CN109867445A - A kind of high strength safe glass and its preparation process - Google Patents
A kind of high strength safe glass and its preparation process Download PDFInfo
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- CN109867445A CN109867445A CN201910279810.8A CN201910279810A CN109867445A CN 109867445 A CN109867445 A CN 109867445A CN 201910279810 A CN201910279810 A CN 201910279810A CN 109867445 A CN109867445 A CN 109867445A
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Abstract
The invention discloses a kind of high strength safe glass and its preparation processes, it is related to safety glass technical field, the raw material of high strength safe glass is according to parts by weight of component are as follows: 35~45 parts of quartz sand, 9~14 parts of borax, 12~20 parts of soda ash, 19~30 parts of broken cullet, 8~15 parts of dolomite, 10~21 parts of fluorite, 1~3 part of antimony oxide, 10~15 parts of lead oxide, 12~18 parts of nickel oxide, 1~5 part of cobalt sulfide, 2~10 parts of tackifier, 1~5 part of plasticizer, 5~12 parts of photosensitizer.The safety glass that the present invention designs can enhance transmission of ultraviolet rays, improve its transparency and heat resistance, and utilize high intensity, the wearability of inorganic raw material, the compression strength of safety glass can be effectively improved, and is covered with tough film layer on safety glass surface, prevents safety glass surface from being scraped damage, improve its wearability and service life, and preparation process is at low cost, and high-quality, the safety glass intensity of production is high, performance is good.
Description
Technical field
The present invention relates to safety glass technical field, specifically a kind of high strength safe glass and its preparation process.
Background technique
Safety glass is that one kind is not crushed through high vibration or shock, is not easy the glass hurted sb.'s feelings broken.For vapour
Vehicle, aircraft and door and window of special constructure etc..Building uses safety glass, can resist bullet or per hour 100 kms
The attack of folded chopped cooked entrails of sheep stone in hurricane, this has especially important meaning to the modern architecture of host glass structure.Common peace
Full glass types have pad pasting glass, tempered glass etc..
Now with society development, great attention of the use of safety glass by various circles of society, though for glass material
The research of material has been achieved for certain progress, but still has some problems demands to solve, some high-strength with the progress of science
Degree, high temperature workplace need glass to observe practical situation in real time, it is good not only to have required glass high-temperature stability, but also require glass
The characteristic that the intensity of glass is good, anti-pressure ability is strong, light transmittance is good, and existing glass material does not have these characteristics, or i.e.
Make there are these characteristics, requirement is also not achieved, it is difficult to meet the market demand, therefore, those skilled in the art provide one kind
High strength safe glass and its preparation process, to solve the problems mentioned in the above background technology.
Summary of the invention
The purpose of the present invention is to provide a kind of high strength safe glass and its preparation processes, to solve above-mentioned background technique
The problem of middle proposition.
To achieve the above object, the invention provides the following technical scheme: a kind of high strength safe glass, the high-intensitive peace
All-glass raw material is according to parts by weight of component are as follows: 35~45 parts of quartz sand, 9~14 parts of borax, 12~20 parts of soda ash, broken cullet
19~30 parts, 8~15 parts of dolomite, 10~21 parts of fluorite, 1~3 part of antimony oxide, 10~15 parts of lead oxide, nickel oxide 12
~18 parts, 1~5 part of cobalt sulfide, 2~10 parts of tackifier, 1~5 part of plasticizer, 5~12 parts of photosensitizer.
As a further solution of the present invention: the tackifier use one of methyl or acrylic acid.
As further scheme of the invention: the plasticizer uses dioctyl phthalate or phthalic acid two
One or both of butyl ester.
As further scheme of the invention: the photosensitizer selects benzoin ethyl ether or benzoin isobutyl ether.
As the present invention further scheme: a kind of above-mentioned high strength safe glass and its preparation process, preparation
Technique is following steps:
S1, raw material grinding: the quartz sand of certain component, broken cullet, dolomite and fluorite are put into ball mill, with
Speed 10~20min of ball milling of 250~300r/min, obtains powder, spare；
S2, raw material mixing: powder obtained in S1 is put into blender, sequentially adds borax, soda ash, three oxidations two
Antimony, lead oxide, nickel oxide, cobalt sulfide carry out uniform stirring, and with the revolving speed of 100~120r/min stir 20min, during which again to
Tackifier, plasticizer, photosensitizer are sequentially added in blender, until raw material after evenly mixing, obtains mixture；
S3, heating are melted: raw material mixed in S2 being heated, then in 1000~1200 DEG C of at a temperature of constant temperature
3h, then be warming up to 1200~1400 DEG C with the heating speed of 20 DEG C/min and keep the temperature 2~4h, it forms liquid glass and melts liquid；
S4, injection molding: the S3 liquid glass prepared is melted in the mold after liquid is injected into the pre-heat treatment and is molded into
Type, mold heat pre-treatment temperature is at 400~500 DEG C, then by glass after molding under 400~600 DEG C of constant temperature
It keeps the temperature 2h and obtains molding safety glass after cooling；
S5, surface treatment: the resulting safety glass of S4 is put into the processing pond equipped with high-intensitive treatment fluid and is electroplated
Processing makes safety glass surface be covered with tough film layer of a layer thickness control at 2~8 μm；
S6, drying and processing: the safety glass after being electroplated in S5 is put into dryer and is toasted, after cooling, can be obtained
High strength safe glass.
As further scheme of the invention: high-intensitive treatment fluid is by sodium acrylate, potassium fluoride, fourth two in the S6
Alcohol, polyethylene glycol and polyurethane resin composition.
As the present invention further scheme: in the S6 baking temperature control be in 100~140 DEG C, time
20min。
Compared with prior art, the beneficial effects of the present invention are: the present invention devise a kind of high strength safe glass and its
Broken cullet is recycled by preparation process in actual use, and in the feed by be added dolomite, fluorite,
Nickel oxide cooperates quartz sand, soda ash and broken cullet, the mechanical strength of safety glass can be enhanced, and pass through lead oxide and boron
X-ray and r ray can be absorbed in sand, enhances transmission of ultraviolet rays, improves the transparency and heat resistance of safety glass, utilizes
Antimony oxide and cobalt sulfide make the light transmittance height of safety glass, the hot spot uniformity high, utilize the high-strength of these inorganic raw materials
Degree, wearability, can effectively improve the compression strength of safety glass, and in one layer of tough film layer of safety glass electroplating surface, i.e.,
Can prevent safety glass surface from being scraped damage influences using quality, and its wearability and service life can be improved, and the present invention
Preparation process it is at low cost, high-quality, the safety glass intensity of production is high, performance is good.
Detailed description of the invention
Fig. 1 is a kind of high strength safe glass and its structural schematic diagram of preparation process；
Fig. 2 is the experiment knot of Examples 1 to 3 and comparative example 1 in a kind of high strength safe glass and its preparation process
Fruit schematic diagram.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Please refer to Fig. 1~2, in the embodiment of the present invention,
Embodiment 1
A kind of high strength safe glass, the raw material of high strength safe glass is according to parts by weight of component are as follows: 35 parts of quartz sand, boron
9 parts of sand, 12 parts of soda ash, 19 parts of broken cullet, 8 parts of dolomite, 10 parts of fluorite, 1 part of antimony oxide, 10 parts of lead oxide, oxidation
12 parts of nickel, 1 part of cobalt sulfide, 2 parts of tackifier, 1 part of plasticizer, 5 parts of photosensitizer.
Further, tackifier use one of methyl or acrylic acid.
Further, plasticizer uses one of dioctyl phthalate or dibutyl phthalate or two
Kind.
Further, photosensitizer selects benzoin ethyl ether or benzoin isobutyl ether.
Further, a kind of high strength safe glass and its preparation process, preparation process are following steps:
S1, raw material grinding: the quartz sand of certain component, broken cullet, dolomite and fluorite are put into ball mill, with
Speed 10~20min of ball milling of 250~300r/min, obtains powder, spare；
S2, raw material mixing: powder obtained in S1 is put into blender, sequentially adds borax, soda ash, three oxidations two
Antimony, lead oxide, nickel oxide, cobalt sulfide carry out uniform stirring, and with the revolving speed of 100~120r/min stir 20min, during which again to
Tackifier, plasticizer, photosensitizer are sequentially added in blender, until raw material after evenly mixing, obtains mixture；
S3, heating are melted: raw material mixed in S2 being heated, then in 1000~1200 DEG C of at a temperature of constant temperature
3h, then be warming up to 1200~1400 DEG C with the heating speed of 20 DEG C/min and keep the temperature 2~4h, it forms liquid glass and melts liquid；
S4, injection molding: the S3 liquid glass prepared is melted in the mold after liquid is injected into the pre-heat treatment and is molded into
Type, mold heat pre-treatment temperature is at 400~500 DEG C, then by glass after molding under 400~600 DEG C of constant temperature
It keeps the temperature 2h and obtains molding safety glass after cooling；
S5, surface treatment: the resulting safety glass of S4 is put into the processing pond equipped with high-intensitive treatment fluid and is electroplated
Processing makes safety glass surface be covered with tough film layer of a layer thickness control at 2~8 μm；
S6, drying and processing: the safety glass after being electroplated in S5 is put into dryer and is toasted, after cooling, can be obtained
High strength safe glass.
Wherein, in S6 high-intensitive treatment fluid by sodium acrylate, potassium fluoride, butanediol, polyethylene glycol and polyurethane resin group
At.
Further, baking temperature control is at 100~140 DEG C in S6, time 20min.
Embodiment 2
A kind of high strength safe glass, the raw material of high strength safe glass is according to parts by weight of component are as follows: 45 parts of quartz sand, boron
14 parts of sand, 20 parts of soda ash, 30 parts of broken cullet, 15 parts of dolomite, 21 parts of fluorite, 3 parts of antimony oxide, 15 parts of lead oxide, oxygen
Change 18 parts of nickel, 5 parts of cobalt sulfide, 10 parts of tackifier, 5 parts of plasticizer, 12 parts of photosensitizer.
Further, tackifier use one of methyl or acrylic acid.
Further, plasticizer uses one of dioctyl phthalate or dibutyl phthalate or two
Kind.
Further, photosensitizer selects benzoin ethyl ether or benzoin isobutyl ether.
Further, a kind of high strength safe glass and its preparation process, preparation process are following steps:
S1, raw material grinding: the quartz sand of certain component, broken cullet, dolomite and fluorite are put into ball mill, with
Speed 10~20min of ball milling of 250~300r/min, obtains powder, spare；
S2, raw material mixing: powder obtained in S1 is put into blender, sequentially adds borax, soda ash, three oxidations two
Antimony, lead oxide, nickel oxide, cobalt sulfide carry out uniform stirring, and with the revolving speed of 100~120r/min stir 20min, during which again to
Tackifier, plasticizer, photosensitizer are sequentially added in blender, until raw material after evenly mixing, obtains mixture；
S3, heating are melted: raw material mixed in S2 being heated, then in 1000~1200 DEG C of at a temperature of constant temperature
3h, then be warming up to 1200~1400 DEG C with the heating speed of 20 DEG C/min and keep the temperature 2~4h, it forms liquid glass and melts liquid；
S4, injection molding: the S3 liquid glass prepared is melted in the mold after liquid is injected into the pre-heat treatment and is molded into
Type, mold heat pre-treatment temperature is at 400~500 DEG C, then by glass after molding under 400~600 DEG C of constant temperature
It keeps the temperature 2h and obtains molding safety glass after cooling；
S5, surface treatment: the resulting safety glass of S4 is put into the processing pond equipped with high-intensitive treatment fluid and is electroplated
Processing makes safety glass surface be covered with tough film layer of a layer thickness control at 2~8 μm；
S6, drying and processing: the safety glass after being electroplated in S5 is put into dryer and is toasted, after cooling, can be obtained
High strength safe glass.
Wherein, in S6 high-intensitive treatment fluid by sodium acrylate, potassium fluoride, butanediol, polyethylene glycol and polyurethane resin group
At.
Further, baking temperature control is at 100~140 DEG C in S6, time 20min.
Embodiment 3
A kind of high strength safe glass, the raw material of high strength safe glass is according to parts by weight of component are as follows: 40 parts of quartz sand, boron
10 parts of sand, 16 parts of soda ash, 25 parts of broken cullet, 12 parts of dolomite, 15 parts of fluorite, 2 parts of antimony oxide, 13 parts of lead oxide, oxygen
Change 16 parts of nickel, 3 parts of cobalt sulfide, 7 parts of tackifier, 3 parts of plasticizer, 9 parts of photosensitizer.
Further, tackifier use one of methyl or acrylic acid.
Further, plasticizer uses one of dioctyl phthalate or dibutyl phthalate or two
Kind.
Further, photosensitizer selects benzoin ethyl ether or benzoin isobutyl ether.
Further, a kind of high strength safe glass and its preparation process, preparation process are following steps:
S1, raw material grinding: the quartz sand of certain component, broken cullet, dolomite and fluorite are put into ball mill, with
Speed 10~20min of ball milling of 250~300r/min, obtains powder, spare；
S2, raw material mixing: powder obtained in S1 is put into blender, sequentially adds borax, soda ash, three oxidations two
Antimony, lead oxide, nickel oxide, cobalt sulfide carry out uniform stirring, and with the revolving speed of 100~120r/min stir 20min, during which again to
Tackifier, plasticizer, photosensitizer are sequentially added in blender, until raw material after evenly mixing, obtains mixture；
S3, heating are melted: raw material mixed in S2 being heated, then in 1000~1200 DEG C of at a temperature of constant temperature
3h, then be warming up to 1200~1400 DEG C with the heating speed of 20 DEG C/min and keep the temperature 2~4h, it forms liquid glass and melts liquid；
S4, injection molding: the S3 liquid glass prepared is melted in the mold after liquid is injected into the pre-heat treatment and is molded into
Type, mold heat pre-treatment temperature is at 400~500 DEG C, then by glass after molding under 400~600 DEG C of constant temperature
It keeps the temperature 2h and obtains molding safety glass after cooling；
S5, surface treatment: the resulting safety glass of S4 is put into the processing pond equipped with high-intensitive treatment fluid and is electroplated
Processing makes safety glass surface be covered with tough film layer of a layer thickness control at 2~8 μm；
S6, drying and processing: the safety glass after being electroplated in S5 is put into dryer and is toasted, after cooling, can be obtained
High strength safe glass.
Wherein, in S6 high-intensitive treatment fluid by sodium acrylate, potassium fluoride, butanediol, polyethylene glycol and polyurethane resin group
At.
Further, baking temperature control is at 100~140 DEG C in S6, time 20min.
Comparative example 1
Select the safety glass of common safety glass preparation process preparation.
Requirement of experiment: respectively from safety glass prepared by embodiment 1, embodiment 2, embodiment 3 and comparative example 1
Taking an area is 500*500mm, the safety glass with a thickness of 1.1mm, compares experiment, detects embodiment 1, embodiment 2
The performances such as compression strength, flexural strength, the light transmittance of safety glass selected with embodiment 3 and comparative example 1, experiment pair
It is more as shown in Figure 2 than result.
In conclusion the present invention using nickel oxide, dolomite and fluorite as raw material, and cooperate quartz sand, soda ash and broken
Cullet, can be enhanced the mechanical strength of safety glass, and lead oxide be added and X-ray and r ray can be absorbed in borax, increase
The transmissivity of intensive ultraviolet improves the transparency and heat resistance of safety glass, so that the light transmittance of safety glass is high, hot spot is equal
Evenness is high, using the high intensity of these inorganic raw materials, wearability, can effectively improve the compression strength of safety glass, while pacifying
One layer of tough film layer is electroplated in full glass surface, can prevent safety glass surface from being scraped damage, and its wearability can be improved and make
With the service life, and preparation process of the invention is at low cost, high-quality, and the safety glass intensity of production is high, performance is good.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (7)
1. a kind of high strength safe glass, which is characterized in that the raw material of the high strength safe glass is according to parts by weight of component are as follows:
35~45 parts of quartz sand, 9~14 parts of borax, 12~20 parts of soda ash, 19~30 parts of broken cullet, 8~15 parts of dolomite, fluorite 10
~21 parts, 1~3 part of antimony oxide, 10~15 parts of lead oxide, 12~18 parts of nickel oxide, 1~5 part of cobalt sulfide, tackifier 2~
10 parts, 1~5 part of plasticizer, 5~12 parts of photosensitizer.
2. a kind of high strength safe glass according to claim 1, which is characterized in that the tackifier use methyl or third
One of olefin(e) acid.
3. a kind of high strength safe glass according to claim 1, which is characterized in that the plasticizer uses O-phthalic
One or both of dioctyl phthalate or dibutyl phthalate.
4. a kind of high strength safe glass according to claim 1, which is characterized in that the photosensitizer selects styrax second
Ether or benzoin isobutyl ether.
5. a kind of high strength safe glass and its preparation process, feature described according to claim 1~any one of 4 exist
In preparation process is following steps:
S1, raw material grinding: the quartz sand of certain component, broken cullet, dolomite and fluorite are put into ball mill, with 250~
Speed 10~20min of ball milling of 300r/min, obtains powder, spare；
S2, raw material mixing: powder obtained in S1 is put into blender, borax, soda ash, antimony oxide, oxygen are sequentially added
Change lead, nickel oxide, cobalt sulfide and carry out uniform stirring, and 20min is stirred with the revolving speed of 100~120r/min, during which again to stirring
Tackifier, plasticizer, photosensitizer are sequentially added in machine, until raw material after evenly mixing, obtains mixture；
S3, heating are melted: raw material mixed in S2 heated, then in 1000~1200 DEG C of at a temperature of constant temperature 3h,
1200~1400 DEG C are warming up to the heating speed of 20 DEG C/min again and keeps the temperature 2~4h, are formed liquid glass and are melted liquid；
S4, injection molding: the S3 liquid glass prepared is melted in the mold after liquid is injected into the pre-heat treatment and carries out injection molding, mould
Have heat pre-treatment temperature at 400~500 DEG C, then keeps the temperature glass after molding under 400~600 DEG C of constant temperature
2h obtains molding safety glass after cooling；
S5, surface treatment: the resulting safety glass of S4 being put into the processing pond equipped with high-intensitive treatment fluid and carries out electroplating processes,
Safety glass surface is set to be covered with tough film layer of a layer thickness control at 2~8 μm；
S6, drying and processing: the safety glass after being electroplated in S5 is put into dryer and is toasted, after cooling, can be obtained high-strength
Spend safety glass.
6. a kind of high strength safe glass according to claim 5 and its preparation process, which is characterized in that high in the S6
Intensity treatment fluid is made of sodium acrylate, potassium fluoride, butanediol, polyethylene glycol and polyurethane resin.
7. a kind of high strength safe glass according to claim 5 and its preparation process, which is characterized in that dried in the S6
Roasting temperature control is at 100~140 DEG C, time 20min.
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| CN201910279810.8A CN109867445A (en) | 2019-04-09 | 2019-04-09 | A kind of high strength safe glass and its preparation process |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110845140A (en) * | 2019-10-22 | 2020-02-28 | 惠州市佳美兴玻璃制品有限公司 | Scratch-resistant high-strength screen glass cover plate and preparation method thereof |
| CN114482807A (en) * | 2022-01-26 | 2022-05-13 | 台玻长江玻璃有限公司 | Preparation process of high-temperature-resistant low-radiation coated glass |
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| US6521557B1 (en) * | 1999-10-08 | 2003-02-18 | Kabushiki Kaisha Ohara | Transparent glass and a method for manufacturing the same |
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| US20080087044A1 (en) * | 2004-08-26 | 2008-04-17 | Carty William M | Selective batching for boron-containing glasses |
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| CN87103395A (en) * | 1987-05-08 | 1988-11-16 | 河北化工学院 | High-strength safety sandwich-glass and production method thereof |
| US6521557B1 (en) * | 1999-10-08 | 2003-02-18 | Kabushiki Kaisha Ohara | Transparent glass and a method for manufacturing the same |
| CN1250755A (en) * | 1999-10-21 | 2000-04-19 | 哈尔滨医药股份有限公司制药三厂 | Tubular blue glass bottle for medicinal oral liquid and its making method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110845140A (en) * | 2019-10-22 | 2020-02-28 | 惠州市佳美兴玻璃制品有限公司 | Scratch-resistant high-strength screen glass cover plate and preparation method thereof |
| CN114482807A (en) * | 2022-01-26 | 2022-05-13 | 台玻长江玻璃有限公司 | Preparation process of high-temperature-resistant low-radiation coated glass |
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