CN109852216A - A kind of water-based metal metallic finishe - Google Patents
A kind of water-based metal metallic finishe Download PDFInfo
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- CN109852216A CN109852216A CN201811524129.7A CN201811524129A CN109852216A CN 109852216 A CN109852216 A CN 109852216A CN 201811524129 A CN201811524129 A CN 201811524129A CN 109852216 A CN109852216 A CN 109852216A
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Abstract
The present invention relates to a kind of metal flash paints, are suitable for coating lacquer enterprise, it discloses a kind of water-based metal metallic finishe and mating blending resin;Water-based metal metallic finishe includes following parts by weight raw material: aluminum paste 3~20, film-forming cosolvent 3~20, high molecular weight dispersant 0.1~1, amine neutralizer 0.1~3, metal flash paint arranges agent 0.5~3, makes aqueous polyurethane base-material 50~80, deionized water 5~30 by oneself.Mating blending resin includes following parts by weight raw material: water-based acrylic resin 30~70, amine neutralizer 0.1~3, defoaming agent 0.1~1, wetting agent 0.1~1, self-control powdered-metal metallic finishe arrangement agent aqueous solution 30~60, deionized water 3~20.Product of the present invention storage stability is good, volatile organic content (VOC) can control in 100g/L or less, paint film rate of drying obtained by water-based metal metallic finishe and blending resin complete use is fast, paint film is consistent with water-based metal metallic finishe form and aspect, no color differnece, metal flash paint arrangement effect is good, has excellent performance.
Description
Technical field:
The present invention relates to a kind of automotive varinishing enamel paint, especially a kind of aqueous paint with flash metal luster paint.
Background technique:
The volatilization (VOC) of solvent is the third-largest air after motor vehicle exhaust emission and smog in traditional solvent type coating
Pollution sources, are PM2.5 main sources, and Water-borne modification can substantially reduce the discharge of VOC.As client is to vehicle color aesthetic effect
Pursuit, the metallic finishes dosage such as metal, pearly-lustre increases rapidly.Prepare that storge quality is good, paint film arrangement effect is good, rate of drying is fast
Water-based metal metallic finishe be very beneficial for car repair Water-borne modification popularization.Water-based acrylic resin is as main film forming substance institute
Metal flash paint side band blue light or white light are prepared, dry and wet film color difference is big, should not mix colours, and it is fast to be unable to satisfy mending paint market
The requirement of velocity modulation color, but its advantage is that it is at low cost, rate of drying is fast.Aqueous polyurethane is as flash metal luster prepared by film forming matter
Qi Gan wet coating color difference is small, and different spraying technologies influence small, strong covering power to color effects, and coating efficiency is high.Metal dodges
Lac varnish has color travel, and paint film arrangement is most important to its color and flash effect, but adds different metal metallic finishe row
When column agent or a large amount of solvents are needed, or cause product poor storage stability.
Summary of the invention:
The object of the present invention is to provide a kind of water-based metal metallic finishes, its storage stability is good, normal temperature self-drying, and low temperature dries
Dry (50-60 DEG C, 5min).
Technical solution is a kind of water-based metal metallic finishe, it includes a kind of water-based metal metallic finishe and mating blending
Resin.Water-based metal metallic finishe includes following parts by weight raw material:
Aluminum paste 3~20, film-forming cosolvent 3~20, the high molecular weight dispersant 0.1 of polyacrylate copolymer solution~
1, the metal flash paint of the amine neutralizer 0.1~3 of ammonium hydroxide, triithylamine or dimethylethanolamine, aqueous EVA wax emulsion arranges agent
0.5~3, make aqueous polyurethane base-material 50~80, deionized water 5~30 by oneself.Mating blending resin includes that following parts by weight are former
Material: water-based acrylic resin 30~70, amine neutralizer 0.1~3, type siloxane defoaming agent 0.1~1, organic silicon surfactant
Wetting agent 0.1~1, self-control powdered-metal metallic finishe arrange agent aqueous solution 30~60, deionized water 3~20.
The self-control aqueous polyurethane base-material includes following parts by weight raw material: waterborne polyurethane resin 50~70, silicon
Oxygen alkanes defoaming agent 0.1~1, organic silicon surfactant wetting agent 0.1~1, the anti-settling agent 1~10 of polyamide sodium salt lotion,
Deionized water 20~50.The preparation method comprises the following steps: waterborne polyurethane resin is added to the container, neutralizer is added under dispersity and adjusts
PH value disperses 5~10min to 7~7.5;Sequentially add defoaming agent, wetting agent, anti-settling agent, deionized water etc., stirring 20~
30min, with 300 mesh filter-cloth filterings to obtain the final product.
The self-control powdered-metal metallic finishe arranges agent aqueous solution, includes following parts by weight raw material: deionized water 70
~95, powdered-metal metallic finishe arranges agent 1~20, is middle low molecular poly, polypropylene glycol or polyoxyethylene
The polyalcohol 2~20 of alkene --- propylene oxide glycol, emulsifier 0.1~2.The preparation method comprises the following steps: powdery metal metallic finishe is arranged
It being added in deionized water under column agent dispersity, 15~20min of dispersion to abundant dissolution is added polyalcohol, disperses 3~5min,
Substitution alkyl phenol environment-friendly type emulsifier is added, disperses 10~20min.
The water-based metal metallic finishe, preparation comprise the steps of: with part cosolvent impregnate metal flash paint 1~
2h is added under dispersity in self-control aqueous polyurethane base-material, is cleaned with remaining cosolvent, disperses 5~10min.Successively
Defoaming agent, wetting agent, deionized water is added, part neutralizer is added and adjusts pH to 7.5 or so, disperses 5~10min.It is added certainly
Metal flash paint processed arranges agent aqueous solution, disperses 3~5min, and remaining neutralizer is added and adjusts pH to 8.5~9.
The mating blending resin, preparation, which comprises the steps of:, is added to the container water-based acrylic resin, dispersed
Neutralizer is added under state and adjusts pH to 7~7.5, disperses 5~10min;Defoaming agent, wetting agent, deionized water are sequentially added, is dispersed
2~3min;The powdered-metal metallic finishe arrangement agent aqueous solution prepared is added, disperses 5~8min, is with 300 mesh filter-cloth filterings
?.
Above-mentioned film-forming cosolvent includes the tertiary butyl ether of ethylene glycol, polyol ester, isopropanol, the tertiary monobutyl ether acetate one of ethylene glycol
Kind is a variety of;High molecular weight dispersant is polyacrylate copolymer solution;Wetting agent is organic silicon surfactant;Defoaming agent
Using type siloxane defoaming agent;Neutralizer includes that ammonium hydroxide, triethylamine or dimethylethanolamine are one or more;Flash metal luster arrangement
Agent is aqueous EVA wax emulsion;It is Bi Ke phyllosilicate (BYK Laponite RD) that powdered-metal metallic finishe, which arranges agent, polynary
Alcohol is that middle low molecular poly, polypropylene glycol, polyethylene glycol oxide-propylene oxide glycol are one or more;Emulsifier be for
Substituted alkyl phenol environment-friendly type emulsifier, anti-settling agent are aqueous polyamide sodium salt lotion.
In the present invention, water-based metal metallic finishe need to be matched with blending resin.Agent and blending are arranged in metal flash paint
It makes powdered-metal metallic finishe in resin by oneself and arranges agent collective effect, to obtain excellent metallic coating film arrangement effect, but two
When kind metal flash paint arrangement agent is added in metal flash paint simultaneously, thick, poor storage stability is returned in one month.Aqueous poly- ammonia
Ester is small as metal flash paint dry and wet film color difference prepared by film forming matter, and different spraying technologies influence color effects
It is small, strong covering power, coating efficiency height.When water-based acrylic resin is used to prepare metal flash paint as main film forming substance, institute
Metal flash paint side band blue light or white light are prepared, dry and wet film color difference is big, should not mix colours, and it is fast to be unable to satisfy mending paint market
The requirement of velocity modulation color, but its advantage is that it is at low cost, rate of drying is fast.Mating water soluble acrylic acid blending resin is prepared in the present invention,
Added when spraying, sprayed paint film be not added with mating blending resin before metal flash paint form and aspect it is consistent, no color differnece not only improves
Dry and wet paint film color difference is big when improving metallic coating film rate of drying, and can avoid mixing colours, and meets quickly toning and requires.This
The addition that aqueous blending resin key is polyalcohol and emulsifier is invented, blending resin is made to keep excellent stable storing
Property.Volatile organic content (VOC) of the present invention can control in 100g/L hereinafter, storage stability is good, and metal flash paint arranges
Effect is good, and paint film property is excellent.
Specific embodiment:
Embodiment 1
1 prepares water-based metal metallic finishe
(1) aqueous polyurethane base-material is prepared, includes following parts by weight raw material: waterborne polyurethane resin 60, type siloxane
Defoaming agent 0.1, organic silicon surfactant wetting agent 0.15, aqueous polyamide sodium salt lotion anti-settling agent 3, deionized water 36.75.
The preparation method comprises the following steps: waterborne polyurethane resin is added to the container, dimethyl ethanol amine neutralizer is added under dispersity and adjusts pH
Value disperses 5~10min to 7~7.5;Sequentially add type siloxane defoaming agent, organic silicon surfactant wetting agent, aqueous poly-
Chlorseptol lotion anti-settling agent, deionized water etc. stir 20~30min, with 300 mesh filter-cloth filterings to obtain the final product.
(2) water-based metal metallic finishe is prepared, includes following parts by weight raw material: aluminum paste 3, polyol ester film-forming cosolvent
3, polyacrylate copolymer solution high molecular weight dispersant 0.1, the amine neutralizer 0.1 of dimethylethanolamine, aqueous EVA wax cream
The metal flash paint of liquid arranges agent 2, makes aqueous polyurethane base-material 60, deionized water 31.8 by oneself.Preparation step is as follows: being helped with part
Solvent soaking 1~2h of aluminum paste is added under dispersity in self-control aqueous polyurethane base-material, is cleaned with remaining cosolvent,
Disperse 5~10min.Defoaming agent, wetting agent, deionized water are sequentially added, part neutralizer is added and adjusts pH to 7.5 or so, point
Dissipate 5~10min.Metal flash paint is added and arranges agent, disperses 3~5min, remaining neutralizer is added and adjusts pH to 8.5~9.
2 prepare mating blending resin
(1) powdered-metal metallic finishe arrangement agent aqueous solution is prepared, includes following parts by weight raw material: deionized water 94, layer
The powdered-metal metallic finishe of shape silicate arranges agent 2, in, the polyalcohol 3 of low molecular poly, substitute alkyl phenol environment-friendly type
Emulsifier 1.It is added in deionized water under agent dispersity the preparation method comprises the following steps: powdery metal metallic finishe is arranged, dispersion 15~
20min is to abundant dissolution, in addition, the polyalcohol of low molecular poly, disperses 3~5min, substitution alkyl phenol ring is added
Guarantor's type emulsifier disperses 10~20min.
(2) mating blending resin is prepared, includes following parts by weight raw material: water-based acrylic resin 50, dimethyl ethanol
Amine neutralizer 0.1, type siloxane defoaming agent 0.1, the wetting agent 0.15 of organic surfactant make powdered-metal metallic finishe by oneself
Arrange agent aqueous solution 40, deionized water 9.65.Preparation step is as follows: water-based acrylic resin being added to the container, dispersity
The lower neutralizer that dimethylethanolamine is added adjusts pH to 7~7.5, disperses 5~10min.Sequentially add type siloxane defoaming agent,
Organic silicon surfactant wetting agent, deionized water disperse 2~3min.Self-control powdered-metal prepared by step (1) is added to dodge
Lac varnish arranges agent aqueous solution, disperses 5~8min, with 300 mesh filter-cloth filterings to obtain the final product.
The water-based metal metallic finishe of preparation and the mating blending resin of preparation, are stirred evenly i.e. sprayable with the proportion of 1:1.
Water-based metal metallic finishe of the present invention and its mating blending resin paint film property are as follows:
Embodiment 2
1 prepares water-based metal metallic finishe
(1) aqueous polyurethane base-material is prepared, includes following parts by weight raw material: waterborne polyurethane resin 60, type siloxane
Defoaming agent 0.1, organic silicon surfactant wetting agent 0.15, aqueous polyamide sodium salt anti-settling agent 3, deionized water 36.75.Preparation
Method are as follows: waterborne polyurethane resin is added to the container, triethylamine neutralizer is added under dispersity and adjusts pH value to 7~7.5,
Disperse 5~10min;Sequentially add type siloxane defoaming agent, organic silicon surfactant wetting agent, aqueous polyamide sodium salt lotion
Anti-settling agent, deionized water etc., stir 20~30min, with 300 mesh filter-cloth filterings to obtain the final product.
(2) water-based metal metallic finishe is prepared, includes following parts by weight raw material: aluminum paste 8, the tertiary butyl ether 5 of ethylene glycol, isopropyl
The film-forming cosolvent of alcohol 3, the high molecular weight dispersant 0.5 of polyacrylate copolymer, the amine neutralizer 1.5 of triethylamine are aqueous
The metal flash paint of EVA wax emulsion arranges agent 0.5, the self-control aqueous polyurethane base-material 65 of step (1), deionized water 16.5.System
Standby steps are as follows: impregnating 1~2h of aluminum paste with part cosolvent, the self-control aqueous polyurethane of step (1) is added under dispersity
It in base-material, is cleaned with remaining cosolvent, disperses 5~10min.Defoaming agent, wetting agent, deionized water are sequentially added, is added
Part neutralizer adjusts pH to 7.5 or so, disperses 5~10min.Metal flash paint is added and arranges agent, disperses 3~5min, is added
Remaining neutralizer adjusts pH to 8.5~9.
2 prepare mating blending resin
(1) powdered-metal metallic finishe arrangement agent aqueous solution is prepared, includes following parts by weight raw material: deionized water 94, layer
The powdered-metal metallic finishe of shape silicate arranges agent 2, and the polyalcohol 3 of polypropylene glycol substitutes alkyl phenol environment-friendly type emulsifier 1.System
Preparation Method are as follows: powdery metal metallic finishe is arranged and is added in deionized water under agent dispersity, 15~20min is to abundant for dispersion
The polyalcohol of polypropylene glycol is added in dissolution, disperses 3~5min, is added and substitutes alkyl phenol environment-friendly type emulsifier, and dispersion 10~
20min。
(2) mating blending resin is prepared, includes following parts by weight raw material: water-based acrylic resin 25, the amine of triethylamine
The self-control powdered-metal of neutralizer 1.5, type siloxane defoaming agent 0.5, the wetting agent 1 of organic silicon surfactant, step (1) dodges
Lac varnish arranges agent aqueous solution 60, deionized water 12.Preparation step is as follows: water-based acrylic resin being added to the container, dispersed
The neutralizer that triethylamine is added under state adjusts pH to 7~7.5, disperses 5~10min.Sequentially add type siloxane defoaming agent, organic
The wetting agent of silicon surface active agent, deionized water disperse 2~3min.The row of powdered-metal metallic finishe prepared by step (1) is added
Column agent aqueous solution disperses 5~8min, with 300 mesh filter-cloth filterings to obtain the final product.
The mating blending resin of the water-based metal metallic finishe and preparation prepared, being stirred evenly with the proportion of 1:1 can spray
It applies.
Water-based metal metallic finishe of the present invention and its mating blending resin paint film property are as follows:
Embodiment 3
1 prepares water-based metal metallic finishe
(1) aqueous polyurethane base-material is prepared, includes following parts by weight raw material: waterborne polyurethane resin 60, type siloxane
Defoaming agent 0.1, the wetting agent 0.15 of organic silicon surfactant, aqueous polyamide sodium salt lotion anti-settling agent 3, deionized water
36.75.The preparation method comprises the following steps: waterborne polyurethane resin is added to the container, the neutralizer that ammonium hydroxide is added under dispersity adjusts pH
Value disperses 5~10min to 7~7.5;Sequentially add type siloxane defoaming agent, organic silicon surfactant wetting agent, aqueous poly-
Anti-settling agent, deionized water of chlorseptol lotion etc. stir 20~30min, with 300 mesh filter-cloth filterings to obtain the final product.
(2) water-based metal metallic finishe is prepared, includes following parts by weight raw material: aluminum paste 3, the film forming of the tertiary butyl ether of ethylene glycol
Cosolvent 20, the high molecular weight dispersant 1 of polyacrylate copolymer solution, the amine neutralizer 1 of ammonium hydroxide, aqueous EVA wax emulsion
Metal flash paint arrange agent 3, the self-control aqueous polyurethane base-material 50 of step (1), deionized water 22.Preparation step is as follows: using
Part cosolvent impregnates 1~2h of aluminum paste, is added in the self-control aqueous polyurethane base-material of step (1) under dispersity, with residue
Cosolvent is cleaned, and 5~10min is dispersed.It sequentially adds type siloxane defoaming agent, organic silicon surfactant wetting agent, go
Ionized water, the neutralizer that partial ammonia water is added adjust pH to 7.5 or so, disperse 5~10min.The metal of phyllosilicate is added
Metallic finishe arranges agent, disperses 3~5min, and the neutralizer that remained ammonia is added adjusts pH to 8.5~9.
2 prepare mating blending resin
(1) powdered-metal metallic finishe arrangement agent aqueous solution is prepared, includes following parts by weight raw material: deionized water 94, powder
Last metal flash paint arranges agent 2, the polyalcohol 3 of polyethylene glycol oxide --- propylene oxide glycol, emulsifier 1.The preparation method comprises the following steps: will
Powdery metal metallic finishe is arranged and is added in deionized water under agent dispersity, and 15~20min of dispersion to abundant dissolution is added poly-
Ethylene oxide --- the polyalcohol of propylene oxide glycol disperses 3~5min, and substitution alkyl phenol environment-friendly type emulsifier, dispersion is added
10~20min.
(2) mating blending resin is prepared, includes following parts by weight raw material: water-based acrylic resin 60, in the amine of ammonium hydroxide
With agent 3, type siloxane defoaming agent 1, the wetting agent 0.5 of organic silicon surfactant, self-control powdered-metal metallic finishe arrangement agent water
The self-control powdered-metal metallic finishe of solution 30, deionized water 5.5, step (1) arranges agent aqueous solution 30, deionized water 5.50.System
It is standby that steps are as follows: water-based acrylic resin is added to the container, be added under dispersity ammonium hydroxide neutralizer adjust pH to 7~
7.5, disperse 5~10min.Type siloxane defoaming agent, the wetting agent of organic silicon surfactant, deionized water are sequentially added, point
Dissipate 2~3min.The self-control powdered-metal metallic finishe that step (1) is added arranges agent aqueous solution 30, deionized water 5.50.Powdered-metal
Metallic finishe arranges agent, disperses 5~8min, with 300 mesh filter-cloth filterings to obtain the final product.
The mating blending resin of the water-based metal metallic finishe and preparation prepared, being stirred evenly with the proportion of 1:1 can spray
It applies.
Water-based metal metallic finishe of the present invention and its mating blending resin paint film property are as follows:
Claims (8)
1. a kind of water-based metal metallic finishe, which is characterized in that it includes a kind of water-based metal metallic finishe and mating blending resin;
Water-based metal metallic finishe includes following parts by weight raw material: aluminum paste 3~20, film-forming cosolvent 3~20, high molecular weight dispersant
0.1~1, amine neutralizer 0.1~3, metal flash paint arranges agent 0.5~3, makes aqueous polyurethane base-material 50~80, deionization by oneself
Water 5~30.Mating blending resin include following parts by weight raw material: water-based acrylic resin 30~70, amine neutralizer 0.1~3,
Defoaming agent 0.1~1, wetting agent 0.1~1, self-control powdered-metal metallic finishe arrange agent aqueous solution 30~60, deionized water 3~20.
2. a kind of water-based metal metallic finishe according to claim 1, which is characterized in that making aqueous polyurethane base-material by oneself includes
Following parts by weight raw material: waterborne polyurethane resin 50~70, type siloxane defoaming agent 0.1~1, organic silicon surfactant profit
Humectant 0.1~1, anti-settling agent 1~10, deionized water 20~50.
3. a kind of water-based metal metallic finishe according to claim 1, which is characterized in that the metal of aqueous EVA wax emulsion dodges
Lac varnish arranges agent, includes following parts by weight raw material: deionized water 70~95, and Bi Ke powdered-metal metallic finishe arranges agent 1~20,
Polyalcohol 2~20 substitutes alkyl environment-friendly type emulsifier 0.1~2.
4. a kind of water-based metal metallic finishe according to claim 1, it is characterized in that high molecular weight dispersant is polyacrylate
Copolymer solution.
5. a kind of water-based metal metallic finishe according to claim 1, it is characterized in that amine neutralizer is ammonium hydroxide, triethylamine or diformazan
Ethylethanolamine.
6. according to claim 2, a kind of water-based metal metallic finishe, it is characterized in that anti-settling agent is aqueous polyamide sodium salt cream
Liquid.
7. water-based metal metallic finishe according to claim 1, it is characterized in that film-forming cosolvent is, for improving its low temperature freeze thawing
The tertiary butyl ether of the ethylene glycol of stability, polyol ester, isopropanol, the tertiary monobutyl ether acetate of ethylene glycol.
8. a kind of according to claim 3, water-based metal metallic finishe, it is characterized in that in mating blending resin polyalcohol be in it is low
Molecular weight polyethylene glycol, polypropylene glycol or polyethylene glycol oxide --- propylene oxide glycol.
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CN201811524129.7A CN109852216B (en) | 2018-12-13 | 2018-12-13 | Water-based metal flashing paint |
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CN201811524129.7A CN109852216B (en) | 2018-12-13 | 2018-12-13 | Water-based metal flashing paint |
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CN109852216B CN109852216B (en) | 2021-04-30 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112852271A (en) * | 2019-11-28 | 2021-05-28 | 雅图高新材料有限公司 | Superfine atomized all-weather low-viscosity multipurpose water-based blended water and preparation method thereof |
CN116904098A (en) * | 2023-08-15 | 2023-10-20 | 株洲市九华新材料涂装实业有限公司 | Water-based metallic flashing base paint and preparation method and application thereof |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09504335A (en) * | 1994-04-30 | 1997-04-28 | ヘルバーツ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Modular system and method of making an aqueous coating composition |
JP2007217548A (en) * | 2006-02-16 | 2007-08-30 | Nisshin Steel Co Ltd | Metallic coating and precoat metal sheet superior in weatherability and color stability |
CN102363701A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Waterborne double-component metallic flashy finish paint and preparation method thereof |
CN102604497A (en) * | 2012-02-15 | 2012-07-25 | 上海天地涂料有限公司 | Water-based metallic flashing paint and preparation method of the flashing paint |
CN102876167A (en) * | 2012-10-08 | 2013-01-16 | 浙江圣力邦漆业有限公司 | Aqueous silvery aluminum powder flashing paint |
EP2808365A1 (en) * | 2013-05-31 | 2014-12-03 | FL-Services GmbH | Layer structure and mixture for use in a method for producing the layer structure |
CN105399883A (en) * | 2015-12-31 | 2016-03-16 | 东莞市隆海新材料科技有限公司 | Directional arraying agent for waterborne effect pigment, and preparation method and application thereof |
CN105670427A (en) * | 2014-11-21 | 2016-06-15 | 沈阳顺风新城建筑材料有限公司 | Metal flashing paint |
CN107151293A (en) * | 2017-04-24 | 2017-09-12 | 东莞市隆海新材料科技有限公司 | A kind of aqueous effect pigment of amide modifications aligns agent and preparation method thereof |
-
2018
- 2018-12-13 CN CN201811524129.7A patent/CN109852216B/en active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09504335A (en) * | 1994-04-30 | 1997-04-28 | ヘルバーツ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Modular system and method of making an aqueous coating composition |
JP2007217548A (en) * | 2006-02-16 | 2007-08-30 | Nisshin Steel Co Ltd | Metallic coating and precoat metal sheet superior in weatherability and color stability |
CN102363701A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Waterborne double-component metallic flashy finish paint and preparation method thereof |
CN102604497A (en) * | 2012-02-15 | 2012-07-25 | 上海天地涂料有限公司 | Water-based metallic flashing paint and preparation method of the flashing paint |
CN102876167A (en) * | 2012-10-08 | 2013-01-16 | 浙江圣力邦漆业有限公司 | Aqueous silvery aluminum powder flashing paint |
EP2808365A1 (en) * | 2013-05-31 | 2014-12-03 | FL-Services GmbH | Layer structure and mixture for use in a method for producing the layer structure |
CN105670427A (en) * | 2014-11-21 | 2016-06-15 | 沈阳顺风新城建筑材料有限公司 | Metal flashing paint |
CN105399883A (en) * | 2015-12-31 | 2016-03-16 | 东莞市隆海新材料科技有限公司 | Directional arraying agent for waterborne effect pigment, and preparation method and application thereof |
CN107151293A (en) * | 2017-04-24 | 2017-09-12 | 东莞市隆海新材料科技有限公司 | A kind of aqueous effect pigment of amide modifications aligns agent and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112852271A (en) * | 2019-11-28 | 2021-05-28 | 雅图高新材料有限公司 | Superfine atomized all-weather low-viscosity multipurpose water-based blended water and preparation method thereof |
CN116904098A (en) * | 2023-08-15 | 2023-10-20 | 株洲市九华新材料涂装实业有限公司 | Water-based metallic flashing base paint and preparation method and application thereof |
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