CN109876622A - A kind of equipment and deodorizing methods for livestock manure fermented foul smell emission reduction - Google Patents

A kind of equipment and deodorizing methods for livestock manure fermented foul smell emission reduction Download PDF

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Publication number
CN109876622A
CN109876622A CN201910179336.1A CN201910179336A CN109876622A CN 109876622 A CN109876622 A CN 109876622A CN 201910179336 A CN201910179336 A CN 201910179336A CN 109876622 A CN109876622 A CN 109876622A
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low level
foul smell
equipment
deodorant liquid
liquid
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CN109876622B (en
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张昊
皮劲松
陈芳
梁振华
蒲跃进
申杰
潘爱銮
吴艳
孙静
杜金平
梁逸夫
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Institute of Animal Science and Veterinary of Hubei Academy of Agricultural Sciences
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Institute of Animal Science and Veterinary of Hubei Academy of Agricultural Sciences
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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Abstract

The present invention provides a kind of equipment and deodorizing methods for livestock manure fermented foul smell emission reduction, which includes throwing the flusher for turning over machine device, pressurization pump machine and being turned on machine device positioned at the throwing;The flusher includes low level spraying mechanism and high-order spraying mechanism;Low level spraying mechanism includes low level delivery tube road, first spray head, the low level holding vessel equipped with the first deodorant liquid;First deodorant liquid includes the liquid lactic acid and water of solid-state citric acid, 75%~85%;The high position spraying mechanism includes high-order transfer pipeline, second spray head, the high-order holding vessel equipped with the second deodorant liquid, and second deodorant liquid includes bacillus pumilus, exerts than halogen anaerobic bacillus, thiobacillus denitrificans, enterococcus faecalis and short distance nitration bacterium.This method is using chemical method and bioanalysis is neutralized to the chemistry of release foul smell and functional microorganism converts, and achievees the purpose that reduce the foul smell amount that can be discharged into environment, deodorizing rate is high.

Description

A kind of equipment and deodorizing methods for livestock manure fermented foul smell emission reduction
Technical field
The present invention relates to animal waste harmless treatment fields, in particular to a kind of to subtract for livestock manure fermented foul smell The equipment and deodorizing methods of row.
Background technique
Compost is one of the effective means of feces of livestock and poultry harmless treatment, is widely used in poultry excrement and urine disposal.Compost face The greatest problem faced is foul smell caused by compost, does not influence ambient enviroment singly, also reduction fertility, and therefore, deodorization is compost Important process link.Compost deodorizing mainly passes through three steps and is realized, respectively source emission reduction, process emission reduction and end-o f-pipe -control. Currently, related deodorization process focuses primarily upon two stages of source emission reduction and end-o f-pipe -control, the technique of foul smell process emission reduction is rarely seen Report.
Compost foul smell release can be divided into concentration release and two stages of unordered release, concentrate the release stage mainly turning with 0.5 to 1 hour after turning, other times were the foul smell unordered release stage.The release stage is concentrated in foul smell, since foul smell discharges Measure huge, and concentration is high, influences very extensive.And in the foul smell unordered release stage, since heap body ventilation quantity is limited, and upper layer heap Material has shadowing effect, and the foul smell burst size of compost is less.Therefore, the process emission reduction of compost foul smell should pay close attention to foul smell and concentrate release In the stage, in this stage, a large amount of foul smell and vapor are distributed into environment.Concentrate release odor components mainly include ammonia, Hydrogen sulfide and volatile organic compounds (VOC) etc., wherein ammonia concentration highest, volatile organic compounds type are complicated.Needle The characteristics of to feces of livestock and poultry trough composting foul smell, suitable deodorizing methods should be selected.
Deodorizing methods mainly includes physical method, chemical method and three kinds of bioanalysis.Wherein, physical method mainly utilizes a kind of object The smell of foul smell is covered and is diluted by matter, or foul smell is converted to other phases, this method suitable treatment low concentration by gas phase Foul smell.Chemical method mainly includes chemical absorption method and combustion method, chemical absorption method be suitble to atm number, intermediate concentration exhaust gas at Reason, the scope of application are wider;Combustion method is mainly to utilize the combustibility of foul smell by its gasification, and combustion or pyrolytic, is converted into nothing Evil substance, however some organic compounds can be converted into harmful hydrogen halides, sulfur dioxide, nitrogen dioxide etc., bring secondary dirt Dye, and combustion method generally requires fuel auxiliary combustion so that using deodorization device higher cost made of this method, operation compared with For complexity.The physiological metabolism that biological odor removal method mainly passes through microorganism will have substance frowzy and be converted, and keep target dirty It contaminates object and decomposes removal by effective, to reach the improvement purpose of stench.Three kinds of deodorizing methodss have respective excellent in terms of foul smell removing Gesture, meanwhile, also respectively have certain drawbacks, such as: chemical reaction method: i.e. with sterilization or disinfection chemicals by kill bacterium or Person and colony house fecaluria, which are chemically reacted, carrys out deodorization, such as trichlorine isocyanide, strong acid, highly basic etc., though deodorizing effect is good, human body Harmful with animal, when deodorization, needs to abide by stringent program;Though biological odor removal method can deodorization well, a variety of bacterium one Play culture in use, will appear certain bacterium fermentation condition in mixed culture be not suitable for competitiveness not enough and grow it is difficult, together When different types of microorganisms will appear when being used in mixed way and interfere with each other, deodorization operation cannot be preferably applied for.It therefore, should basis The constituent and concentration in smelly source are reasonably used.
For the process emission abatement device and related-art process that there is no at present for livestock excrement composting foul smell, this field Technical staff wishes to combine chemical method and bioanalysis, prepares one kind and be capable of the realization foul smell emission reduction of compost foul smell concentration release stage Equipment simultaneously establishes related process standard, realizes and realizes efficient emission-reducing to important odoriferous thing in composting process, existing to make up There is the shortcoming of technical matters.
Summary of the invention
It is an object of the invention to overcome the defect of the prior art, provide a kind of for the emission reduction of livestock manure fermented foul smell Equipment and deodorizing methods, which is utilized respectively chemical method and bioanalysis, to the odor components being collected into upper and lower two It is removed in a spatial position, the chemistry of release foul smell is neutralized and functional microorganism converts, reaches reduction and is discharged into ring The purpose of foul smell amount in border, odor removal efficient are high.
The present invention is implemented as follows:
It include throwing to turn over machine one of the objects of the present invention is to provide a kind of equipment for livestock manure fermented foul smell emission reduction Device is pressurized pump machine and turns over the flusher on machine device positioned at the throwing;Wherein, the flusher includes low level sprinkling Mechanism and high-order spraying mechanism;
The low level spraying mechanism includes low level delivery tube road, first spray head, the low level holding vessel equipped with the first deodorant liquid, Low level holding vessel described in the pressurization pump machine, low level delivery tube Lu Junyu is connected, and it is defeated that the first spray head is set to the low level It send on pipeline;First deodorant liquid includes the liquid lactic acid and water of solid-state citric acid, 75%~85%;
The high position spraying mechanism includes high-order transfer pipeline, second spray head, the high-order holding vessel equipped with the second deodorant liquid, The pressurization pump machine, high-order transfer pipeline are connected with the high-order holding vessel, and it is defeated that the second spray head is set to the high position It send on pipeline;Second deodorant liquid includes bacillus pumilus, exerts than halogen anaerobic bacillus, thiobacillus denitrificans, excrement intestines Coccus and short distance nitration bacterium.
Preferably, solid-state citric acid, 75%~85% liquid lactic acid and the parts by weight of water in first deodorant liquid Number is than being 1~30 part, 1~30 part, 340~400 parts.
Preferably, the bacillus pumilus in second deodorant liquid, exert than halogen anaerobic bacillus, denitrogenation sulphur bar Bacterium, enterococcus faecalis, short distance nitration bacterium portion rate be 0.5~2 part, 0.5~2 part, 0.5~2 part, 0.5~2 part, 0.5~2 Part.
Preferably, vortex evenly mixing device is equipped in the low level holding vessel and high-order holding vessel;The low level holding vessel Adherent layer is coated with the inner surface of high-order holding vessel.
Preferably, it includes turner, turner dipping control and rack that machine device is turned in the throwing, the turner, Turner dipping control is installed in the rack, and the turner dipping control and the gantry rotation connect It connects.
Preferably, it is equipped with high-order transfer gantry below the high-order transfer pipeline, is equipped with below the low level delivery tube road Low level transfer gantry, the low level transfer gantry and high-order transfer gantry are respectively positioned in the rack.
Preferably, the height distance between the low level transfer gantry and livestock excrement composting surface to be processed be 30~ 60cm, the low level transfer gantry are 20~50cm at a distance from the turner device.In order to avoid acid deodorization corrosion Turn over throwing rake.
Preferably, the height distance between the high-order transfer gantry and livestock excrement composting surface to be processed is 100 ~150cm, the high position transfer gantry is 70~120cm at a distance from the turner device.In order to avoid acid deodorant liquid Throwing rake is turned in corrosion.
The second object of the present invention, which is to provide, a kind of carries out deodorization to livestock excrement composting using the deodorizing device Method, described method includes following steps:
Step 1, equipment installation, above-mentioned deodorizing device are mounted at livestock excrement composting to be processed;
Prepare before step 2, deodorization:
S1, the first deodorant liquid of preparation: by solid-state citric acid, 75%~85% liquid lactic acid and water mix after obtained first Deodorant liquid;
S2, the second deodorant liquid of preparation: by bacillus pumilus, than halogen anaerobic bacillus, thiobacillus denitrificans, excrement intestines are exerted After coccus and short distance nitration bacterium mix;It takes 3-10ml, is added enriched medium, 28 DEG C, revolving speed 150-300rpm shaking table culture After 2-4 days, 100 mesh net filtrations are made;
Step 3, heap body turn over throwing preceding 5~15 minutes and meanwhile open be pressurized pump machine, throwing turn over machine device, turn over cast aside the beginning when, Start to spray deodorant liquid progress Odor control, after being disposed, simultaneously closes off throwing and turn over machine device, be pressurized pump machine, stop sprinkling and removes Smelly liquid.
Compared with prior art, the invention has the following advantages:
1, a kind of equipment for livestock manure fermented foul smell emission reduction provided by the invention, in conjunction with chemical method and bioanalysis pair Foul smell is removed, and a variety of odor components of different nature can be removed;The detailed process of deodorization are as follows: generated greatly when heap body turns over throwing When measuring foul smell, the hydrogen sulfide of ammonia and high smelly threshold value including high concentration.In the process, low level spray assembly sprays Faintly acid deodorant liquid, water-soluble alkaline stink odor of the deodorant liquid dissolution including ammonia including, and the deodorization by spraying Liquid is deposited to heap body surface face.Meanwhile the functional microbial deodorant liquid that high-order spray assembly sprays, the solable matter of foul smell By aqueous phase dissolved, heap body surface face is further deposited to by the deodorant liquid sprayed, functional microbial not only can be by dissolution Soluble odor components are converted into sulphur simple substance, nitrite or mycoprotein, moreover it is possible to heap body surface face are covered in, in suitable temperature Under the conditions of longer performance deodorization.In addition, the functional microbial being free in air can also nearby certain area it is empty Between play deodorization.
2, the first deodorant liquid uses the small molecular organic acid of debita spissitudo, does not influence the functional microorganism in the second deodorant liquid Deodorizing effect and deodorizing capability.Common chemical deodorizing agent (strong acid, highly basic or oxidizing species) can be unfavorable in the market The growth of functional microorganism.
3, the bacillus pumilus of the second deodorant liquid is mainly used for removing H2S;Short distance nitration bacterium is mainly used for removing NH3; The process of thiobacillus denitrificans energy sulfur oxide compound obtains energy, and generates nitrogen by electron acceptor of nitrate;Enterococcus faecalis energy The feed residual in excrement is reduced, stink is eliminated, improves feeding environment, reduces pollution of the cultivation to environment;Exert than halogen anaerobic Bacillus is thermoduric bacteria, can be survived under conditions of temperature is high again;Pass through the organic assembling of a variety of strains and the essence of culture solution The heart is prepared, and ensure that deodorant can remain efficient deodorizing effect under the conditions of normality;And the present inventor is found by experiment that When being mixed together culture to all strains in the first deodorizing microorganism using culture solution of the invention, between different types of microorganisms It will not interfere with each other, different types of microorganisms can survive well and each other be not in inhibiting effect, can be well Applied to deodorization operation.First deodorizing microorganism deodorization passes through 3 stages: the dissolution of foul gas is transferred to liquid phase by gas phase; Odor pollutant is by microorganism adsorption, absorption in aqueous solution;Into microbial cell odor pollutant as nutriment be micro- life Object decomposes utilization, so that microorganism is removed.Inhibit the number of anaerobic bacteria or other harmful bacteria by strain balanced action Amount, can reduce the generation of foul smell, and microorganism can further be grown using the organic matter of decomposition, then machine from source Tool decomposes foul smell, reaches permanent sustainable deodorizing effect.Since the deodorizing methods reduces the release of ammonia and utilizes micro- life Object is converted ammonia nitrogen, which also contributes to the nitrogen content of composting production.
4, the deodorizing methods can continue deodorization by being covered in the function bacterium on compost surface.
5, the deodorizing methods is not limited to enclosed composting conditions, can also be used in opening/semi-open compost place, It realizes foul smell removing, increases the usage scenario of the equipment and technique.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell;
Fig. 2 is the structure of flusher in the equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell Schematic diagram;
Fig. 3 is the connection of flusher in the equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell Schematic diagram;
Fig. 4 is the structural representation of rack in the equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell Figure;
Fig. 5 turns over the structure of machine for the throwing in the equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell Schematic diagram;
Fig. 6 is the high low-key of turner in the equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell The structural schematic diagram of regulating device;
Fig. 7 is that machine walking dress is turned in the throwing in the equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell The structural schematic diagram set;
In Fig. 1,1, throw turn over machine device;11, it throws and turns over machine;12, turner dipping control;13, rack;14, it throws and turns over machine Running gear;2, it is pressurized pump machine;3, flusher;31, low level spraying mechanism;311, low level delivery tube road;312, first spray head; 313, low level holding vessel;32, high-order spraying mechanism;321, high-order transfer pipeline;322, second spray head;323, high-order holding vessel; 4, vortex evenly mixing device.
Specific embodiment
One, the equipment for livestock manure fermented foul smell emission reduction
As Figure 1-Figure 4, the embodiment of the present invention provides a kind of equipment for livestock manure fermented foul smell emission reduction, including Throw the flusher 3 for turning over machine device 1, pressurization pump machine 2 and being turned on machine device positioned at the throwing;Wherein, the flusher 3 wraps Include low level spraying mechanism 31 and high-order spraying mechanism 32;
The low level spraying mechanism 31 includes low level delivery tube road 311, first spray head 312, equipped with the low of the first deodorant liquid Position holding vessel 313, the pressurization pump machine 2, low level delivery tube road 311 are connected with the low level holding vessel 313, and described first Spray head 312 is set on the low level delivery tube road 311;First deodorant liquid is by the liquid lactic acid of solid-state citric acid, 80% By ratio of weight and the number of copies be 3 parts with water, 3 parts, 394 parts mix after be made;
The high position spraying mechanism 32 includes high-order transfer pipeline 321, second spray head 322, the height equipped with the second deodorant liquid Position holding vessel 323, the pressurization pump machine 2, high-order transfer pipeline 321 are connected with the high-order holding vessel 323, and described second Spray head 322 is set on the high-order transfer pipeline 321;Second deodorant liquid is by bacillus pumilus, exerts than halogen anaerobic Bacillus, thiobacillus denitrificans, enterococcus faecalis, short distance nitration bacterium weight fraction ratio be 1 part, 1 part, 1 part, 1 part, 1 part, take Enriched medium is added in 3~10ml, and after 28 DEG C, revolving speed 150-300rpm shaking table culture 2-4 days, 100 mesh net filtrations are obtained. The bacillus pumilus exerts than halogen anaerobic bacillus, thiobacillus denitrificans, enterococcus faecalis, short distance nitration bacterium, purchase in Japanese JCM microbial material develops room.The enrichment culture based formulas are as follows: glucose 10.0g, NaCl 1.0g, Na2S2O35g, K2HPO4·2H2O 2.0g, KH2PO4·2H2O 2.0g, NH4Cl 0.5g, MgCl20.2g, trace element solution 1.0ml, water 1000mL, pH value 7.2-7.4;
Wherein, trace element water-soluble formula of liquid are as follows: EDTA 10.0g, ZnSO41.2g, CaCl21.5g, MnCl2·4H2O 1.0g, FeSO4·H2O 2.0g, (NH4)6Mo7O24·4H2O 1.0g, CuSO4·5H2O 1g, CoCl2·6H2O 1.0g, water 1000mL, pH value 7.2-7.4;
Equipment provided in an embodiment of the present invention for the emission reduction of livestock manure fermented foul smell, first/second holding vessel pass through It is pressurized pump machine, is connect through first/second transfer pipeline with first/second spray head, while opening pressurization pump machine, throwing and turn over machine device When, throwing turns over the throwing of machine device when turning over, and heap body turns over throwing and generates a large amount of foul smell, the vulcanization of ammonia and high smelly threshold value including high concentration Hydrogen.In the process, the faintly acid deodorant liquid (the first deodorant liquid) that low level spraying mechanism 31 sprays, deodorant liquid dissolution include ammonia Water-soluble alkaline stink odor including gas, and the deodorant liquid by spraying is deposited to heap body surface face.Meanwhile high-order spraying machine The functional microbial deodorant liquid (the second deodorant liquid) that structure 32 sprays, the solable matter of foul smell is by aqueous phase dissolved, into one Step is deposited to heap body surface face by the deodorant liquid sprayed, and functional microbial can not only convert the soluble odor components of dissolution For sulphur simple substance, nitrite or mycoprotein, moreover it is possible to be covered in heap body surface face, longer performance removes under the conditions of suitable temperature Smelly effect.In addition, the functional microbial being free in air also nearby can play deodorization in certain area space.It is described First deodorant liquid uses small molecular organic acid, does not influence the deodorizing effect and deodorization energy of the functional microorganism in the second deodorant liquid Power.The release of ammonia is reduced due to the deodorizing methods and is converted ammonia nitrogen using microorganism, so the deodorizing methods Also contribute to the nitrogen content of composting production.
Preferably, vortex evenly mixing device 4 is equipped in the low level holding vessel 313 and high-order holding vessel 323;The low level The inner surface of holding vessel and high-order holding vessel is coated with adherent layer.
As shown in Figure 5-Figure 7, it is preferable that it includes turner 11, turner dipping control 12 that machine device 1 is turned in the throwing With rack 13, the turner 11, turner dipping control 13 are installed in 13 in the rack.
It is further preferable that it further includes throwing to turn over machine running gear 14 that machine device 1 is turned in the throwing, throwing turns over machine running gear 14 and includes Idler wheel below the rack 13 is set.It can use billowing wheel and push turner.
Preferably, high-order transfer gantry is equipped with below the high-order transfer pipeline 321, under the low level delivery tube road 311 Side is equipped with low level transfer gantry.
Preferably, the height distance between the low level transfer gantry and livestock excrement composting surface to be processed be 30~ The height distance of 60cm, the low level transfer gantry and the turner device 1 is 20~50cm.
Preferably, the height distance between the high-order transfer gantry and livestock excrement composting surface to be processed is 100 The height distance of~150cm, the high position transfer gantry and the turner device 1 is 70~120cm.
Two, the method that deodorization is carried out to livestock excrement composting using the deodorizing device
Described method includes following steps:
Step 1, equipment installation, above-mentioned deodorizing device are mounted at livestock excrement composting to be processed;
Prepare before step 2, deodorization:
S1, the first deodorant liquid of preparation: by solid-state citric acid, 75%~85% liquid lactic acid and water mix after obtained first Deodorant liquid;
S2, the second deodorant liquid of preparation: by bacillus pumilus, than halogen anaerobic bacillus, thiobacillus denitrificans, excrement intestines are exerted The second deodorant liquid is made after mixing in coccus and short distance nitration bacterium;
Step 3, heap body turn over throwing preceding 5~15 minutes and meanwhile open be pressurized pump machine, throwing turn over machine device, turn over cast aside the beginning when, Start to spray deodorant liquid progress Odor control, after being disposed, simultaneously closes off throwing and turn over machine device, be pressurized pump machine, stop sprinkling and removes Smelly liquid.First holding vessel and second needs holding vessel routine observation detection liquid level or setting liquid sensor to be monitored, and mends on demand It fills.
Embodiment 2
The embodiment is except the formula replacement in first deodorant liquid are as follows: solid-state citric acid, 80% liquid lactic acid and water Weight fraction ratio be 1 part, 1 part, 398 parts;Remaining is the same as embodiment 1.
Embodiment 3
The embodiment is except the formula replacement in first deodorant liquid are as follows: solid-state citric acid, 80% liquid lactic acid and water Weight fraction ratio be 30 parts, 30 parts, 340 parts;Remaining is the same as embodiment 1.
Embodiment 4
The embodiment is except the formula replacement in first deodorant liquid are as follows: solid-state citric acid, 75% liquid lactic acid and water Weight fraction ratio be 3 parts, 1 part, 396 parts;Remaining is the same as embodiment 1.
Embodiment 5
The embodiment is except the formula replacement in first deodorant liquid are as follows: solid-state citric acid, 85% liquid lactic acid and water Weight fraction ratio be 3 parts, 1 part, 396 parts;Remaining is the same as embodiment 1.
Embodiment 6
The embodiment except in second deodorant liquid bacillus pumilus, exert than halogen anaerobic bacillus, denitrogenation Thiobacillus, enterococcus faecalis, short distance nitration bacterium weight fraction ratio be 0.5 part, 2 parts, 2 parts, 2 parts, 0.5 part;Remaining is the same as implementation Example 1.
Embodiment 7
The embodiment except in second deodorant liquid bacillus pumilus, exert than halogen anaerobic bacillus, denitrogenation Thiobacillus, enterococcus faecalis, short distance nitration bacterium weight fraction ratio be 2 parts, 2 parts, 0.5 part, 0.5 part, 2 parts;Remaining is the same as implementation Example 1.
Comparative example 1
For the comparative example in addition to not utilizing deodorant liquid of the invention, remaining composting process is identical, obtained composting production.
Comparative example 2
In second deodorant liquid of the comparative example in addition to without bacillus pumilus, remaining is the same as embodiment 1.
Comparative example 3
Except without in addition to exerting than halogen anaerobic bacillus, remaining is the same as embodiment 1 in second deodorant liquid of the comparative example.
Comparative example 4
In second deodorant liquid of the comparative example in addition to without thiobacillus denitrificans, remaining is the same as embodiment 1.
Comparative example 5
In second deodorant liquid of the comparative example in addition to without enterococcus faecalis, remaining is the same as embodiment 1.
Comparative example 6
In second deodorant liquid of the comparative example in addition to without short distance nitration bacterium, remaining is the same as embodiment 1.
Experimental example 1
The nitrogen loss for the composting production that the composting production and the embodiment of the present invention 1 that comparative example 1 obtains obtain carries out pair Than (nitrogen content detection is carried out using kjeldahl apparatus), as shown in table 1.
Table 1
Project Nitrogen loss (%)
Embodiment 1 20.98%
Comparative example 1 35.24%
As shown in Table 1, the nitrogen loss of 1 composting production of comparative example is 35.24%, the nitrogen of composting production in embodiment 1 Loss is 20.98%.As a result illustrate, the release of ammonia is reduced due to the deodorizing methods and carried out ammonia nitrogen using microorganism Conversion, this patent deodorizing methods help to improve the nitrogen content of composting production.
Experimental example 2
Odor removal efficient in Statistics Implementation example 1- embodiment 7 and comparative example 2- comparative example 6, deodorization index include ammonia removal Rate, hydrogen sulfide removal rate are specifically shown in Table 1.
Table 1
Group Ammonia removal rate Hydrogen sulfide removal rate
Embodiment 1 73.4% 90.3%
Embodiment 2 66.1% 93.4%
Embodiment 3 80.4% 81.3%
Embodiment 4 74.0% 85.2%
Embodiment 5 77.1% Heap body is without H before and after deodorization2S release
Embodiment 6 68.2% 95.2%
Embodiment 7 75.7% Heap body is without H before and after deodorization2S release
Comparative example 2 90.0% 76.4%
Comparative example 3 80.8% 85.1%
Comparative example 4 75.2% 78.1%
Comparative example 5 88.1% 90.4%
Comparative example 6 77.4% 91.6%
As shown in Table 1, after equipment operation, ammonia removal rate is 65%-80% during turning, and hydrogen sulfide removal rate is 80%-95%.4h (banking up the phase) after turning, ammonia removal rate 50%-70%, and hydrogen sulfide release is not detected.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of equipment for livestock manure fermented foul smell emission reduction, which is characterized in that including throw turn over machine device, pressurization pump machine with And the flusher on machine device is turned over positioned at the throwing;Wherein, the flusher includes low level spraying mechanism and high-order sprinkling Mechanism;
The low level spraying mechanism includes low level delivery tube road, first spray head, the low level holding vessel equipped with the first deodorant liquid, described Low level holding vessel described in pressurization pump machine, low level delivery tube Lu Junyu is connected, and the first spray head is set to the low level delivery tube On the road;First deodorant liquid includes the liquid lactic acid and water of solid-state citric acid, 75%~85%;
The high position spraying mechanism includes high-order transfer pipeline, second spray head, the high-order holding vessel equipped with the second deodorant liquid, described Pressurization pump machine, high-order transfer pipeline are connected with the high-order holding vessel, and the second spray head is set to the high-order delivery pipe On the road;Second deodorant liquid includes bacillus pumilus, exerts than halogen anaerobic bacillus, thiobacillus denitrificans, enterococcus faecalis With short distance nitration bacterium.
2. being used for the equipment of livestock manure fermented foul smell emission reduction as described in claim 1, it is characterised in that first deodorization Solid-state citric acid in liquid, 75%~85% liquid lactic acid and the weight fraction ratio of water be 1~30 part, 1~30 part, 340~ 400 parts.
3. being used for the equipment of livestock manure fermented foul smell emission reduction as described in claim 1, which is characterized in that second deodorization Bacillus pumilus in liquid, the weight for exerting than halogen anaerobic bacillus, thiobacillus denitrificans, enterococcus faecalis, short distance nitration bacterium Measuring portion rate is 0.5~2 part, 0.5~2 part, 0.5~2 part, 0.5~2 part, 0.5~2 part.
4. being used for the equipment of livestock manure fermented foul smell emission reduction as described in claim 1, which is characterized in that the low level storage Vortex evenly mixing device is equipped in tank and high-order holding vessel.
5. being used for the equipment of livestock manure fermented foul smell emission reduction as described in claim 1, which is characterized in that the low level storage The inner surface of tank and high-order holding vessel is coated with adherent layer.
6. being used for the equipment of livestock manure fermented foul smell emission reduction as described in claim 1, which is characterized in that machine dress is turned in the throwing It sets including turner, rack and for turning over the turner dipping control that machine moves up and down in the rack so that throwing, it is described Turner, turner dipping control are installed in the rack, the turner dipping control and the rack Rotation connection.
7. being used for the equipment of livestock manure fermented foul smell emission reduction as claimed in claim 6, which is characterized in that the high-order conveying It is equipped with high-order transfer gantry below pipeline, low level transfer gantry, the low level conveying branch are equipped with below the low level delivery tube road Frame and high-order transfer gantry are respectively positioned in the rack.
8. being used for the equipment of livestock manure fermented foul smell emission reduction as claimed in claim 7, which is characterized in that the low level conveying Height distance between bracket and livestock excrement composting surface to be processed is 30~60cm, the low level transfer gantry with it is described The distance of turner device is 20~50cm.
9. being used for the equipment of livestock manure fermented foul smell emission reduction as claimed in claim 7, which is characterized in that the high-order conveying Height distance between bracket and livestock excrement composting surface to be processed is 100~150cm, the high position transfer gantry and institute The distance for stating turner device is 70~120cm.
10. a kind of method for carrying out deodorization to livestock excrement composting using any equipment of claim 1-9, feature exist In described method includes following steps:
Step 1, equipment installation, above-mentioned deodorizing device are mounted at livestock excrement composting to be processed;
Prepare before step 2, deodorization:
S1, the first deodorant liquid of preparation: by solid-state citric acid, 75%~85% liquid lactic acid and water mix after obtained first deodorization Liquid;
S2, the second deodorant liquid of preparation: by bacillus pumilus, than halogen anaerobic bacillus, thiobacillus denitrificans, enterococcus faecalis are exerted The second deodorant liquid is made after mixing with short distance nitration bacterium;
Step 3, heap body turn over throwing preceding 5~15 minutes and meanwhile open pressurization pump machine, throwing turn over machine device, turn over cast aside the beginning when, beginning It sprays deodorant liquid and carries out Odor control, after being disposed, simultaneously close off throwing and turn over machine device, be pressurized pump machine, stop sprinkling deodorant liquid.
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