CN109810627A - A kind of high covering UV inorganic agent and its treatment process - Google Patents
A kind of high covering UV inorganic agent and its treatment process Download PDFInfo
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- CN109810627A CN109810627A CN201910037605.0A CN201910037605A CN109810627A CN 109810627 A CN109810627 A CN 109810627A CN 201910037605 A CN201910037605 A CN 201910037605A CN 109810627 A CN109810627 A CN 109810627A
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Abstract
The present invention relates to a kind of high covering UV inorganic agent and its treatment process, including special modification acrylate, urethane acrylate, polyester acrylate, improved silica, TMP3EOTA, HDDA, Ciba184, TPO, BASF819, levelling agent, butyl glycol ether, toluene, isopropanol, ethyl acetate, butyl acetate and organosilicon levelling agent.Using formula and treatment process of the invention treated product has many advantages, such as high covering, high-wearing feature, easily recoating, surface drying speed are fast, curing rate is fast and film forming is fast, there is not the problem of lifting, bleeding and binding force difference in coating surface after it is recoated, treated coat side smoothness is high, glossiness is high, finish is good and yields is high, has the problems such as degree of roughness is different, covering is poor, recoating effect is poor, inconvenience of constructing is low with yields which solve the surface covering using UV inorganic agent conventional at present treated product.
Description
Technical field
The present invention relates to paint fields, more particularly to one kind to be suitble to made of the plastic rubber substrates such as PC, ABS and ABS+PC
The shell of phone housing, automotive upholstery and some cosmetics of super quality has the UV inorganic agent and its treatment process of high covering.
Background technique
As mobile phone market is growing, the application of mobile phone coating is also increasing, however, the competition of all trades and professions also day
Become fierce, other than wanting variant in terms of function, price also becomes the one aspect mainly considered, so, PC, ABS and ABS
For the plastic rubber substrates such as+PC in spray process, yields becomes the key index that can reduce production cost.And at present by
The plastic rubber substrates such as PC, ABS and ABS+PC produce the product to form out, and surface is different with degree of roughness, heat resistance is poor
The deficiencies of poor with upper plating performance, some even materials also added with miscellaneous material and recycling, cause using conventional UV coating or
With the problem that poor quality and yields are low when UV inorganic agent directly sprays it or handles.As notification number is
The UV type material inorganic agent of " CN104946119A " uses it although realizing the adhesive force that can improve engineering plastics finished product
Formula and the inorganic agent produced of manufacture craft the phenomenon that not only will appear agglomeration, do not have fireproof function also, in addition,
Adopt when using it to the product poor to material and handling, the bottom or coating when recoating often will appear lifting, bleeding and
The problems such as binding force is poor causes its yields that only up to reach 70%, yields, covering and recoatability etc.
Performance it still needs further improvement.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of high covering UV inorganic agent and its treatment process, using its
Formula and treatment process treated product have high covering, high-wearing feature, easily recoating, surface drying speed is fast, curing rate is fast
The advantages that fast with film forming speed, the coating surface after recoating is not in the problem of lifting, bleeding and binding force difference, through at it
The smoothness of coat side after reason is high, glossiness is high, finish is good and yields is high, at using UV conventional at present
The surface covering for managing agent treated product has that degree of roughness is different, covering is poor, recoating effect is poor, construction inconvenience and good
The low problem of product rate.The present invention is achieved through the following technical solutions:
A kind of high covering UV inorganic agent comprising following weight ratio composition:
Special modification acrylate 15-30%,
Urethane acrylate 15-20%,
Polyester acrylate 2-5%,
Improved silica 0.3%,
TMP3EOTA 1-5%,
HDDA 5-10%,
Ciba184 0.1-0.3%,
TPO 0.1-0.5%,
BASF819 0.1-5%,
Levelling agent 0.5-1.0%,
Butyl glycol ether 5-15%,
Toluene 5-8%,
Isopropanol 5-15%,
Ethyl acetate 15-35%,
Butyl acetate 5-10%,
Organosilicon levelling agent 0.5-6%.
Preferably, the TMP3EOTA is ethoxyquin trimethylolpropane trimethacrylate.
Preferably, the HDDA is 1,6-hexanediyl esters.
Preferably, the Ciba184 is 1- hydroxy-cyclohexyl phenyl ketone.
Preferably, the TPO is 2,4,6 trimethylbenzoy-dipheny phosphine oxides.
Preferably, the BASF819 is bis- (2,4, the 6 trimethylbenzoyl) phosphine oxides of phenyl.
Preferably, the levelling agent is polyether-modified Dimethicone Copolyol body.
Preferably, the coloration of the special modification acrylate is 75-80Hazen max, viscosity 200-
400mPas, acid value is in 100-130mgKOH/g, and flash-point is at 125 DEG C, functional group 2-5.It is preferred as viscosity, special modification third
The viscosity of olefin(e) acid ester is 350mPas.
The partial size of the improved silica is 20-50nm, specific surface area 150-300m2/ g, pH value 4-8.As grain
Diameter is preferred, and the partial size of improved silica is 28nm, 30nm, 33nm and 35nm.It is preferred as specific surface area, the ratio of improved silica
Surface area is 180m2/g、200m2/g、250m2/ g and 280m2/g.Preferred as pH value, the pH value of improved silica is 5,6,7.
Using above-mentioned coloration, viscosity, acid value, flash-point and functional group special modification acrylate and using above-mentioned partial size,
The improved silica of specific surface area and pH value is applied in combination with urethane acrylate and polyester acrylate jointly can be significantly
Increase the degree of cross linking of the invention, toughness, consistency, covering and cementability, it can be to using the modeling such as PC, ABS and ABS+PC
The products such as phone housing, automotive upholstery made of gum base materials and some cosmetics of super quality shells have very high covering,
Meanwhile it can also make that there is preferable wearability and preferably upper plating property using the product after its spray treatment, and ensure product
The coating on surface is smooth, and to solve after using conventional UV coating directly to product spray treatment at present, the surface of product has
The different problem low with yields of degree of roughness.
Preferably, the limited public affairs of the thick trade of Guangzhou benefit can be used in the urethane acrylate and polyester acrylate
The urethane acrylate of sale is taken charge of, it is AgiSyn that the easy Chemical Co., Ltd.'s production model of sea light, which can be used, in the TMP3EOTA
Guangzhou Pu Tai new material Co., Ltd production product can be used in 2897 ethoxyquin trimethylolpropane trimethacrylate, the HDDA
1, the 6-hexanediyl esters that board is Taiwan Changxing, production article No. is EM221-TF, the Ciba184, which can be used, to be raised
The 1- hydroxy-cyclohexyl phenyl ketone of Chemical Co., Ltd., Siping City, city production, it is limited that chemical industry on the town of Dongguan can be used in the TPO
This sharp chemistry of Dongguang County gram can be used in 2,4,6 trimethylbenzoy-dipheny phosphine oxides of company's production, the BASF819
Co., Ltd's production model is bis- (2,4, the 6 trimethylbenzoyl) phosphine oxides of phenyl of P70001, and the levelling agent can be used
Dongguan City is good and the model BYK333 of more new material Co., Ltds sale, the levelling agent that the place of production is Germany, the ethylene glycol fourth
The butyl glycol ether of Zhu Yuan Chemical Co., Ltd. production can be used in ether, and alumstone oil Chemical trade in Dongguan City can be used in the toluene
The toluene of Co., Ltd's production, the isopropanol of Wuxi Xiang Yue chemical products Co., Ltd production can be used in the isopropanol, described
Ethyl acetate can be used the ethyl acetate of Taizhou City Jiang Ping oiling Co., Ltd production or use density for 0.902(g/cm3)
The butyl acetate of Wuxi Jia Wo Chemical Co., Ltd. production, the organosilicon levelling can be used in ethyl acetate, the butyl acetate
The organosilicon levelling agent that Foshan City thousand helps Chemical Co., Ltd.'s production can be used in agent.
In another embodiment, the present invention also provides a kind for the treatment of process of high covering UV inorganic agent are as follows: Step 1: first
First, the workpiece surface that treating need to be handled is cleaned or is cleaned；After workpiece cleans or cleans, using by above-mentioned weight ratio
Special modification acrylate, urethane acrylate, polyester acrylate, improved silica, TMP3EOTA, HDDA,
Ciba184, TPO, BASF819, levelling agent, butyl glycol ether, toluene, isopropanol, ethyl acetate, butyl acetate and organosilicon stream
The high covering UV inorganic agent that flat agent is formulated equably sprays the surface of workpiece.
Step 2: being carried out using UV priming paint to workpiece equal after workpiece is equably sprayed the high covering UV inorganic agent
Even spraying.
Step 3: putting the workpiece in roasting plant and being toasted after workpiece completes the spraying operation of UV priming paint.
Step 4: workpiece is taken out out of oven, after workpiece is completed to toast then, using ultraviolet light curing apparatus pair
Workpiece carries out ultraviolet light curing process for the first time.It makes the photocuring high treating effect of workpiece by being added into TPO.
Step 5: indium plating or tin are carried out in the state of ultraviolet light solidification for the first time being completed treated workpiece is placed on vacuum
Alloy.It is by mixing improved silica with special modification acrylate, urethane acrylate and polyester acrylate
It uses, and the process of indium plating or tin alloy is placed on behind the treatment process of ultraviolet light solidification for the first time, this design can ensure that work
The upper plating performance of part reaches most preferably, and make the adhesive force of workpiece substrate reach most preferably, with realize can covering to workpiece it is strong.
Step 6: equably being carried out to the workpiece for completing indium plating or tin alloy again using the high covering UV inorganic agent
Spraying；After workpiece is completed to spray, puts the workpiece in carry out secondary baking in roasting plant again.
Step 7: the workpiece for completing secondary baking is taken out out of roasting plant, ultraviolet light is then put the workpiece in again
Secondary ultraviolet light curing process is carried out in curing apparatus.It uses high covering UV inorganic agent produced by the present invention by first spraying
Spray painting UV primer again afterwards then successively carries out ultraviolet light curing process, indium plating or electroplating tin alloy, secondary for the first time to workpiece
The high covering UV inorganic agent of even application, secondary baking and secondary ultraviolet light curing process, the design of above-mentioned treatment process is not only
The present invention can be made to realize that the effect of covering workpiece is good and adhesive force is good, the present invention is also made to realize easily recoating, easy construction and to work
The spraying yields of part is high.
Preferably, the baking temperature of roasting plant is set as 55-65 DEG C, roasting plant in the step 3
Baking time is set as 3-5 minutes.
Preferred as the time, the baking time of roasting plant is set as 4-5 minutes.
Preferably, workpiece carries out the time of secondary baking in roasting plant as 3-5 points in the step 6
Clock.Preferred as the time, the time that workpiece carries out secondary baking in roasting plant is 4 minutes.
Implement a kind of high covering UV inorganic agent of the invention and its treatment process, has the advantages that (1) utilizes
Alcohol occurs under conditions of being used in mixed way for isopropanol and special modification acrylate, urethane acrylate and polyester acrylate
Amphipathic polyester is made in sour polycondensation reaction, and by being added into improved silica, ethyl acetate and butyl acetate, makes amphipathic
Polyester, ethyl acetate and butyl acetate can form the suction of high covering with improved silica surface hydroxyl by Hydrogenbond
Attached layer, height, which covers, refers to that the contrast ratio of its reflectivity is to realize complete hiding more than or equal to 0.98(), coating can be increased
Hardness and enhance its scratch resistance, and ensure the smooth of product surface coating, meanwhile, the present invention is also by being added into first
Benzene can make the dispersion effect of all components of the invention good and rate of dispersion after toluene is used in mixed way with improved silica
Fastly, to realize the purpose of energy rapid dispersion mixing, to improve its mobility in the production process, and system of the present invention can be prevented
The phenomenon that inorganic agent for making to come out agglomerates.
(3) present invention passes through addition TMP3EOTA, HDDA, levelling agent and organosilicon levelling agent and ethyl acetate and acetic acid fourth
Ester is used in mixed way, and so that the present invention is realized the suppleness that can substantially improve it, is further increased its crosslink density and covering, and
It also has the advantages that dissolubility is good, shrinking percentage is low, curing rate is fast and film forming is fast, achieves easy recoating, effectively solves
When current conventional UV inorganic agent of having determined recoats product, often there is the problem of lifting, bleeding and binding force difference in bottom.
(4) butyl glycol ether of the invention by being added into the BASF819 and 0.5-1.0% of 0.1-5%, BASF819 and second
After glycol butyl ether mix with components of the invention other, it can make to have using the surface of present invention progress UV treated product
There is coarse different phenomenon in the advantage that glossiness is good and finish is good, the surface that can efficiently avoid product, meanwhile,
It can also make that treated that product has the function of is fire-retardant using the present invention.
(5) present invention is by joined Ciba184, can make after mix with components of the invention other using it is of the invention into
Coating after row UV is handled and solidified the phenomenon that jaundice will not occur long-time exposes in the sun, which ensure that product
It is high-quality；Meanwhile further through TPO is added into, can ensure solid using the light of formula of the invention in treatment process
Change high treating effect and photocuring treatment effeciency is high.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
A kind of high covering UV inorganic agent comprising following weight ratio composition:
Special modification acrylate 15-30%,
Urethane acrylate 15-20%,
Polyester acrylate 2-5%,
Improved silica 0.3%,
TMP3EOTA 1-5%,
HDDA 5-10%,
Ciba184 0.1-0.3%,
TPO 0.1-0.5%,
BASF819 0.1-5%,
Levelling agent 0.5-1.0%,
Butyl glycol ether 5-15%,
Toluene 5-8%,
Isopropanol 5-15%,
Ethyl acetate 15-35%,
Butyl acetate 5-10%,
Organosilicon levelling agent 0.5-6%.
In one embodiment, the TMP3EOTA is ethoxyquin trimethylolpropane trimethacrylate.
In one embodiment, the HDDA is 1,6-hexanediyl esters.
In one embodiment, the Ciba184 is 1- hydroxy-cyclohexyl phenyl ketone.
In one embodiment, the TPO is 2,4,6 trimethylbenzoy-dipheny phosphine oxides.
In one embodiment, the BASF819 is bis- (2,4, the 6 trimethylbenzoyl) phosphine oxides of phenyl.
Embodiment 1:
A kind of high covering UV inorganic agent comprising following weight ratio composition:
Special modification acrylate 17.2%,
Urethane acrylate 16%,
Polyester acrylate 5%,
Improved silica 0.3%,
TMP3EOTA 2%,
HDDA 6%,
Ciba184 0.2%,
TPO 0.3%,
BASF819 0.2%,
Levelling agent 0.8%,
Butyl glycol ether 6%,
Toluene 7%,
Isopropanol 13%,
Ethyl acetate 17%,
Butyl acetate 7%,
Organosilicon levelling agent 2%.
In one embodiment, the TMP3EOTA is ethoxyquin trimethylolpropane trimethacrylate.
In one embodiment, the HDDA is 1,6-hexanediyl esters.
In one embodiment, the Ciba184 is 1- hydroxy-cyclohexyl phenyl ketone.
In one embodiment, the TPO is 2,4,6 trimethylbenzoy-dipheny phosphine oxides.
Embodiment 2:
A kind of high covering UV inorganic agent comprising following weight ratio composition:
Special modification acrylate 20.8%,
Urethane acrylate 17%,
Polyester acrylate 4%,
Improved silica 0.3%,
TMP3EOTA 3%,
HDDA 8%,
Ciba184 0.3%,
TPO 0.1%,
BASF819 0.4%,
Levelling agent 0.5%,
Butyl glycol ether 9%,
Toluene 6%,
Isopropanol 8%,
Ethyl acetate 16%,
Butyl acetate 6%,
Organosilicon levelling agent 0.6%.
In one embodiment, the TMP3EOTA is ethoxyquin trimethylolpropane trimethacrylate.
In one embodiment, the HDDA is 1,6-hexanediyl esters.
In one embodiment, the Ciba184 is 1- hydroxy-cyclohexyl phenyl ketone.
In one embodiment, the TPO is 2,4,6 trimethylbenzoy-dipheny phosphine oxides.
Embodiment 3:
A kind of high covering UV inorganic agent comprising following weight ratio composition:
Special modification acrylate 15%,
Urethane acrylate 18%,
Polyester acrylate 3%,
Improved silica 0.3%,
TMP3EOTA 4%,
HDDA 7%,
Ciba184 0.1%,
TPO 0.2%,
BASF819 0.3%,
Levelling agent 0.4%,
Butyl glycol ether 10%,
Toluene 6%,
Isopropanol 10%,
Ethyl acetate 18%,
Butyl acetate 7%,
Organosilicon levelling agent 0.7%.
In one embodiment, the TMP3EOTA is ethoxyquin trimethylolpropane trimethacrylate.
In one embodiment, the HDDA is 1,6-hexanediyl esters.
In one embodiment, the Ciba184 is 1- hydroxy-cyclohexyl phenyl ketone.
In one embodiment, the TPO is 2,4,6 trimethylbenzoy-dipheny phosphine oxides.
It will be using the workpiece equally poor to material respectively of high covering UV inorganic agent made from the formula of above-described embodiment 1-3
Handled, treatment process are as follows: Step 1: being cleaned or being cleaned firstly, treating the workpiece surface that need to be handled；Work as workpiece
After cleaning or cleaning, using by special modification acrylate, urethane acrylate, polyester acrylate, modified dioxy
SiClx, TMP3EOTA, HDDA, Ciba184, TPO, BASF819, levelling agent, butyl glycol ether, toluene, isopropanol, acetic acid second
High covering UV inorganic agent made from ester, butyl acetate and organosilicon levelling agent to carry out even application behaviour to the surface of workpiece
Make.
Step 2: being carried out using UV priming paint to workpiece equal after workpiece is equably sprayed the high covering UV inorganic agent
Even spraying.
Step 3: putting the workpiece in roasting plant and being toasted for the first time after workpiece completes the spraying operation of UV priming paint.
Step 4: taking out workpiece out of oven after workpiece is completed to toast for the first time, then, set using ultraviolet light solidification
It is standby that ultraviolet light curing process for the first time is carried out to workpiece.
Step 5: indium plating or electricity are carried out in the state of ultraviolet light solidification for the first time being completed treated workpiece is placed on vacuum
Plate tin alloy.
Step 6: using the high covering UV inorganic agent again to completing the workpiece of indium plating or electroplating tin alloy equably
It is sprayed；After workpiece is completed to spray, puts the workpiece in carry out secondary baking in roasting plant again.
Step 7: the workpiece for completing secondary baking is taken out out of roasting plant, ultraviolet light is then put the workpiece in again
Secondary ultraviolet light curing process is carried out in curing apparatus.
In one embodiment, in the step 3, the baking temperature of roasting plant is set as 55-65 DEG C, dries
The baking time of roasting equipment is set as 3-5 minutes.Preferred as temperature, the baking temperature of roasting plant can be set as 61 DEG C, 62
DEG C, 63 DEG C, 64 DEG C and 65 DEG C.Preferred as the time, the baking time of roasting plant is set as 4-5 minutes.
In one embodiment, in the step 6, workpiece carries out the time of secondary baking in roasting plant
It is 3-5 minutes.Preferred as the time, the time that workpiece carries out secondary baking in roasting plant is 4 minutes.
By the UV inorganic agent for using routine and the formula for using embodiment 1, embodiment 2 and embodiment 3 and using the present invention
Treatment process to carry out UV processing to same poor material or product, properties correlation data be as follows:
As can be known from the above table, the yields of UV inorganic agent of the invention reaches 95% or more, and the contrast ratio of the reflectivity of covering power reaches
To 0.98, realize complete hiding, covering and UV inorganic agent conventional at present covering power reflectivity contrast ratio
Highest only reaches 0.72 and compares, covering and yields be significantly improved, repainting time with 20 minutes make
For time interval, coating has been done on surface in recoating, and it is poor that lifting, bleeding and binding force does not occur in the coating surface after recoating
The problem of, that is, prove that it has the advantages that easily recoating, surface drying speed are fast, curing rate is fast and film forming is fast；And use light of the present invention
Gu treated, coating surface is not in color difference, and coating surface smoothness is high, glossiness is high and finish is good, and has resistance
The function of combustion, and the wearability of its coating is compared with using UV inorganic agent conventional at present treated coating, it is wear-resisting
Property also greatly improved, which solve the surface covering using UV inorganic agent conventional at present treated product have it is thick
The problems such as rough degree is different, covering is poor, recoating effect is poor, construction is inconvenient low with yields.
The present invention is not limited to above-mentioned preferred forms, anyone obtain under the inspiration of the present invention other it is any with
The identical or similar product of the present invention, is within the scope of the present invention.
Claims (6)
1. a kind of high covering UV inorganic agent, it is characterised in that: it includes following weight ratio composition:
Special modification acrylate 15-30%,
Urethane acrylate 15-20%,
Polyester acrylate 2-5%,
Improved silica 0.3%,
TMP3EOTA 1-5%,
HDDA 5-10%,
Ciba184 0.1-0.3%,
TPO 0.1-0.5%,
BASF819 0.1-5%,
Levelling agent 0.5-1.0%,
Butyl glycol ether 5-15%,
Toluene 5-8%,
Isopropanol 5-15%,
Ethyl acetate 15-35%,
Butyl acetate 5-10%,
Organosilicon levelling agent 0.5-6%.
2. a kind of high covering UV inorganic agent according to claim 1, it is characterised in that: the TMP3EOTA is ethoxyquin
Trimethylolpropane trimethacrylate.
3. a kind of high covering UV inorganic agent according to claim 1 and its treatment process, it is characterised in that: the HDDA
For 1,6-hexanediyl esters.
4. a kind of high covering UV inorganic agent according to claim 1, it is characterised in that: the Ciba184 is 1- hydroxyl
Cyclohexyl phenyl ketone.
5. a kind of high covering UV inorganic agent according to claim 1, it is characterised in that: the TPO is 2,4,6 front threes
Base benzoyl-diphenyl phosphine oxide.
6. a kind of high covering UV inorganic agent according to claim 1, it is characterised in that: the BASF819 is that phenyl is double
(2,4,6 trimethylbenzoyl) phosphine oxide.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008016301A1 (en) * | 2006-08-04 | 2008-02-07 | Fujifilm Manufacturing Europe B.V. | Porous membranes and recording media comprising same |
| CN101311296A (en) * | 2007-05-22 | 2008-11-26 | 比亚迪股份有限公司 | Ultraviolet cured paint composition for vacuum coating |
| CN102167950A (en) * | 2011-03-18 | 2011-08-31 | 赣州市赐彩油墨涂料实业有限公司 | Vacuum plating paint, and preparation and construction methods thereof |
-
2019
- 2019-01-16 CN CN201910037605.0A patent/CN109810627A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008016301A1 (en) * | 2006-08-04 | 2008-02-07 | Fujifilm Manufacturing Europe B.V. | Porous membranes and recording media comprising same |
| CN101311296A (en) * | 2007-05-22 | 2008-11-26 | 比亚迪股份有限公司 | Ultraviolet cured paint composition for vacuum coating |
| CN102167950A (en) * | 2011-03-18 | 2011-08-31 | 赣州市赐彩油墨涂料实业有限公司 | Vacuum plating paint, and preparation and construction methods thereof |
Non-Patent Citations (1)
| Title |
|---|
| 符韵林等: "《用二氧化硅改良木材表面性能的研究》", 31 October 2011, 中国环境科学出版社 * |
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