CN109735060A - A kind of thermoplastic composite and preparation method thereof for laser direct structuring technique - Google Patents
A kind of thermoplastic composite and preparation method thereof for laser direct structuring technique Download PDFInfo
- Publication number
- CN109735060A CN109735060A CN201811652792.5A CN201811652792A CN109735060A CN 109735060 A CN109735060 A CN 109735060A CN 201811652792 A CN201811652792 A CN 201811652792A CN 109735060 A CN109735060 A CN 109735060A
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- Prior art keywords
- laser
- thermoplastic composite
- direct structuring
- laser direct
- structuring technique
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- 239000002131 composite material Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 21
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 19
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 21
- 230000000996 additive effect Effects 0.000 claims abstract description 21
- 229920000728 polyester Polymers 0.000 claims abstract description 19
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 17
- 238000001125 extrusion Methods 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000000945 filler Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 150000001491 aromatic compounds Chemical class 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 230000004913 activation Effects 0.000 abstract description 7
- 238000002156 mixing Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000007747 plating Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 229920000106 Liquid crystal polymer Polymers 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229920007019 PC/ABS Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000004974 Thermotropic liquid crystal Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011246 composite particle Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811652792.5A CN109735060B (en) | 2018-12-28 | 2018-12-28 | Thermoplastic composite material for laser direct forming technology and preparation method thereof |
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CN201811652792.5A CN109735060B (en) | 2018-12-28 | 2018-12-28 | Thermoplastic composite material for laser direct forming technology and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN109735060A true CN109735060A (en) | 2019-05-10 |
CN109735060B CN109735060B (en) | 2021-09-17 |
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CN201811652792.5A Active CN109735060B (en) | 2018-12-28 | 2018-12-28 | Thermoplastic composite material for laser direct forming technology and preparation method thereof |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11258184B2 (en) | 2019-08-21 | 2022-02-22 | Ticona Llc | Antenna system including a polymer composition having a low dissipation factor |
CN114381093A (en) * | 2021-12-28 | 2022-04-22 | 上海普利特化工新材料有限公司 | Thermoplastic composite material with high dielectric constant and low dielectric loss and preparation method thereof |
US11555113B2 (en) | 2019-09-10 | 2023-01-17 | Ticona Llc | Liquid crystalline polymer composition |
US11637365B2 (en) | 2019-08-21 | 2023-04-25 | Ticona Llc | Polymer composition for use in an antenna system |
US11646760B2 (en) | 2019-09-23 | 2023-05-09 | Ticona Llc | RF filter for use at 5G frequencies |
WO2023103273A1 (en) * | 2021-12-07 | 2023-06-15 | 富海(东营)新材料科技有限公司 | Liquid crystalline polymer composite material for rapid injection molding and preparation method therefor, and injection molding screw for rapid injection molding |
US11721888B2 (en) | 2019-11-11 | 2023-08-08 | Ticona Llc | Antenna cover including a polymer composition having a low dielectric constant and dissipation factor |
US11729908B2 (en) | 2020-02-26 | 2023-08-15 | Ticona Llc | Circuit structure |
US11728559B2 (en) | 2021-02-18 | 2023-08-15 | Ticona Llc | Polymer composition for use in an antenna system |
US11917753B2 (en) | 2019-09-23 | 2024-02-27 | Ticona Llc | Circuit board for use at 5G frequencies |
US11912817B2 (en) | 2019-09-10 | 2024-02-27 | Ticona Llc | Polymer composition for laser direct structuring |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103450675A (en) * | 2012-05-31 | 2013-12-18 | 金发科技股份有限公司 | Resin composition having laser direct-structuring function and its preparation method and use |
CN103694697A (en) * | 2012-09-27 | 2014-04-02 | 金发科技股份有限公司 | Thermal conducting material capable of selectively depositing metal, preparation method of the material and applications of the material |
CN103906803A (en) * | 2011-10-31 | 2014-07-02 | 提克纳有限责任公司 | Thermoplastic composition for use in forming a laser direct structured substrate |
CN104961922A (en) * | 2015-07-11 | 2015-10-07 | 刘帅 | Co-modified LDS (Laser Direct Structuring) additive and LCP (Liquid Crystal Polymer) composition containing same |
WO2018130970A1 (en) * | 2017-01-11 | 2018-07-19 | Sabic Global Technologies B.V. | Laser platable thermoplastic compositions with a laser activatable metal compound and shaped articles therefrom |
-
2018
- 2018-12-28 CN CN201811652792.5A patent/CN109735060B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103906803A (en) * | 2011-10-31 | 2014-07-02 | 提克纳有限责任公司 | Thermoplastic composition for use in forming a laser direct structured substrate |
CN103450675A (en) * | 2012-05-31 | 2013-12-18 | 金发科技股份有限公司 | Resin composition having laser direct-structuring function and its preparation method and use |
CN103694697A (en) * | 2012-09-27 | 2014-04-02 | 金发科技股份有限公司 | Thermal conducting material capable of selectively depositing metal, preparation method of the material and applications of the material |
CN104961922A (en) * | 2015-07-11 | 2015-10-07 | 刘帅 | Co-modified LDS (Laser Direct Structuring) additive and LCP (Liquid Crystal Polymer) composition containing same |
WO2018130970A1 (en) * | 2017-01-11 | 2018-07-19 | Sabic Global Technologies B.V. | Laser platable thermoplastic compositions with a laser activatable metal compound and shaped articles therefrom |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11258184B2 (en) | 2019-08-21 | 2022-02-22 | Ticona Llc | Antenna system including a polymer composition having a low dissipation factor |
US11637365B2 (en) | 2019-08-21 | 2023-04-25 | Ticona Llc | Polymer composition for use in an antenna system |
US11705641B2 (en) | 2019-08-21 | 2023-07-18 | Ticoan Llc | Antenna system including a polymer composition having a low dissipation factor |
US11555113B2 (en) | 2019-09-10 | 2023-01-17 | Ticona Llc | Liquid crystalline polymer composition |
US11912817B2 (en) | 2019-09-10 | 2024-02-27 | Ticona Llc | Polymer composition for laser direct structuring |
US11646760B2 (en) | 2019-09-23 | 2023-05-09 | Ticona Llc | RF filter for use at 5G frequencies |
US11917753B2 (en) | 2019-09-23 | 2024-02-27 | Ticona Llc | Circuit board for use at 5G frequencies |
US11721888B2 (en) | 2019-11-11 | 2023-08-08 | Ticona Llc | Antenna cover including a polymer composition having a low dielectric constant and dissipation factor |
US11729908B2 (en) | 2020-02-26 | 2023-08-15 | Ticona Llc | Circuit structure |
US11728559B2 (en) | 2021-02-18 | 2023-08-15 | Ticona Llc | Polymer composition for use in an antenna system |
WO2023103273A1 (en) * | 2021-12-07 | 2023-06-15 | 富海(东营)新材料科技有限公司 | Liquid crystalline polymer composite material for rapid injection molding and preparation method therefor, and injection molding screw for rapid injection molding |
CN114381093A (en) * | 2021-12-28 | 2022-04-22 | 上海普利特化工新材料有限公司 | Thermoplastic composite material with high dielectric constant and low dielectric loss and preparation method thereof |
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Publication number | Publication date |
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CN109735060B (en) | 2021-09-17 |
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Effective date of registration: 20240125 Address after: No.230, Xiasheng Road, Jinshan District, Shanghai, 201502 Patentee after: SHANGHAI PRET NEW CHEMICAL MATERIAL Co.,Ltd. Country or region after: China Patentee after: Shanghai Pret Composites Co.,Ltd. Patentee after: ZHEJIANG PRET NEW MATERIALS Co.,Ltd. Patentee after: CHONGQNG PULITE NEW MATERIAL Co.,Ltd. Address before: No.230, Xiasheng Road, Jinshan District, Shanghai, 201502 Patentee before: SHANGHAI PRET NEW CHEMICAL MATERIAL Co.,Ltd. Country or region before: China Patentee before: Shanghai Pret Composites Co.,Ltd. Patentee before: ZHEJIANG PRET NEW MATERIALS Co.,Ltd. Patentee before: CHONGQNG PULITE NEW MATERIAL Co.,Ltd. Patentee before: SHANGHAI PRET MATERIAL TECHNOLOGY Co.,Ltd. |
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