CN109826020A - A kind of effective coating cloth of oil transportation and preparation method thereof - Google Patents
A kind of effective coating cloth of oil transportation and preparation method thereof Download PDFInfo
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- CN109826020A CN109826020A CN201810629099.XA CN201810629099A CN109826020A CN 109826020 A CN109826020 A CN 109826020A CN 201810629099 A CN201810629099 A CN 201810629099A CN 109826020 A CN109826020 A CN 109826020A
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- coating
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- base fabric
- cloth
- oil transportation
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- 239000011248 coating agent Substances 0.000 title claims abstract description 141
- 238000000576 coating method Methods 0.000 title claims abstract description 141
- 239000004744 fabric Substances 0.000 title claims abstract description 110
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 56
- 239000006096 absorbing agent Substances 0.000 claims abstract description 28
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 21
- 239000003063 flame retardant Substances 0.000 claims abstract description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004014 plasticizer Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 13
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 13
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 13
- 150000002367 halogens Chemical class 0.000 claims abstract description 13
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 13
- 239000011574 phosphorus Substances 0.000 claims abstract description 13
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 11
- 229920001971 elastomer Polymers 0.000 claims abstract description 9
- 238000010410 dusting Methods 0.000 claims abstract description 8
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 8
- 239000003112 inhibitor Substances 0.000 claims abstract description 8
- 239000000853 adhesive Substances 0.000 claims abstract description 5
- 230000001070 adhesive effect Effects 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims description 40
- 238000009940 knitting Methods 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 22
- 230000001680 brushing effect Effects 0.000 claims description 20
- 238000009472 formulation Methods 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 15
- 239000010410 layer Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 229920003023 plastic Polymers 0.000 claims description 10
- 239000004033 plastic Substances 0.000 claims description 10
- 239000006255 coating slurry Substances 0.000 claims description 8
- 239000004636 vulcanized rubber Substances 0.000 claims description 8
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000011247 coating layer Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims description 4
- 239000008199 coating composition Substances 0.000 claims description 4
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 claims description 4
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000003918 triazines Chemical class 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- -1 diisobutyl ester Chemical class 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims 1
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 21
- 239000004800 polyvinyl chloride Substances 0.000 description 21
- 239000002002 slurry Substances 0.000 description 12
- 239000003208 petroleum Substances 0.000 description 6
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- ACOGMWBDRJJKNB-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.CC(O)=O ACOGMWBDRJJKNB-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of effective coating cloth of oil transportation, including base fabric, the first coating that is applied to base fabric upper and lower surface, the organosilicon-modified acrylate layer for being applied to the second coating of first coating outer surface and being applied to second coating outer surface；First coating raw material are as follows: PVC paste resin, plasticizer, modified ultraviolet absorbing agent, mould inhibitor, nano silver, heat stabilizer, super fine calcium carbonate, nanometer calcium carbonate, adhesive, Halogen phosphorus flame retardant, antimony oxide, dusting rubber powder, titanium dioxide；Second coating raw material are as follows: PVC paste resin, plasticizer, modified ultraviolet absorbing agent, mould inhibitor, nano silver, heat stabilizer, super fine calcium carbonate, nanometer calcium carbonate, Halogen phosphorus flame retardant, antimony oxide, dusting rubber powder, titanium dioxide；Contain DOA in plasticizer.The present invention also provides the preparation methods of above-mentioned coating cloth.Product of the present invention cold resistance is good, intensity is high, long service life, and mould proof, antibacterial, uvioresistant.
Description
Technical field
The present invention relates to coating cloth technical fields more particularly to a kind of effective coating cloth of oil transportation and preparation method thereof.
Background technique
Coating cloth is primarily referred to as being coated with one layer of material with specific function using special process on the basis of cloth, makes
Cloth increases special function, so also referred to as functional coating fabric, coating cloth be widely used in tent, clothes, luggage,
The numerous areas such as national defence, transport.
PVC material, that is, polyvinyl chloride is one of maximum plastic product of yield in the world, cheap, is widely used, and is gathered
Vinyl chloride resin is white or buff powder, cannot individually be used, it is necessary to by being modified.PVC is the white of amorphous structure
Powder, the degree of branching is smaller, poor to the stability of light and heat.Different additives, polychlorostyrene second can be added according to different purposes
Different physical property and mechanical property can be presented in alkene plastics.Suitable plasticizer is added in Corvic and other add
Add agent, can be used for making anti-corrosion pipeline, pipe fitting, petroleum pipeline, centrifugal pump and air blower etc..
With the development of the social economy, demand of the people to petroleum pipeline is continuously increased, wherein be more no lack of that there are some functions
The demand of property.Through counting, the effective coating cloth of oil transportation has developed into a big hot topic of petroleum pipeline preparation field, especially PVC at present
Material coating cloth.However, but there is the following not in the effective PVC material coating cloth of most of oil transportation of existing market circulation
Foot: (1) when facing low temperature environment, cold tolerance is poor, is unfavorable for the routine use of petroleum pipeline；(2) face it is moist or some
When the extreme environmental condition of rather harsh, antimildew and antibacterial effect is poor；(3) intensity is not generally high.
Accordingly, it is badly in need of improving the effective PVC material coating cloth of existing oil transportation at present, to provide a kind of cold resistance
It is good, intensity is high, and can effective antimildew and antibacterial the effective coating cloth of oil transportation and preparation method thereof.
Summary of the invention
A kind of cold resistance is good, intensity is high technical problem to be solved by the present invention lies in providing, and can effective antimildew and antibacterial
The effective coating cloth of oil transportation and preparation method thereof.
The present invention solves above-mentioned technical problem using following technical scheme:
Including base fabric, the first coating in base fabric upper and lower surface is respectively coated, coated on each in a kind of effective coating cloth of oil transportation
The second coating of first coating outer surface and organosilicon-modified acrylate layer coated on each second coating outer surface；
The formulation for coating material of the first coating is as follows: 125-130 parts of PVC paste resin, 98-108 parts of plasticizer, changing
10-14 parts of ultraviolet absorbing agent of property, 10-14 parts of mould inhibitor, 10-12 parts of nano silver, 6-8 parts of heat stabilizer, super fine calcium carbonate
33-38 parts, 26-28 parts of nanometer calcium carbonate, 15-19 parts of adhesive, 58-65 parts of Halogen phosphorus flame retardant, antimony oxide 8-10
Part, 8-10 parts of dusting rubber powder, 8-10 parts of titanium dioxide；
The formulation for coating material of the second coating is as follows: 125-130 parts of PVC paste resin, 90-100 parts of plasticizer, changing
10-14 parts of ultraviolet absorbing agent of property, 10-14 parts of mould inhibitor, 10-12 parts of nano silver, 6-8 parts of heat stabilizer, super fine calcium carbonate
28-32 parts, 20-23 parts of nanometer calcium carbonate, 58-65 parts of Halogen phosphorus flame retardant, 8-10 parts of antimony oxide, dusting rubber powder 8-10
Part, 8-10 parts of titanium dioxide；
Wherein, plasticizer is specially the plasticizer system including cold-resistant agent DOA, also, the parts by weight of DOA are
26-30 parts.
As one of preferred embodiment of the invention, the base fabric is specially warp knitting cloth.
As one of preferred embodiment of the invention, the PVC paste resin in the first coating formulation for coating material is
PSM31 model PVC paste resin；PVC paste resin in the second coating formulation for coating material then includes two kinds, i.e.,
PSM31 model PVC paste resin and SYZ-170 model PVC paste resin.
As one of preferred embodiment of the invention, the super fine calcium carbonate is LD-100 super fine calcium carbonate；Mould inhibitor
For JLK-106PVC plastic mould-proof agent；Dusting rubber powder is fine vulcanized rubber powder, and mesh number is below 100 mesh.
As one of preferred embodiment of the invention, in the plasticizer system, the other compositions in addition to DOA are specially neighbour
Rutgers, diisobutyl phthalate, ditridecyl phthalate, diisobutyl phthalate, adipic acid two
One of monooctyl ester and diisononyl phthalate are a variety of.
As one of preferred embodiment of the invention, the heat stabilizer is specially barium zinc, calcium zinc, in dibasic lead phosphite
It is one or more.
As one of preferred embodiment of the invention, described adhesive is specially epoxy resin, polyurethane, polystyrene, second
Alkene-one of acetate ethylene copolymer and carboxymethyl cellulose is a variety of.
As one of preferred embodiment of the invention, the production method of the modified ultraviolet absorbing agent are as follows: by triazines
Ultraviolet absorbing agent, reflection-type uvioresistant finishing agent are in 1:(0.02-0.04) ratio be put into ball mill, ethyl alcohol is medium,
It is fully ground mixing, places into Muffle furnace and keeps the temperature, furnace cooling takes out to arrive modified ultraviolet absorbing agent.
As one of preferred embodiment of the invention, the ultraviolet absorbing agent of the triazines is specially 3,5- dihydroxy -6-
(2,6 dihydroxy phenol) -1,2,4- triazines and 3- sulfydryl -5,6- (2,6 dihydroxy phenol) -1, one of 2,4- triazines or more
Kind.
As one of preferred embodiment of the invention, the reflection-type uvioresistant finishing agent is specially kaolin, talcum powder
One of or it is a variety of.
A kind of preparation method of the effective coating cloth of above-mentioned oil transportation, includes the following steps:
(1) according to the formulation for coating material of above-mentioned first coating, corresponding raw material is mixed, after mixing, obtaining viscosity is
The first coating slurry of 11000-13000CP；The upper and lower surface in base fabric is coated with by the way of vertical brushing, it is ensured that
The hole of base fabric is covered, control base fabric adds coating layer thickness to be 0.2-0.24mm, then places it in vertical drying oven with 170-175
Dry 22-28min at a temperature of DEG C；
(2) according to the formulation for coating material of above-mentioned second coating, corresponding raw material is mixed, after mixing, obtaining viscosity is
The second coating slurry of 11000-13000CP；
(3) second coating slurry is continued by the way of horizontal brushing the base fabric after primary coating drying to be coated in base
Cloth one side, and control overall thickness and reach 0.25-0.27mm, it then places it in dry with 170-175 DEG C of temperature in vertical drying oven
Dry 22-28min is to complete secondary drying；
(4) base fabric after secondary coating drying is continued second coating slurry in such a way that face applies another coated in base fabric
The opposite face of brushing surface in outer one side, i.e. step (3), and control overall thickness and reach 0.3-0.32mm, base fabric is then put into rolling
Carry out third time drying in dynamic baking oven, regulation speed 10-12m/min, dry 12-14min at a temperature of 170-185 DEG C；
(5) base fabric after third time coating drying is applied organosilicon-modified acrylate layer by the way of vertical brushing
Material is coated with the upper and lower surface in base fabric, and control overall thickness is 0.35-0.37mm, then places it in vertical drying oven with 170-
At a temperature of 175 DEG C dry 22-28min to get.
As one of preferred embodiment of the invention, base fabric uses after 130-140 DEG C of high temperature presses in the step (1).
The present invention compared with prior art the advantages of be:
(1) each raw material of the present invention is rationally cooperated, and is learnt from other's strong points to offset one's weaknesses, and perfection plays the comprehensive advantage of each raw material, makes finally to make
The comprehensive performance of the standby obtained effective coating cloth of oil transportation is very excellent；Through the experience that comes into operation for a long time, petroleum pipeline of the present invention
The effect of with coating cloth, not only cold resistance is good, intensity is high, long service life, is also provided simultaneously with mould proof, antibacterial, uvioresistant, can
It is widely used as various petroleum pipelines；
(2) present invention increases the mutual of the two by adding a certain proportion of preservative and nano silver (as antibacterial agent)
Cooperation, to further reach effective antimildew and antibacterial effect；
(3) outermost layer of the present invention by organosilicon-modified acrylate (SA) as the effective coating cloth of oil transportation, is effectively improved
The uvioresistant of PVC profile, self-cleaning performance；SA lotion has excellent physicochemical property and lower surface tension (29.20mN/
M), the PVC profile for being coated with SA has good resistance to ultraviolet, anti-aging property and self-cleaning performance；
(4) general triazines can only absorb 80% ultraviolet light, and reflection-type uvioresistant finishing agent is to ultraviolet light without suction
Adduction uniquely relies on the reflex to light, reduces the transmitance of ultraviolet light, and this kind of screener has nontoxic, tasteless, nothing
Irritation, thermal stability are good, do not decompose and the performances such as non-volatile, to wavelength 310-400nm ultraviolet reflection rate up to 90%,
But whether being ultraviolet absorbing agent or reflection-type uvioresistant finishing agent, there is certain ultraviolet light to penetrate；Of the invention
Modified ultraviolet absorbing agent makes ultraviolet absorbing agent and reflection-type uvioresistant finishing agent act synergistically, and makes ultraviolet ray transmissivity
Down to 5%；
(5) one aspect of the present invention adds Halogen phosphorus flame retardant, greatly improves the flame retardant property of product itself, another party
Face, then antimony oxide is added as anti-flaming smoke-inhibiting agent, cooperate fire retardant to use, postpone burning time, reduces cigarette rate of release
Peak value PSPR；
(6) dusting rubber powder is added in the present invention in formula, and coating cloth finished product is made to keep good flexible and strong in severe cold
Degree, it is not easy to crack, its cold resistance in severe cold is improved, and ensure that the intensity of the effective coating cloth of oil transportation at low temperature.
Detailed description of the invention
Fig. 1 is the cross-sectional structure schematic diagram of the effective coating cloth of oil transportation in embodiment 1-3.
In figure: 1 is warp knitting cloth, and 2 be first coating, and 3 be second coating, and 4 be organosilicon-modified acrylate layer.
Specific embodiment
It elaborates below to the embodiment of the present invention, the present embodiment carries out under the premise of the technical scheme of the present invention
Implement, the detailed implementation method and specific operation process are given, but protection scope of the present invention is not limited to following implementation
Example.
Embodiment 1
As shown in Figure 1, a kind of effective coating cloth of oil transportation of the present embodiment, including warp knitting cloth 1, it is respectively coated in warp knitting cloth 1
The first coating 2 of upper and lower surface, the second coating 3 coated on each 2 outer surface of first coating and be coated on each second coating 3 outside
The organosilicon-modified acrylate layer 4 on surface.
The formulation for coating material of first coating 2 is as follows: 125 parts of PSM31 model PVC paste resin, repefral
72 parts, 26 parts of cold-resistant agent DOA, modified 10 parts of ultraviolet absorbing agent, 10 parts of JLK-106PVC plastic mould-proof agent, 10 parts of nano silver,
6 parts of barium zinc, 33 parts of LD-100 super fine calcium carbonate, 26 parts of nanometer calcium carbonate, 15 parts of epoxy resin, Halogen phosphorus flame retardant 58
Part, 8 parts of antimony oxide, 8 parts, 8 parts of titanium dioxide of fine vulcanized rubber powder (80 mesh).
The formulation for coating material of second coating 3 is as follows: 62.5 parts of PSM31 model PVC paste resin, SYZ-170 model polychlorostyrene
Ethylene pastes 62.5 parts of resin, 64 parts of repefral, 26 parts of cold-resistant agent DOA, is modified 10 parts of ultraviolet absorbing agent,
10 parts of JLK-106PVC plastic mould-proof agent, 10 parts of nano silver, 6 parts of barium zinc, 28 parts of LD-100 super fine calcium carbonate, nanometer calcium carbonate
20 parts, 58 parts of Halogen phosphorus flame retardant, 8 parts of antimony oxide, 8 parts, 8 parts of titanium dioxide of fine vulcanized rubber powder (80 mesh).
Wherein, the production method of modified ultraviolet absorbing agent are as follows: by 3,5- dihydroxy -6- (2,6 dihydroxy phenol) -1,2,
4- triazine, kaolin are put into ball mill in the ratio of 1:0.02, and ethyl alcohol is medium, are fully ground mixing, place into Muffle furnace
Heat preservation, furnace cooling take out to arrive modified ultraviolet absorbing agent.
Embodiment 2
As shown in Figure 1, a kind of effective coating cloth of oil transportation of the present embodiment, including warp knitting cloth 1, it is respectively coated in warp knitting cloth 1
The first coating 2 of upper and lower surface, the second coating 3 coated on each 2 outer surface of first coating and be coated on each second coating 3 outside
The organosilicon-modified acrylate layer 4 on surface.
The formulation for coating material of first coating 2 is as follows: 130 parts of PSM31 model PVC paste resin, the different nonyl of phthalic acid two
78 parts of ester, 30 parts of cold-resistant agent DOA, modified 14 parts of ultraviolet absorbing agent, 14 parts of JLK-106PVC plastic mould-proof agent, nano silver 12
Part, 8 parts of dibasic lead phosphite, 38 parts of LD-100 super fine calcium carbonate, 28 parts of nanometer calcium carbonate, 19 parts of carboxymethyl cellulose,
65 parts of Halogen phosphorus flame retardant, 10 parts of antimony oxide, 10 parts, 10 parts of titanium dioxide of fine vulcanized rubber powder (99 mesh).
The formulation for coating material of second coating 3 is as follows: 65 parts of PSM31 model PVC paste resin, SYZ-170 model polychlorostyrene second
Alkene pastes 65 parts of resin, 70 parts of diisononyl phthalate, 30 parts of cold-resistant agent DOA, is modified 14 parts of ultraviolet absorbing agent, JLK-
14 parts of 106PVC plastic mould-proof agent, 12 parts of nano silver, 8 parts of dibasic lead phosphite, 32 parts of LD-100 super fine calcium carbonate, nanometer
23 parts of calcium carbonate, 65 parts of Halogen phosphorus flame retardant, 10 parts of antimony oxide, fine 10 parts of vulcanized rubber powder (99 mesh), titanium dioxide 10
Part.
Wherein, the production method of modified ultraviolet absorbing agent are as follows: by 3- sulfydryl -5,6- (2,6 dihydroxy phenol) -1,2,4-
Triazine, talcum powder are put into ball mill in the ratio of 1:0.04, and ethyl alcohol is medium, are fully ground mixing, place into Muffle furnace and protect
Temperature, furnace cooling take out to arrive modified ultraviolet absorbing agent.
Embodiment 3
As shown in Figure 1, a kind of effective coating cloth of oil transportation of the present embodiment, including warp knitting cloth 1, it is respectively coated in warp knitting cloth 1
The first coating 2 of upper and lower surface, the second coating 3 coated on each 2 outer surface of first coating and be coated on each second coating 3 outside
The organosilicon-modified acrylate layer 4 on surface.
The formulation for coating material of first coating 2 is as follows: 128 parts of PSM31 model PVC paste resin, ditridecyl phthalate 72
Part, 28 parts of cold-resistant agent DOA, modified 12 parts of ultraviolet absorbing agent, 12 parts of JLK-106PVC plastic mould-proof agent, 11 parts of nano silver, calcium
7 parts of zinc, 35 parts of LD-100 super fine calcium carbonate, 27 parts of nanometer calcium carbonate, 17 parts of polystyrene, 61 parts of Halogen phosphorus flame retardant,
9 parts of antimony oxide, 9 parts, 9 parts of titanium dioxide of fine vulcanized rubber powder (90 mesh).
The formulation for coating material of second coating 3 is as follows: 64 parts of PSM31 model PVC paste resin, SYZ-170 model polychlorostyrene second
Alkene pastes 67 parts of resin, 95 parts of ditridecyl phthalate, 28 parts of cold-resistant agent DOA, is modified 12 parts of ultraviolet absorbing agent, JLK-
12 parts of 106PVC plastic mould-proof agent, 11 parts of nano silver, 7 parts of calcium zinc, 30 parts of LD-100 super fine calcium carbonate, nanometer calcium carbonate 21
Part, 61 parts of Halogen phosphorus flame retardant, 9 parts of antimony oxide, 9 parts, 9 parts of titanium dioxide of fine vulcanized rubber powder (90 mesh).
Wherein, the production method of modified ultraviolet absorbing agent are as follows: by 3,5- dihydroxy -6- (2,6 dihydroxy phenol) -1,2,
4- triazine, talcum powder are put into ball mill in the ratio of 1:0.03, and ethyl alcohol is medium, are fully ground mixing, place into Muffle furnace
Heat preservation, furnace cooling take out to arrive modified ultraviolet absorbing agent.
Embodiment 4
The preparation method of the effective coating cloth of oil transportation, includes the following steps: in a kind of above-described embodiment of the present embodiment
(1) according to the formulation for coating material of above-mentioned first coating 2, corresponding raw material is mixed, after mixing, obtaining viscosity is
2 slurry of first coating of 11000CP；It is coated with by the way of vertical brushing and (is pressed through 130 DEG C of high temperature in warp knitting cloth 1
Use afterwards) upper and lower surface, it is ensured that cover the hole of warp knitting cloth 1, control warp knitting cloth 1 plus coating layer thickness are 0.2mm, then by it
It is placed in vertical drying oven with 22min dry at a temperature of 170 DEG C；
(2) according to the formulation for coating material of above-mentioned second coating 3, corresponding raw material is mixed, after mixing, obtaining viscosity is
3 slurry of second coating of 11000CP；
(3) 3 slurry of second coating is continued to coat by the warp knitting cloth 1 after primary coating drying by the way of horizontal brushing
It in certain one side of warp knitting cloth 1, and controls overall thickness and reaches 0.25mm, then place it in dry with 170 DEG C of temperature in vertical drying oven
22min is to complete secondary drying；
(4) 3 slurry of second coating is continued in such a way that face applies the warp knitting cloth 1 after secondary coating drying to be coated in warp
Cloth 1 in addition one side, i.e., the opposite face of brushing surface in step (3) are compiled, and controls overall thickness and reaches 0.3mm, then puts warp knitting cloth 1
Enter to roll in baking oven progress third time drying, regulation speed 10m/min, dry 12min at a temperature of 170 DEG C；
(5) warp knitting cloth 1 after drying third time coating is by the way of vertical brushing by organosilicon-modified acrylate
4 coating of layer are coated in the upper and lower surface of warp knitting cloth 1, and control overall thickness is 0.35mm, then place it in vertical drying oven with
At a temperature of 170 DEG C dry 22min to get.
Embodiment 5
The preparation method of the effective coating cloth of oil transportation, includes the following steps: in a kind of above-described embodiment of the present embodiment
(1) according to the formulation for coating material of above-mentioned first coating 2, corresponding raw material is mixed, after mixing, obtaining viscosity is
2 slurry of first coating of 13000CP；It is coated with by the way of vertical brushing and (is pressed through 140 DEG C of high temperature in warp knitting cloth 1
Use afterwards) upper and lower surface, it is ensured that cover the hole of warp knitting cloth 1, control warp knitting cloth 1 plus coating layer thickness are 0.24mm, then will
It is placed in vertical drying oven with 28min dry at a temperature of 175 DEG C；
(2) according to the formulation for coating material of above-mentioned second coating 3, corresponding raw material is mixed, after mixing, obtaining viscosity is
3 slurry of second coating of 13000CP；
(3) 3 slurry of second coating is continued to coat by the warp knitting cloth 1 after primary coating drying by the way of horizontal brushing
It in certain one side of warp knitting cloth 1, and controls overall thickness and reaches 0.27mm, then place it in dry with 175 DEG C of temperature in vertical drying oven
28min is to complete secondary drying；
(4) 3 slurry of second coating is continued in such a way that face applies the warp knitting cloth 1 after secondary coating drying to be coated in warp
Cloth 1 in addition one side, i.e., the opposite face of brushing surface in step (3) are compiled, and controls overall thickness and reaches 0.32mm, then by warp knitting cloth 1
It is put into roll and carries out third time drying in baking oven, regulation speed 12m/min, dry 14min at a temperature of 185 DEG C；
(5) warp knitting cloth 1 after drying third time coating is by the way of vertical brushing by organosilicon-modified acrylate
4 coating of layer are coated in the upper and lower surface of warp knitting cloth 1, and control overall thickness is 0.37mm, then place it in vertical drying oven with
At a temperature of 175 DEG C dry 28min to get.
Embodiment 6
The preparation method of the effective coating cloth of oil transportation, includes the following steps: in a kind of above-described embodiment of the present embodiment
(1) according to the formulation for coating material of above-mentioned first coating 2, corresponding raw material is mixed, after mixing, obtaining viscosity is
2 slurry of first coating of 11000CP；It is coated with by the way of vertical brushing and (is pressed through 135 DEG C of high temperature in warp knitting cloth 1
Use afterwards) upper and lower surface, it is ensured that cover the hole of warp knitting cloth 1, control warp knitting cloth 1 plus coating layer thickness are 0.22mm, then will
It is placed in vertical drying oven with 25min dry at a temperature of 173 DEG C；
(2) according to the formulation for coating material of above-mentioned second coating 3, corresponding raw material is mixed, after mixing, obtaining viscosity is
3 slurry of second coating of 11000CP；
(3) 3 slurry of second coating is continued to coat by the warp knitting cloth 1 after primary coating drying by the way of horizontal brushing
It in certain one side of warp knitting cloth 1, and controls overall thickness and reaches 0.26mm, then place it in dry with 173 DEG C of temperature in vertical drying oven
25min is to complete secondary drying；
(4) 3 slurry of second coating is continued in such a way that face applies the warp knitting cloth 1 after secondary coating drying to be coated in warp
Cloth 1 in addition one side, i.e., the opposite face of brushing surface in step (3) are compiled, and controls overall thickness and reaches 0.31mm, then by warp knitting cloth 1
It is put into roll and carries out third time drying in baking oven, regulation speed 11m/min, dry 13min at a temperature of 175 DEG C；
(5) warp knitting cloth 1 after drying third time coating is by the way of vertical brushing by organosilicon-modified acrylate
4 coating of layer are coated in the upper and lower surface of warp knitting cloth 1, and control overall thickness is 0.36mm, then place it in vertical drying oven with
At a temperature of 173 DEG C dry 25min to get.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. a kind of effective coating cloth of oil transportation, which is characterized in that including base fabric, be respectively coated in base fabric upper and lower surface first apply
Layer, the second coating coated on each first coating outer surface and the organic-silicon-modified propylene coated on each second coating outer surface
Acid esters layer；
The formulation for coating material of the first coating is as follows: 125-130 parts of PVC paste resin, 98-108 parts of plasticizer, modified purple
10-14 parts of ultraviolet absorbers, 10-14 parts of mould inhibitor, 10-12 parts of nano silver, 6-8 parts of heat stabilizer, super fine calcium carbonate 33-38
Part, 26-28 parts of nanometer calcium carbonate, 15-19 parts of adhesive, 58-65 parts of Halogen phosphorus flame retardant, 8-10 parts of antimony oxide, powder
Change rubber powder 8-10 parts, 8-10 parts of titanium dioxide；
The formulation for coating material of the second coating is as follows: 125-130 parts of PVC paste resin, 90-100 parts of plasticizer, modified purple
10-14 parts of ultraviolet absorbers, 10-14 parts of mould inhibitor, 10-12 parts of nano silver, 6-8 parts of heat stabilizer, super fine calcium carbonate 28-32
Part, 20-23 parts of nanometer calcium carbonate, 58-65 parts of Halogen phosphorus flame retardant, 8-10 parts of antimony oxide, 8-10 parts of dusting rubber powder, titanium
8-10 parts of white powder；
Wherein, plasticizer is specially the plasticizer system including cold-resistant agent DOA, also, the parts by weight of DOA are 26-30
Part.
2. the effective coating cloth of oil transportation according to claim 1, which is characterized in that the base fabric is specially warp knitting cloth.
3. the effective coating cloth of oil transportation according to claim 1, which is characterized in that poly- in the first coating formulation for coating material
Vinyl chloride paste resin is PSM31 model PVC paste resin；PVC paste resin in the second coating formulation for coating material
It then include two kinds, i.e. PSM31 model PVC paste resin and SYZ-170 model PVC paste resin.
4. the effective coating cloth of oil transportation according to claim 1, which is characterized in that the super fine calcium carbonate is super for LD-100
Fine calcium carbonate；Mould inhibitor is the agent of JLK-106PVC plastic mould-proof；Dusting rubber powder be fine vulcanized rubber powder, mesh number 100 mesh with
Under.
5. the effective coating cloth of oil transportation according to claim 1, which is characterized in that in the plasticizer system, in addition to DOA
Other compositions be specially repefral, diisobutyl phthalate, ditridecyl phthalate, phthalic acid
One of diisobutyl ester, dioctyl adipate and diisononyl phthalate are a variety of.
6. the effective coating cloth of oil transportation according to claim 1, which is characterized in that the heat stabilizer is specially barium zinc, calcium
One of zinc, dibasic lead phosphite are a variety of.
7. the effective coating cloth of oil transportation according to claim 1, which is characterized in that described adhesive be specially epoxy resin,
One of polyurethane, polystyrene, ethylene-vinyl acetate copolymer and carboxymethyl cellulose are a variety of.
8. the effective coating cloth of oil transportation according to claim 1, which is characterized in that the production of the modified ultraviolet absorbing agent
Method are as follows: by the ultraviolet absorbing agent of triazines, reflection-type uvioresistant finishing agent in 1:(0.02-0.04) ratio be put into ball
Grinding machine, ethyl alcohol are medium, are fully ground mixing, place into Muffle furnace and keep the temperature, and furnace cooling takes out to arrive the ultraviolet of modification
Light absorbers.
9. a kind of preparation method of the effective coating cloth of oil transportation a method as claimed in any one of claims 1-8, which is characterized in that including as follows
Step:
(1) according to the formulation for coating material of above-mentioned first coating, corresponding raw material is mixed, after mixing, obtaining viscosity is
The first coating slurry of 11000-13000CP；The upper and lower surface in base fabric is coated with by the way of vertical brushing, it is ensured that
The hole of base fabric is covered, control base fabric adds coating layer thickness to be 0.2-0.24mm, then places it in vertical drying oven with 170-175
Dry 22-28min at a temperature of DEG C；
(2) according to the formulation for coating material of above-mentioned second coating, corresponding raw material is mixed, after mixing, obtaining viscosity is
The second coating slurry of 11000-13000CP；
(3) second coating slurry is continued by the way of horizontal brushing the base fabric after primary coating drying to be coated in base fabric
On one side, it and controls overall thickness and reaches 0.25-0.27mm, then place it in vertical drying oven with the dry 22- of 170-175 DEG C of temperature
28min is to complete secondary drying；
(4) second coating slurry is continued in such a way that face applies the base fabric after secondary coating drying to be coated in base fabric other one
The opposite face of brushing surface in face, i.e. step (3), and control overall thickness and reach 0.3-0.32mm, base fabric is then put into rolling and is dried
Carry out third time drying in case, regulation speed 10-12m/min, dry 12-14min at a temperature of 170-185 DEG C；
(5) base fabric after third time coating drying is equal by organosilicon-modified acrylate coating by the way of vertical brushing
Upper and lower surface coated on base fabric, control overall thickness are 0.35-0.37mm, are then placed it in vertical drying oven with 170-175
At a temperature of DEG C dry 22-28min to get.
10. the preparation method of the effective coating cloth of oil transportation according to claim 9, which is characterized in that it is characterized in that, described
Base fabric uses after 130-140 DEG C of high temperature presses in step (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810629099.XA CN109826020A (en) | 2018-06-19 | 2018-06-19 | A kind of effective coating cloth of oil transportation and preparation method thereof |
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| CN201810629099.XA CN109826020A (en) | 2018-06-19 | 2018-06-19 | A kind of effective coating cloth of oil transportation and preparation method thereof |
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Application publication date: 20190531 |