CN109735895A - A kind of the electrolyte plasma polishing fluid and polishing process of aluminium alloy - Google Patents
A kind of the electrolyte plasma polishing fluid and polishing process of aluminium alloy Download PDFInfo
- Publication number
- CN109735895A CN109735895A CN201811496473.XA CN201811496473A CN109735895A CN 109735895 A CN109735895 A CN 109735895A CN 201811496473 A CN201811496473 A CN 201811496473A CN 109735895 A CN109735895 A CN 109735895A
- Authority
- CN
- China
- Prior art keywords
- polishing
- polishing fluid
- fluid
- mol
- aluminium alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- ing And Chemical Polishing (AREA)
Abstract
The present invention relates to the electrolyte plasma polishing fluid and polishing process of a kind of aluminium alloy, include following component in polishing fluid: sulfuric acid concentration of iron is 2%~2.5%mol/L, and ammonium sulfate concentrations 2%mol/L, additive is several, remaining is water.The present invention is by experimental study, optimization of C/C composites, the General Promotion performance of polishing fluid, and provides the polishing process using the polishing fluid.Using the solution of the present invention, polishing time is short, and effect is obvious, and service life is long；Pernicious gas will not be generated using this polishing fluid, and there are no pollution to the environment.
Description
Technical field
The present invention relates to polishing fluid fields, and in particular to a kind of electrolyte plasma polishing fluid of aluminium alloy and buffer
Skill.
Background technique
Electrolyte-plasma processing techniques be a kind of new-modernization, it is high-effect, surface is carried out to complex shape metal parts
The technology of processing.The technology is suitable for eliminating burr to metal surface polishing, and blunt point sword clears up soldered, removes material table
The oxidation tint in face, oxide skin and spot, surface degreasing etc..Electrode (polishing workpiece), discharge medium, gas-bearing formation under the polishing system
The chemistry removal of traditional plasma polishing is different from by discharge removal surfacing with four phase collective effect of polishing fluid,
It is different from the two-phase interaction of the electrode, electrolyte under electrobrightening system, completes to throw using the electrochemical dissolution of electrolyte
Light.Polishing fluid uses the neutral salt solution of low concentration to environment almost without pollution, and quality of finish and efficiency are all traditional polishings
Method is unapproachable.
Electrolyte-plasma process is electrochemistry, the plasmochemical process of a kind of complexity, electrolyte single factor test parameter pair
Exemplar, which removes speed, suface processing quality etc., has very important influence, and different materials carries out electrolyte-plasma process
Required electrolyte parameter is also not quite similar.It is undesirable using existing polishing fluid formula polishing effect for aluminium alloy, it deposits
After oxidation film influences polishing the problem of aluminum alloy surface brightness.Therefore, the present invention will be from the angle of aluminium alloy polishing fluid formula
Degree is studied, to improve the polishing effect of aluminium alloy.
The difference of the electrolysis plasma polishing process and stainless steel of aluminium alloy, is not that processing temperature is higher, process time
The longer the better, and reason is that the chemical property of aluminium is too active, and processing temperature is higher, process time is longer, aluminum alloy surface oxidation
It may be more serious.Therefore, present invention research and disclose electrolyte plasma polishing technological parameter.
Summary of the invention
The object of the present invention is to provide the electrolyte plasma polishing fluid and polishing process of a kind of aluminium alloy, which is used
When aluminum alloy surface processing, polishing time is short and effect is obvious, using simple process, does not generate pernicious gas in use process
And there are no pollution to the environment.
To achieve the above object, present invention provide the technical scheme that
A kind of electrolyte plasma polishing fluid of aluminium alloy includes following component in polishing fluid: sulfuric acid concentration of iron is 2%~
2.5%mol/L, ammonium sulfate concentrations 2%mol/L, additive is several, remaining is water.
The additive include PEG600 concentration be 1%mol/L, citric acid concentration 3%mol/L, EDTA concentration is
0.07%mol/L, gluconic acid na concn are 5%mol/L.
The polishing process of the electrolyte plasma polishing fluid using the aluminium alloy is also disclosed in the present invention, including following
Step:
A) aluminum alloy materials are subjected to polishing pre-treatment；
B) polishing fluid of any of claims 1 or 2 is poured into the polishing trough of electrolyte plasma polishing machine, setting heating
Polishing fluid temperature sets polishing time；
C) aluminum alloy materials are placed on polishing machine hanger, polishing machine hanger connects positive pole, and polishing trough connects power cathode；
D) aluminum alloy materials are completely submerged in polishing fluid by hanger according to certain way dive；
E) polishing time arrives, on-hook rapid increase, and workpiece is made to be detached from polishing fluid；Polishing fluid is the salting liquid of low concentration, can
It is recycled.
F) aluminum alloy materials are subjected to polishing post-processing.
In step a), the pre-treatment includes removing substrate surface dirt.
In step b), setting heating polishing fluid temperature sets polishing time as 1~3 minute to 80~85 DEG C.
In step c), out-put supply is controlled in 300~330V.
In step f), the post-processing includes washing, drying.
Compared with prior art, the beneficial effects of the present invention are:
The present invention provides a kind of electrolyte plasma polishing fluid of aluminium alloy, the present invention is matched by experimental study, optimization
Side, the General Promotion performance of polishing fluid, and provide the polishing process using the polishing fluid.Using the solution of the present invention, throw
Short between light time, effect is obvious, and service life is long；Pernicious gas will not be generated using this polishing fluid, and there are no pollution to the environment.
Specific embodiment
The present invention is further explained in the light of specific embodiments.
Embodiment 1
A kind of electrolyte plasma polishing fluid of aluminium alloy, the optimum formula of 1050 type aluminium alloy polishing fluids are as follows: ferric sulfate
Concentration is 2%mol/L, ammonium sulfate concentrations 2%mol/L, PEG600 concentration be 1%mol/L, remaining be water.
It treats polishing material first with roughmeter to measure, roughness is 4.8 μm.
Specific polishing process is as follows:
A) aluminum alloy materials are subjected to polishing pre-treatment.The pre-treatment includes removing substrate surface dirt.
B) above-mentioned polishing fluid is poured into the polishing trough of electrolyte plasma polishing machine, setting heating polishing fluid temperature to 80
℃.Polishing time is set as 3 minutes.
C) aluminum alloy materials being placed on polishing machine hanger, polishing machine hanger connects positive pole, and polishing trough connects power cathode,
Out-put supply is controlled in 330V.
D) aluminum alloy materials are completely submerged in polishing fluid by hanger according to certain way dive.
E) polishing time arrives, on-hook rapid increase, and workpiece is made to be detached from polishing fluid.Polishing fluid is the salting liquid of low concentration, can
It is recycled.
F) aluminum alloy materials are subjected to polishing post-processing.The post-processing includes washing, drying.
Material after polishing is measured using roughmeter, roughness is 1.8 μm.
Embodiment 2
A kind of electrolyte plasma polishing fluid of aluminium alloy, the optimum formula of 5052 type aluminium alloy polishing fluids are as follows: ferric sulfate
Concentration is 2.5%mol/L, ammonium sulfate concentrations 2%mol/L, citric acid concentration 3%mol/L, remaining be water；
It treats polishing material first with roughmeter to measure, roughness is 5.4 μm.
Specific polishing process is as follows:
A) aluminum alloy materials are subjected to polishing pre-treatment.The pre-treatment includes removing substrate surface dirt.
B) above-mentioned polishing fluid is poured into the polishing trough of electrolyte plasma polishing machine, setting heating polishing fluid temperature to 80
℃.Polishing time is set as 1 minute.
C) aluminum alloy materials being placed on polishing machine hanger, polishing machine hanger connects positive pole, and polishing trough connects power cathode,
Out-put supply is controlled in 330V.
D) aluminum alloy materials are completely submerged in polishing fluid by hanger according to certain way dive.
E) polishing time arrives, on-hook rapid increase, and workpiece is made to be detached from polishing fluid.Polishing fluid is the salting liquid of low concentration, can
It is recycled.
F) aluminum alloy materials are subjected to polishing post-processing.The post-processing includes washing, drying.
Material after polishing is measured using roughmeter, roughness is 1.6 μm.
Embodiment 3
A kind of electrolyte plasma polishing fluid of aluminium alloy, the optimum formula of 6061 type aluminium alloy polishing fluids are as follows: ferric sulfate
Concentration is 2%mol/L, ammonium sulfate concentrations 2%mol/L, EDTA concentration is 0.07%mol/L, gluconic acid na concn is 5%
Mol/L, remaining be water.
It treats polishing material using roughmeter to measure, roughness is 4.2 μm.
Specific polishing process is as follows:
A) aluminum alloy materials are subjected to polishing pre-treatment.The pre-treatment includes removing substrate surface dirt.
B) above-mentioned polishing fluid is poured into the polishing trough of electrolyte plasma polishing machine, setting heating polishing fluid temperature to 85
℃.Polishing time is set as 3 minutes.
C) aluminum alloy materials being placed on polishing machine hanger, polishing machine hanger connects positive pole, and polishing trough connects power cathode,
Out-put supply is controlled in 330V.
D) aluminum alloy materials are completely submerged in polishing fluid by hanger according to certain way dive.
E) polishing time arrives, on-hook rapid increase, and workpiece is made to be detached from polishing fluid.Polishing fluid is the salting liquid of low concentration, can
It is recycled.
F) aluminum alloy materials are subjected to polishing post-processing.The post-processing includes washing, drying.
Material after polishing is measured using roughmeter, roughness is 1.8 μm.
It can be seen that the roughness that polishing fluid of the invention can be substantially reduced substrate from three above embodiment, and throw
Light technology is easy to operate.
The above is only presently preferred embodiments of the present invention, is not intended to limit the present invention in any form, any ripe
Professional and technical personnel is known, without departing from the scope of the present invention, according to the technical essence of the invention, to the above reality
Any simple modifications, equivalent substitutions and improvements etc. made by example are applied, it is fallen within the scope of protection of the technical scheme of the present invention
It is interior.
Claims (7)
1. a kind of electrolyte plasma polishing fluid of aluminium alloy, it is characterised in that: include following component in polishing fluid: ferric sulfate is dense
Degree is 2%~2.5%mol/L, and ammonium sulfate concentrations 2%mol/L, additive is several, remaining is water.
2. the electrolyte plasma polishing fluid of aluminium alloy according to claim 1, it is characterised in that: the additive includes
PEG600 concentration is 1%mol/L, citric acid concentration 3%mol/L, EDTA concentration is 0.07%mol/L, sodium gluconate is dense
Degree is 5%mol/L.
3. the polishing process of the electrolyte plasma polishing fluid using aluminium alloy of any of claims 1 or 2, it is characterised in that:
The following steps are included:
A) aluminum alloy materials are subjected to polishing pre-treatment；
B) polishing fluid of any of claims 1 or 2 is poured into the polishing trough of electrolyte plasma polishing machine, setting heating polishing
Liquid temperature sets polishing time；
C) aluminum alloy materials are placed on polishing machine hanger, polishing machine hanger connects positive pole, and polishing trough connects power cathode；
D) aluminum alloy materials are completely submerged in polishing fluid by hanger according to certain way dive；
E) polishing time arrives, on-hook rapid increase, and workpiece is made to be detached from polishing fluid；Polishing fluid is the salting liquid of low concentration, is recycled
It uses；
F) aluminum alloy materials are subjected to polishing post-processing.
4. polishing process according to claim 3, it is characterised in that: in step a), the pre-treatment includes removing substrate
Surface smut.
5. polishing process according to claim 3, it is characterised in that: in step b), setting heating polishing fluid temperature to 80
~85 DEG C, polishing time is set as 1~3 minute.
6. polishing process according to claim 3, it is characterised in that: in step c), out-put supply control 300~
330V。
7. polishing process according to claim 3, it is characterised in that: in step f), the post-processing includes washing, dries
It is dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811496473.XA CN109735895A (en) | 2018-12-07 | 2018-12-07 | A kind of the electrolyte plasma polishing fluid and polishing process of aluminium alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811496473.XA CN109735895A (en) | 2018-12-07 | 2018-12-07 | A kind of the electrolyte plasma polishing fluid and polishing process of aluminium alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109735895A true CN109735895A (en) | 2019-05-10 |
Family
ID=66358627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811496473.XA Pending CN109735895A (en) | 2018-12-07 | 2018-12-07 | A kind of the electrolyte plasma polishing fluid and polishing process of aluminium alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109735895A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110129872A (en) * | 2019-05-23 | 2019-08-16 | 广州市雷傲科技有限公司 | Polishing fluid is used in a kind of polishing of cobalt chrome metal electrolyte plasma |
| CN112500802A (en) * | 2020-12-24 | 2021-03-16 | 黄楚燊 | Plasma polishing agent and preparation method and application thereof |
| CN113600824A (en) * | 2021-08-25 | 2021-11-05 | 和超高装(中山)科技有限公司 | Preparation method and preparation device of metal niobium nano powder |
| CN113664302A (en) * | 2021-08-25 | 2021-11-19 | 和超高装(中山)科技有限公司 | Metal niobium surface processing reconstruction method and reconstruction device |
| CN114517299A (en) * | 2022-03-16 | 2022-05-20 | 常熟理工学院 | Water-based cement block dissolving agent and preparation method thereof |
| CN114645313A (en) * | 2022-05-23 | 2022-06-21 | 中唯精密工业有限公司 | Nickel-based alloy nano polishing solution and polishing method of nickel-based alloy workpiece |
| TWI790834B (en) * | 2021-11-26 | 2023-01-21 | 財團法人金屬工業研究發展中心 | Method of Plasma Electrolytic Polishing |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044307A (en) * | 1988-10-21 | 1990-08-01 | 白俄罗斯多科性工艺学院 | The electrochemical process for treating of products of conductive materials |
| TW451003B (en) * | 1998-11-04 | 2001-08-21 | Cosmos Vacuum Technology Corp | Physical chemistry electron beam polishing method |
| CN1388274A (en) * | 2001-05-25 | 2003-01-01 | 环宇真空科技股份有限公司 | Physiochemical electron beam polishing method |
| RU2260079C2 (en) * | 2003-11-25 | 2005-09-10 | Государственное образовательное учреждение высшего профессионального образования Самарский государственный технический университет | Method of combined treatment of parts made from aluminum and its alloys |
| CN101173361A (en) * | 2007-11-29 | 2008-05-07 | 西安理工大学 | Non-equilibrium liquid condition composite pulse plasma polishing method |
| CN102310357A (en) * | 2011-10-20 | 2012-01-11 | 无锡源清高新技术研究所有限公司 | Liquid-phase plasma polishing liquid and polishing process of aluminum product |
| CN103122475A (en) * | 2011-11-21 | 2013-05-29 | 比亚迪股份有限公司 | Electrochemical polishing solution for aluminum alloy and electrochemical polishing method of aluminum alloy |
| RU2550393C1 (en) * | 2014-05-27 | 2015-05-10 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Method for electrolyte-plasma treatment of metal surface |
| CN105887178A (en) * | 2016-06-25 | 2016-08-24 | 张孝春 | Plasma aluminum alloy polishing salt preparation and polishing method |
| EP3269848A1 (en) * | 2016-07-13 | 2018-01-17 | Airbus Defence and Space GmbH | A method for the surface finishing of metals and alloys |
| CN108070899A (en) * | 2017-12-20 | 2018-05-25 | 深圳市锆安材料科技有限公司 | A kind of non-crystaline amorphous metal local polishing technique |
-
2018
- 2018-12-07 CN CN201811496473.XA patent/CN109735895A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044307A (en) * | 1988-10-21 | 1990-08-01 | 白俄罗斯多科性工艺学院 | The electrochemical process for treating of products of conductive materials |
| TW451003B (en) * | 1998-11-04 | 2001-08-21 | Cosmos Vacuum Technology Corp | Physical chemistry electron beam polishing method |
| CN1388274A (en) * | 2001-05-25 | 2003-01-01 | 环宇真空科技股份有限公司 | Physiochemical electron beam polishing method |
| RU2260079C2 (en) * | 2003-11-25 | 2005-09-10 | Государственное образовательное учреждение высшего профессионального образования Самарский государственный технический университет | Method of combined treatment of parts made from aluminum and its alloys |
| CN101173361A (en) * | 2007-11-29 | 2008-05-07 | 西安理工大学 | Non-equilibrium liquid condition composite pulse plasma polishing method |
| CN102310357A (en) * | 2011-10-20 | 2012-01-11 | 无锡源清高新技术研究所有限公司 | Liquid-phase plasma polishing liquid and polishing process of aluminum product |
| CN103122475A (en) * | 2011-11-21 | 2013-05-29 | 比亚迪股份有限公司 | Electrochemical polishing solution for aluminum alloy and electrochemical polishing method of aluminum alloy |
| RU2550393C1 (en) * | 2014-05-27 | 2015-05-10 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Method for electrolyte-plasma treatment of metal surface |
| CN105887178A (en) * | 2016-06-25 | 2016-08-24 | 张孝春 | Plasma aluminum alloy polishing salt preparation and polishing method |
| EP3269848A1 (en) * | 2016-07-13 | 2018-01-17 | Airbus Defence and Space GmbH | A method for the surface finishing of metals and alloys |
| CN108070899A (en) * | 2017-12-20 | 2018-05-25 | 深圳市锆安材料科技有限公司 | A kind of non-crystaline amorphous metal local polishing technique |
Non-Patent Citations (2)
| Title |
|---|
| KLAUS NESTLER等: "Plasma Electrolytic Polishing – an Overview of Applied Technologies and Current Challenges to Extend the Polishable Material Range", 《PROCEDIA CIRP》 * |
| 隗倩: "基于小型电解等离子抛光机的铝合金配方优化及应用研究", 《哈尔滨工业大学硕士学位论文》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110129872A (en) * | 2019-05-23 | 2019-08-16 | 广州市雷傲科技有限公司 | Polishing fluid is used in a kind of polishing of cobalt chrome metal electrolyte plasma |
| CN110129872B (en) * | 2019-05-23 | 2020-08-21 | 广州市雷傲科技有限公司 | Polishing solution for cobalt-chromium metal electrolyte plasma polishing |
| CN112500802A (en) * | 2020-12-24 | 2021-03-16 | 黄楚燊 | Plasma polishing agent and preparation method and application thereof |
| CN113600824A (en) * | 2021-08-25 | 2021-11-05 | 和超高装(中山)科技有限公司 | Preparation method and preparation device of metal niobium nano powder |
| CN113664302A (en) * | 2021-08-25 | 2021-11-19 | 和超高装(中山)科技有限公司 | Metal niobium surface processing reconstruction method and reconstruction device |
| TWI790834B (en) * | 2021-11-26 | 2023-01-21 | 財團法人金屬工業研究發展中心 | Method of Plasma Electrolytic Polishing |
| CN114517299A (en) * | 2022-03-16 | 2022-05-20 | 常熟理工学院 | Water-based cement block dissolving agent and preparation method thereof |
| CN114517299B (en) * | 2022-03-16 | 2023-08-22 | 常熟理工学院 | Cement block water-based dissolving agent and preparation method thereof |
| CN114645313A (en) * | 2022-05-23 | 2022-06-21 | 中唯精密工业有限公司 | Nickel-based alloy nano polishing solution and polishing method of nickel-based alloy workpiece |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109735895A (en) | A kind of the electrolyte plasma polishing fluid and polishing process of aluminium alloy | |
| CN102953108B (en) | One automatically controls Hard Anodic Oxidation Process | |
| CN102260461A (en) | Smoke-free polishing treatment solution for high-gloss aluminum sectional material and use method thereof | |
| CN108754596A (en) | A kind of the environmental protection polishing electrolyte and polishing method of titanium alloy | |
| CN107747113A (en) | A kind of surface treatment method of non-ferrous metal workpiece | |
| CN102747406B (en) | Magnesium alloy anodic oxidation electrolyte and magnesium alloy surface treatment method | |
| CN102899709A (en) | Liquid phase plasma derusting solution of steel and derusting process | |
| CN105401151B (en) | A kind of iron matrix coating neutrality remover | |
| CN105887178A (en) | Plasma aluminum alloy polishing salt preparation and polishing method | |
| CN103147112B (en) | A kind of electrolytic solution and for the preparation of the purposes of nuclear fuel rod zirconium alloy cladding micro-arc oxidation films and method | |
| CN104711577A (en) | Copper and copper alloy workpiece chemical polishing working solution and production method thereof | |
| CN106011976A (en) | Surface treatment technology of high-precision spring | |
| CN105316741B (en) | A kind of method for carrying out surface by micro-arc oxidation processing to aluminium alloy using grading current | |
| CN103266343A (en) | Surface roughening method of metal material | |
| CN102310357B (en) | Liquid-phase plasma polishing liquid and polishing process of aluminum product | |
| CN108796583B (en) | A kind of preparation method of the super-hydrophobic passivating film of Pure Iron Surface corrosion resistance | |
| CN108914192A (en) | A kind of stainless steel matt treatment process | |
| CN105543937A (en) | Electrolytic passivation solution for stainless steel cookware and passivation technique thereof | |
| CN110394694A (en) | A kind of plasma point discharge flash removed processing method | |
| CN104109865A (en) | Environment-friendly type normal-temperature efficient steel-pipe acid lotion | |
| CN106119826A (en) | A kind of surface of the work blackening process method | |
| CN106191879A (en) | A kind of Coating Pretreatment inorganic agent | |
| CN113913916A (en) | Method for removing oxide skin on surface of titanium alloy | |
| CN111676508B (en) | Electrolytic corrosion solution and application thereof | |
| CN107988611A (en) | A kind of aluminium shape surface pre-treating technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190510 |
|
| RJ01 | Rejection of invention patent application after publication |