CN106223054B - A kind of puggaree and its processing method with endurance life - Google Patents

A kind of puggaree and its processing method with endurance life Download PDF

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CN106223054B
CN106223054B CN201610627005.6A CN201610627005A CN106223054B CN 106223054 B CN106223054 B CN 106223054B CN 201610627005 A CN201610627005 A CN 201610627005A CN 106223054 B CN106223054 B CN 106223054B
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puggaree
parts
titanium dioxide
pvc
endurance life
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CN106223054A (en
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苏跃锋
张伟忠
沈金
凌建丰
陆慧斌
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ZHEJIANG HUIFENG NEW MATERIALS CO Ltd
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ZHEJIANG HUIFENG NEW MATERIALS CO Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/065—Insulating
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    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1678—Resistive to light or to UV
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/125—Awnings, sunblinds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of puggarees with endurance life, are made of warp knitting cloth, PVC laminating layers and durable function layer；PVC laminating layers are mainly made by PVC paste resin, environment-friendly plasticizer, stabilizer, filler, fire retardant, mould inhibitor, antioxidant, adhesive, and durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.01~0.1mm；The invention also discloses a kind of processing methods with endurance life puggaree.Puggaree in the present invention has good anti-light corrosive nature, can extend the service life of puggaree, can also play shielding action to ultraviolet light；Using tiny balloon titanium dioxide, certain thermal insulation function can be played；Production method in the present invention is simple and fast, and effect is good, is prepared using existing equipment, and industry alteration difficulty is small.

Description

A kind of puggaree and its processing method with endurance life
Technical field
The present invention relates to puggaree technical fields, more particularly, to a kind of puggaree with endurance life and its processing side Method.
Background technology
Puggaree is also referred to as black-out cloth, is exactly to be used for keeping the sun off and sunshine in brief, is the complementary fabric of function, leads to Often together with other fabrics, play the role of avoiding contacting with strong light for covering article, there is good shading effect, nontoxic, nothing Taste, it is soft the features such as, be widely used in hold court from behind a screen, be on roller shutter modern house life model.With the development of social economy Environment is increasingly severe now, and puggaree increasingly becomes the indispensable object of family, especially as the usage amount of outer layer curtain, Even more swift and violent growth, but there are many problems for existing puggaree, wherein most important is exactly reliable under burning sun irradiation Property decaying it is serious, the service life is shorter, it is permanent after puggaree blocking heat and ultraviolet light reduced capability.
Invention content
To solve the above problems, the present invention, which provides one kind, having endurance life, the excellent puggaree of blocking ultraviolet light function；
The present invention also provides a kind of processing methods with endurance life puggaree.
To achieve the above object, the technical solution adopted by the present invention is as follows：
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, environment-friendly plasticizer 50~80 Part, 2~5 parts of stabilizer, 0~60 part of filler, 0~20 part of fire retardant, 0~5 part of mould inhibitor, 0~5 part of antioxidant, adhesive 0 ~10 parts；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.01~0.1mm.
Titanium dioxide is a kind of UV resistant agent with excellent results, while titanium dioxide also has good self-cleaning Effect, and titanium dioxide has good reflective function；Titanium dioxide-coated is being played into uvioresistant in puggaree surface, It prevents from that self-cleaning net effect can also be played while photoetch, organic matter of cleaning puggaree surface attachment etc. has the puggaree service life There is dysgenic dust etc.；In addition the not traditional powdered titanium dioxide of the titanium dioxide used uses titanium dioxide Titanium microballoon, one can cover the surface area of bigger in minimum amount of titanium, secondly hollow microsphere structure can rise To the effect of heat-insulation and heat-preservation, that is, play the role of obstructing ultraviolet light, and indoor temperature can be kept to maintain a nice and cool level.
Preferably, environment-friendly plasticizer is butyl epoxy stearate, octyl epoxy stearate or epoxy tetrahydrochysene O-phthalic Dioctyl phthalate.
Preferably, stabilizer is calcium stearate, zinc stearate or zinc ricinate.
Preferably, mould inhibitor is phenol, pentachlorophenol or tributyl tin.
Preferably, antioxidant is butylated hydroxy anisole, dibutyl hydroxy toluene or propylgallate.
Preferably, fire retardant is magnesium hydroxide, aluminium hydroxide or tricresyl phosphate.
Preferably, titanium dioxide microballoon sphere is made by following steps：By a diameter of 0.008~0.08mm of 3~6 parts by weight Polyethylene foamed microballoon be added in 20~25 parts by weight water, and thereto be added 0.1~0.5 parts by weight detergent alkylate Sodium sulfonate is sufficiently stirred, backward solution in be added appropriate NaOH solution make pH value be 11.5~12, then thereto be added 1~ The titanium tetrachloride of 6 parts by weight, constant pH are stirred to react 2~3 hours, are dried 2.5~3 hours after filtration washing, are then heated up It calcines 0.5~1.5 hour, is calcined 2~3 hours followed by being warming up to 600~700 DEG C, last natural cooling to 400~500 DEG C, Screen the titanium dioxide microballoon sphere of a diameter of 0.01~0.1mm.
Titanium dioxide microballoon sphere is prepared using polyethylene foamed microsphere template method, good can control titanium dioxide microballoon sphere The uniformity of size and size；Polyethylene foamed is a kind of common resin foamed substance, and making is simple and easy to get, and its high temperature fires Not will produce uncontrollable harmful substance after burning, at the same its it is surface-modified after titanium tetrachloride can be made to be attached to its table well Face, to which titanium dioxide microballoon sphere be made.In constant pH reaction process, titanium compound precipitation is generated, polyethylene microballoon table is attached to Face；In calcination process, heat preservation is to form hollow-core construction to make polyethylene ball react for the first time, second when keeping the temperature in order to make Preliminary molding titanium dioxide microballoon sphere is grown more solid close.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）1~5 hour obtained PVC laminating layers slurry is stirred after the raw material for making PVC laminating layers is mixed at 50~80 DEG C Material；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The puggaree of life.
After hot pressing fitting, titanium dioxide microballoon sphere spray treatment is carried out immediately in the case of not cooling, is synthesized using heat posted Titanium dioxide microballoon sphere is bonded in PVC and is bonded layer surface by the viscosity still having when uncolled, and titanium dioxide microballoon sphere is made to will not fall off, The energy is also saved simultaneously, reduces cost.
Preferably, in step b, after the coating of PVC laminating layer slurries, the thickness of PVC laminating layers is 0.05~0.1mm.
Preferably, after titanium dioxide microballoon sphere spraying, the quality of upper titanium dioxide microballoon sphere every square centimeter is 0.1~ 0.2g。
Therefore, the invention has the advantages that：
（1）With good anti-light corrosive nature, the service life of puggaree can be extended, ultraviolet light can also be played Shielding action；
（2）Using tiny balloon titanium dioxide, certain thermal insulation function can be played；
（3）Production method is simple and fast, and effect is good, is prepared using existing equipment, and industry alteration difficulty is small.
Specific implementation mode
Technical scheme of the present invention is further described With reference to embodiment.
Embodiment 1
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, butyl epoxy stearate 50 Part, 2 parts of zinc ricinate；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.01mm；
Titanium dioxide microballoon sphere is made by following steps：The polyethylene foamed microballoon of a diameter of 0.008mm of 3 parts by weight is added Enter into 20 parts by weight water, and the neopelex that 0.1 parts by weight are added thereto is sufficiently stirred, backward solution in Appropriate NaOH solution, which is added, makes pH value be 11.5, the titanium tetrachloride of 1 parts by weight is then added thereto, constant pH is stirred to react It 2 hours, is dried 2.5 hours after filtration washing, is then warming up to 400 DEG C and calcines 0.5 hour, 2 are calcined followed by being warming up to 600 DEG C Hour, last natural cooling screens the titanium dioxide microballoon sphere of a diameter of 0.01mm.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）1 hour obtained PVC laminating layers slurry is stirred at 50 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded, PVC patches After closing the coating of layer slurry, the thickness of PVC laminating layers is 0.05mm, after titanium dioxide microballoon sphere spraying；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The quality of the puggaree of life, upper titanium dioxide microballoon sphere every square centimeter is 0.1g.
Embodiment 2
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, octyl epoxy stearate 65 Part, 4 parts of zinc stearate, 30 parts of filler, 10 parts of aluminium hydroxide, 3 parts of pentachlorophenol, 2 parts of dibutyl hydroxy toluene, 5 parts of adhesive；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.05mm；
Titanium dioxide microballoon sphere is made by following steps：The polyethylene foamed microballoon of a diameter of 0.04mm of 4 parts by weight is added Enter into 23 parts by weight water, and the neopelex that 0.3 parts by weight are added thereto is sufficiently stirred, backward solution in Appropriate NaOH solution, which is added, makes pH value be 11.5, the titanium tetrachloride of 4 parts by weight is then added thereto, constant pH is stirred to react It 2.5 hours, is dried 2.5 hours after filtration washing, is then warming up to 450 DEG C and calcines 1 hour, followed by being warming up to 650 DEG C of calcinings 2.5 hours, last natural cooling screened the titanium dioxide microballoon sphere of a diameter of 0.05mm.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）3 hours obtained PVC laminating layers slurries are stirred at 65 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded, PVC patches After closing the coating of layer slurry, the thickness of PVC laminating layers is 0.07mm, after titanium dioxide microballoon sphere spraying；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The quality of the puggaree of life, upper titanium dioxide microballoon sphere every square centimeter is 0.15g.
Embodiment 3
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, epoxy tetrahydrochysene O-phthalic 80 parts of dioctyl phthalate, 5 parts of zinc ricinate, 60 parts of filler, 20 parts of tricresyl phosphate, 5 parts of tributyl tin, propylgallate 5 parts, 10 parts of adhesive；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.1mm；
Titanium dioxide microballoon sphere is made by following steps：The polyethylene foamed microballoon of a diameter of 0.08mm of 6 parts by weight is added Enter into 25 parts by weight water, and the neopelex that 0.5 parts by weight are added thereto is sufficiently stirred, backward solution in Appropriate NaOH solution, which is added, makes pH value be 12, the titanium tetrachloride of 6 parts by weight is then added thereto, constant pH is stirred to react 3 Hour, it is dried 3 hours after filtration washing, is then warming up to 500 DEG C and calcines 1.5 hours, 700 DEG C of calcinings 3 are small followed by being warming up to When, last natural cooling screens the titanium dioxide microballoon sphere of a diameter of 0.1mm.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）5 hours obtained PVC laminating layers slurries are stirred at 80 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded, PVC patches After closing the coating of layer slurry, the thickness of PVC laminating layers is 0.1mm；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The puggaree of life, after titanium dioxide microballoon sphere spraying, the quality of upper titanium dioxide microballoon sphere every square centimeter is 0.2g.
Embodiment 4
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, butyl epoxy stearate 50 Part, 2 parts of zinc ricinate；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.01mm；
Titanium dioxide microballoon sphere is made by following steps：The polyethylene foamed microballoon of a diameter of 0.008mm of 3 parts by weight is added Enter into 20 parts by weight water, and the neopelex that 0.1 parts by weight are added thereto is sufficiently stirred, backward solution in Appropriate NaOH solution, which is added, makes pH value be 11.5, the titanium tetrachloride of 1 parts by weight is then added thereto, constant pH is stirred to react It 2 hours, is dried 2.5 hours after filtration washing, is then warming up to 400 DEG C and calcines 0.5 hour, 2 are calcined followed by being warming up to 600 DEG C Hour, last natural cooling screens the titanium dioxide microballoon sphere of a diameter of 0.01mm.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）1 hour obtained PVC laminating layers slurry is stirred at 50 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded, PVC patches After closing the coating of layer slurry, the thickness of PVC laminating layers is 0.05mm；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The puggaree of life, after titanium dioxide microballoon sphere spraying, the quality of upper titanium dioxide microballoon sphere every square centimeter is 0.1g.
Embodiment 5
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, butyl epoxy stearate 50 Part, 2 parts of calcium stearate, 10 parts of filler, 2 parts of magnesium hydroxide, 1 part of phenol, 2 parts of butylated hydroxy anisole, 3 parts of adhesive；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.01mm；
Titanium dioxide microballoon sphere is made by following steps：The polyethylene foamed microballoon of a diameter of 0.01mm of 3 parts by weight is added Enter into 20 parts by weight water, and the neopelex that 0.1 parts by weight are added thereto is sufficiently stirred, backward solution in Appropriate NaOH solution, which is added, makes pH value be 11.5, the titanium tetrachloride of 2 parts by weight is then added thereto, constant pH is stirred to react It 2 hours, is dried 2.5 hours after filtration washing, is then warming up to 400 DEG C and calcines 0.5 hour, 2 are calcined followed by being warming up to 600 DEG C Hour, last natural cooling screens the titanium dioxide microballoon sphere of a diameter of 0.03mm.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）1 hour obtained PVC laminating layers slurry is stirred at 50 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded, PVC patches After closing the coating of layer slurry, the thickness of PVC laminating layers is 0.05mm；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The puggaree of life, after titanium dioxide microballoon sphere spraying, the quality of upper titanium dioxide microballoon sphere every square centimeter is 0.1g.
Embodiment 6
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, octyl epoxy stearate 65 Part, 4 parts of zinc stearate, 30 parts of filler, 10 parts of aluminium hydroxide, 3 parts of pentachlorophenol, 2 parts of dibutyl hydroxy toluene, 5 parts of adhesive；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.05mm；
Titanium dioxide microballoon sphere is made by following steps：The polyethylene foamed microballoon of a diameter of 0.04mm of 4 parts by weight is added Enter into 22 parts by weight water, and the neopelex that 0.3 parts by weight are added thereto is sufficiently stirred, backward solution in Appropriate NaOH solution, which is added, makes pH value be 12, the titanium tetrachloride of 4 parts by weight is then added thereto, constant pH is stirred to react It 2.5 hours, is dried 2.7 hours after filtration washing, is then warming up to 450 DEG C and calcines 1 hour, followed by being warming up to 650 DEG C of calcinings 2.5 hours, last natural cooling screened the titanium dioxide microballoon sphere of a diameter of 0.05mm.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）3 hours obtained PVC laminating layers slurries are stirred at 65 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded, PVC patches After closing the coating of layer slurry, the thickness of PVC laminating layers is 0.07mm；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The puggaree of life, after titanium dioxide microballoon sphere spraying, the quality of upper titanium dioxide microballoon sphere every square centimeter is 0.15g.
Embodiment 7
A kind of puggaree with endurance life is made of warp knitting cloth, PVC laminating layers and durable function layer；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, epoxy tetrahydrochysene O-phthalic 80 parts of dioctyl phthalate, 5 parts of zinc ricinate, 60 parts of filler, 20 parts of tricresyl phosphate, 5 parts of tributyl tin, propylgallate 5 parts, 10 parts of adhesive；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.1mm；
Titanium dioxide microballoon sphere is made by following steps：The polyethylene foamed microballoon of a diameter of 0.08mm of 6 parts by weight is added Enter into 25 parts by weight water, and the neopelex that 0.5 parts by weight are added thereto is sufficiently stirred, backward solution in Appropriate NaOH solution, which is added, makes pH value be 12, the titanium tetrachloride of 6 parts by weight is then added thereto, constant pH is stirred to react 3 Hour, it is dried 3 hours after filtration washing, is then warming up to 500 DEG C and calcines 1.5 hours, 700 DEG C of calcinings 3 are small followed by being warming up to When, last natural cooling screens the titanium dioxide microballoon sphere of a diameter of 0.1mm.
A kind of processing method of the puggaree with endurance life, includes the following steps：
a）5 hours obtained PVC laminating layers slurries are stirred at 80 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of grid cloth, and hot pressing is bonded, PVC patches After closing the coating of layer slurry, the thickness of PVC laminating layers is 0.1mm；
c）Titanium dioxide microballoon sphere even application had into the durable longevity being made through thermal-adhering treated PVC fitting layer surface The puggaree of life, after titanium dioxide microballoon sphere spraying, the quality of upper titanium dioxide microballoon sphere every square centimeter is 0.2g.
Technique effect：
1. at 35 DEG C, under the irradiation of summer sunlight, the temperature in the lower region of puggaree covering is 2~3 DEG C lower than uncovered area； The puggaree of the present invention can stop 85% or more ultraviolet light irradiation；
2. at 30 DEG C, under 60% humidity environment, by two years, the coating of the puggaree of the various embodiments described above is not sent out It is raw to loosen and fall off, still there is good adhesion property, there is longer service life.

Claims (9)

1. a kind of puggaree with endurance life, it is characterised in that：It is by warp knitting cloth, PVC laminating layers and durable function layer group At；
Wherein, PVC laminating layers are made by the raw material of following parts by weight：100 parts of PVC paste resin, 50~80 parts of environment-friendly plasticizer, surely Determine 2~5 parts of agent, 0~60 part of filler, 0~20 part of fire retardant, 0~5 part of mould inhibitor, 0~5 part of antioxidant, adhesive 0~10 Part；
Durable function layer is made of the titanium dioxide microballoon sphere that grain size is 0.01~0.1mm；
The titanium dioxide microballoon sphere is made by following steps：By the foaming of a diameter of 0.008~0.08mm of 3~6 parts by weight Polyethylene microballoon is added in 20~25 parts by weight water, and the neopelex of 0.1~0.5 parts by weight is added thereto Be sufficiently stirred, backward solution in be added appropriate NaOH solution make pH value be 11.5~12, then thereto be added 1~6 weight The titanium tetrachloride of part, constant pH are stirred to react 2~3 hours, are dried 2.5~3 hours after filtration washing, be then warming up to 400 ~500 DEG C are calcined 0.5~1.5 hour, are calcined 2~3 hours followed by being warming up to 600~700 DEG C, last natural cooling, screening The titanium dioxide microballoon sphere of a diameter of 0.01~0.1mm.
2. a kind of puggaree with endurance life according to claim 1, it is characterised in that：The environment-friendly plasticizer For butyl epoxy stearate, octyl epoxy stearate or epoxy tetrahydro-2-ethylhexyl phthalate.
3. a kind of puggaree with endurance life according to claim 1, it is characterised in that：The stabilizer is hard Resin acid calcium, zinc stearate or zinc ricinate.
4. a kind of puggaree with endurance life according to claim 1, it is characterised in that：The mould inhibitor is benzene Phenol, pentachlorophenol or tributyl tin.
5. a kind of puggaree with endurance life according to claim 1, it is characterised in that：The antioxidant is Butylated hydroxy anisole, dibutyl hydroxy toluene or propylgallate.
6. a kind of puggaree with endurance life according to claim 1, it is characterised in that：The fire retardant is hydrogen Magnesia, aluminium hydroxide or tricresyl phosphate.
7. a kind of processing method of the puggaree according to claim 1 with endurance life, it is characterised in that including with Lower step：
a）1~5 hour obtained PVC laminating layers slurry is stirred at 50~80 DEG C after the raw material for making PVC laminating layers is mixed；
b）PVC laminating layer slurries after stirring are coated uniformly on to two surfaces of warp knitting cloth, and hot pressing is bonded；
c）Titanium dioxide microballoon sphere even application is made through thermal-adhering treated PVC fitting layer surface with endurance life Puggaree.
8. a kind of processing method of puggaree with endurance life according to claim 7, it is characterised in that：The step In rapid b, after the coating of PVC laminating layer slurries, the thickness of PVC laminating layers is 0.05~0.1mm.
9. a kind of processing method of puggaree with endurance life according to claim 7, it is characterised in that：Described two After titania microsphere spraying, the quality of upper titanium dioxide microballoon sphere every square centimeter is 0.1~0.2g.
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