A kind of phytoremediation agent and preparation method thereof
Technical field
The invention belongs to detergent technical fields, and in particular to the preparation side of a kind of phytoremediation agent and the stain remover
Method.
Background technique
Present stain remover can be divided into powder detergent, liquid detergent and solid detergent according to mode of appearance,
Detergent for household use and industrial detergent can be divided into according to use scope.In addition, stain remover can also according to effective component into
Row classification is broadly divided into sodium metasilicate, sodium tripolyphosphate, fatty alcohol polyoxyethylene ether (AEO) series, alkyl phenol polyoxyethylene ether system
Column etc..The purposes of stain remover is to remove food, tableware, weaving, traffic, building, electric appliance, engineering equipment, five metalworkings, plastics
Etc. dust, greasy dirt, due to easy to use, significant effect, deep to be liked by the majority of consumers, the market demand is high.
Contain surfactant, defoaming agent, solubilizer, cosolvent, chelating agent, preservative and bacteriostatic agent in traditional stain remover
Deng because of its ingredient reason, having the disadvantage in that 1, active constituent residual is high, water consumption is big, although remaining amount will not be short-term
The health of people is impacted, but is inevitably accumulated in human body with the accumulation of usage time, and people's health is realized
It is continuously improved, therefore the acceptance level of this traditional stain remover is gradually reduced;2, surfactant in traditional stain remover etc. at
Divide and is difficult to degrade in the natural environment, waste water treatmentntrol difficult, environmental pollution weight.
In order to overcome these disadvantages, start to become research hotspot as the stain remover of active constituent using plant extracts.It is some
Containing natural surfactant, water skiing agent and chelating agent etc. in plant extracts, have the effect of dedusting decontamination, and these
Substance can natural degradation, with waste water discharge obvious pressure will not be caused to environment, human body is almost harmless.Patent
CN101768524A discloses a kind of washing using salt lake aqueous concentrate, surfactant and Chinese medical extract as main active
Clean essence, Chinese medical extract be coconut oil, Rosa Damascana or Lavender and Fructus Gleditsiae Abnormalis extract, Radix et Caulis Opuntiae Dillenii extract or
The mixture of aloe extract.Then contain aloe, cactus, soap in plant fruits and vegetables dish washing liquid disclosed in patent CN103103038A
The plant extract components such as angle, tea seed cake.In order to protect skin, patent CN103725444A also adds while plant extracts is added
Enter emollient, obtains the dish washing liquid with skin-friendliness.Patent CN103555480A then discloses a kind of fruits and vegetables dish washing liquid, contains
Aloe extract, Ginger P.E, Radix et Caulis Opuntiae Dillenii extract, gleditsia sinensis, tea seed cake etc..Although these stain removers all introduce plant substantially
Extract, but because formula or dosage reason causes scavenging effect undesirable or stain remover character is poor, it is necessary to simultaneously plus
Enter a large amount of surfactant, there is no the comprehensive substitution for really realizing plant extracts, aforementioned problem is still remained;Together
When because extraction operation, preparation method not enough optimize, the extract dissolubility caused is poor, to be added a large amount of ethyl alcohol and
Cosolvent, leads to stain remover complicated components, and stability is difficult to adjust;Moreover, the stain remover containing plant extracts, because extracting
Containing some substances for being easy to happen chemical structure change in object, the shelf-life is shorter;In addition, the acquisition side of these extracts
Formula causes some substances being easy in conjunction with cotton fiber to retain wherein it is difficult to rinse, and causes to change colour in sunning or placement process.
Summary of the invention
In view of the above-mentioned problems existing in the prior art, good, stability that the purpose of the present invention is to provide a kind of scavenging effects
Good, clean and environmental protection phytoremediation agent, and the preparation method of the stain remover is further provided.
Above-mentioned purpose of the invention is achieved through the following technical solutions:
A kind of phytoremediation agent is including 2-5 parts of extract solution from aloe in terms of 100 parts by total weight, gleditsia sinensis extracting solution 10-20
Part, 15-20 parts of cactus extraction, 0.1-0.5 parts of potassium sorbate, 1-2 parts of borate, 1-6 parts of ethylene glycol, ethylenediamine tetra-acetic acid
0.1-0.15 parts, surplus is deionized water, the aloe be fresh aloe, the cactus be fresh cactus, and aloe and
Cactus prepares extracting solution after being intended to peeling again.
Further, above-mentioned phytoremediation agent, the extract solution from aloe are obtained by fresh aloe juice, the cactus
Extracting solution is alcohol-water extracting solution, and the gleditsia sinensis extracting solution is aqueous extract.
Further, above-mentioned phytoremediation agent further includes 0.005-0.007 parts of Victoria C, ties up E 0.0025-0.003 parts.
Further, above-mentioned phytoremediation agent further includes 0.1-0.3 parts of sodium lauroyl sarcosine.
Further, above-mentioned phytoremediation agent further includes 1-3 parts of sodium phytate.
Further, above-mentioned phytoremediation agent further includes 0.01-0.05 parts of essence.
The above-mentioned phytoremediation agent of the present invention is prepared by the following method:
1) cleaning appliance, pre- bacteriological protection enter in Aloe Vera Gel, fresh aloe are cleaned up, artificial to remove the peel, and are put into juice processed
Essence filtering again after asparagus juice coarse filtration is obtained extract solution from aloe by juice processed in machine;
2) dry gleditsia sinensis is crushed to partial size 2-3mm, takes 1 part of gleditsia sinensis crushed material with 9 parts of deionized water in 50-60
It is impregnated 12-24 hours at DEG C, coarse filtration;After filtrate is stirred 40-80 minutes at 50-60 DEG C, essence filtering;Deionized water is added to arrive
10 parts, obtain gleditsia sinensis extracting solution;
3) cleaning appliance, pre- bacteriological protection enter, and after taking 30 parts of fresh cactus peelings, crushing, are put into 50 parts of deionized waters
In the mixed solution of 5 parts of ethyl alcohol;Water-bath keeps the temperature 45-50 DEG C extraction 6-10 hours;Deionized water is mended after pressure filtration to 100
Part, obtain cactus extraction;
4) by step 1) -3) obtained extracting solution is sufficiently mixed in proportion, adds other components, be eventually adding surplus and go
Ionized water is uniformly mixed;It is 20-30 minutes ultrasonic, filtering, then 50 DEG C~60 DEG C be stirred until homogeneous it is transparent, it is cooling to get.
The present invention sufficiently substitutes traditional surfactant with plant extracts and produces stain remover, and ingredient is safe, and
It is environmental-friendly, it is easy natural degradation, solves the problems, such as that component residue may cause security risk and environmental pollution.The present invention
It is first extracted using dry aloe and cactus in research process, has been found that and then active constituent extracted amount is extracted with water
Few, cost of material increases severely, if extracted with alcohol or other organic solvents, is re-dissolved in water after dry and prepares stain remover, Ke Yi great
It is big to improve active component content, but, there are a large amount of precipitatings in when extract is dissolved in water, needs additionally to add ethyl alcohol or other hydrotropies
Agent or solubilizer could prepare the stain remover of clear homogeneous, are not inconsistent with environmental-friendly purpose, finally find, using fresh
Aloe and cactus prepare extract can be to avoid this problem.Fresh aloe juice directly processed, juice is soluble easily in water, fresh cactus
It does not dry after being extracted with alcohol-water mixture, is directly diluted with water, precipitating will not be generated, the content of active constituent is also high.Meanwhile it grinding
It has also been found that natural component is complicated in plant extracts during studying carefully, the reactions such as oxidation, hydrolysis easily occur in placement process, cause
Keep the long-time stability of stain remover poor, easy to change, the shelf-life is short, unobvious antioxidant is added and improves;And with containing
The stain remover of a large amount of plant extracts handles when containing cotton fiber, and in sunning or use process, cotton fiber is easy yellowing.Finally originally
Invention only prepares extract with interior tissue, is found surprisingly that stain remover by the way of removing the peel aloe and cactus completely
Shelf lives significantly extend, and no longer there is the case where cotton fiber discoloration, thus it is speculated that its reason may is that, fresh aloe
With in the crust of cactus contain a large amount of polyphenols and substance that show color, extracted with fresh feed, these substances lack
The constraint effect of few dry matter, is easily dissolved and releases, and these ingredients are apt to deteriorate in placement process, so as to shorten
Shelf-life, but these substances contain the group being easy in conjunction with cotton fiber, are difficult to be rinsed with water after attachment, and then lead to cotton fiber
Change colour.Technical solution of the present invention preferably solves these problems.
Specific embodiment
It is illustrated below by way of specific embodiment is further to summary of the invention of the invention, but should not be construed as the present invention
Range be only limitted to example below, invention thinking according to the present invention and entire contents, can will be each in following instance
Technical characteristic makes combination/replacement/adjustment/modification appropriate etc., this is will be obvious to those skilled in the art that still
Belong to the scope that the present invention protects.
Extract solution from aloe, gleditsia sinensis extracting solution and cactus extraction are prepared as follows:
1) cleaning appliance, pre- bacteriological protection enter in Aloe Vera Gel, fresh aloe are cleaned up, artificial to remove the peel, and are put into juice processed
Essence filtering again after asparagus juice coarse filtration is obtained extract solution from aloe A by juice processed in machine;
2) dry gleditsia sinensis is crushed to partial size 2-3mm, takes 1 part of gleditsia sinensis crushed material with 9 parts of deionized water in 50-60
It is impregnated 12-24 hours at DEG C, coarse filtration;After filtrate is stirred 40-80 minutes at 50-60 DEG C, essence filtering;Deionized water is added to arrive
10 parts, obtain gleditsia sinensis extracting solution B;
3) cleaning appliance, pre- bacteriological protection enter, and after taking 30 parts of fresh cactus peelings, crushing, are put into 50 parts of deionized waters
In the mixed solution of 5 parts of ethyl alcohol;Water-bath keeps the temperature 45-50 DEG C extraction 6-10 hours;Deionized water is mended after pressure filtration to 100
Part, obtain cactus extraction C.
Stain remover tests the scourability of tableware according to standard " GB 9985-2000 manual dishwashing detergent ".
Embodiment 1
4 parts of extract solution from aloe A, 20 parts of 12 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.1 part of potassium sorbate are taken,
1 part of borate, 1 part of ethylene glycol, 0.12 part of ethylenediamine tetra-acetic acid, supplement 61.78 parts of deionized water.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 20 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 50 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 18 months under room temperature environment.
Embodiment 2
5 parts of extract solution from aloe A, 15 parts of 10 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.5 part of potassium sorbate are taken,
1 part of borate, 2 parts of ethylene glycol, 0.15 part of ethylenediamine tetra-acetic acid, supplement 66.35 parts of deionized water.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 60 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 18 months under room temperature environment.
Embodiment 3
2 parts of extract solution from aloe A, 15 parts of 15 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.5 part of potassium sorbate are taken,
2 parts of borate, 6 parts of ethylene glycol, 0.1 part of ethylenediamine tetra-acetic acid, supplement 59.4 parts of deionized water.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 60 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 18 months under room temperature environment.
Embodiment 4
3 parts of extract solution from aloe A, 18 parts of 12 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.2 part of potassium sorbate are taken,
1 part of borate, 3 parts of ethylene glycol, 0.1 part of ethylenediamine tetra-acetic acid, 0.005 part of Victoria C, 0.0028 part of E is tieed up, supplements deionized water
62.6922 parts.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 60 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 24 months under room temperature environment.
Embodiment 5
4 parts of extract solution from aloe A, 16 parts of 13 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.2 part of potassium sorbate are taken,
2 parts of borate, 4 parts of ethylene glycol, 0.15 part of ethylenediamine tetra-acetic acid, 0.1 part of sodium lauroyl sarcosine, 0.006 part of Victoria C, tie up E
0.0025 part, supplement 60.5415 parts of deionized water.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 60 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 24 months under room temperature environment.
Embodiment 6
3 parts of extract solution from aloe A, 17 parts of 13 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.3 part of potassium sorbate are taken,
1.5 parts of borate, 5 parts of ethylene glycol, 0.15 part of ethylenediamine tetra-acetic acid, 0.3 part of sodium lauroyl sarcosine, 0.007 part of Victoria C, tie up E
0.003 part, supplement 59.74 parts of deionized water.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 60 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 25 months under room temperature environment.
Embodiment 7
4 parts of extract solution from aloe A, 17 parts of 12 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.3 part of potassium sorbate are taken,
1.5 parts of borate, 5 parts of ethylene glycol, 0.12 part of ethylenediamine tetra-acetic acid, 0.2 part of sodium lauroyl sarcosine, 0.006 part of Victoria C, tie up E
0.003 part, 1.5 parts of sodium phytate, supplement 58.371 parts of deionized water.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 60 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 24 months under room temperature environment.
Embodiment 8
2 parts of extract solution from aloe A, 20 parts of 15 parts of gleditsia sinensis extracting solution B, cactus extraction C, 0.3 part of potassium sorbate are taken,
1.5 parts of borate, 5 parts of ethylene glycol, 0.12 part of ethylenediamine tetra-acetic acid, 0.2 part of sodium lauroyl sarcosine, 0.006 part of Victoria C, tie up E
0.003 part, 3 parts of sodium phytate, 0.01 part of essence, supplement 52.861 parts of deionized water.
First extracting solution A, B, C are sufficiently mixed, add potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid, most
Balance deionized water is added afterwards to be uniformly mixed;Ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering, is then stirred for 60 DEG C
Mix to homogeneous transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Essence fragrance;Stability meets the requirements;
Detergency is qualified.
Cotton fiber is washed at 35 DEG C, cotton fiber is without color change.
Container sealing placement starts to occur faint yellow for 24 months under room temperature environment.
Stain remover prepared by above embodiments is used for industrial appliances such as washing by soaking metal and plastics at 35 DEG C, consumptive material
Greasy dirt still has preferable clean effect.
Comparative example 1
Aloe, gleditsia sinensis and the cactus of dosage same as Example 1 are taken, gleditsia sinensis prepares extracting solution according to the method for the present invention,
Aloe and cactus contain skin, are dried at 50 DEG C, are then extracted three times with 15 times of water respectively, take filtrate to be concentrated and dried and lacked
Dry cream extract is measured, is added in 61.78 parts of deionized water, there is a small amount of insoluble matter, filters, potassium sorbate is added into filtrate
0.1 part, 1 part of borate, 1 part of ethylene glycol, 0.12 part of ethylenediamine tetra-acetic acid, dissolution, ultrasound 20 minutes, ultrasonic power is sufficiently stirred
300W, revolving speed 15r/s, is filtered again, then 50 DEG C be stirred until homogeneous it is transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, faint yellow, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;
Detergency is unqualified.
Comparative example 2
Aloe, gleditsia sinensis and the cactus of dosage same as Example 1 are taken, gleditsia sinensis prepares extracting solution according to the method for the present invention,
Aloe and cactus contain skin, are dried at 50 DEG C, are then extracted three times with 12 times of amount ethyl alcohol respectively, filtrate is taken to be concentrated and dried
It to a large amount of dry cream extracts, is added in 61.78 parts of deionized water, there is a large amount of insoluble matters, dissolved substantially after adding 30 parts of ethyl alcohol,
0.1 part of potassium sorbate is added into filtrate, 1 part of borate, 1 part of ethylene glycol, 0.12 part of ethylenediamine tetra-acetic acid, sufficiently stirs for filtering
Mix dissolution, ultrasound filters for 20 minutes, ultrasonic power 300W, revolving speed 15r/s again, then 50 DEG C be stirred until homogeneous it is transparent, it is cold
But to get.
Obtained liquid stain remover homogeneous transparent, faint yellow, no suspended substance and precipitating;Free from extraneous odour;Detergency is qualified;Skin
There is aculea sense in contact a period of time, general red, thus it is speculated that be caused by a large amount of ethyl alcohol.
Comparative example 3
Aloe, gleditsia sinensis and the cactus of dosage same as Example 1 are taken, gleditsia sinensis prepares extracting solution according to the method for the present invention,
But aloe and cactus belt leather extract, and 0.1 part of potassium sorbate, 1 part of borate, 1 part of ethylene glycol, ethylenediamine tetra-acetic acid
0.12 part, supplement 61.78 parts of deionized water.
First extracting solution is sufficiently mixed, potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid is added, is eventually adding
Balance deionized water is uniformly mixed;Then ultrasound 20 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering are stirred to equal for 50 DEG C
It is even transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Free from extraneous odour;Stability meets the requirements;It goes
Dirty power is qualified.After washing cotton fiber at 35 DEG C, cotton fiber color is in faint yellow change.Sealing is placed in container under room temperature environment
Begin to change into yellow within 6 months.
Comparative example 4
Aloe, gleditsia sinensis and the cactus of dosage same as Example 8 are taken, gleditsia sinensis prepares extracting solution according to the method for the present invention,
But aloe and cactus belt leather extract, and 0.3 part of potassium sorbate, 1.5 parts of borate, 5 parts of ethylene glycol, ethylenediamine tetra-acetic acid
0.12 part, 0.2 part of sodium lauroyl sarcosine, 0.006 part of Victoria C, 0.003 part of E is tieed up, 3 parts of sodium phytate, 0.01 part of essence, is supplemented
52.861 parts of deionized water.
First extracting solution is sufficiently mixed, potassium sorbate, borate, ethylene glycol, ethylenediamine tetra-acetic acid is added, is eventually adding
Balance deionized water is uniformly mixed;Then ultrasound 30 minutes, ultrasonic power 300W, revolving speed 15r/s, filtering are stirred to equal for 60 DEG C
It is even transparent, it is cooling to get.
Obtained liquid stain remover homogeneous transparent, colourless, no suspended substance and precipitating;Essence fragrance;Stability meets the requirements;
Detergency is qualified.After washing cotton fiber at 35 DEG C, cotton fiber color is in faint yellow change.Sealing is put in container under room temperature environment
It sets 8 months and begins to change into yellow.