anode flow field plate (1) and are staggered and not communicated with each other, and the product outlet (13) is an outlet of the product recovery flow path (12) connected with the outer side of the fuel cell;
the anode current collecting plate (2) is a flat plate with array distribution holes, the pore channels in the anode current collecting plate (2) are communicated with the outlet of the tree-shaped fuel supply branch (10) and the inlet of the array-shaped product discharge branch (11), the cathode current collecting plate (6) is a flat plate with pore channels corresponding to the flow channels of the cathode flow field plate (7), and the cathode flow field plate (7) is a flat plate with flow channels.
2. The multi-stage uniform flow field fuel cell of claim 1, wherein: the product recovery flow path (12) is longitudinally arranged in the anode flow field plate (1), the product outlet (13) is positioned at the top of the anode flow field plate (1), and the fuel inlet (8) is positioned on the side wall of the anode flow field plate (1).
3. The multi-stage uniform flow field fuel cell of claim 2, wherein: the outlets of the tree-shaped fuel supply branches (10) and the inlets of the array-shaped product discharge branches (11) are arranged at equal intervals.
4. The multi-stage uniform flow field fuel cell of claim 3, wherein: the tree-shaped fuel supply branch (10) is a binary tree-shaped stepwise dispersion flow field, namely the tree-shaped fuel supply branch is divided into 4 branches by 1 electrolyte supply flow path in a 90-degree rotary array, the 4 branches are further divided into 16 branches, and the branches are distributed in a stepwise dispersion mode of 1-4-16.
5. The multi-stage uniform flow field fuel cell of claim 4, wherein: the array-shaped product discharge branches (11) are distributed on the outer side of the electrode in a 3 x 3 array.
6. The multi-stage uniform flow field fuel cell according to any one of claims 1 to 5, wherein: the anode flow field plate (1) and the cathode flow field plate (7) are made of inorganic non-metallic materials, metal composite materials or organic polymer materials.
7. The multi-stage uniform flow field fuel cell according to any one of claims 1 to 5, wherein: the anode current collecting plate (2) and the cathode current collecting plate (6) are made of inorganic nonmetal or metal conductive materials.
8. The multi-stage uniform flow field fuel cell according to any one of claims 1 to 5, wherein: the anode electrode (3) and the cathode electrode (5) are conductive metal materials or carbon materials coated with corresponding catalysts and having porous structures.
9. The multi-stage uniform flow field fuel cell according to any one of claims 1 to 5, wherein: the exchange membrane (4) is a cation exchange membrane, an anion exchange membrane or a middle exchange membrane.
10. A method of operating a multi-stage uniform flow field fuel cell as recited in claim 1, comprising the steps of:
step S100: uniform distribution of fuel into the electrodes:
unreacted fuel of the fuel cell enters the anode side of the fuel cell through a fuel inlet (8), is uniformly distributed to tree-shaped fuel supply branches (10) through a fuel distribution flow path (9) under the action of pumping work, and enters an anode electrode (3); meanwhile, the oxidant enters the cathode electrode (5) through a cathode flow field plate (7) and a cathode collector plate (6);
step S200: and (3) battery discharge reaction:
the fuel carries out discharge reaction on the surface of the anode electrode (3);
step S300: the product flowed out of the cell:
after the fuel reaction is finished, the fuel flowing in from the outlet of each tree-shaped fuel supply branch (10) flows out from the inlet of the array-shaped product discharge branch (11) through the anode electrode (3) in a downstream manner, converges to the product recovery flow path (12), and is discharged through the product outlet (13).
CN201910054353.2A 2019-01-21 2019-01-21 Multi-stage uniform flow field fuel cell and working method thereof Active CN109888325B (en)

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