CN109806176A - A kind of botanical hair dye and preparation method - Google Patents
A kind of botanical hair dye and preparation method Download PDFInfo
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- CN109806176A CN109806176A CN201910229944.9A CN201910229944A CN109806176A CN 109806176 A CN109806176 A CN 109806176A CN 201910229944 A CN201910229944 A CN 201910229944A CN 109806176 A CN109806176 A CN 109806176A
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Abstract
The invention discloses a kind of botanical hair dye and preparation method thereof, botanical hair dye includes softening agent, colorant, color developing agent；Softening agent includes following components in percentage by weight: phytochrome liquid 1~20%, the deionized water of carbon nanotube 0.01~1%, sodium carboxymethylcellulose 0.1~1%, 1618 alcohol 1~2%, olive oil 1~2%, monoglyceride 1~3%, preservative 0.01~0.05%, essence 0.5~1% and surplus；Softening agent includes following components in percentage by weight: sodium carboxymethylcellulose 1~3%, L-cysteine 0.4~2%, and triethanolamine adjusts pH 8~10 in right amount, preservative 0.01~0.05%, the deionized water of essence 0.5~1% and surplus；Color developing agent includes following components in percentage by weight: metal salt 0.5~2%, xanthan gum 0.2-2%, water-soluble Lu fragrant plant oil 1~6%, glycerol 3~5%, vitamin C 0.5~2%, propylene glycol 0.2~6%, the deionized water of preservative 0.01~0.05%, essence 0.5~1% and surplus.
Description
Technical field
The present invention relates to cosmetic technical field, it is specifically related to botanical hair dye and the preparation side of a kind of carbon nanotubes
Method.
Background technique
In recent years, hair dyeing has become the fashion selection of people.It is found in the investigation that one is had hair dyed situation to modern resident,
90% or more people contaminated hair, and the people of half or so started to have hair dyed before 30 years old.Unquestionably, hair dye has melted
Enter people's lives, becomes indispensable a part.Therefore whether its ingredient is weight concerning people's health safely
Want problem.It is reported that at present there is the disadvantages of sensitization, carcinogenic in existing hair dye mostly.Gradually reduce harmful substance in hair dye
Content and the extent of damage to human body, making great efforts to explore environmental type natural hair dye will be that the development in the following hair dye market becomes
Gesture.Natural botanical hair dye is assisted mainly using natural plant pigment as raw material by physical method or minute quantity chemical method
Complete hair dyeing.Compared with chemical hair dye, plant is derived from, less toxic or even nontoxic, quality is naturally, there is unique physiology living
Property.That however, there are also stability is poor, dye-uptake is low, dyeing is uneven and is easy to fade under light illumination, decoloration etc.
Defect, it is higher with metal salt content most in natural hair dye made of pure plant pigment at present in order to overcome drawbacks described above,
The metal salt of high-content can cause environmental pollution to using crowd to will cause great health hazard.With consumer
The raising of health perception, the botanical hair dye of natural environmental-protective have become the development trend of domestic and international Cosmetic Market.
Summary of the invention
Botanical hair dye and the preparation side of a kind of carbon nanotubes are provided it is an object of the invention to overcome the above problem
Method, the present invention using the organic compound of Nantural non-toxic and with biocompatibility, receive by the carbon that antistatic and coloring is integrated
Mitron is that raw material is prepared with low metal salt mordant, and dyeing time is shorter, is formed a film, natural in color after dye, not fugitive color
And the natural black hair dye of high fastness is kept, the health risk that consumer absorbed multi-metal is reduced, preferably
Meet pursuit of the east market to dark hair beauty and health.
To achieve the above object, the technical solution adopted by the present invention is that a kind of botanical hair dye, including first dose of component,
Two doses of components and third agent component, described first dose be softening agent, second dose be colorant, third agent is color developing agent, described
Toner includes phytochrome liquid and carbon nanotube.
The present invention is resisted quiet using pure plant pigment solution and right nontoxic organic compound and with biocompatibility
The Carbon nanotubes that electricity and coloring are integrated are compounded, using the water-soluble carbon nanometer tube of carboxylated, in common carbon
Functional modification has been carried out on the basis of nanotube, it is made to have excellent water solubility and colloidality, it can be with dye liquor and thickener etc.
It stirs, is distributed evenly in emulsion, improve the contact rate with mordant metal salt, further improve hair dyeing
Uniformity and stability improve dye-uptake, and reduce metal salt content, can avoid the metal salt of high-content to using crowd's meeting
The problem of causing great health hazard, and can cause environmental pollution, solves and contains phenylenediamine in hair dye, has and causes
The shortcomings that quick, teratogenesis, carcinogenic risk and botanical hair dye stability, are poor, dye-uptake is low, dyeing unevenly and under light illumination
The problems such as being easy the metal salt of colour fading, decoloration and high-content.Softening agent, colorant in the present invention, between the weight of color developing agent
Proportion according to using human hair's situation to match, do not have and specific limit proportion.
As the preferred embodiment of botanical hair dye of the invention, weight percent of the phytochrome liquid in colorant
Than being 1~20%, weight percent of the carbon nanotube in colorant is 0.01~1%；
Preferably, the phytochrome liquid colorant weight percent be 10~20%, the carbon nanotube
Weight percent in toner is 0.02%.With the increase of the content of phytochrome liquid, coloring effect increases, and works as Chinese gall
When pigment liquid hold-up is 10~20%, color fastness effect is preferable.The hair dye of carbon nano-tube material is added to relative to not adding
There is extraordinary antistatic property, while best when carbon nanotube additive amount is in 0.2Wt% for the hair dye added.
As the preferred embodiment of botanical hair dye of the invention, the weight ratio of the phytochrome liquid and carbon nanotube
For 100:1.When the weight ratio of phytochrome liquid and modified carbon nano-tube is 100:1, color fastness is best.
As the preferred embodiment of botanical hair dye of the invention, the colorant further includes following weight percent
Component: sodium carboxymethylcellulose 0.1~1%, 1618 alcohol 1~2%, olive oil 1~2%, monoglyceride 1~3%, preservative 0.01
~0.05%, the deionized water of essence 0.5~1% and surplus.
As the preferred embodiment of botanical hair dye of the invention, the softening agent includes the group of following weight percent
Point: sodium carboxymethylcellulose 1~3%, L-cysteine 0.4~2%, triethanolamine adjust pH 8~10 in right amount, preservative
0.01~0.05%, the deionized water of essence 0.5~1% and surplus；
The color developing agent includes following components in percentage by weight: metal salt 0.5~2%, xanthan gum 0.2-2%, water-soluble
Property Lu fragrant plant oil 1~6%, glycerol 3~5%, vitamin C 0.5~2%, propylene glycol 0.2~6%, preservative 0.01~0.05%,
The deionized water of essence 0.5~1% and surplus.
As the preferred embodiment of botanical hair dye of the invention, the phytochrome liquid is Hai Na, bush, English walnut are green
Skin, Chinese gall, gooseberry, tealeaves, cape jasmine, the sophora bud, Asian puccoon, betel nut, madder, turmeric and at least one middle extraction of Eclipta prostrata color
Element；Preferably, the phytochrome liquid is Chinese gall pigment solution.
As the preferred embodiment of botanical hair dye of the invention, the carbon nanotube is that the water-soluble carbon of carboxylated is received
Mitron, it is preferable that the carbon nanotube partial size is 5~300nm.
As the preferred embodiment of botanical hair dye of the invention, the metal salt is the water solubility Asia of divalent or trivalent
One or more of molysite, molysite, zinc salt, aluminium salt, preferably water-soluble ferrous salt.
As the preferred embodiment of botanical hair dye of the invention, the water-soluble carbon nanometer tube will be the preparation method comprises the following steps: will
Carbon nanotube is put into concentrated nitric acid and the concentrated sulfuric acid, after mixing evenly in 100 DEG C of oil baths reflux 16h, is slow added into deionized water
Carboxylated water-soluble carbon nanometer tube is prepared to neutral, vacuum freeze drying in dilution, cooling, suction filtration, washing pH.
The present invention also provides a kind of preparation methods of botanical hair dye, comprising the following steps:
(1) by sodium carboxymethylcellulose deionized water dissolving, L-cysteine is added, is adjusted in right amount with appropriate triethanolamine
Saving pH is 8~11, is eventually adding preservative and essence；
(2) phytochrome liquid, carbon nanotube, sodium carboxymethylcellulose are dissolved in deionized water, are heated to 70~90 DEG C,
1618 alcohol, olive oil, monoglyceride are added with stirring in homogenizer, and after homogeneous, anti-corrosion is added after being cooled to about 35 DEG C -45 DEG C
Agent, essence；
(3) xanthan gum is dissolved in deionized water, be separately added into frerrous chloride water solubility Lu fragrant plant oil, glycerol, vitamin C,
After propylene glycol homogeneous, preservative and essence are added, is stirred evenly.
Beneficial effects of the present invention: the botanical hair dye of carbon nanotubes provided in an embodiment of the present invention utilizes partial size 5-
300nm and the water-soluble carbon nanometer tube for introducing carboxylated have carried out functional modification on the basis of common carbon nanotube, have made it
Have excellent water solubility and colloidality, can be stirred with dye liquor and thickener etc., be distributed evenly in emulsion, mention
The high contact rate with mordant metal salt, further improves the uniformity and stability of hair dyeing, improves dye-uptake.
Detailed description of the invention
Fig. 1 is the antistatic test chart of the present invention.
Specific embodiment
The present invention is made with specific embodiment with reference to the accompanying drawings of the specification and further being elaborated, the embodiment
It is served only for explaining the present invention, be not intended to limit the scope of the present invention.Test method as used in the following examples is such as without spy
Different explanation, is conventional method；Used material, reagent etc., unless otherwise specified, for the reagent commercially obtained
And material.
Each raw material involved by following embodiment is commercially available versatile material unless otherwise instructed.
The present invention relates to phytochrome liquid the preparation method comprises the following steps: plant is smashed with pulverizer；Powder after smashing
Be added in solvent and carry out ultrasonication, condensing reflux extracts natural pigment therein, then through revolving removal organic solvent or
After concentration, obtains phytochrome extracting solution or be freeze-dried the pigmented powder produced；And redissolve the pigmented powder, it prepares
Obtain the phytochrome liquid.
Carbon nanotube used in the embodiment of the present invention is 5~300nm of partial size water-soluble carbon nanometer tube；
The water-soluble carbon nanometer tube the preparation method comprises the following steps: 10g carbon nanotube is put into single necked round bottom flask, in flask
It is separately added into 60ml concentrated nitric acid and the 180ml concentrated sulfuric acid, under magnetic stirring after mixing evenly in 100 DEG C of oil baths reflux 16h, then
It is slowly added to the dilution of 500mL deionized water, cooling is poured into 1000ml beaker, is filtered, and washing pH is to neutral, vacuum refrigeration is dry
It is dry, partial size 5-500nm carboxylated water-soluble carbon nanometer tube is prepared.
Embodiment 1
As a kind of embodiment of botanical hair dye of the present invention, the botanical hair dye includes first dose of component, second dose
Component and third agent component, described first dose be softening agent, second dose be colorant, third agent is color developing agent；
Based on softening agent overall weight percent 100%, the softening agent includes following components in percentage by weight: carboxymethyl
Sodium cellulosate 1%, L-cysteine 0.06%, the deionized water of preservative 0.01%, essence 0.6%, triethanolamine and surplus；
It is counted according to toner overall weight percent 100%, the colorant includes following components in percentage by weight: Chinese gall
Pigment solution 10%, carbon nanotube 0.1%, sodium carboxymethylcellulose 0.5%, 1618 alcohol 1.2%, olive oil 1%, monoglyceride 2%,
The deionized water of preservative 0.01%, essence 0.5% and surplus；
Based on color developing agent overall weight percent 100%, the color developing agent includes following components in percentage by weight: xanthan gum
1.0%, frerrous chloride 1.5%, water-soluble Lu fragrant plant oil 2%, glycerol 4%, vitamin C 1.5%, propylene glycol 2.0%, preservative
0.01%, the deionized water of essence 0.6% and surplus.
The preparation method of the botanical hair dye of the present embodiment, comprising the following steps:
(1) by sodium carboxymethylcellulose deionized water dissolving, L-cysteine is added, is adjusted in right amount with appropriate triethanolamine
Saving pH is 9, is eventually adding preservative and essence；
(2) Chinese gall pigment solution, carbon nanotube, sodium carboxymethylcellulose are dissolved in deionized water, are heated to 75~90
DEG C, be added with stirring 1618 alcohol, olive oil, monoglyceride in homogenizer, after homogeneous 5min, after being cooled to about 35 DEG C -45 DEG C plus
Enter preservative, essence；
(3) xanthan gum is dissolved in deionized water, be separately added into frerrous chloride water solubility Lu fragrant plant oil, glycerol, vitamin C,
After propylene glycol homogeneous 5min, preservative and essence are added, is stirred evenly.
Hair colouring methods: it is first dry to hair cleaning and wiping, then softening agent is evenly coated on hair, keeps 20min at 30 DEG C,
Colorant is evenly coated on hair again, 20min is kept at 30 DEG C, is finally uniformly applied to color developing agent on hair, is protected at 30 DEG C
20min is held, hair is cleaned into drying.
Embodiment 2
As a kind of embodiment of botanical hair dye of the present invention, the botanical hair dye includes first dose of component, second dose
Component and third agent component, described first dose be softening agent, second dose be colorant, third agent is color developing agent；
Based on softening agent overall weight percent 100%, the softening agent includes following components in percentage by weight: carboxymethyl
Sodium cellulosate 2%, L-cysteine 0.4%, the deionized water of triethanolamine, preservative 0.02%, essence 0.5% and surplus；
It is counted according to toner overall weight percent 100%, the colorant includes following components in percentage by weight: Chinese gall
Pigment solution 15%, carbon nanotube 0.05%, sodium carboxymethylcellulose 1%, 1618 alcohol 1%, olive oil 1%, monoglyceride 1.5%,
The deionized water of preservative 0.01%, essence 0.6% and surplus；
Based on color developing agent overall weight percent 100%, the color developing agent includes following components in percentage by weight: xanthan gum
1.0%, frerrous chloride 1.0%, water-soluble Lu fragrant plant oil 2%, glycerol 4%, vitamin C 1.0%, propylene glycol 2.0%, preservative
0.05%, the deionized water of essence 0.1% and surplus.
The preparation method and hair colouring methods of the hair dye of the present embodiment are same as Example 1.
Embodiment 3
As a kind of embodiment of botanical hair dye of the present invention, the botanical hair dye includes first dose of component, second dose
Component and third agent component, described first dose be softening agent, second dose be colorant, third agent is color developing agent；
Based on softening agent overall weight percent 100%, the softening agent includes following components in percentage by weight: carboxymethyl
Sodium cellulosate 1%, L-cysteine 0.8%, the deionized water of triethanolamine, preservative 0.01%, essence 0.6% and surplus；
It is counted according to toner overall weight percent 100%, the colorant includes following components in percentage by weight: Chinese gall
Pigment solution 15%, carbon nanotube 0.2%, sodium carboxymethylcellulose 0.5%, 1618 alcohol 1.2%, olive oil 2%, monoglyceride 2%,
The deionized water of preservative 0.05%, essence 1% and surplus；
Based on color developing agent overall weight percent 100%, the color developing agent includes following components in percentage by weight: xanthan gum
1.5%, frerrous chloride 1.0%, water-soluble Lu fragrant plant oil 3%, glycerol 2%, vitamin C 1.5%, propylene glycol 2.0%, preservative
0.01%, the deionized water of essence 0.5% and surplus.
The preparation method and hair colouring methods of the hair dye of the present embodiment are same as Example 1.
Embodiment 4
As a kind of embodiment of botanical hair dye of the present invention, the botanical hair dye includes first dose of component, second dose
Component and third agent component, described first dose be softening agent, second dose be colorant, third agent is color developing agent；
Based on softening agent overall weight percent 100%, the softening agent includes following components in percentage by weight: carboxymethyl
Sodium cellulosate 1%, L-cysteine 1%, the deionized water of triethanolamine, preservative 0.01%, essence 0.6% and surplus；
It is counted according to toner overall weight percent 100%, the colorant includes following components in percentage by weight: Chinese gall
Pigment solution 20%, carbon nanotube 0.3%, sodium carboxymethylcellulose 1%, 1618 alcohol 1%, olive oil 1%, monoglyceride 2%, anti-corrosion
Agent 0.05%, essence 1% and surplus deionized water；
Based on color developing agent overall weight percent 100%, the color developing agent includes following components in percentage by weight: xanthan gum
1%, frerrous chloride 1.5%, water-soluble Lu fragrant plant oil 4%, glycerol 4%, vitamin C 2%, propylene glycol 2.0%, preservative
0.01%, the deionized water of essence 0.5% and surplus.
The preparation method and hair colouring methods of the hair dye of the present embodiment are same as Example 1.
Embodiment 5
The present embodiment difference from Example 1 is only that, the difference of the additive amount of the Chinese gall pigment solution, this implementation
The weight percentage of the Chinese gall pigment solution of example is 1%.
Embodiment 6
The present embodiment difference from Example 1 is only that, the difference of the additive amount of the Chinese gall pigment solution, this implementation
The weight percentage of the Chinese gall pigment solution of example is 5%.
Embodiment 7
As a kind of embodiment of botanical hair dye of the present invention, the botanical hair dye includes first dose of component, second dose
Component and third agent component, described first dose be softening agent, second dose be colorant, third agent is color developing agent；
Based on softening agent overall weight percent 100%, the softening agent includes following components in percentage by weight: carboxymethyl
Sodium cellulosate 3%, L-cysteine 2%, the deionized water of triethanolamine, preservative 0.015%, essence 1% and surplus；
It is counted according to toner overall weight percent 100%, the colorant includes following components in percentage by weight: Hai Nase
Plain liquid 5%, hematoxylin liquid 5%, english walnut exocarp pigment solution 5%, carbon nanotube 0.01%, sodium carboxymethylcellulose 0.1%,
The deionized water of 1618 alcohol 2%, olive oil 1%, monoglyceride 1%, preservative 0.05%, essence 1% and surplus；
Based on color developing agent overall weight percent 100%, the color developing agent includes following components in percentage by weight: xanthan gum
0.2%, iron chloride 1%, zinc chloride 1%, water-soluble Lu fragrant plant oil 1%, glycerol 3%, vitamin C 0.5%, propylene glycol 0.2%, anti-
Rotten agent 0.01%, essence 0.5% and surplus deionized water.
The preparation method of the botanical hair dye of the present embodiment, comprising the following steps:
(1) by sodium carboxymethylcellulose deionized water dissolving, L-cysteine is added, is adjusted in right amount with appropriate triethanolamine
Saving pH is 8, is eventually adding preservative and essence；
(2) extra large Na pigment solution, hematoxylin liquid, english walnut exocarp pigment solution, carbon nanotube, sodium carboxymethylcellulose are dissolved in
In deionized water, 80 DEG C are heated to, is added with stirring 1618 alcohol, olive oil, monoglyceride in homogenizer, after homogeneous 5min, drop
Preservative, essence is added after 35 DEG C -45 DEG C of Wen Zhiyue；
(3) xanthan gum is dissolved in deionized water, be separately added into frerrous chloride water solubility Lu fragrant plant oil, glycerol, vitamin C,
After propylene glycol homogeneous 5min, preservative and essence are added, is stirred evenly.
Hair colouring methods are same as Example 1.
Embodiment 8
As a kind of embodiment of botanical hair dye of the present invention, the botanical hair dye includes first dose of component, second dose
Component and third agent component, described first dose be softening agent, second dose be colorant, third agent is color developing agent；
Based on softening agent overall weight percent 100%, the softening agent includes following components in percentage by weight: carboxymethyl
Sodium cellulosate 3%, L-cysteine 0.4%, the deionized water of triethanolamine, preservative 0.05%, essence 1% and surplus；
It is counted according to toner overall weight percent 100%, the colorant includes following components in percentage by weight: gooseberry color
Plain liquid 5%, tealeaves pigment solution 5%, gardenin liquid 5%, carbon nanotube 1%, sodium carboxymethylcellulose 0.5%, 1618 alcohol
1.5%, the deionized water of olive oil 1.5%, monoglyceride 3%, preservative 0.05%, essence 1% and surplus；
Based on color developing agent overall weight percent 100%, the color developing agent includes following components in percentage by weight: xanthan gum
2%, aluminium chloride 0.5%, water-soluble Lu fragrant plant oil 6%, glycerol 5%, vitamin C 2%, propylene glycol 6%, preservative 0.01%, perfume
The deionized water of essence 0.5% and surplus.
The preparation method of the botanical hair dye of the present embodiment, comprising the following steps:
(1) by sodium carboxymethylcellulose deionized water dissolving, L-cysteine is added, is adjusted in right amount with appropriate triethanolamine
Saving pH is 11, is eventually adding preservative and essence；
(2) by gooseberry pigment solution, tealeaves pigment solution, gardenin liquid, carbon nanotube, sodium carboxymethylcellulose be dissolved in from
In sub- water, 80 DEG C are heated to, 1618 alcohol, olive oil, monoglyceride is added with stirring in homogenizer, after homogeneous 5min, is cooled to
Preservative, essence is added after about 35 DEG C -45 DEG C；
(3) xanthan gum is dissolved in deionized water, be separately added into frerrous chloride water solubility Lu fragrant plant oil, glycerol, vitamin C,
After propylene glycol homogeneous 5min, preservative and essence are added, is stirred evenly.
Hair colouring methods are same as Example 1.
Comparative example 1
This comparative example is that business commonly uses hair dye, including I dose and II dose:
I dose of composition, based on gross mass percentage 100%, cetostearyl alcohol 6%, octadecyltrimethylammonium chloride
1.1%, oleyl alcohol ether 52%, p-phenylenediamine 2.0%, resorcinol 0.5%, m-aminophenol 0.3%, sulfurous acid 0.4%, different anti-
Bad hematic acid 0.3%, ethanol amine 5%, surplus are water；
I dose of composition, based on gross mass percentage 100%, cetostearyl alcohol 5%, oleyl alcohol ether 51%, 50% hydrogen peroxide
10%, disodium hydrogen phosphate 0.4%, phosphoric acid 0.1%, sodium stannate 0.1%, surplus are water.
Hair colouring methods: I dose and II dose is mixed evenly according to mass ratio 1:1.5 ratio, is cleaned after drying hair,
Scalp coats face cream, then starts hair dye and is evenly coated on hair, keeps 40min at 30 DEG C, and hair is cleaned drying.
Comparative example 2
The botanical hair dye of this comparative example includes softening agent, colorant, color developing agent；
Based on overall weight percent 100%, the softening agent includes following components in percentage by weight: carboxymethyl cellulose
Sodium 1%, L-cysteine 0.6%, the deionized water of triethanolamine, preservative 0.01%, essence 0.6% and surplus；
Based on overall weight percent 100%, the colorant includes following components in percentage by weight: Chinese gall pigment solution
10%, sodium carboxymethylcellulose 0.5%, 1618 alcohol 1.2%, olive oil 1%, monoglyceride 2%, preservative 0.01%, essence
0.5% and surplus deionized water；
Based on overall weight percent 100%, the color developing agent includes following components in percentage by weight: xanthan gum 1%, chlorine
Change ferrous iron 1.5%, water-soluble Lu fragrant plant oil 2%, glycerol 4%, vitamin C 1.5%, propylene glycol 2%, preservative 0.01%, essence
0.6% and surplus deionized water.
The preparation method of the botanical hair dye of the present embodiment, comprising the following steps:
(1) by sodium carboxymethylcellulose deionized water dissolving, L-cysteine is added, is adjusted in right amount with appropriate triethanolamine
Saving pH is 9, is eventually adding preservative and essence；
(2) Chinese gall pigment solution, sodium carboxymethylcellulose are dissolved in deionized water, 80 DEG C are heated to, in homogenizer
It is added with stirring 1618 alcohol, olive oil, monoglyceride, after homogeneous 5min, preservative, essence is added after being cooled to about 35 DEG C -45 DEG C
?；
(3) xanthan gum is dissolved in deionized water, be separately added into frerrous chloride water solubility Lu fragrant plant oil, glycerol, vitamin C,
After propylene glycol homogeneous 5min, preservative and essence are added, is stirred evenly.
Hair colouring methods are same as Example 1.
Comparative example 3
This comparative example is only that the carbon nanotube uses unmodified carbon nanotube with the difference of embodiment 1.
Embodiment 9
(1) color fastness is tested
Above-described embodiment 1~8 and comparative example 1~3 are subjected to color fastness test, specific test process is as follows: after dyeing
Hair, be placed in the aqueous solution containing 5% shampoo, be then placed on vortex favourable turn on, control revolving speed be 40r/min turned
It is dynamic.The results are shown in Table 1:
Table 1
| Group | Coloring effect | The washing times to fade for the first time |
| Embodiment 1 | Bright black gloss | 88 |
| Embodiment 2 | Bright black gloss | 78 |
| Embodiment 3 | Bright black gloss | 79 |
| Embodiment 4 | Bright black gloss | 87 |
| Embodiment 7 | Bright black gloss | 70 |
| Embodiment 8 | Bright black gloss | 75 |
| Comparative example 1 | Black | 51 |
| Comparative example 2 | Furvous | 64 |
| Comparative example 3 | Bright black gloss | 66 |
From 1 experimental data of table it is found that the hair dye coloring effect and water washing effect of the embodiment of the present invention are better than comparative example,
Wherein phytochrome liquid is better than the effect using other plant pigment solution using the water washing effect of Chinese gall pigment solution；Comparative example 1
Compared with comparative example 2, comparative example 2 is good without comparison 1 in coloring effect, but water-fastness number is wanted relative to 1 effect of comparative example
It is good, illustrate to be substantially better than comparison 1 on the Recipe, after being added to carbon nanotube, the coloring effect of hair will be apparently higher than pair
Than 1 with comparison 2, illustrate that carbon nanotube has the function of auxiliary colouring, so that bright black gloss is presented in hair, washing times are average
Reach 80 times or so, unmodified carbon nanotube washing times are not much different with comparative example 2, illustrate modified carbon nanotube
Color fastness is improved relative to unmodified carbon nanotube.
(2) antistatic test
The size of surface electrostatic pressure value is measured by application surface D.C. voltmeter to measure antistatic effect, specifically in fact
Operation is tested by the way that with friction polyethylene piece ten times on wisp of hair, surface D.C. voltmeter is placed at sample 2.5cm
Its surface electrostatic pressure value is measured, measures 5 times and takes its average value, Examples 1 to 4 and comparative example 2 are tested, as a result such as Fig. 1 institute
Show:
From fig. 1, it can be seen that be added to the hair dye of carbon nano-tube material have for the hair dye not added it is non-
Often good antistatic property, at the same it is best when carbon nanotube additive amount is in 0.2Wt%.
(3) coloring effect measure of merit is carried out to the hair dye of Examples 1 to 6 preparation, test result is as shown in table 2:
Table 2
| Group | Coloring effect |
| Embodiment 1 | Black glossy, colouring are uniform |
| Embodiment 2 | Black glossy, colouring are uniform |
| Embodiment 3 | Black glossy, colouring are uniform |
| Embodiment 4 | Black glossy, colouring are uniform |
| Embodiment 5 | Not black enough, colouring is uneven, moreover it is possible to see a large amount of white hairs |
| Embodiment 6 | Furvous, colouring are uneven |
Examples 1 to 6 is the Chinese gall pigment solution using various concentration, as known from Table 2, with containing for Chinese gall pigment solution
The increase of amount, coloring effect increase, and when Chinese gall pigment liquid hold-up is 10~20%, pigment effect is preferable.
Embodiment 10
The present embodiment is the influence for investigating the weight ratio of phytochrome liquid and modified carbon nano-tube to performance of the invention, is
Investigate influence of the weight ratio of phytochrome liquid and modified carbon nano-tube to botanical hair dye performance, wherein in total plant color
In the case of the additive amount of plain liquid and modified carbon nano-tube is 10.1%, applicant is prepared for different heavy according to the method for embodiment 1
The test group botanical hair dye of ratio, and the test method of the performance in accordance with the above-mentioned embodiment 1 are measured, the present embodiment test is tested
The performance of group botanical hair dye.The composition and the performance test results of 1~5 botanical hair dye of test group are as shown in table 3.
Table 3
As known from Table 3, when the weight ratio of phytochrome liquid and modified carbon nano-tube is 100:1, color fastness is best.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should be included within the scope of the present invention.
Claims (10)
1. a kind of botanical hair dye, including first dose of component, second dose of component and third agent component, described first dose is softening
Agent, second dose be colorant, third agent is color developing agent, which is characterized in that the colorant includes phytochrome liquid and carbon nanometer
Pipe.
2. botanical hair dye according to claim 1, which is characterized in that weight hundred of the phytochrome liquid in colorant
Divide than being 1~20%, weight percent of the carbon nanotube in colorant is 0.01~1%；Preferably, the plant color
Plain liquid is 10~20% in the weight percent of colorant, and weight percent of the carbon nanotube in colorant is
0.02%.
3. botanical hair dye according to claim 2, which is characterized in that the weight of the phytochrome liquid and carbon nanotube
Than for 100:1.
4. botanical hair dye according to claim 2, which is characterized in that the colorant further includes following weight percent
Component: sodium carboxymethylcellulose 0.1~1%, 1618 alcohol 1~2%, olive oil 1~2%, monoglyceride 1~3%, preservative 0.01
~0.05%, the deionized water of essence 0.5~1% and surplus.
5. botanical hair dye according to claim 4, which is characterized in that the softening agent includes the group of following weight percent
Point: sodium carboxymethylcellulose 1~3%, L-cysteine 0.4~2%, triethanolamine adjust pH 8~10 in right amount, preservative
0.01~0.05%, the deionized water of essence 0.5~1% and surplus；
The color developing agent includes following components in percentage by weight: metal salt 0.5~2%, xanthan gum 0.2-2%, water-soluble Lu
Fragrant plant oil 1~6%, glycerol 3~5%, vitamin C 0.5~2%, propylene glycol 0.2~6%, preservative 0.01~0.05%, essence
0.5~1% and surplus deionized water.
6. botanical hair dye according to claim 1 or claim 2, which is characterized in that the phytochrome liquid is Hai Na, bush, Hu
It is extracted in peach green peel, Chinese gall, gooseberry, tealeaves, cape jasmine, the sophora bud, Asian puccoon, betel nut, madder, turmeric and at least one of Eclipta prostrata
Pigment；Preferably, the phytochrome liquid is Chinese gall pigment solution.
7. botanical hair dye according to claim 1 or claim 2, which is characterized in that the carbon nanotube is the water solubility of carboxylated
Carbon nanotube, it is preferable that the carbon nanotube partial size is 5~300nm.
8. botanical hair dye according to claim 5, which is characterized in that the metal salt is the water solubility of divalent or trivalent
One or more of ferrous salt, molysite, zinc salt, aluminium salt, preferably water-soluble ferrous salt.
9. botanical hair dye according to claim 7, which is characterized in that the water-soluble carbon nanometer tube will be the preparation method comprises the following steps: will
Carbon nanotube is put into concentrated nitric acid and the concentrated sulfuric acid, after mixing evenly in 100 DEG C of oil baths reflux 16h, is slow added into deionized water
Carboxylated water-soluble carbon nanometer tube is prepared to neutral, vacuum freeze drying in dilution, cooling, suction filtration, washing pH.
10. a kind of preparation method of botanical hair dye as claimed in claim 4, which comprises the following steps:
(1) by sodium carboxymethylcellulose deionized water dissolving, L-cysteine is added, adjusts pH in right amount with appropriate triethanolamine
It is 8~11, is eventually adding preservative and essence；
(2) phytochrome liquid, carbon nanotube, sodium carboxymethylcellulose are dissolved in deionized water, 70~90 DEG C are heated to, equal
Matter machine is added with stirring 1618 alcohol, olive oil, monoglyceride, and after homogeneous, preservative is added after being cooled to about 35 DEG C -45 DEG C, fragrant
Essence；
(3) xanthan gum is dissolved in deionized water, is separately added into frerrous chloride water solubility Lu fragrant plant oil, glycerol, vitamin C, the third two
After alcohol homogeneous, preservative and essence are added, is stirred evenly.
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| CN112870147A (en) * | 2021-03-17 | 2021-06-01 | 浙江章华保健美发实业有限公司 | Plant type hair dyeing and perming integrated hair beautifying agent |
| CN114028252A (en) * | 2021-12-16 | 2022-02-11 | 四川美拉宁高分子材料有限公司 | Artificial melanin hair dye with antistatic function, preparation method and application |
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