CN109763155A - A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane - Google Patents
A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane Download PDFInfo
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- CN109763155A CN109763155A CN201711096623.3A CN201711096623A CN109763155A CN 109763155 A CN109763155 A CN 109763155A CN 201711096623 A CN201711096623 A CN 201711096623A CN 109763155 A CN109763155 A CN 109763155A
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- epoxychloropropane
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Abstract
A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane, in parts by weight, comprising: 30-50 parts of epoxychloropropane, 40-50 parts of aluminum sulfate, 30-60 parts of copper chloride, 15-20 parts of nickel hydroxide cobaltous sulfate, 10-20 parts of cobalt chloride, 15-30 parts of ferric sulfate, 10-20 parts of frerrous chloride, 10-15 parts of cuprous oxide, 15-20 parts of potassium carbonate, 3-5 parts of acetic acid, 10-15 parts of dibastic sodium phosphate, 15-20 parts of sodium nitrite, 20-30 parts of potassium cyanide, 20-50 parts of sodium stannate, 20-50 parts of potassium hydroxide, 50-80 parts of ethylenediamine tetra-acetic acid, 1000-3000 parts of deionized water.It joined ethylenediamine tetra-acetic acid in electroplate liquid of the present invention, can effectively realize antioxidant effect.
Description
Technical field
The present invention relates to electroplate liquids, and in particular to a kind of copper facing electroplate liquid.
Background technique
In mechanical processing process, the anti-corrosive grease of component surface adherency, cutting fluid, machinery oil, lubricant grease, grinding
Liquid, release agent etc. are mixed and are sticked together with dust, polishing dust, form thicker dirt.If the above dirt is not removed before heat treatment
It goes, then degreasing and rust removal is difficult to clean up after its quenching sinters obstinate solid grease into, and bubble attachment makes to plate thereon when plating
Layer forms gas detention type pin hole.Heat treated part surface inevitably adheres to one layer of greasy dirt, when dust is fallen on the surface,
And mix and stick together with grease, it is difficult to clean up over time, so that workpiece surface be made to form unconspicuous tiny oil mark, applies
Bubble residence forms pin hole thereon when plating.When in addition using mesh band type resistor furnace quenching, the greasy dirt and dust etc. of workpiece surface are miscellaneous
Matter particle is mixed to stick together, and sinters obstinate solid grease into, and when salt made from earth containing a comparatively high percentage of sodium chloride is tempered, the above grease forms with nitro salt obstinate again
Thermopolymer, when plating, are difficult that the above dirt is thoroughly cleared, and bubble hydrogen is easily adhered to above dirt, it is difficult to is discharged, to make
Coating generates pin hole and point phenomenon, and as bubble is gradually grown up, coating can be burst automatically, decortication phenomenon is generated, to lead
Send a telegraph the disadvantage of plating solution difference of hardness, dispersion performance and covering power difference.
In view of the above shortcomings, the designer, is actively subject to research and innovation, to found a kind of new structural copper facing
With electroplate liquid, make it with more the utility value in industry.
Summary of the invention
In order to solve the above technical problems, the object of the present invention is to provide a kind of anti-oxidant plating of the copper facing containing epoxychloropropane
Liquid.
Technical scheme is as follows:
The anti-oxidant electroplate liquid of a kind of copper facing containing epoxychloropropane, which is characterized in that in parts by weight, comprising:
30-50 parts of epoxychloropropane, 40-50 parts of aluminum sulfate, 30-60 parts of copper chloride, 15-20 parts of nickel hydroxide cobaltous sulfate,
10-20 parts of cobalt chloride, 15-30 parts of ferric sulfate, 10-20 parts of frerrous chloride, 10-15 parts of cuprous oxide, 15-20 parts of potassium carbonate, second
3-5 parts sour, 10-15 parts of dibastic sodium phosphate, 15-20 parts of sodium nitrite, 20-30 parts of potassium cyanide, 20-50 parts of sodium stannate, potassium hydroxide
20-50 parts, 50-80 parts of ethylenediamine tetra-acetic acid, 1000-3000 parts of deionized water.
Further, in parts by weight, comprising: 40 parts of epoxychloropropane, 44 parts of aluminum sulfate, 34 parts of copper chloride, hydrogen
18 parts of nickel oxide cobaltous sulfate, 15 parts of cobalt chloride, 20 parts of ferric sulfate, 15 parts of frerrous chloride, 12 parts of cuprous oxide, 18 parts of potassium carbonate,
4 parts of acetic acid, 12 parts of dibastic sodium phosphate, 18 parts of sodium nitrite, 25 parts of potassium cyanide, 30 parts of sodium stannate, 35 parts of potassium hydroxide, ethylenediamine tetraacetic
60 parts of acetic acid, 2000 parts of deionized water.
A kind of preparation method of the anti-oxidant electroplate liquid of copper facing containing epoxychloropropane, it is characterised in that: by epoxychloropropane,
Aluminum sulfate, copper chloride, nickel hydroxide cobaltous sulfate, cobalt chloride, ferric sulfate, frerrous chloride, cuprous oxide, potassium carbonate, acetic acid, phosphoric acid
After hydrogen sodium, sodium nitrite, potassium cyanide, sodium stannate, potassium hydroxide, ethylenediamine tetra-acetic acid are mixed, then pass through dispersion machine dispersion
After be add to deionized water, the electroplate liquid is obtained after stirring by high-speed mixer.
According to the above aspect of the present invention, the present invention has at least the following advantages:
It joined ethylenediamine tetra-acetic acid in electroplate liquid of the present invention, can effectively realize antioxidant effect.
Specific embodiment
With reference to embodiment, the embodiment of the present invention is furthur described in detail.Following embodiment is used for
Illustrate the present invention, but is not intended to limit the scope of the invention.
The preparation method of the anti-oxidant electroplate liquid of a kind of copper facing containing epoxychloropropane, by epoxychloropropane, aluminum sulfate, chlorination
Copper, nickel hydroxide cobaltous sulfate, cobalt chloride, ferric sulfate, frerrous chloride, cuprous oxide, potassium carbonate, acetic acid, dibastic sodium phosphate, nitrous acid
Sodium, potassium cyanide, sodium stannate, potassium hydroxide, ethylenediamine tetra-acetic acid be mixed after, then by dispersion machine dispersion after be added to from
In sub- water, the electroplate liquid is obtained after stirring by high-speed mixer.
Embodiment 1
A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane, in parts by weight, comprising:
30 parts of epoxychloropropane, 40 parts of aluminum sulfate, 30 parts of copper chloride, 15 parts of nickel hydroxide cobaltous sulfate, 10 parts of cobalt chloride, sulphur
15 parts of sour iron, 10 parts of frerrous chloride, 10 parts of cuprous oxide, 15 parts of potassium carbonate, 3 parts of acetic acid, 10 parts of dibastic sodium phosphate, sodium nitrite 15
Part, 20 parts of potassium cyanide, 20 parts of sodium stannate, 20 parts of potassium hydroxide, 50 parts of ethylenediamine tetra-acetic acid, 1000 parts of deionized water.
Embodiment 2
A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane, in parts by weight, comprising:
40 parts of epoxychloropropane, 45 parts of aluminum sulfate, 45 parts of copper chloride, 18 parts of nickel hydroxide cobaltous sulfate, 15 parts of cobalt chloride, sulphur
20 parts of sour iron, 15 parts of frerrous chloride, 12 parts of cuprous oxide, 18 parts of potassium carbonate, 4 parts of acetic acid, 12 parts of dibastic sodium phosphate, sodium nitrite 18
Part, 25 parts of potassium cyanide, 30 parts of sodium stannate, 30 parts of potassium hydroxide, 30 parts of ethylenediamine tetra-acetic acid, 2000 parts of deionized water.
Embodiment 3
A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane, in parts by weight, comprising:
50 parts of epoxychloropropane, 50 parts of aluminum sulfate, 60 parts of copper chloride, 20 parts of nickel hydroxide cobaltous sulfate, 20 parts of cobalt chloride, sulphur
30 parts of sour iron, 20 parts of frerrous chloride, 15 parts of cuprous oxide, 20 parts of potassium carbonate, 5 parts of acetic acid, 15 parts of dibastic sodium phosphate, sodium nitrite 20
Part, 30 parts of potassium cyanide, 50 parts of sodium stannate, 50 parts of potassium hydroxide, 80 parts of ethylenediamine tetra-acetic acid, 3000 parts of deionized water.
It joined ethylenediamine tetra-acetic acid in electroplate liquid of the present invention, can effectively realize antioxidant effect.
The above is only a preferred embodiment of the present invention, it is not intended to restrict the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is several improvement and
Modification, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (3)
1. a kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane, which is characterized in that in parts by weight, comprising:
30-50 parts of epoxychloropropane, 40-50 parts of aluminum sulfate, 30-60 parts of copper chloride, 15-20 parts of nickel hydroxide cobaltous sulfate, chlorination
10-20 parts of cobalt, 15-30 parts of ferric sulfate, 10-20 parts of frerrous chloride, 10-15 parts of cuprous oxide, 15-20 parts of potassium carbonate, acetic acid 3-5
Part, 10-15 parts of dibastic sodium phosphate, 15-20 parts of sodium nitrite, 20-30 parts of potassium cyanide, 20-50 parts of sodium stannate, potassium hydroxide 20-50
Part, 50-80 parts of ethylenediamine tetra-acetic acid, 1000-3000 parts of deionized water.
2. the anti-oxidant electroplate liquid of a kind of copper facing containing epoxychloropropane according to claim 1, which is characterized in that according to weight
Measure number meter, comprising: 40 parts of epoxychloropropane, 44 parts of aluminum sulfate, 34 parts of copper chloride, 18 parts of nickel hydroxide cobaltous sulfate, cobalt chloride
15 parts, 20 parts of ferric sulfate, 15 parts of frerrous chloride, 12 parts of cuprous oxide, 18 parts of potassium carbonate, 4 parts of acetic acid, 12 parts of dibastic sodium phosphate, Asia
18 parts of sodium nitrate, 25 parts of potassium cyanide, 30 parts of sodium stannate, 35 parts of potassium hydroxide, 60 parts of ethylenediamine tetra-acetic acid, deionized water 2000
Part.
3. a kind of preparation method of the anti-oxidant electroplate liquid of copper facing containing epoxychloropropane according to claim 2, feature
It is: epoxychloropropane, aluminum sulfate, copper chloride, nickel hydroxide cobaltous sulfate, cobalt chloride, ferric sulfate, frerrous chloride, oxidation is sub-
Copper, potassium carbonate, acetic acid, dibastic sodium phosphate, sodium nitrite, potassium cyanide, sodium stannate, potassium hydroxide, ethylenediamine tetra-acetic acid are mixed
Afterwards, then after being dispersed by dispersion machine it is add to deionized water, the electroplate liquid is obtained after stirring by high-speed mixer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711096623.3A CN109763155A (en) | 2017-11-09 | 2017-11-09 | A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711096623.3A CN109763155A (en) | 2017-11-09 | 2017-11-09 | A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane |
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| Publication Number | Publication Date |
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| CN109763155A true CN109763155A (en) | 2019-05-17 |
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| CN201711096623.3A Pending CN109763155A (en) | 2017-11-09 | 2017-11-09 | A kind of anti-oxidant electroplate liquid of copper facing containing epoxychloropropane |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103556191A (en) * | 2013-10-29 | 2014-02-05 | 常熟市伟达电镀有限责任公司 | Non-toxic electroplating liquid |
| CN104911656A (en) * | 2015-06-13 | 2015-09-16 | 梁胜光 | Metal alloy electroplating liquid |
| CN106065486A (en) * | 2016-06-10 | 2016-11-02 | 太原工业学院 | A kind of non-cyanide copper electroplating compound additive and production technology thereof |
| CN106119911A (en) * | 2016-08-21 | 2016-11-16 | 无锡瑾宸表面处理有限公司 | Stable type electroplate liquid |
-
2017
- 2017-11-09 CN CN201711096623.3A patent/CN109763155A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103556191A (en) * | 2013-10-29 | 2014-02-05 | 常熟市伟达电镀有限责任公司 | Non-toxic electroplating liquid |
| CN104911656A (en) * | 2015-06-13 | 2015-09-16 | 梁胜光 | Metal alloy electroplating liquid |
| CN106065486A (en) * | 2016-06-10 | 2016-11-02 | 太原工业学院 | A kind of non-cyanide copper electroplating compound additive and production technology thereof |
| CN106119911A (en) * | 2016-08-21 | 2016-11-16 | 无锡瑾宸表面处理有限公司 | Stable type electroplate liquid |
Non-Patent Citations (1)
| Title |
|---|
| 刘雅敏等: "《药物制剂常用辅料》", 31 January 1994, 天津科技翻译出版公司 * |
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Application publication date: 20190517 |